Commercial Mixture Research Articles

Development and Testing of Innovative Carbon Nanotubes/ Copper Composite Foils, Towards Lighter and Mechanically Improved Anode Current Collector for Lithium-Ion Batteries

Up to now, copper is an essential material for lithium-ion battery industry as preferential candidate for anode current collectors due to its high conductivity, low price, and electrochemical stability in the working potential range of the anodic electroactive material. However, such component, accounting for 8.1% of the battery total weight, does not participate in any energy storage processes. [1] Thus, the trend is in this industry is to decrease the weight as well as the thickness of the collector foil to optimize the gravimetric energy of the whole lithium-ion battery system. It is therefore of interest to explore the development of lighter current collectors with equal/improved mechanical and electrical properties.Nanocarbon materials such as Multi-Wall Carbon Nanotubes (MWCNTs) and Single-Wall Carbon Nanotubes (SWCNTs) display a combination of performances, namely high electrical conductivity, low density and high mechanical stability, of a high interests to be combined with copper as innovative lightweight current collectors. Such nanocarbon/copper composite represents a valid alternative to foster the rapid change the battery technology is undergoing.In 2013, Subramaniam et al. [2] reported the fabrication of a Copper /Carbon nanotubes (Cu-CNTs) composites with a similar specific conductivity than that of copper and an ampacity increased by two orders of magnitude. Moreover, Arai et al. have shown, by Electrochemical impedance analysis, that MWCNTs additive in a copper matrix can serve as preferential electron conduction pathway inside a Lithium-ion battery anode. [3]Recently, a new promising and scalable way to fabricate nanocarbon/copper composite has been demonstrated by our team. The process involved the coating of MWCNTs by a dispersing agent, namely the Polydopamine biopolymer, their spraying, and finally the electrochemical plating of metallic copper inside the porosity of the MWCNTs network.[4]Following similar approach, the present work exhibits the fabrication of a free standing MWCNTs/ Copper composite current collector foil of a thickness of 9 µm, a value reaching the industrial standards required by the Lithium-ion battery market players for the next generation cells.[5] Scanning Electron Microscopy and Transmission Microscopy have been used to investigate the interaction between the copper matrix and the carbonaceous reinforcement additive. Figure 1. displays a cross section of nanocarbon/copper composite obtain via Focused Ion Beam slicing, where homogeneous mixing of copper and carbon phases down to nanoscale is highlighted. Such experiments contribute to the understanding of the copper nucleation mode on modified MWCNTs which remains insufficiently controlled to this day.Nanoindentation technique and electromechanical tensile testing bench were combined to study the mechanical properties of such material to be used under mechanical stress as battery collector. In contrary to conventional indentation technique where the mechanical properties of micro-size area are probed, indentation at nanoscale allow the probing of the local mechanical heterogeneity of a composite material. Using such technique, the fabricated self-standing nanocarbon/copper composite was shown to display average hardness and Young modulus close to those of pure carbon (3.5 GPa and 152 GPa respectively).Electrochemical performances of the composite as anode battery collector are under test into pouch and coin-cells battery architecture. The adhesion strength between the electrode slurry and the nanocomposite substrate material is expected to be reinforced by the addition of a nanocarbon. A focus was made on the impact of the use of this new collector material on the cycling stability of typical Lithium-ion battery commercial mixture. Preliminary results indicate that the Cu/MWCNT composite is a promising current collector material to withstand the expansion/contraction imposed by the working cycles of a rechargeable Lithium-ion battery.[1] Zhu, P. Gastol, D. Marshall, J. Sommerville, R. Goodship, V. Kendrick, E. J Power Sources, 485, 229321 (2021)[2] Subramaniam, C. Yamada, T. Kobashi, K. Sekiguchi, A. Futaba, Yumura, D. N. Hata, K. Nat Commun,4, 2202 (2013).[3] Shimizu, M. Ohnuki, T. Ogasawara, T. Banno, Arai, S., RSC Advances, 9(38), 21939-21945 (2019)[4] Duhain, A. Guillot, J. Lamblin, G. Lenoble, D., RSC Advances,11(63), 40159-40172 (2020)[5] Copper Foil Market, Straits Research, 9.5.2.3.(2022)Figure 1. Scanning Electron Microscopy imaging of the cross section of MWCNTs/Copper composite with a thickness lower than 3 µm – 7kV acceleration, 45° tilt.. Figure 1

Niobium Boronizing: Influence of the Treatment Temperature and Time

Abstract The application of niobium borides to components such as lamination cylinders, hightemperature devices, and medical equipment shows their importance and versatility in engineering. To improve niobium’s mechanical resistance and possible oxidation resistance at temperature, this research applied boronizing to pure niobium, carried out with double pack cementation. Boronizing at 950°C and 1,100°C was carried out for 1 and 4 h. Ekabor commercial pack mixture with a nominal chemical composition of 90 % silicon carbide, 5 % boron carbide, and 5 % potassium tetrafluoroborate was used with and without 10 percent by weight (wt%) silicon addition. Scanning electron microscope, energy dispersive spectroscopy, and X-ray diffraction analyses and microhardness tests were used to characterize the treated samples. A continuous high-hardness 2,394-HV0.1 (23.5 GPa) niobium diboride layer was formed at the surface of the niobium substrate. A maximum layer thickness of 53.6 ± 2.9 µm was measured after 4 h at 1,100°C, whereas after 1 h at 950°C, no visible layer was identified with the applied characterization techniques, suggesting a threshold in this temperature. Adding 10 wt% silicon to the pack mixture impacted the kinetics of the diffusion process, which resulted in an increase in layer thickness of 72.6 ± 10.1 µm after processing for 1 h at 1,100°C, but cracks formed in the processed surface.

Experimental study of catalytic hydro-dechlorination (HDC) of Aroclor 1232

Polychlorinated biphenyls (PCBs) is a group of persistent organic pollutants that still requires remediation and reduction long after the production is discontinued. Aroclor 1232 is a commercial PCB mixture that has been much less studied. To address this void, this paper presented catalytic hydro-dechlorination (HDC) of Aroclor 1232 using palladium on activated carbon (Pd/AC) at atmospheric pressure. Experimental variables studied including three mild temperatures, 22.5 °C, 50 °C, and 80 °C, and four different co-catalyst loadings. This batch of Aroclor 1232 constituted of more than 83% of mono-, di-, and tri-, chlorinated biphenyls (CB), in addition to biphenyl, tetra- and penta CBs. HDC efficiency increased with temperature, and reached 99.9% within 4 h of reaction at 80 °C. HDC efficiency also increased with co-catalyst loading. HDC efficiencies followed the trend of para > meta > ortho positions among isomers. The increase of temperature and Et3N dosage are especially effective in dechlorination at ortho and meta positions. The apparent activation energy of Aroclor 1232 HDC was estimated as 25.57 kJ/mol based on pseudo-first order assumption, indicating that the reaction may be diffusion limited. Given the modest reaction conditions used, the HDC of Aroclor 1232 can potentially be a low-cost process.

Improvement of water quality with probiotics inclusion during simulated transport of Yellowfin Seabream Acanthopagrus latus larvae.

The expansion of marine aquaculture requires the shipment of early life stages from hatcheries to breeding centers. Thus, maintaining water quality parameters during transportation is crucial. This experiment investigated the effects of a commercial probiotic mixture (PM) (consisting of Bacillus licheniformis, Bacillus subtilis, Pediococcus acidilactici, and Lactobacillus acidophilus with a total count of 107 CFU/g) on water quality, bacterial population, and the survival of larvae of Yellowfin Seabream Acanthopagrus latus during a 24-h simulated transportation experiment. To simulate transportation, purified seawater was used as a control and purified seawater supplemented with 3 g of PM was used as the PM48 treatment. For the PM48 treatment, 3 g of PM was added to 1 L of purified seawater and mixed with 200 L of purified seawater 48 h prior to the main experiment. The use of probiotics resulted in an increase in larval survival up to 93.3% compared with 89.85% in the control group. Initial sampling showed a statistically significant difference in levels between the control and PM48 treatments. After transportation, the pH of the control treatment showed a significant decrease. The total number of bacteria and the total number of Vibrio spp. in water and fish larvae showed that within 48 h, the probiotics became the dominant population in the PM48 treatment. After 24 h, water samples and larvae from the control treatment showed a significant increase in bacterial load. The results showed that probiotics can play a significant role in maintaining biotic and abiotic water quality parameters, leading to a better survival rate of larvae during transportation. These findings represent an important step in improving long-distance transport protocols.

Three-stage pyrolysis–steam reforming–water gas shift processing of household, commercial and industrial waste plastics for hydrogen production

Five common single plastics and nine different household, commercial and industrial waste plastics were processed using a three-stage (i) pyrolysis, (ii) catalytic steam reforming and (iii) water gas shift reaction system to produce hydrogen. Pyrolysis of plastics produces a range of different hydrocarbon species which are subsequently catalytically steam reformed to produce H2 and CO and then undergo water gas shift reaction to produce further H2. The process mimics the commercial process for hydrogen production from natural gas. Processing of the single polyalkene plastics (high-density polyethylene (HDPE), low-density polyethylene (LDPE), and polypropylene (PP)) produced similar H2 yields between 115 mmol and 120 mmol per gram plastic. Even though PS produced an aromatic product slate from the pyrolysis stage, further stages of reforming and water gas shift reaction produced a gas yield and composition similar to that of the polyalkene plastics (115 mmol H2 per gram plastic). PET gave significantly lower H2 yield (41 mmol per gram plastic) due to the formation of mainly CO, CO2 and organic acids from the pyrolysis stage which were not conducive to further reforming and water gas shift reaction. A mixture of the single plastics typical of that found in municipal solid waste produced a H2 yield of 102 mmol per gram plastic. Knowing the gas yields and composition from the single plastics enabled an estimation of the yields from a simulated waste plastic mixture and a ‘real-world’ waste plastic mixture to be determined. The different household, commercial and industrial waste plastic mixtures produced H2 yields between 70 mmol and 107 mmol per gram plastic. The H2 yield and gas composition from the single waste plastics gave an indication of the type of plastics in the mixed waste plastic samples.Graphical abstract

Microbial consortia degrade several widely used organic UV filters, but a number of hydrophobic filters remain recalcitrant to biodegradation

Organic UV filters are important ingredients in many personal care products, including sunscreens. Evaluating the biodegradability of organic UV filters is key to estimate their recalcitrance and environmental fate and thus central to their overall environmental risk assessment. In order to further understand the degradation process, the aim was to investigate whether specific consortia could degrade certain UV filters. Several bacterial strains were isolated from enrichment cultures actively degrading octocrylene (OC), butyl methoxydibenzoylmethane (BM), homosalate (HS), and 2-ethylhexyl salicylate (ES) and were utilized to construct an in-house consortium. This synthetic consortium contained 27 bacterial strains and degraded OC, BM, HS, and ES 60–80% after 12 days, but not benzophenone-3 (BP3), methoxyphenyl triazine (BEMT), methylene bis-benzotriazolyl tetramethylbutylphenol (MBBT), diethylhexyl butamido triazone (DBT), ethylhexyl triazone (EHT), or diethylamino hydroxybenzoyl hexyl benzoate (DHHB). Furthermore, several commercial microbial mixtures from Greencell were tested to assess their degradation activity toward the same organic UV filters. ES and HS were degraded by some of the commercial consortia, but to a lesser extent. The rest of the tested UV filters were not degraded by any of the commercial bacterial mixes. These results confirm that some organic UV filters are recalcitrant to biodegradation, while others are degraded by a specific set of microorganisms.

Some Unmodified Household Adsorbents for the Adsorption of Benzalkonium Chloride-A Kinetic and Thermodynamic Case Study for Commercially Available Paper.

The extensive use of biocide surfactant benzalkonium chloride (BAC) during the SARS-CoV-2 pandemic has led to the buildup of this hazardous chemical in waste, surface and groundwater. e The study aims to elucidate whether various low-cost household materials are suitable, in their unmodified and untreated form, to effectively adsorb BAC from its aqueous solutions.. Additionally, if a proper adsorbent is identified, a description of the kinetics and thermodynamics of the process is also targeted. From among the five tested materials, a commercially available white household paper towel was chosen to best satisfy the criteria of low price, large availability, and standardization degree, as well as high adsorption capacity within a fairly short time window needed until equilibrium. Batch experiments were carried out with a commercial mixture of BAC-12 and BAC-14 within a temperature range of 18-45 degrees Celsius, and a 25-100 mg/g BAC/adsorbent initial mass ratio range, respectively. The overall process follows a pseudo-second-order kinetic law, with an apparent activation energy of 73.35 KJ/mole. Both the Langmuir and the Redlich-Peterson isotherms describe the equilibrium data at 298 K well, with a Gibbs free energy of -20.64 KJ/mole. These findings are in agreement with previous reports and suggest a hybrid but chemisorption-dominated process.

A Commercial Clay-Based Material as a Carrier for Targeted Lysozyme Delivery in Animal Feed.

The controlled supply of bioactive molecules is a subject of debate in animal nutrition. The release of bioactive molecules in the target organ, in this case the intestine, results in improved feed, as well as having a lower environmental impact. However, the degradation of bioactive molecules' in transit in the gastrointestinal passage is still an unresolved issue. This paper discusses the feasibility of a simple and cost-effective procedure to bypass the degradation problem. A solid/liquid adsorption procedure was applied, and the operating parameters (pH, reaction time, and LY initial concentration) were studied. Lysozyme is used in this work as a representative bioactive molecule, while Adsorbo®, a commercial mixture of clay minerals and zeolites which meets current feed regulations, is used as the carrier. A maximum LY loading of 32 mgLY/gAD (LY(32)-AD) was obtained, with fixing pH in the range 7.5-8, initial LY content at 37.5 mgLY/gAD, and reaction time at 30 min. A full characterisation of the hybrid organoclay highlighted that LY molecules were homogeneously spread on the carrier's surface, where the LY-carrier interaction was mainly due to charge interaction. Preliminary release tests performed on the LY(32)-AD synthesised sample showed a higher releasing capacity, raising the pH from 3 to 7. In addition, a preliminary Trolox equivalent antioxidant capacity (TEAC) assay showed an antioxidant capacity for the LY of 1.47 ± 0.18 µmol TroloxEq/g with an inhibition percentage of 33.20 ± 3.94%.

Heat transfer and thermal resistance analysis under various heat transfer fluid flow rates based on a medium-temperature pilot-scale latent heat storage system

Assessments often rely on experimentally observed factors when examining heat transfer variations due to different heat transfer fluid (HTF) flow rates. To better comprehend limiting factors and guide operational parameter design for shell-and-tube latent heat system (LHS) systems, a quantitative analysis of thermal resistance hindering heat transfer is crucial. Hence, this article conducted experimental evaluations at various flow rates to critically analyze its thermal performance based on a large-capacity (1000 MJ) medium-temperature LHS system loaded with 4130 kg commercial nitrate mixture (peak melting temperature: 219.90 °C). The heat transfer coefficient and thermal resistance during charging and discharging were quantitatively investigated to identify the main factors influencing heat transfer and dominant mechanisms. The results suggested that augmenting the charging flow rate from 5 to 15 L/min resulted in 2.65 times increase in average power (from 24.01 to 63.64 kW). Besides, during charging, the overall thermal resistance primarily came from the phase change material (PCM) side initially. As PCM melted, the thermal resistance on the PCM side became equivalent to that on the HTF side. Increasing the charging flow rate enhanced heat transfer through two mechanisms: reducing the thermal resistance on the HTF side and increasing the driving force of heat transfer by elevating the average HTF temperature. During discharging, the overall thermal resistance was predominantly derived from the PCM side after solidification. Increasing the discharging flow rate caused a limited influence on decreasing thermal resistance. Enhancing the discharging flow rate only bolstered the driving force for heat transfer by elevating the average HTF temperature. This study provides valuable insights into the factors influencing heat transfer in LHS systems and contributes to optimizing LHS technology.

Fate and transport analysis of a Dowtherm–A chemical release event

AbstractA hypothetical chemical release of Dowtherm–A into the environment was simulated using a chemodynamics code. The chemical release was assumed to come from a concentrating solar power plant adjacent to Lake Tahoe. Dowtherm–A is viscous water‐insoluble nonvolatile oil found mostly in liquid form at standard temperature and pressure; however, trace amounts slowly diffuse into the three environmental phases: air, water, and soil. It is a commercial eutectic binary mixture of diphenyl oxide and biphenyl—both are toxic and flammable. Therminol VP–1 is another commercial heat transfer oil made by Eastman that is essentially the same oil as Dowtherm–A made by Dow: same constituents at equal proportions. Therefore, the results reported in this study apply to both fluids. Solar thermal power generation represents a clean source of energy that almost uses no fossil fuels and thus does not emit any greenhouse gases. However, the oil employed in those solar thermal power plants is dangerous and should be carefully handled to avoid leakage.

Spatial distribution, conversion, and ecological risk assessment of hexabromocyclododecanes in the sediments of black-odorous urban rivers nationwide in China

Hexabromocyclododecanes (HBCDs) have become a global pollution problem, particularly in China—a major producer and user of HBCDs. However, little is known about the HBCD pollution status in urban rivers nationwide in China. In this study, we comprehensively investigated the pollution characteristics of HBCDs in 173 sediment samples from black-odorous urban rivers across China. Total HBCD concentrations ranged from not-detected to 848 ng/g dw, showing significant differences among the various sampling cities, but generally increasing from west to east China. This distribution pattern of HBCDs was strongly associated with the local industrial output, gross domestic product, and daily wastewater treatment capacity. α-HBCD was the predominant diastereoisomer in most sediments, with an average proportion of 63.8 ± 18.8 %, followed by γ-HBCD (23.8 ± 19.5 %) and β-HBCD (12.4 ± 6.49 %), showing a significant increase of the α-HBCD proportions relative to those in HBCD commercial mixtures and an opposite trend for that of γ-HBCD. These results suggested that HBCDs might undergo isomerization from γ- to α-HBCD and biotic/abiotic degradation with preference for γ-HBCD. Of these conversions, the microbial degradation of HBCDs was further verified by the preferential transformation of (−)-α-, (+)-β-, and (−)-γ-HBCDs and the detection of HBCD-degrading bacteria, including Dehalococcoides, Bacillus, Sphingobium, and Pseudomonas. A risk assessment indicated that HBCDs pose low to moderate risks to aquatic organisms in most black-odorous urban river sediments.

Viruses Demonstrate Selective Survival During Simulated Anaerobic Digestion of Plant Biomass

Objective. This research aimed at laboratory simulation of anaerobic digestion of plant biomass contaminated by a mixture of viruses with a wide host range to evaluate if viruses can retain their infectivity and pose a biohazard during the use of plant-based reusable resources such as digestate. Methods. Anaerobic digestion was simulated in air-tight desiccators using anaerobic bags and indicator strips to ensure proper conditions, and using fresh biomass of naturallyvirus-infected plants. In one of the variants, a commercial mixture of anaerobic bacteria and enzymes was also added to see if it would be more efficient in terms of plant digestion and virus inactivation. For serological detection of the tomato mosaic virus, cucumber mosaic virus, and potato virus Y, DAS-ELISA was used with commercial diagnostic kits and positive controls. Absorbance values were measured at 405 nm. Total RNA was extracted using a RNeasy Plant Mini kit following the manufacturer’s instructions. Molecular detection of viruses was carried out by two-step RT-PCR using specific oligonucleotide primers available from the literature. To check if the viruses can retain their infectivity after the anaerobic digestion of plant biomass waste, a bioassay was used where Nicotiana rustica plants producing necrotic lesions upon infection with many viruses were mechanically inoculated at the stage of 2 true leaves. For statistical processing of data, the mean and standard error were calculated using Microsoft Excel software. Results. After prolonged anaerobic digestion, tomato mosaic virus was still detected in plant residues, but it is important to note that it was also found in high concentration in the liquid phase. Hence, during the anaerobic digestion, a significant proportion of the virus was successfully eluted from plant residues into the digestate. Interestingly and contrary to tomato mosaic virus, cucumber mosaic virus has not practically eluted to the liquid phase. On the other hand, potato virus Y was supposedly completely decomposed during the anaerobic digestion of plant biomass waste, as it was not detected either by ELISA or by PCR. It is likely that not all of the investigated viruses represent a potential biohazard in the context of the use of renewable resources. RT-PCR outcomes showed the presence of tomato mosaic virus and cucumber mosaic virus both in the solid and the liquid phases, augmenting the ELISA data. Lastly, bioassay results have confirmed that at least tomato mosaic tobamovirus may escape the aggressive process of waste decomposition and remain able to infect host plants raising issues about the safety of reusable plant resources. Conclusions. The survival of plant viruses during plant biomass waste processing was studied in the context of biological safety. The preservation of serological markers and genetic signatures of model viruses in the process of anaerobic digestion has been confirmed. For the first time, it was proven that tomato mosaic virus may preserve its infectivity during long-term incubation of plant biomass waste in anaerobic conditions, which requires further attention when using renewable resources. On the example of PVY, it has been shown that potyviruses do not survive during anaerobic digestion and therefore may not pose an epidemic risk in using processed renewable resources. It has been demonstrated that artificial introduction of anaerobic microorganisms does not have a decisive effect on the stability of the studied model viruses.

Effect of a diet supplemented with fennel (Foeniculum vulgare) and goat’s rue (Galega officinalis L.) on growth, slaughter traits and meat quality of rabbits

The purpose of the study was to compare the growth, slaughter performance and selected meat quality traits (such as meat texture and basic chemical composition of meat) of Termond White rabbits fed fodder with addition of fennel (Foeniculum vulgare) and goat’s rue (Galega officinalis L.). The rabbits were divided into three feeding groups after weaning. The control group (n=22; 10♂, 12♀) received a commercial complete feed mixture, the first test group (n=18; 12♂, 6♀) was fed with the commercial pellet containing 1% of fennel seeds. Group II (n=22; 14♂,8♀) was fed with the commercial pellet containing 1% of extra goat's rue leaves. Feed and water was available ad libitum. At day 84, the animals were slaughtered, during which post-slaughter traits were examined, and detailed dissection was performed. At 45 minutes and 24 hours after slaughter, the pH and colour of rabbit meat were measured on the m. longissimus lumborum and m. biceps femoris. During dissection, samples of m. longissimus lumborum were collected on which texture profiling analysis was performed. The experiment showed that the highest weight of carcasses obtained, as well as of individual cuts, was found in animals fed the control diet. The highest dressing out percentage was also found in this group. Fennel and goat's rue were shown to increase pH and affect meat colour. The highest value of shear force, hardness, chewiness and cohesiveness was recorded in meat from animals in the goat's rue feeding group. The conducted analysis did not show a positive effect of the herbs studied on the post-slaughter traits and quality of rabbit meat.

Heat transfer and thermal performance investigation on a visualized latent heat storage system in pilot-scale: Scalable medium-temperature thermal energy storage system

Large-capacity medium-temperature (100–300 °C) and high-temperature (>300 °C) latent heat storage (LHS) systems can enhance the reliability and performance of solar thermal utilization systems due to their characteristics of balancing the gap between energy supply and demand. In this study, a pilot-scale LHS system was developed and investigated, incorporating a mass of 270 kg of phase change material (PCM), specifically a commercial nitrate mixture. Moreover, the thermal energy storage unit featured a rectangular aperture at its center, covered by a quartz visualization window to facilitate the observation of the melting and solidification behavior of the PCM. The charging process lasted 111 min, with a mean average power, accumulated energy and efficiency of 11.90 kW, 79.33 MJ, and 77.67%, while those of the discharging process were 56.5 min, 12.99 kW, 44.11 MJ, and 71.41%, respectively. Furthermore, a comparative analysis was conducted concerning heat transfer performance and mechanisms during the charging and discharging processes. The heat transfer coefficients and average thermal resistances of the LHS system during charging and discharging were 613.08 W/(m2·K), 295.28 W/(m2·K), and 0.001984 (m2·K)/W, 0.005285 (m2·K)/W, respectively. The average thermal resistance observed during the charging process was notably lower than that observed during the discharging process, attributable to the variance in the predominant heat transfer mechanism. For a substantial portion of the charging process duration, heat transfer was dominantly governed by natural convection, whereas throughout a significant duration of the discharging process, heat transfer was primarily driven by thermal conduction.

Advantages and limitations of tree mixtures in enhancing avian diversity in commercial timber plantations: Early insights from southern China

Commercial timber plantations, particularly monocultures, have limited capacity to support biodiversity. A widely promoted approach to enhance this capacity is the diversification of monocultures into tree mixtures, by adding “secondary” timber species while retaining the production focus on the monoculture species. However, the presumed biodiversity benefits of tree mixtures are yet to be robustly tested, because current evidence predominantly comes from mixed plantations in the general sense, which are often not under active production or differ from monocultures in other important ways. To address this gap, we assess the effectiveness of early-stage tree mixtures in enhancing the avian diversity of Eucalyptus monocultures in southern China, which is the country's most important timber production region and has been pioneering tree mixtures in large trials over the past decade. During the avian breeding and non-breeding seasons in 2021, we conducted rigorous surveys to compare the avian diversity of Eucalyptus monocultures and their tree mixtures involving slow-growing native species, against the reference baseline of mature native forests. We found that tree mixtures exhibited modest advantages over monocultures during the breeding season, and both plantation types had notable shortfalls relative to mature native forests. We additionally found that tree mixtures tended to benefit species that foraged in the medium–low strata, consumed diets of higher trophic levels, and depended more on mature forest habitat. We conclude that the biodiversity benefits of early-stage commercial tree mixtures were rather limited and more modest than typically assumed, highlighting the importance of studying tree mixtures in real-world production settings. Our study also underscores the conservation importance of protecting existing mature native forests.

Millisecond-Response Nematic Liquid Crystal for Augmented Reality Displays

Developing fast-response liquid crystals (LCs) is an essential way to achieve low cost, high resolution, and good visual experience for augmented reality (AR) displays. In this paper, we optimized one new nematic LC mixture SNUP01 to meet the requirements of fast-response phase-only liquid crystal on silicon (LCoS) devices in AR displays. The photoelectric performance of this new LC mixture and three commercial LC mixtures were further comparatively evaluated, and the 2π phase-change response speed of this new LC mixture was extrapolated. The research results indicate that SNUP01 possesses high birefringence, moderate dielectric anisotropy, low viscoelastic coefficient, low activation energy, and high figure of merit values. When using this LC mixture at 25 °C @ λ = 633 nm, a 2π phase change can be achieved at 5 V with a total response time of up to millisecond response. Widespread applications of this LC mixture for AR displays are foreseeable.

Antimicrobial and anticarcinogenic activity of bioactive peptides derived from abalone viscera (Haliotis fulgens and Haliotis corrugata)

Bioactive peptides have been studied in several sources due to their valuable potential in the pharmaceutical and food industries. Abalone viscera, which are normally discarded as byproducts, are a rich source of protein. Thus, the aim of this study was to explore the potential bioactivity of peptides derived from abalone viscera (Haliotis fulgens and Haliotis corrugata) after hydrolysis with a commercial mixture of enzymes. The hydrolysates obtained were fractionated using gel filtration chromatography. The resulting hydrolysate fractions were investigated for their antimicrobial and cytotoxic activities, including the expression of gelatinases mmp-2 and mmp-9 in human prostate cancer cell lines (PC3). Results showed antimicrobial activity for protein fractions of H. corrugata against Proteus mirabilis and Pseudomona aeuroginosa (66.2–116.25 kDa), Bacillus subtilis (6.5–21.5 kDa), and Aspergillus niger (97.4–116.25 kDa), while H. fulgens peptide fractions (200–31 kDa) displayed activity against six bacterial strains, and fractions from 116.25 to 21.5 kDa had effects on the fungus A. niger, Alternaria alternata, and Aspergillus flavus. Additionally, protein fractions displayed cytotoxic activity, inhibiting 30.4–53.8% of PC3 cellular growth. Selected fractions decreased the PMA-induced and not-induced expressions of mmp-2 and mmp-9 in PC3 cells. Abalone viscera, as byproducts, can be used as a potential source of antimicrobial and anticancer peptides.

The influence of dietary white button mushrooms (Agaricus bisporus) on the kinetics of changes in the proportion of peripheral blood CD4+ CD8+ T lymphocytes in lambs

The primary focus of the current study was to determine the potential benefits of supplementing sheep diet with white button mushrooms (WBM) in terms of growth, health and the kinetics of systemic CD4+ CD8+ memory T lymphocytes in lambs. Forty-five female lambs (Lika breed) were divided into three groups: A – the control group fed on a free-range pasture for the 222 days of the experiment, while groups B and C were housed in a separate facility for 42 days and fed either a commercial feed mixture (FM) or a FM supplemented with 15% of freshly prepared WBM, respectively, and ad libitum forage. For the remaining 180 days of the experiment, both groups (B and C) of lambs were kept free-range and fed pasture only. The lambs were monitored daily starting on Day 0 (or 90 days of age) before the treatments, weighed and blood sampled on Days 0, 21, 42 and 222, and were clinically observed for the incidence/severity of diarrhea and/or other signs of disease. In addition to morbidity, mortality was also monitored, and dead lambs were examined for gross pathology changes. The lambs fed FM supplemented with WBM (group C) had significantly higher body weight gain (P<0.05) on Days 42 and 222. They were neither diarrheic nor had any mortality cases throughout the experiment. Also, these lambs had a significantly increased (P<0.05) proportion of CD4+CD8+ T cells on Days 42 and 222. The data obtained supported our assumption of the efficacy of dietary WBM in the immunostimulation of CD4+CD8+ memory T lymphocytes in lambs, resulting in protection against on-farm diarrhea and providing an increased growth rate.

Tackling PFAS Complexity with HRMS and Bioanalytical Techniques

Per- and polyfluoroalkyl substances (PFASs) are highly persistent anthropogenic compounds that are widespread in the environment. There are thousands of PFASs, yet few neat standards exist for unequivocal identification, quantification, or toxicity assays. The bioanalytical study of complex commercial PFAS mixtures is an innovative route to better understand novel PFAS exposure and toxicity. Here, we highlight efforts using high-resolution mass spectrometry (HRMS) and exposure-relevant mixtures to prioritize PFASs based on their potential to accumulate in living organisms.

Biodegradation of commercial textile reactive dye mixtures by industrial effluent adapted bacterial consortium VITPBC6: a potential technique for treating textile effluents.

Textile industries release major fraction of dyestuffs in effluents leading to a major environmental concern. These effluents often contain more than one dyestuff, which complicates dye degradation. In this study ten reactive dyes (Reactive Yellow 145, Reactive Yellow 160, Reactive Orange 16, Reactive Orange 107, Reactive Red 195, Reactive Blue 21, Reactive Blue 198, Reactive Blue 221, Reactive Blue 250, and Reactive Black 5) that are used in textile industries were subjected to biodegradation by a bacterial consortium VITPBC6, formulated in our previous study. Consortium VITPBC6 caused single dye degradation of all the mentioned dyes except for Reactive Yellow 160. Further, VITPBC6 efficiently degraded a five-dye mixture (Reactive Red 195, Reactive Orange 16, Reactive Black 5, Reactive Blue 221, and Reactive Blue 250). Kinetic studies revealed that the five-dye mixture was decolorized by VITPBC6 following zero order reaction kinetic; Vmax and Km values of the enzyme catalyzed five-dye decolorization were 128.88mg L-1day-1 and 1003.226mg L-1 respectively. VITPBC6 degraded the dye mixture into delta-3,4,5,6-Tetrachlorocyclohexene, sulfuric acid, 1,2-dichloroethane, and hydroxyphenoxyethylaminohydroxypropanol. Phytotoxicity, cytogenotoxicity, microtoxicity, and biotoxicity assays conducted with the biodegraded metabolites revealed that VITPBC6 lowered the toxicity of five-dye mixture significantly after biodegradation.