Cometary Material Research Articles

Cometary dust analogues for physics experiments

ABSTRACT The CoPhyLab (Cometary Physics Laboratory) project is designed to study the physics of comets through a series of earth-based experiments. For these experiments, a dust analogue was created with physical properties comparable to those of the non-volatile dust found on comets. This ‘CoPhyLab dust’ is planned to be mixed with water and CO2 ice and placed under cometary conditions in vacuum chambers to study the physical processes taking place on the nuclei of comets. In order to develop this dust analogue, we mixed two components representative for the non-volatile materials present in cometary nuclei. We chose silica dust as a representative for the mineral phase and charcoal for the organic phase, which also acts as a darkening agent. In this paper, we provide an overview of known cometary analogues before presenting measurements of eight physical properties of different mixtures of the two materials and a comparison of these measurements with known cometary values. The physical properties of interest are particle size, density, gas permeability, spectrophotometry, and mechanical, thermal, and electrical properties. We found that the analogue dust that matches the highest number of physical properties of cometary materials consists of a mixture of either 60 per cent/40 per cent or 70 per cent/30 per cent of silica dust/charcoal by mass. These best-fit dust analogue will be used in future CoPhyLab experiments.

Discrete Element Modeling of Aeolian-like Morphologies on Comet 67P/Churyumov-Gerasimenko

Context. Even after the Rosetta mission, some of the mechanical parameters of comet 67P/Churyumov-Gerasimenko’s surface material are still not well constrained. They are needed to improve our understanding of cometary activity or for planning sample return procedures. Aims. We discuss the physical process dominating the formation of aeolian-like surface features in the form of moats and wind taillike bedforms around obstacles and investigate the mechanical and geometrical parameters involved. Methods. By applying the discrete element method (DEM) in a low-gravity environment, we numerically simulated the dynamics of the surface layer particles and the particle stream involved in the formation of aeolian-like morphological features. The material is composed of polydisperse spherical particles that consist of a mixture of dust and water ice, with interparticle forces given by the Hertz contact model, cohesion, friction, and rolling friction. We determined a working set of parameters that enables simulations to be reasonably realistic and investigated morphological changes when modifying these parameters. Results. The aeolian-like surface features are reasonably well reproduced using model materials with a tensile strength on the order of 0.1–1 Pa. Stronger materials and obstacles with round shapes impede the formation of a moat and a wind tail. The integrated dust flux required for the formation of moats and wind tails is on the order of 100 kg m−2, which, based on the timescale of morphological changes inferred from Rosetta images, translates to a near-surface particle density on the order of 10−6–10−4 kgm−3. Conclusions. DEM modeling of the aeolian-like surface features reveals complex formation mechanisms that involve both deposition of ejected material and surface erosion. More numerical work and additional in situ measurements or sample return missions are needed to better investigate mechanical parameters of cometary surface material and to understand the mechanics of cometary activity.

Back Cover: ESA's Cometary Mission Rosetta—Re‐Characterization of the COSAC Mass Spectrometry Results (Angew. Chem. Int. Ed. 29/2022)

The cometary Rosetta mission visited the nucleus of Comet 67P/Churyumov-Gerasimenko by placing the Philae Lander on its surface. Philae was equipped with a time-of-flight mass spectrometer that analyzed, for the first time, cometary surface material in situ. Uwe J. Meierhenrich and co-workers describe in their Research Article (DOI: 10.1002/anie.202201925) the characterization of this mass spectrum through non-negative least square fitting and Monte Carlo analysis revealing the chemical composition of cometary ices.

The Evolution of the Nucleus Surface in the Context of the Change in the Brightness of a Comet* *University of Rzeszów, Poland.

The paper presents a model of the thermodynamic evolution of the comet nucleus surface. In the proposed approach, we focus on the analysis of the formation of pits visible on the surface of the cometary nucleus. These pits are a consequence of the thermodynamic evolution of both the surface layers and the inner layers of the cometary nucleus. As a result of complex thermodynamic processes, the surface layer is destroyed. A measure of this destruction is the amount of comet material that is thrown into a coma as a result of sublimation. The effect of this process is an increase in the area on which the incident light scatters. Then we can notice a sudden increase in the brightness of the comet, i.e., its outburst. A measure of the amplitude of a given outburst is the diameter and thickness of the surface layer that has been destroyed. The mechanism of the evolution of the pits was proposed based on the analysis of many photos taken by the Rosetta probe. The obtained numerical values correspond to the actual brightness changes of the Jupiter family comets during their outburst.

Meteoritic noble gas constraints on the origin of terrestrial volatiles

The elemental and isotopic compositions of noble gases trapped in primitive meteorites have the potential to yield stringent constraints on the origin of matter in the solar system. The isotopic compositions of key elements like O, Ti, Ru, Mo suggest that the Earth accreted from material having similarities with two classes of meteorites, carbonaceous chondrites (CC) and non‑carbonaceous chondrites (NC), in particular enstatite chondrites (EC). In this contribution, I examine published noble gas (neon and argon) data for CI-CM as representative of CCs, and ECs as representative of NC terrestrial building blocks. Data were corrected for contributions of cosmic ray-produced isotopes in order to identify the trapped component compositions. For both CCs and ECs, corrected noble gas data indicate that high temperature objects such as chondrules were evolving in a dusty environment. The dust consisted of refractory phases including nanodiamonds, impacts-related debris, medium to low temperature phases mainly made of organics and, in the case of CC, hydrated minerals and icy grains. Remnants of such a dust are found as rims around chondrules and as a matrix between high temperature assemblages. The dust was probably the main source of volatiles on Earth.In terrestrial reservoirs, covariations of 20Ne/22Ne ratios with 36Ar/22Ne ratios are consistent with mixing between a solar-like neon component trapped in the mantle and a chondritic Ne–Ar component mainly present in the atmosphere and hydrosphere. The chondritic end-member is clearly of the CC type and excludes EC-like material as the source of atmospheric volatiles. In addition to CC-like material, the isotopic composition of heavy noble gases (Kr and Xe) in the atmosphere points to a ~ 20% contribution of cometary material akin of the composition of comet 67P/Churyumov-Gerasimenko. In contrast, comets might have contributed less than 1% terrestrial water, C and N. Solar-like neon in the terrestrial mantle might have originated from solar irradiation of free-floating dust before parent body compaction, but this would require a cleared, dust-free environment. Trapping of nebular gas into forming solids during the gas epoch of the nascent solar system appears a more promising possibility. For other mantle volatiles, the stable isotopes of H, N, Ar, Kr and Xe point to a chondritic origin. The hydrogen and nitrogen isotopic signatures of mantle rocks and minerals are consistent with an EC-like contribution whereas those of heavy noble gases are still too imprecise to conclude. Further progress in the field will require high precision analysis of noble gases (in particular, Kr and Xe) trapped in the terrestrial (and martian) mantle(s), as well as documenting the composition of the Venusian atmosphere.

A Geoscientific Review on CO and CO2 Ices in the Outer Solar System

Ground-based telescopes and space exploration have provided outstanding observations of the complexity of icy planetary surfaces. This work presents our review of the varying nature of carbon dioxide (CO2) and carbon monoxide (CO) ices from the cold traps on the Moon to Pluto in the Kuiper Belt. This review is organized into five parts. First, we review the mineral physics (e.g., rheology) relevant to these environments. Next, we review the radiation-induced chemical processes and the current interpretation of spectral signatures. The third section discusses the nature and distribution of CO2 in the giant planetary systems of Jupiter and Saturn, which are much better understood than the satellites of Uranus and Neptune, discussed in the subsequent section. The final sections focus on Pluto in comparison to Triton, having mainly CO, and a brief overview of cometary materials. We find that CO2 ices exist on many of these icy bodies by way of magnetospheric influence, while intermixing into solid ices with CH4 (methane) and N2 (nitrogen) out to Triton and Pluto. Such radiative mechanisms or intermixing can provide a wide diversity of icy surfaces, though we conclude where further experimental research of these ices is still needed.

Abundance and importance of petrological type 1 chondritic material

AbstractWe review the mineralogy, petrology, and abundance of petrological type 1 extraterrestrial material. Such material has been completely altered by aqueous processing on its parent bodies. As well as the four meteorite groups that contain type 1 members (CI, CM, CR, and CY), we summarize data from the 2019 fall Flensburg and a recent reanalysis of the “meteorite” Bench Crater found on the Moon, along with fine‐grained micrometeorites, interplanetary dust particles, and xenoliths in meteorites. Type 1 materials exhibit a remarkably high diversity of alteration conditions (temperature, water‐to‐rock [W/R] ratios, and fluid composition) and starting mineralogy. Type 1 material comprises a significant component of the modern extraterrestrial flux to the Earth and was likely common throughout the solar system during the whole course of its history, pointing to both widespread accretion with ices and heating of parent bodies. Type 1 materials are composed predominantly of various phyllosilicates, carbonates, sulfides, and magnetite. Some type 1 materials appear to be part of a “CM clan” typified by serpentine‐rich phyllosilicate compositions and an oxygen isotope composition that falls in the 16O‐rich part of the CM field. Others span a wide range in δ18O (>30‰) and fall on or above the terrestrial fractionation line (+ve Δ17O). Positive Δ17O values are unusual for carbonaceous meteorites but are relatively common in type 1 materials. The wide variation in oxygen isotopes, as well as in textures, mineralogy, and bulk chemistry, points to multiple parent bodies that may originate in the inner and/or outer solar system. Cometary materials, or transition objects such as Main Belt comets or type D asteroids, are likely the source of much of the type 1 materials on Earth but relating them to specific parents requires more study.

The CoPhyLab comet-simulation chamber.

The Comet Physics Laboratory (CoPhyLab) is an international research program to study the physical properties of cometary analog materials under simulated space conditions. The project is dedicated to studying, with the help of multiple instruments and the different expertise and background from the different partners, the physics of comets, including the processes inside cometary nuclei, the activity leading to the ejection of dust and gas, and the sub-surface and surface evolution of cometary nuclei when exposed to solar illumination. CoPhyLab will provide essential information on the formation and evolution of comets and insights into the origins of primitive Solar System bodies. To this end, we constructed a new laboratory that hosts several small-scale experiments and a large-scale comet-simulation chamber (L-Chamber). This chamber has been designed and constructed to host ice-dust samples with a diameter of up to 250 mm and a variable height between 100 and 300 mm. The cometary-analog samples will be kept at temperatures below 120 K and pressures around 10-6 mbar to ensure cometary-like conditions. In total, 14 different scientific instruments are attached to the L-Chamber to study the temporal evolution of the physical properties of the sample under different insolation conditions. Due to the implementation of a scale inside the L-Chamber that can measure weight changes of the samples with high precision, the cooling system is mechanically decoupled from the sample holder and cooling of the samples occurs by radiation only. The constructed chamber allows us to conduct uninterrupted experiments at low temperatures and pressures up to several weeks.

Thermodynamic model of the activity of the comet 103P/Hartley* *University of Rzeszów, Poland.

The paper presents three processes related to the dynamics of cometary particles. The following thermodynamic mechanisms were taken into account: quiet sublimation, emission of cometary matter via jet and migration of particles on the surface of the comet 103P/Hartley. Based on the first two mechanisms, the maximum particle size that can be lifted into the coma was determined. Additionally, in the case of a jet, the angle at which it is emitted from inside the cometary nucleus was determined. However, in the case of migration, the maximum width of individual belts within which a given particle can move was determined. In the context of the discussed mechanisms related to the activity of comet 103P/Hartley, the coefficient of friction and the structure of the solid or porous particles are of key importance.

Water-susceptible primordial noble gas components in less-altered CR chondrites: A possible link to cometary materials

We report detailed characterizations of the petrology, mineralogy, and noble gas signatures of Renazzo-type (CR) chondrites EET 92048, MIL 090657, NWA 801, and hydrothermally treated MIL 090657 samples to investigate primordial noble gases hosted by water-susceptible materials in aqueously less-altered CR chondrites. The noble gases were extracted by a stepwise heating method. The hydrothermal treatment on MIL 090657 resulted in the alteration of amorphous silicates in the matrix and the removal of large amounts of He and Ne that were released at low temperature from the untreated sample. The 36Ar/132Xe ratios in EET 92048 and MIL 090657 are ~5 times higher than that of the Q noble gas component, although both meteorites do not show any evidence for solar wind noble gases. The analyses revealed that aqueously less-altered CR chondrites contain two distinct primordial noble gas components hosted by water-susceptible materials: an isotopically Q-like Ne-rich component and an Ar-rich component. The characteristics of the Q-like Ne-rich component are consistent with those of Q-like Ne in cometary materials. We propose that the CR chondrites formed at a greater heliocentric distance and share similar materials hosting the Q-like Ne-rich component with comets. The presence of the Ar-rich component in the CR chondrites, as well as in ordinary chondrites and other anhydrous carbonaceous chondrites, provides evidence of the global distribution of the Ar-rich carriers in the ordinary and carbonaceous chondrite forming regions.

The destruction of the cometary nucleus – The case of 73P/Schwassmann-Wachmann

The paper presents an analysis of the actual brightness change of comet 73P/Schwassmann-Wachmann, which took place in 1995. The consequence of a cometary outburst is the destruction of a fragment of its surface. This causes the emission of comet material from both the surface and from exposed subsurface layers. Therefore, the calculations take into account the scattering cross-sections that come from ice and dust particles. It was assumed that the dust particles are silicates which are characterized by high irregularity of their structure. This assumption is a consequence of the analysis of the results provided by the Rosetta mission to the comet 67P/Churyumov-Gerasimenko. The main factor determining the amplitude of a cometary outburst is the mass ejected as well as the loss of ice that holds the individual nucleus structures together. Consequently, this phenomenon can significantly contribute to the destruction and even decay of the cometary nucleus.

The Main Asteroid Belt: The Primary Source of Debris on Comet-like Orbits

Abstract Jupiter-family comets (JFCs) contribute a significant amount of debris to near-Earth space. However, telescopic observations of these objects seem to suggest that they have short physical lifetimes. If this is true, the material generated will also be short-lived, but fireball observation networks still detect material on cometary orbits. This study examines centimeter-to-meter-scale sporadic meteoroids detected by the Desert Fireball Network from 2014 to 2020 originating from JFC-like orbits. Analyzing each event’s dynamic history and physical characteristics, we confidently determined whether they originated from the main asteroid belt or the trans-Neptunian region. Our results indicate that <4% of sporadic meteoroids on JFC-like orbits are genetically cometary. This observation is statistically significant and shows that cometary material is too friable to survive in near-Earth space. Even when considering shower contributions, meteoroids on JFC-like orbits are primarily from the main belt. Thus, the presence of genuine cometary meteorites in terrestrial collections is highly unlikely.

Sublimation of ice-dust mixtures in cooled vacuum environments to reproduce cometary morphologies

Aims. The morphology of cometary surfaces can provide important information to constrain the composition and evolution of comets. In this work, we investigate the sublimation behavior of comet analog materials and how the sample composition affects the evolution of morphological features in laboratory experiments. In our experiments, we used dust ice mixtures as analog material to form observed cometary morphologies. Methods. We used ice-dust mixtures in different mixing ratios as cometary analog material. In order to obtain realistic results, we scaled the expected cohesive and gravitational forces on comets to laboratory conditions. The samples were placed in a vacuum sublimation chamber and permanently cooled down to temperatures below 150 K to simulate the space environment. In the experiment, the samples were insolated with a light source from two different directions and alterations on the surface were recorded with a camera. Results. We find that the morphology of sublimation residues of ice-dust mixtures is strongly dependent on the ice-dust ratio as well as the insolation direction. High amounts of ice cause constant surface alteration and lead to exotic morphologies. Low amounts cause fewer and more episodic surface changes during its sublimation. Collapse events resulting in irregular and very rough surfaces occur during horizontal insolation.

Viscous and Knudsen gas flow through dry porous cometary analogue material

ABSTRACTAccording to current theories of the formation of stellar systems, comets belong to the oldest and most pristine class of bodies to be found around a star. When approaching the Sun, the nucleus shows increasing activity and a pressure increase inside the material causes sublimated and trapped gas molecules to stream away from their regions of origin towards the surface. The present work studies two essential mechanisms of gas transport through a porous layer, namely the Darcy and the Knudsen flow. Gas flow measurements are performed in the laboratory with several analogue materials, which are mimicking dry cometary surface properties. In this first series of measurements, the aim was to separate gas transport properties from internal sources like local sublimation or release of trapped gases. Therefore, only dry granular materials were used and maintaining a low temperature environment was unnecessary. The gas permeability and the Knudsen diffusion coefficient of the sample materials are obtained, thereby representing the relative importance of the respective flow mechanism. The experiments performed with air at a stable room temperature show that the grain size distribution and the packing density of the sample play a major role for the permeability of the sample. The larger the grains, the bigger the permeability and the Knudsen diffusion coefficient. From the latter, we estimated effective pore diameters. Finally, we explain how these parameters can be adapted to obtain the gas flow properties of the investigated analogue materials under the conditions to be expected on the comet.

Neutral–neutral synthesis of organic molecules in cometary comae

ABSTRACT Remote and in situ observations of cometary gases have revealed the presence of a wealth of complex organic molecules, including carbon chains, alcohols, imines, and the amino acid glycine. Such chemical complexity in cometary material implies that impacts by comets could have supplied reagents for prebiotic chemistry to young planetary surfaces. However, the assumption that some of the molecules observed in cometary comae at millimetre wavelengths originate from ices stored inside the nucleus has not yet been proven. In fact, the comae of moderately-active comets reach sufficient densities within a few thousand kilometres of the nucleus for an active (solar radiation-driven) photochemistry to ensue. Here, we present results from our latest chemical-hydrodynamic models incorporating an updated reaction network, and show that the commonly-observed HC3N (cyanoacetylene) and NH2CHO (formamide) molecules can be efficiently produced in cometary comae as a result of two-body, neutral–neutral, gas-phase reactions involving well-known coma species. In the presence of a near-nucleus distributed source of CN (similar to that observed by the Rosetta spacecraft at comet 67P), we find that sufficient HC3N and NH2CHO can be synthesized to match the abundances of these molecules observed previously in Oort cloud comets. The precise coma origins of these (and other) complex organic molecules can be verified through radio interferometric mapping observations, for example using the Atacama Large Millimeter/submillimeter Array.

The Case for Non-Cryogenic Comet Nucleus Sample Return

Comets hold answers to mysteries of the Solar System by recording presolar history, the initial states of planet formation and prebiotic organics and volatiles to the early Earth. Analysis of returned samples from a comet nucleus will provide unparalleled knowledge about the Solar System starting materials and how they came together to form planets and give rise to life: 1. How did comets form? 2. Is comet material primordial, or has it undergone a complex alteration history? 3. Does aqueous alteration occur in comets? 4. What is the composition of cometary organics? 5. Did comets supply a substantial fraction of Earth's volatiles? 6. Did cometary organics contribute to the homochirality in life on Earth? 7. How do complex organic molecules form and evolve in interstellar, nebular, and planetary environments? 8. What can comets tell us about the mixing of materials in the protosolar nebula?

Laboratory investigation into the dielectric properties of a L-chondrite (NWA 12857)

Ground Penetrating Radar (GPR) is a terrestrial geophysical exploration method that has recently become one of the most promising technique for planetary, asteroidal and cometary subsurface exploration. The capability of GPR to sound Solar System's bodies relies on the electromagnetic properties of the constitutive materials. Enstatite and ordinary chondrites represent class of asteroids occurring in the inner asteroid belt whereas carbonaceous chondrites and their icy mixtures are reasonable analogues for cometary material as well as constituent of shallow part of some Jovian satellite crusts. Therefore, the knowledge of electromagnetic properties of meteorites is very important because it allows to estimate the radar response in terms of signal velocity and attenuation. In this work we measured the real and imaginary parts of the permittivity of a L5 chondrite meteorite as a function of frequency (20 Hz-1 MHz) by using a capacitive cell connected to a self-balancing bridge. We studied the spatial variability of dielectric properties of the sample that exhibits areas with different textures characterized by a darker appearance. In general, the meteorite sample shows a stronger dispersive behavior compared to terrestrial rocks with higher values for both real and imaginary part of permittivity. In particular, the occurrence of very small grains (<10 μm) of FeNi metal, troilite and chromite scattered in some areas of the meteorite seems to be the cause of such behavior.

Possibility of concentration of nonvolatile species near the surface of comet 67P/Churyumov-Gerasimenko

Context. Cometary materials are thought to be the reservoir of the primitive materials of the Solar System. The recent detection of glycine and CH3NH2 by the ROSINA mass spectrometer in the coma of 67P/Churyumov-Gerasimenko suggests that amino acids and their precursors may have formed in an early evolutionary phase of the Solar System. Aims. We aim to investigate the evolution of the interior of comets considering the evaporation process of water followed by the concentration of nonvolatile species. Methods. We developed a Simplified Cometary Concentration Model (SCCM) to simulate the evaporation and concentration processes on the cometary surface. We use 67P/Churyumov-Gerasimenko as the benchmark of the SCCM. We investigated the depth of the layer where nonvolatile species concentrate after the numerous passages of perihelion after the formation of the Solar System. Results. We find that the SCCM explains the observed production rates of water and CH3NH2 at 100 comet years. Results from the SCCM suggest that the nonvolatile species would concentrate in the top 100 cm of the comet surface within 10 comet years. Our results also suggest that the nonvolatile species would concentrate several meters beneath the surface before it hit the early Earth. This specific mass of nonvolatile species may provide unique chemical conditions for the volcanic hot spring pools.

“Water” abundance at the surface of C-complex main-belt asteroids

Recently published space-based observations of main-belt asteroids with the AKARI telescope provide a full description of the 3 μm band, related to the presence of OH bearing minerals. Here, we use laboratory spectra of carbonaceous chondrites obtained under controlled atmosphere (CI,CM,CO,CV,CR Tagish Lake) to derive spectral metrics related to the water content in the samples. After testing several spectral metrics, we use a combination of band depth at 2.75 μm and 2.80 μm that shows a correlation with [H2O] in the sample determined by TGA, though with a high uncertainty (4 wt% H2O). This relation is used to determine water content at the surface of large C-complex main-belt asteroids and discuss the origin of the variability found. On average C-complex Main-Belt Asteroids (MBA) have water contents of 4.5 wt% (volume average, (1) Ceres excluded), significantly lower than average CM chondrites. The estimated water content for the most hydrated asteroids are lower than those of the most hydrated meteorites, a difference that could be attributed to space-weathering. An anti-correlation is also present between water content and overall spectral slope, which is opposite to expectation from laboratory simulations of space weathering on dark carbonaceous chondrites. This suggests that part of the variability in the surface hydration among the different C-complex asteroids is not due to space-weathering, but to the composition of surface material. When applied to Ceres, the hygrometer presented in this work enables us to estimate that at least 1.22 wt% of the hydrogen is present in the form of organics. This richness in organics strengthens the connection between Ceres and cometary materials.

Tensile strength of dust-ice mixtures and their relevance as cometary analog material

Aims. The tensile strength of granular matter is of great importance to our understanding of the evolution of comets and to our attempts to reproduce processes on cometary surfaces in laboratory experiments. In this work, we investigate the tensile strength of three different materials and their mixtures, which can be used as cometary analog materials in the laboratory. Methods. We used two types of siliceous dusts and granular water ice whose polydisperse particles were either angular or spherical. Our samples were cooled to below 150 K to better simulate the conditions of a cometary surface and to avoid thermal alteration of the material. We used the Brazilian disk test method to exert stress on the cooled samples and determine the tensile strength at the moment the samples broke. Results. We find that the tensile strength of two component mixtures is strongly dominated by the component with the higher tensile strength. The materials made of mostly angular dust particles have a lower filling fraction, but a higher tensile strength compared to materials made of spherical particles. Furthermore, the tensile strength of the cooled components is substantially lower than the tensile strength of the same components at room temperature. This implies that the surface energy of the investigated materials at low temperatures is significantly lower than previously assumed.