Combustion Technique Research Articles

Modified energy storage properties of lead-free Sr0.3Bi0.35Na0.335Li0.015TiO3 ceramics with La3+ substitution via the solid-state combustion technique

In this study, the influence of La3+ substitution on the phase structure, microstructure, electrical and energy storage properties of (Sr0.3Bi0.35Na0.335Li0.015)1-xLaxTiO3 (SBNLT-xLa) ceramics with x = 0–0.05, using the solid-state combustion technique, was investigated. X-ray diffraction (XRD) patterns indicated a pure perovskite structure formed, along with coexisting rhombohedral and tetragonal phases in all ceramics. The Rietveld refinement analysis showed the tetragonal phase increased while the rhombohedral phase decreased with increased La3+ content. The morphology of the SBNLT-xLa ceramics displayed polygonal grain shapes and anisotropic grain growth. Average grain sizes increased from 2.01 to 2.43 μm as x increased from 0 to 0.01 and afterwards decreased as x increased further. Both the measured density and maximum dielectric constant (ɛm) decreased from 5.48 to 5.29 g/cm3 and from 4667 to 2313, respectively, when x increased from 0 to 0.05. A decrease in the dielectric properties caused by the phase ratio shifting away from a morphotropic phase boundary (MPB) condition, poor microstructure and low density was produced with La3+ replacement. The maximum polarization (Pmax), remnant polarization (Pr) and coercive field (Ec) decreased with increased La3+ content. A decline in Pr and Ec improved the energy storage efficiency (ƞ) and energy storage loss (Wloss), resulting in enhanced energy storage properties. At x = 0.02, the ceramic showed good energy storage properties (Wtotal of 0.781 J/cm3, Wrec of 0.624 J/cm3, Wloss of 0.157 J/cm3 and ƞ of 79.8%), measured at 60 kV/cm.

Synthesis and Exploring structural, magnetic, morphology and optical properties of La2−xAlxCuO4 (0 ≤ x ≤ 0.25) perovskite nanoparticles by microwave-assisted combustion method

La2CuO4 perovskite nanoparticles doped with aluminum were synthesized through the microwave-assisted combustion technique. Comprehensive studies on the structural, magnetic optical, functional and morphological properties were conducted using various techniques, including XRD, EDX, VSM, DRS-UV, FT-IR and FESEM respectively, .The XRD patterns of pristine La2CuO4 and Al-doped La2CuO4 unequivocally validated the exclusive development of a perovskite structure, devoid of any impurities. Nevertheless, the augmentation in Al3+ content (x = 0–0.25) induced a noteworthy phase shift from orthorhombic to cubic configuration. The average crystallite dimensions spanned from 54 to 41 nm. Distinct FT-IR bands at approximately 687 and 434 cm-1 were intricately linked to the La-O and Cu-O stretching modes inherent to the orthorhombic La2CuO4 phase. The energy gap determined through the Kubelka–Munk (K–M) methodology, experienced an elevation concomitant with the heightened Al3+ content (1.67–1.72 eV), attributable to quantum confinement phenomena. Within the La2-xAlxCuO4 (x = 0 to 0.25) system, the genesis of nanoscaled crystallized grains, interspersed with pores resulting from the amalgamation of grains, was evident. Analysis of hysteresis curves unveiled the emergence of soft ferromagnetic behavior at ambient temperature.

Effectiveness of green-synthesized nickel-doped calcium ferrite nanoparticles in the X-ray/gamma radiation shielding applications

Nanoparticles comprising calcium ferrite doped with Nickel within a concentration range of 10 to 50 mol% were successfully produced using a solution combustion technique, employing neem leaf extract as a reducing agent. The subsequent calcination process at 500 °C validated the formation of orthorhombic calcium ferrite, featuring distinct Bragg reflections indicative of Nickel doping. An analysis via scanning electron microscopy (SEM) affirmed the presence of irregularly shaped nanoparticles with pores and voids within their structure. The optical energy band gap, determined through Wood and Tauc’s relation, ranged from 2.89 to 2.97 eV. Notably, an increase in Nickel substitution was found to correlate with an increase in the energy band gap and a reduction in crystallite size. The research extensively evaluated the nanoparticles’ efficacy in radiation protection, encompassing parameters such as mass attenuation coefficient, mean free path, half-value layer, and effective atomic number. The mass attenuation coefficient is found to be 0.05353 cm2g−1 for 40 mol% at 1332 KeV. EABF is found to be large for 40 mol% at 0.89 MeV energy. Likewise, 50 mol% has a high Neutron absorption cross section (σab) which is 1.5(barn). Also, the bremsstrahlung dose rate is found to be 1.35 (R/h)*103, at 1.511 MeV.Additionally, the study comprehensively explored variations in the energy-absorbing buildup factor across diverse energy ranges, taking into account the Nickel concentration within the calcium ferrite nanoparticles. This aspect holds significant importance in the field of radiation dosimetry, particularly in applications related to neutron shielding and bremsstrahlung radiation.

Enhanced electrical and energy storage performances of Fe, Sb co-doped BNBCTS ceramics synthesized via the solid-state combustion technique

In this study BNBCTS ceramics were co-doped with Fe and Sb to form (Bi0.5Na0.5)0.93(Ba0.945Ca0.055)0.07(Ti(0.9946-x)Sn0.0054)(Fe0.5Sb0.5)xO3 ceramics (denoted as BNBCTS-xFS) with various x content and were prepared via the solid-state combustion technique to enhance the electrical and energy storage performance. The effect of co-doping Fe and Sb on the phase formation, defect dipole, microstructure, electrical and energy storage properties of BNBCTS-xFS ceramics was studied. When x content increased from 0.0 to 0.030, the amount of the rhombohedral (R) phase decreased from 51 to 24 % while the tetragonal (T) phase increased from 49 to 76 %. The increased Fe and Sb content increased the defect dipole of singly/doubly charged oxygen-vacancies (VO∙/ VO∙∙) and caused more Ti4+ to transition to Ti3+, which caused the transition temperature of the ferroelectric phase to relaxor state (TF-R) in the ceramics to drop to below room temperature and it exhibited relaxor characteristics at room temperature. The ceramic with an x content of 0.010 had the largest grain size (3.06 μm), excellence ferroelectric properties (Pr ∼31.04 μC/cm2, Pm ∼38.98 μC/cm2 and Ec ∼18.28 kV/cm), the largest electro strain (∼0.175 %) and a large d33* of 350 pm/V. Moreover, when x = 0.020, the ergodic relaxor ceramic showed the smallest grain size (1.03 μm), the lowest remanant polarization (Pr) of 4.52 μC/cm2 and the lowest coercive field (Ec) of 8.37 kV/cm, at an electric field of 60 kV/cm. More importantly, energy storage properties at the electric breakdown strength (Eb = 120 kV/cm) of the ceramics with an x content of 0.020 exhibited a recoverable energy storage density (Wrec) of 1.81 J/cm3, a total energy storage density (Wtotal) of 2.95 J/cm3 and an efficiency (η) of 61.30%, with excellent thermal (∼25–150 °C) and frequency stability (∼1–100 Hz). This study provides new insights into the modulation of BNBCTS ceramics with Fe and Sb co-doping, which could effectively improve the electrical properties and energy storage properties of BNBCTS-xFS ceramics.

Investigation on SmBa0.5Sr0.5Co1.5Fe0.5O5+δ double perovskite as an oxygen electrode for reversible solid oxide fuel cell

The conventional oxygen electrode degrades when operated in reversible solid oxide fuel cell (RSOFC) mode. To address this issue, double perovskites have been explored as promising cathode electrodes in RSOFC with proton conducting electrolyte as the electrolyte. In the present study, SmBa0.5Sr0.5Co1.5Fe0.5O5+δ (SBSCF) double perovskite is explored as the oxygen electrode using YSZ as the electrolyte. The SBSCF has been successfully synthesized using a simple and cost-effective solution combustion technique as the oxygen electrode for RSOFC. The structural, morphological and electrical conductivity of SBSCF powder and the electrochemical performance of SOFC containing SBSCF as cathode material are discussed. The performance of the cell in the electrolyzer mode is also discussed.

Preparation and spectroscopic study of nanosized aluminate spinels Al2XO4 (X = Cd, Ni and Co) synthesized by solution combustion technique

Preparation and spectroscopic study of nanosized aluminate spinels Al2XO4 (X = Cd, Ni and Co) synthesized by solution combustion technique

Propagation of Combustion Front within Fractured Shale and Its Influence on Shale Structure and Crude Oil Properties: An Experimental Study

Summary The in-situ combustion (ISC) technique has emerged as a significant approach for shale oil production. However, currently, there is a lack of experimental evidence supporting the stable propagation of combustion front within fractured shale. This study aimed to investigate the combustion characteristics within fractured shale by using a self-designed combustion tube (CT) and an experimental scheme. Subsequently, an analysis of shale structure and oil properties was conducted. The results demonstrated that while the combustion front could propagate through shale with a single fracture width of approximately 43 μm, the combustion intensity gradually diminished, leading to an inability to sustain stable propagation in the later part of the oil-detritus mixtures. The combustion intensity within the shale was enhanced by preheating the shale at 250°C, resulting in an improved oil recovery from 67.8% to 77.9%. The findings indicated that the complex fractured shale allowed for the stable propagation of the combustion front without a significant decrease in combustion intensity. Moreover, the T2 spectrum analysis of shale revealed a gradual expansion of the pore-fracture structure and improved shale connectivity after combustion. The T1-T2 response illustrated the transformation of solid and heavy components into lighter components. Furthermore, the content of saturates and H in the oil increased after combustion, whereas there was a significant decrease in resins, O, and S. Overall, this study provided technical evidence supporting the feasibility of employing the ISC technique for the development of shale oil reservoirs with additional fractures.

Enhancing the arch-fired low-NOx performance with a throat overfire air for lowering NOx and hopper overheating

Upon the background of China's dual-carbon energy and environment strategies and the requirements of green and sustainable development in the new era, how to gradually reduce coal consumption while at the same time enhance the efficient and clean use of coal and reduce pollutant emissions is attracting more and more attention. For a 600-MWe arch-fired furnace facing persistent challenges of high NO x output and an overheating risk in hopper as firing anthracite, a cascade-arched low-NO x and high-efficiency configuration (CLHC) was taken as an alternative to the existing multiple-injection and multiple-staging combustion technique (i.e., the MIMSCT, denoted as the reference furnace or technique in this study). In particular, along the furnace height the CLHC's overfire air (OFA) position in the burnout zone has an important influence on the low-NO x performance due to the shrunk furnace-arch space and a short upper furnace. Aiming at evaluating the OFA-location effect and confirming the CLHC in resolving the above problems, industrial-scale experiments and modeling were performed in the reference furnace and thereafter, the low-NO x characteristics with the CLHC was simulated considering three different OFA locations of the upper-furnace OFA, throat OFA, and arch OFA. In the OFA-location elevated order, the blending position of OFA and the main upward gas first lowered and then elevated, while the OFA penetration, overall combustion performance, and major low-NO x accomplishment indexes related to NO x yield and burnout loss initially improved but then deteriorated. As a result, the medium throat OFA presented the optimal low-NO x merit among the three setups, with the unburnt combustible of 5.3% in fly ash alongside NO x yield of 660 mg/m3 (O2 = 6%), respectively. By comparison to the reference technique, the CLHC gained a 30% NO x reduction ratio without affecting burnout and greatly relieved the hopper overheating issue via reducing sharply its temperatures by 400 K, thereby confirming the CLHC's viability. This study provided guidance on the safe furnace operations and reduction of pollutant emissions, benefiting the efficient and environmentally friendly usage of low-quality coals in industrial-scale furnaces.

Auto-combustion synthesis of lanthanum-doped TiO2 nanostructures for efficient photocatalytic degradation of crystal violet dye

ABSTRACT Utilising the solution combustion technique, nanocrystalline photocatalysts that included both pristine TiO2 and doped TiO2 with various La (III) dopant percentages (1, 3, 5, and 7 mol%) were created. Different methods, including thermal analysis, high resolution-transmission electron microscopy (HR-TEM), X-ray diffractometer (XRD), Fourier transform infrared spectroscopy (FT-IR), and field-emission scanning electron microscopy (FE-SEM), were used to investigate the prepared nanostructures. The XRD results indicated the anatase form and the crystalline nature of the products (pristine and doped TiO2) in the size range of a crystallite (5–16.5) nm. The photocatalytic assessment of the prepared nano-photocatalysts was carried out by crystal violet (CV) decolourisation under ultraviolet (UV) light. The findings revealed that 3% La-TiO2 showed the highest degradation efficiency (95.98%) in 70 min with a pseudo-first-rate constant of k = 4.73 × 10−2 min−1, compared to pristine TiO2 and the other TiO2 nanostructures with various La (III) dopant ratios.

Solution combustion synthesis of Bi2Fe4O9 possessing enhanced magnetic and photocatalytic properties

Bismuth ferrites have attracted much attention in recent years because of the possibility of their promising practical applications in sensing systems as well as digital memory.In this study, nanocrystalline material based on bismuth ferrite with mullite-like structure was synthesized by solution combustion technique. The results of XRD confirmed the formation of a Bi2Fe4O9 orthorhombic phase with an average crystallite size 60 ± 3 nm. The composition, morphology and porosity were characterized by SEM/EDX and helium pycnometry. The peculiarities of the material formation from the initial mixture with a glycine deficiency by subsequent calcination of the combustion product in air, were characterized by XRD, EDX and simultaneous thermal analysis.Magnetic properties of the substance were studied by Mössbauer spectroscopy and magnetometry which showed that its magnetization is enhanced in comparing to similar materials by several times. Specific features in the Bi2Fe4O9 magnetization with changing temperature were analyzed for the first time.The photocatalytic activity of Bi2Fe4O9 during the decay of rhodamine B has been studied. It is demonstrated that the degradation of rhodamine B increased by about 70% when irradiated with visible light.

Effect of cation disorder on basic parameters of ZnFe2O4 nano-particles synthesized by honey mediated solution combustion technique

Nanotechnology contracts by the invention and practice of material using nanoscale dimension. Nanoscale measurement delivers nano-particles a bulky surface area (S) to volume ratio, hence very specific properties. Bulk zinc ferrite (ZnFe2O4) exhibits anti-ferromagnetism, with Néel temperature of 10K, is paramagnetic at room temperature. It displays normal spinel structure with Zn2+ has exclusive tetrahedral - A site preference, whereas Fe3+ ions occupy the octahedral - B site. Cationic disorder induced fractional overturn of the spinel structure, owing to partial immigration of Fe3+ ions from B to A site can prompt ferrimagnetism in nano zinc ferrite. Due to the large ratio of toxic chemicals and extreme environment employed in the chemical and physical production of these ferrites, green methods employing the use of bacteria, plants fungus have been adopted. Present work reports comprehensive study of the synthesis, structural and magnetic investigation of room temperature ferrimagnetism in ZnFe2O4 nanoparticles, prepared by sol gel auto-combustion mode and green synthesis method. Effect of conventional thermal annealing (ann. at 600oC for 3 hours) on magnetic properties is also reported. The structural and magnetic characteristics of as prepared and annealed ZnFe2O4 samples were determined by X-ray diffraction (XRD) and vibrating sample magnetometer (VSM). XRD confirms the formation of single-phase nano-crystalline cubic spinel structure of the samples.

Effect of coercive aluminium on the structural and magnetic characteristics of calcium and magnesium based hexaferrites

Aluminum substituted Calcium-Magnesium (Ca-Mg) hexaferrites having general formula Ca0.5Mg0.5Fe12-xAlxO19 (where x is increased with increment of 0.5 from 0.0 to 2.0) are prepared by sol–gel auto combustion technique. X-ray diffraction patterns confirm the hexagonal structure with no evidence of secondary phases. The reduction in lattice parameters is observed as the Al+3 doping level increases. This can be attributed to the short ionic radii of Al+3 ions (0.535 Å) compared to Fe+3 ions (0.645 Å). The obtained c/a ratio falls within the acceptable range of 3.98. Consequently, the formation of magnetoplumbite structure is also confirmed. The SEM image reveals the uniform distribution of particles. The exchange of Fe+3 ions with coercive Al+3 ions led to a decline in saturation magnetization Ms and a significant increase in the coercivity Hc. The magnetic moment mB and Mr of hexaferrites exhibit a decline when Al ions are introduced. This reduction can be ascribed to several factors: the substitution of non-magnetic Al3+ ions in place of Fe3+ ions, the spin-canted ordering of Fe3+ ions, and the valency of Fe ions from 3+ to 2+.

From Flames to Fuels: A Review of Combustion in Energy Generation

This review paper delves into the nuanced world of combustion in energy generation, exploring the different kinds and their respective influences and utilization. It spans from complete type to explosive combustion, each imparting specific features, environmental implications, and technological advancements. Complete-type combustion, renowned for its cleanliness, contrasts sharply with the hazardous incomplete combustion. Whereas, rapid combustion is extremely good for enhancing engine performance, and spontaneous combustion is marked by its natural incidence without outside triggers. Explosive combustion, prominent by its rapid response rates, underscores the complexity and risks inherent in certain combustion techniques. The paper similarly investigates catalysts, fuel enhancements, and technological innovations aimed toward optimizing combustion performance and reducing environmental detriments. This complete review presents a deep dive into the combustion mechanisms, their utilization, and the ongoing research aimed at mitigating their environmental affects while enhancing efficiency in energy generation systems.

Investigation of upconversion and photoacoustic properties of NIR activated Er3+/Yb3+ doped [RE]VO4 (RE = Y, Gd) phosphors for photothermal conversion applications

Er3+/Yb3+ doped YVO4 and GdVO4 phosphors were prepared through the combustion technique and were characterized through various techniques.

In situ growth of copper oxide on MXene by combustion method for electrochemical ammonia production from nitrate.

The elimination of the nitrogen pollutant nitrate ions through the electrochemical synthesis of ammonia is an important and environment friendly strategy. Electrochemical nitrate reduction requires highly efficient, selective, and stable catalysts to convert nitrate to ammonia. In this work, a composite of copper oxide and MXene was synthesized using a combustion technique. As reported, nitrate ions are effectively adsorbed by CuxO (CuO & Cu2O) nanoparticles. Herein, MXene is an excellent assembly for anchoring CuxO on its layered surface because it has a strong support structure. Powder X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) analyses show the presence of oxidation states of metal ions and the formation of CuxO nanofoam anchors on the surface of MXene (Ti3C2Tx). The optimized CuxO/Ti3C2Tx composite exhibits an improved nitrate reduction reaction. The electrochemical studies of CuxO/Ti3C2Tx show an interesting nitrate reduction reaction (NO3RR) with a current density of 162 mA cm-2. Further, CuxO/Ti3C2Tx shows an electrocatalytic activity with an ammonia production of 41 982 μg h-1 mcat-1 and its faradaic efficiency is 48% at -0.7 V vs. RHE. Thus, such performance by CuxO/Ti3C2Tx indicates a well-suitable candidate for nitrate ion conversion to ammonia.

Thermoluminescence kinetics in beta-irradiated novel ZnGa2O4:Eu3+ phosphor produced via gel combustion synthesis

Eu3+ doped ZnGa2O4 phosphors with varying dopant concentrations were successfully synthesized using the combustion technique. X-ray diffraction analysis confirmed the consistency of both undoped and Eu3+ doped ZnGa2O4 samples with PDF#38–1240 card structure. The investigation of thermoluminescence (TL) characteristics involved studying TL glow curves in Eu3+ doped ZnGa2O4 samples with different dopant concentrations, employing various optical detection filter combinations. Among these, ZnGa2O4: 2%Eu3+ and the IRSL-TL wide blue band (wbb) proved to be the optimal sample and ideal detection filter pairing for identifying TL features. Following preheating experiments, the TL maximum was observed at around 190 °C, with a heating rate of 2 °Cs−1. The dose-response experiment for ZnGa2O4:2%Eu3+ exhibited satisfactory linearity, with a coefficient of b = 0.988 and an R2 value of 0.989 for doses up to 100 Gy. Moreover, for the dose range of 200–500 Gy, a sublinear relationship was maintained, with a coefficient of b = 0.31 and an R2 value of 0.988. Hoogenstraaten's method, along with the initial rise method and the Tm-Tstop experiment, was also employed in conjunction with a glow curve fitting package. This comprehensive approach facilitated the determination of the number of peaks, trap structure, and kinetic parameters within the thermoluminescence glow curve. Glow curve deconvolution using specialized software revealed the presence of five well-isolated and overlapping TL glow peaks, achieving a figure of merit (FOM) value of 1.39.

Enhancing ammonia engine efficiency through pre-chamber combustion and dual-fuel compression ignition techniques

In pursuit of unleashing ammonia’s potential in internal combustion engines, an extensive computational study was conducted to explore the effects of two advanced combustion techniques: pre-chamber combustion (PCC) and dual-fuel compression ignition (DF−CI) on a heavy-duty ammonia engine. In the PCC mode, hydrogen was introduced into the pre-chamber (PC) to generate distributed reacting jets, with a small energy fraction of 0.5%. The case featuring a slightly narrower PC throat (diameter of 5.4 mm) yielded the highest indicated thermal efficiency (ITE) of 50.4%, owing to the rapid distribution of reacting jets and advanced combustion phasing. Further increase in hydrogen energy fraction and reduction in throat diameter resulted in a lower ITE because of the enhanced wall heat transfer loss. The DF−CI mode also exhibited significant potential for achieving high efficiency. Through a systemic optimization of parameters such as diesel injection timing, spray included angle, injection pressure, swirl ratio, and piston shape, a significantly enhanced ITE of 50.3% was attained, 7.2% higher than the baseline scenario. The improvement was primarily attributed to the promoted mixing of diesel with air. Among the design parameters, the swirl ratio and spray included angle exhibited the most significant impact on the engine performance. Overall, both the PCC and DF−CI modes were found to yield high ITE and low ammonia emissions. However, because 20% of the diesel energy fraction was utilized to mitigate ammonia slip in the DF−CI mode, notably higher greenhouse gas emissions (carbon dioxide of 96 g/kW-h) were generated than in the PCC mode. In this regard, the ammonia-hydrogen PCC mode should be a more promising solution to achieve zero-carbon emissions for future ammonia engines.

Optimization of switching charge and recoverable energy density mediated by structural transformation in Sr-substituted BaNiO3 perovskites.

Because of their distinctive characteristics, ferroelectric perovskites are considered among the most potent and auspicious candidates for energy storage and pulsed power devices. But their energy storage properties and switching capabilities need to be further enhanced which can be done by substitutions of appropriate cations. Hence, a series of lead-free Ba1-xSrxNiO3 (x = 0.00, 0.33, 0.67, and 1.00) ceramics was fabricated using a sol-gel auto combustion technique. Rietveld's refinement of X-ray diffraction plots verified the complete development of the required hexagonal perovskite structure. Scanning electron microscopy images revealed a gradual increase in average grain sizes and agglomeration with the increase in Sr-content. Moreover, the existence of all the constituent elements exactly in proportion to their stoichiometric ratios was verified by energy dispersive X-ray spectroscopy. The characteristic parameters of ferroelectric materials such as ferroelectric response, electrical conductivity, and switching charge density were also determined. The P-E loops indicated that with the increase in Sr-content, the coercive field, remanent polarization, and maximum polarization all decreased gradually, but the recoverable energy density (Wrec) increased as the loops became slimmer. The maximum value of Wrec was found in the Ba0.33Sr0.67NiO3 sample. Moreover, SrNiO3 exhibited minimum energy loss with the highest efficiency of ∼47.21%. The existence of a current barrier in all the samples was proved from the low leakage current values (∼10-7 A). In addition, the pure SrNiO3 showed a low electrical conductivity and minimum value of switching charge density. All these findings make SrNiO3 a promising candidate for fast switching and energy storage applications.

Green color emitting pure cubic zirconia nano phosphor synthesized by solution combustion technique

Green color emitting pure cubic zirconia nano phosphor synthesized by solution combustion technique

Gasification Burner Performance Test Using Bio-Coal Fuel

Fuel for high-energy solid fuel combustion systems must meet abundant availability, affordability, and environmental friendliness criteria, particularly having low greenhouse gas emissions. One type of fuel that meets these criteria is bio-coal. Gasification burners employ staged combustion techniques that enhance combustion efficiency and reduce the formation of harmful substances, making them more environmentally friendly. This article discusses the performance testing of gasification burners using bio-coal as fuel, with variable primary air flow rates of 25, 30, 35, 40, and 50 m3/hour and biomass percentages in the bio-coal of 25%, 50%, and 75% by weight. The parameters observed are burner capacity, temperature, and CO2 gas emission factor. The experimental results show that increasing the air flow rate from 25 to 35 m3/hour significantly increases burner capacity and temperature, while further increasing the primary air flow rate to 50 m3/hour results in a gradual increase in burner capacity. The experiments also indicate that increasing the biomass percentage in the bio-coal slightly increases burner capacity and temperature due to the similar calorific values of palm pellet and coal used. The gasification burner technology developed by BBP Tekmira has proven to operate effectively within a capacity range of 8 to 20 kg/hour for bio-coal fuel with biomass percentages ranging from 25% to 75% by weight, producing burner temperatures between 805 and 933 degrees Celsius. Using bio-coal for gasification burners has also been shown to reduce greenhouse gas emissions when the biomass percentage in bio-coal exceeds 64%.