The article is devoted to the investigation of the characteristics of a gas turbine combustion chamber with a steam injection when operating on hydrogen-containing mixtures and pure hydrogen. The parameters of a cannular combustion chamber with a separate injection of ecological and energy steam were studied to ensure the stable and ecologically clean chamber’s operation without the formation of flashback zones. The injection of ecological steam in the area of the vane swirler of the flame tube for the diffusion-type combustion chamber makes it possible to provide low emissions of nitrogen oxides at significant concentrations of hydrogen in its mixtures with natural gas, even if the maximum gas temperature in the primary zone of a combustion chamber increases. For the investigated chamber’s operating modes, the calculated carbon monoxide emission does not exceed 18.1 ppm. Emissions of nitrogen oxide when the hydrogen content changes from 0 to 50% initially decrease from 36.1 to 17.8 ppm due to increased steam injection to the combustion zone and then increase to 38 ppm when operating on pure hydrogen. An increase in the nonuniformity of the temperature field at the combustion chamber outlet with an increase in the hydrogen content in the mixture with natural gas was noted.