Hybrid solar thermal systems are considered to be a promising solution for delivering clean thermal energy for the building sector, especially while combining them with other renewable energy sources. Usually, solar energy production does not match the thermal energy demand, and hence the energy storage must be integrated. Thermochemical energy storage is adapted particularly to be used along with solar thermal applications. In this article, the design of the combined solar thermochemical energy storage system is presented. The experimental prototype was built and tested within atmospheric conditions. The model of the thermochemical reactor was developed using Matlab® and it was validated by the experimental data. The dynamic simulations of the combined solar thermal system for the preparation of domestic hot water were carried out in the TRNSYS environment. The experimental energy storage density of the fully dehydrated material under non-equilibrium conditions was measured between 102 and 158 kWh/m³. Dynamic simulations performed in a broader scope of climate conditions showed that the energy storage density in the material under non-equilibrium conditions could vary between 71 and 247 kWh/m³.
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