Owing to the urgency of energy demand, an enhanced supervisory control scheme (ESCS) is proposed for hybrid microgrids (HMGs) integrating AC and DC grids. This system optimizes energy management within a virtual power plant (VPP) setup, facilitating smart charging stations for electric vehicles (EVs) and enabling vehicle-to-grid (V2G) and grid-to-vehicle (G2V) interactions. The proposed ESCS combines three sub-controllers: a sliding mode approach-based maximum power algorithm (SMA-MPA), active current detection technique (ACDT), and state of charge (SOC) regulation scheme. In this proposed approach, the SMA-MPA method is employed to extract maximum power with necessary stability confirmation. Moreover, ACDT is utilized to mitigate harmonics from nonlinear loads through the DC-AC inverter, thereby improving power quality (PQ). To enhance SOC regulation of the VPP, a detailed flow chart of appropriate converting mode selection associated with SOC controller design is proposed for smoother operation and improved dynamics. The coordination between sub-controllers is achieved by analyzing power demand and supply, DC-link voltage conditions, and SOC states of the VPP. The proposed ESCS approach enhances PQ even during PV shutdown conditions. Through software simulations and real-time Hardware-in-the-Loop (HIL-402) validation, the ESCS's superior power management, PQ, and regulatory compliance are demonstrated against conventional PQ methods. The findings exhibit excellent power management, improved PQ, and better voltage/frequency regulation in accordance with prescribed international IEEE 519 standards.