When G is a complex reductive algebraic group, MV polytopes are in bijection with the non-negative tropical points of the unipotent group of G . By fixing w from the Weyl group, we can define MV polytopes whose highest vertex is labelled by w . We show that these polytopes are in bijection with the non-negative tropical points of the reduced double Bruhat cell labelled by w^{-1} . To do this, we define a collection of generalized minor functions \Delta_{\gamma}^{\mathrm{new}} which tropicalize on the reduced Bruhat cell to the BZ data of an MV polytope of highest vertex w . We also describe the combinatorial structure of MV polytopes of highest vertex w . We explicitly describe the map from the Weyl group to the subset of elements bounded by w in the Bruhat order which sends u \mapsto v if the vertex labelled by u coincides with the vertex labelled by v for every MV polytope of highest vertex w . As a consequence of this map, we prove that these polytopes have vertices labelled by Weyl group elements less than w in the Bruhat order.