Color Rendering Index Research Articles

Mitigating urban light pollution: A review of municipal regulations and implications for planners

ABSTRACT Propelled by more energy-efficient technologies such as light-emitting diodes, the growth of outdoor light at night is raising concerns about light pollution (LP). Given mounting evidence of LP’s risks to human wellbeing, nature and wildlife, and views of the dark sky, this paper examines the extent to which LP concerns are addressed in land use plans, policies, and regulations in nine U.S. cities, including Flagstaff, Arizona, a city known for its model lighting code. Through a review of zoning and other ordinances, area and sectoral plans and policies, media reports, and interviews with planners, this study documents that LP has yet to be taken seriously in municipal codes of most study cities. Drawing from the Flagstaff model, it offers recommendations for evidence-based, objective standards for three key dimensions of LP-mitigation: limiting total illumination or lumens per acre, shielding of lamps, and specifying luminaire characteristics. ABBREVIATIONS AMA: American Medical Association; APA: American Planning Association; CCT: Correlated Color Temperature; CRI: Color Rendition Index; ESCO: Energy Service Companies; f.c.: foot candle; HPS: High-Pressure Sodium; IDA: International Dark-Sky Association; LED: Light-Emitting Diode; LP: Light Pollution; LPS: Low-Pressure Sodium; LZ: Lighting Zone; NSA: Narrow-Spectrum Amber

Functional design and implementation of multilayer Ce:YAG/Cr:YAG composite transparent ceramics by tape casting for white LEDs/LDs

The shortage of red-light emission in Ce3+:Y3Al5O12 (Ce:YAG) luminescent ceramics is a bottleneck problem to realize the key applications of ceramics based white light-emitting diode (LED) and laser diode (LD) devices. However, the energy band-gap engineering for Ce3+ ion via host substitution or red-emission ions co-doping always leads to its decrease of luminescence efficiency (LE), while a spectrum overlay strategy would be simple and effective. In this study, multilayer composite structure Ce:YAG/Cr:YAG transparent ceramics (TCs) with high color rendering index (CRI) were fabricated by tape casting and vacuum sintering. An organic tape casting protocol with low toxicity and environmental protection was developed and the amounts of dispersants, binders, and plasticizers were systematically optimized to produce good quality tapes with no defects. The transmittance of ceramic reached 78% at 800 nm. By using a 455 nm blue chip, the CRI of the Ce:YAG/Cr:YAG TCs based LED device was increased from 26.7 to 77.5, and the LE was decreased from 181.5 to 10.4 lm/W. Additionally, the optimized LE and CRI for LD device were 130.2 lm/W and 78.1, respectively. Therefore, this research displays that the design and implementation of ceramic functional layer to achieve the essential enhancement of CRI in TC based white lighting is a promising method through the tape casting forming technology.

Ionic liquid alkyl chain regulated highly stable and luminescent silica-coated perovskite quantum dots for bright white light-emitting diodes

Silica-coated perovskite quantum dots (QDs), which exhibit exceptional photophysical properties, hold great promise for various optoelectronic applications. Nonetheless, the issue of insufficient stability poses a significant challenge to their continued advancement and widespread adoption. Herein, we present a novel approach for the synthesis of silica-coated CH3NH3PbBr3 (CH3NH3 = MA) QDs with exceptional stability and luminescence, which utilized hydrophobic ionic liquids (ILs) with unlike alkyl chain lengths as surface ligands. As the alkyl chain length of the hydrophobic ILs increased, we observed a blue-shift in the wavelength and a reduction in the time required to reach maximum fluorescence for the silica-coated perovskite QDs. It not only effectively prevents QD aggregation but also accelerates the formation rate of the SiO2 shell. The introduction of ILs generated the enhancement of photoluminescence quantum yield (PLQY) from 85% for the pristine sample to 92.83% for ILs treated C16-QDs@SiO2. Furthermore, the stability of the ILs-treated C16-QDs@SiO2 was notably enhanced, with the fluorescence intensity retaining 80.5% after 40 days of storage. The as-prepared white light emitting diode (LED) displayed a high color rendering index (CRI) of 75.3 and a correlated color temperature (CCT) of 7529 K. This work provides an alternative strategy to solve the challenging stability issue of silica-coated perovskite QDs and promote the silica-coated perovskite QDs to the practical application in solid-state LEDs.

Color Rendering Index over 95 Achieved by Using Light Recycling Process Based on Hybrid Remote-Type Red Quantum-Dot Components Applied to Conventional LED Lighting Devices.

Red color conversion materials have often been used in conventional white LEDs (light-emitting diodes) to enhance the insufficient deep-red component and thus improve the color-rendering property. Quantum dots (QDs) are one of the candidates for this due to their flexibility in controlling the emission wavelength, which is attributed to the quantum confinement effect. Two types of remote QD components, i.e., QD films and QD caps, were prepared and applied to conventional white LED illumination to improve the color-rendering properties. Thanks to the red component near 630 nm caused by the QD components, the color rendering indices (CRIs) of both Ra and R9 could be increased to over 95. It was found that both the diffusing nature of the reflector and the light recycling process in the vertical cavity between the bottom reflector and the top optical films play important roles in improving the color conversion efficiency of remote QD components. The present study showed that the proper application of remote QDs combined with a suitable optical cavity can control the correlated color temperature of the illumination over a wide range, thus realizing different color appearances of white LED illumination. In addition, a high CRI of over 95 could be achieved due to the sufficient excitation from fewer QDs, due to the strong optical cavity effect.

Thermal and Optical Analysis of Quantum-Dot-Converted White LEDs in Harsh Environments

Quantum-dot-converted white LEDs (QD-WLEDs) are promising in both lighting and display applications owing to their high luminous efficiency (LE) and high color-rendering index (CRI). However, their working lifetime is severely limited by the poor reliability of QDs and the LED package. In this work, the variation in photothermal parameters in QD-WLEDs during aging was investigated, and the effect of QDs and the LED package on the optical performance of QD-WLEDs was analyzed. First, the optical properties of phosphor–silicone, QD–silicone, and silicone were measured during the 524 h aging process at 80 °C and 100 °C, respectively. QD-WLEDs with high optical performance were packaged and aged under the same conditions to investigate the variation in their optical parameters and analyze the trends of their CRIs and correlated color temperatures (CCTs). According to the experimental results and the calculation models of the spectra, it was found that the changes in optical parameters are mainly caused by the degradation of QDs, and the aging of QDs has different effects on the CRI and CCT. The analysis of the energy-transfer process shows that the decrease in luminous flux of QD-WLEDs during the aging process is mainly caused by the aging of silicone. Based on optical and thermal analysis, this study proposed different optimization strategies for optical quality and lifetime in the LED design process.

High Emission Efficiency and Thermal Stability in Zero-Dimensional Hybrid Zinc Halide as a Blue Light Emitter.

Exploring highly efficient blue-emissive lead-free halide materials is a significant and challenging objective in the study of luminescent materials. This study reports the synthesis of a new zero-dimensional (0D) hybrid zinc halide of [CYP]ZnBr4 (CYP = 1-cyclohexylpiperazine) containing an isolated [ZnBr4]2- tetrahedron. [CYP]ZnBr4 exhibits strong blue light emission with a high photoluminescence quantum yield (PLQY) of 79.22%, surpassing all previously reported 0D zinc halide counterparts. According to the theoretical and experimental studies, the blue light emission is attributed to intrinsic self-trapped excitons resulting from strong electron-phonon coupling and structural deformation. Importantly, [CYP]ZnBr4 demonstrates excellent structural and luminescence stability toward high temperatures (180 °C) over at least half a month. High luminescence efficiency and stability enable [CYP]ZnBr4 to be an efficient blue phosphor to fabricate white light-emitting diodes (LEDs), which produces high-quality white light with a color rendering index (CRI) of 93.1 and a correlated color temperature (CCT) of 5304 K, closely resembling natural sunlight. This white LED also exhibits consistent performance and stability across different drive currents, suggesting the potential for high-power optoelectronic applications. Overall, this study paves the way for the utilization of 0D hybrid halides in advanced solid-state lighting applications.

Multifunctional Crystalline Coordination Polymers Constructed from 4,4'-Bipyridine-N,N'-dioxide: Photochromism, White-Light Emission, and Photomagnetism.

Multifunctional photochromic coordination polymers (CPs) have shown great potential in many areas, like molecular switches, anticounterfeiting, magnetics, and optoelectronics. Although multifunctional photochromic CPs can be obtained by introducing photoresponsive functional units or by exploiting the synergy effect of each component, relatively limited photochromic ligands hinder the development of various multifunctional photochromic CPs. In this work, we reported two multifunctional coordination polymers {[Zn(bpdo)(fum)(H2O)2]}n (1) and {[Mn(bpdo)(fum)(H2O)2]}n (2) based on an easily accessible but underestimated photoactive molecule 4,4'-bipyridine-N,N'-dioxide (bpdo). Compound 1 exhibits photochromism and white-light emission with an ultra-high color rendering index (CRI) of 92.1. Interestingly, compound 1 could emit intrinsic white light in the crystalline state upon UV irradiation both before and after photochromism. Meanwhile, compound 2 displays photochromic and photomagnetic properties, induced by the photogenerated radicals via a photoinduced electron transfer mechanism.

Orange-red-emitting BaSrGd4O8:Sm3+ phosphors with high thermal stability for applications in w-LEDs and latent fingerprints

Orange-red BaSrGd4O8:Sm3+ phosphors were obtained by a high-temperature solid-phase reaction. During this study, lattice environment, phase purity, element distribution, Photoluminescence (PL) spectra, thermal stability, and color purity of BaSrGd4O8:Sm3+ was systematically explored. The phosphors present a strong excitation with the charge transfer band (CTB) of O2− and Sm3+at 253 nm. Under 253 nm excitation, the BaSrGd4O8:Sm3+ phosphor shows characteristic peaks at 566, 605, 651, and 708 nm, which can be consistent with the 5G5/2→6HJ (J = 5, 7, 9, 11). And 605 nm is the most vigorous emission. The optimal doping concentration of BaSrGd4O8: Sm3+ is x = 1 mol%. Notably, as the temperature rises to 420 K, the BaSrGd4O8:Sm3+ still has outstanding thermal stability, reaching 95.38% of the initial luminescence intensity. Internal quantum efficiency (IQE) is tested as 64.83%. After calculation, the color purity of all phosphors reaches 96.5% or above. In addition, the w-LED (white light emitting diode) and single-colored LED were successfully prepared with 405 nm chips. The CIE (Commission International de L' Eclairage) coordinate of the packaged w-LED is (0.348, 0.335), which has the high color rendering index (CRI) of 90. Besides, the latent fingerprints (LFPs) visualized by BaSrGd4O8:Sm3+ phosphor can be clearly displayed. These experimental results exhibit the BaSrGd4O8:Sm3+ orange-red phosphors have promising application prospects in lighting devices and LFPs.

Efficient Semitransparent Organic Solar Cells with CRI over 90% Enabled by an Ultralow‐Bandgap A‐DA'D‐A Small Molecule Acceptor

AbstractSemitransparent organic solar cells (ST‐OSCs) can function as power‐generating windows due to their ability to allow visible light go‐through for human eyesight while absorbing low‐energy photons in the near‐infrared region for photocurrent generation. In this regard, effective ST‐OSCs with high light utilization efficiency (LUE) and color rendering index (CRI) can be developed via a synergistic material and device engineering strategy. Herein, an A‐DA'D‐A acceptor BZO‐4Cl is synthesized with an ultralow optical bandgap of 1.26 eV and bathochromically shifted absorption of roughly 60 nm with respect to Y6. Initially, the opaque devices using PTB7‐Th as the donor show a high power conversion efficiency (PCE) of 14.12% , which can be listed as one of the highest efficiencies for the PTB7‐Th‐based OSCs so far. Then, through these efforts of optimizations in the bulk‐heterojunction(BHJ) composition, top electrodes and anti‐reflection layer, the cutting‐edge ST‐OSC demonstrates a high LUE of 4.02%, and a CRI of 90.67%, making it one of the best‐performing ST‐OSCs with both high LUE and CRI values. These results indicate that the ST‐OSCs presented in this study have significant potential for use in applications that possess transparent visible light and energy‐generation functions.

Tunable phosphor properties of the CaAl2SiO6 polycrystals doped with chromium, manganese and vanadium ions

Aluminosilicate CaAl2SiO6 (CASO) polycrystals doped with chromium, manganese, and vanadium ions have been synthesized using the sol-gel method. The XRD diffractograms, absorption, excitation, and emission spectra, as well as the decay time profiles, were measured and analyzed. Racah parameters, chromatic coordinates, color purity, color rendering index (CRI), and correlated color temperature (CCT) were estimated for the selected samples. The influence of spectroscopic properties, depending on doped ions and excitation wavelength was analyzed.

Novel solution and solid-state emissive long-wavelength carbon dots for water sensing and white LED applications

Carbon dots (CDs) are among the most popular nanomaterials due to their remarkable fluorescent and electronic properties, as well as their good biocompatibility and low cytotoxicity. Currently, CDs with aggregation-induced emission (AIE) are relatively rare and have become a significant research hotspot. This is because most conventional CDs suffer from severe quenching in a solid state. Herein, novel CDs with both solution and solid-state emissions were obtained using a facile one-step hydrothermal synthesis. Specifically, the CDs exhibit yellow solvent-dependent fluorescence in solution state (λem = 580 nm) and red AIE emission in solid state (λem = 640 nm). CDs powder is utilized as a red phosphor for light-emitting diode (LED). The resulting fabricated white LEDs (WLEDs) demonstrate good performance metrics, including a Color Rendering Index (CRI) of 89.5, Correlated Color Temperature (CCT) of 3876 K, and commission Internationale d’Éclairage (CIE) coordinates of (0.350, 0.331). Furthermore, the solvent-dependent phenomenon observed in AIE-CDs can be exploited to apply their solution as a highly sensitive fluorescence sensor for quantitatively detecting amounts of water in various organic solvents. The method offers both high accuracy and sensitivity, with R2 values varying from 0.853 to 0.994 and a low detection limit ranging from 0.296 to 3.23 % across a wide linear range. This inherent versatility makes the CDs suitable for a wide range of applications, including sensing and LED devices.

Solid-State, Hectogram-Scale Preparation of Red Carbon Dots as Phosphor for Energy-Transfer-Induced High-Quality White LEDs with CRI of 97.

In this study, pre-crystallization-controlled, solid-state preparation of red carbon dots (C-dots) from o-phenylenediamine on a hectogram scale with a 94% yield is reported. Highly efficient red phosphor (C-dots@MCC) is obtained by dispersing the C-dots in microcrystalline cellulose, which matched extremely well with the commercial Y3 Al5 O12 :Ce3+ (YAG) phosphor. White light-emitting diodes (WLEDs) fabricated from the two phosphors emitted warm white light with a correlated color temperature of 3845 K, CIE color coordinates of (0.38, 0.37), and an extremely high color rendering index (CRI) of 95, outperforming all the reported YAG-derived WLEDs. Furthermore, the CRI value of the WLED can be further increased to 97 after fine-tuning, which is the highest CRI for WLEDs of any C-dots derived devices reported so far. The superior performance of the WLED is attributed to a delicate energy transfer between YAG and C-dots@MCC. Most importantly, the WLED maintained excellent stabilities under varied currents, working durations, moistures, and temperatures.

Fabrication of Al2O3[sbnd]GAGG:Ce composite ceramic phosphors with excellent color quality for high-power laser-driven lighting

The application of high-power laser-driven lighting is limited by the insufficient heat dissipation of phosphor converters and the poor color quality of white light. In this study, the Al2O3(Gd,Ce)3(Al,Ga)5O12 (Al2O3GAGG:Ce) composite ceramics were designed to improve thermal performance of phosphors, while maintaining excellent color rendering under high-power laser excitation. Dense composite ceramics were fabricated by pre-sintering at 1600 °C in air followed by HIP at 1700 °C through the investigation of the phase evolution and sintering process. The emission spectrum of GAGG:Ce shows a red shift of 31 nm and a high full width at half maximum (FWHM) of 128 nm. Meanwhile, the thermal conductivity was increased to 13.2 W·m−1K−1 by addition of Al2O3, which is 72% higher than that of single-phase GAGG:Ce ceramic. Therefore, warm white light with high color rendering index (CRI) of 71.4 and low correlated color temperature (CCT) of 4352 K was attained under excitation of high-power LDs.

Pivotal role of Boron-doped graphene quantum dots in stretchable and Self-Healable red emission nanocomposite Film: One step advance for white light emitting diodes application

In this study, red-emitting BGQDs were prepared by a hydrothermal method derived from 1,3,6-Trinitropyrene (TNP) and boric acid. The luminescence properties of as-synthesized BGQDs were characterized through photoluminescence (PL), time-resolved photoluminescence (TRPL), and UV–Vis measurements. After the modification of boron doping, B-GQDs demonstrated superior optical properties and chemical stability compared to pristine ones. For the sake of continued stability in the luminescent layer performance derived from BGQDs, poly{(n-butyl acrylate)–co-[N-(hydroxymethyl)acrylamide]} (PBA0.8-co-PNMA0.2) as an amphiphilic copolymer matrix with tunable mechanical, elastic, and self-healing properties was introduced. Through the synergistic effects between BGQDs and amphiphilic copolymer side chain, the physical and mechanical properties of the red-emitting nanocomposite film were impressively improved. Furthermore, white light-emitting diodes (WLEDs) were successfully fabricated by combining a 450 nm GaN chip, a commercial green-emitting (Ba,Sr)2SiO4:Eu2+ phosphor, and a self-healable red-emitting nanocomposite film, generating a high color rendering index (CRI) value of 89.4.

Full-spectrum and tunable white light emission of germanate glass-ceramic containing defective Zn2GeO4 and Mn2+ ions

The full-spectrum phosphors are key components for improving the light quality of phosphor-converted white light-emitting diodes (pc-WLEDs). In this work, a novel germanate glass-ceramic (GC) doped with Mn2+ was developed to achieve full-spectrum white light emission deriving from the defective Zn2GeO4 crystalline phase and Mn2+ with multisite occupancy. The defective Zn2GeO4 is crystallized in situ from the well-designed precursor germanate glass by a controllable heat treatment. The energy states of intrinsic defects, including oxygen and zinc vacancies and interstitial zinc and oxygen of Zn2GeO4 in GC, have been studied by first-principles calculations. The luminescence property and the energy transfer mechanism between the defect states and Mn2+ ions in the GC material was proposed. Under the UV excitation, the luminescence property can be tuned by adjusting the distribution of Mn2+ ions in between the glassy and crystalline phases. The correlated color temperature (CCT) and color rendering index (CRI) of the UV-excited full-spectrum white light emission can be tuned over a wide range. This combinatorial strategy of intrinsic defects and multisite ion doping for full-spectrum white light emission in GC, which overcomes the limitation of conventional discontinuous white light emitting materials that emit singly from doping ions, has shown good potential for application in pc-WLEDs.

Study on the structure and luminescence properties of a novel Li3Sc2(PO4)3: Eu3+ orange-red emission phosphor for wLEDs

The manufacture of high-efficiency and stable red phosphor is the key to solve the matter of high color temperature and poor color rendering of commercial white light-emitting diodes (wLEDs). In this work, a series of Li3Sc2-x(PO4)3: xEu3+ (x = 0–0.4) phosphor samples were prepared by conventional solid-phase reaction. The structure and optical properties of Li3Sc2(PO4)3: Eu3+ are investigated. When the doping amount of Eu3+ is 0.3 mol, phosphors have the highest luminescence intensity. The temperature-dependent characteristics of the prepared phosphors are studied. The combined emission intensity at 423K is 77.4% of that at 298K, showing significant thermal stability. Finally, the prepared Li3Sc2(PO4)3 phosphor package is tested in the LED device. The results of the color temperature of 5423K, as well as color rendering index (CRI) (Ra = 81.6) and color coordinate CIE (0.3343, 0.3471), are satisfactory, suggesting that this red phosphor has potential for wLEDs applications.

Luminescent properties of the Sr8−xBaxMgY(PO4)7:Eu2+ solid solution

Photoluminescence generated by substituting rare-earth ions on multiple crystallographically independent cation sites within a crystalline host material is one of the most common approaches for creating a full-spectrum phosphor-converted white light-emitting diode (pc-wLED). In this work, a series of complex orthophosphates with the composition (Sr8−xBax)0.99Eu0.08MgY(PO4)7 (x = 0, 1, 2, 3) were synthesized via high-temperature solid-state synthesis. These materials possess five potential substitution sites achieving broadband (5905 cm−1) yellow photoluminescence through multi-site substitution showing a violet-excited photoluminescent quantum yield of nearly 50%. Developing such an efficient broad emission spectrum is crucial for enhancing the color rendering ability of pc-wLEDs. Varying the Sr2+ to Ba2+ shifts the emission color from green-yellow to yellow under violet excitation (λex = 400 nm) while influencing the full-width-at-half-maximum (fwhm). Temperature-dependent photoluminescence measurements indicate that phosphor has good thermal stability with T50, the temperature at which the emission intensity is half of the low-temperature intensity, at 420 K and stable chromaticity coordinates, further supporting that the (Sr8−xBax)0.99Eu0.08MgY(PO4)7 series are promising candidates for LED white lighting. Constructing a prototype pc-wLEDs device using (Sr7Ba)0.99Eu0.08MgY(PO4)7, the highest quantum yield phosphor, produced a functional daylight bulb with a color rendering index (CRI) of 90.

Intense green light emission in Sr2 ZnGe2 O7 :Mn2+ phosphors by the design of high symmetry melilite structure.

A green phosphor Sr2 ZnGe2 O7 :Mn2+ with a melilite structure was prepared using a high-temperature solid-state reaction. When the 535 nm emission was monitored, the excitation spectrum of the Sr2 ZnGe2 O7 :Mn2+ was found to contain two excitation bands in the ultraviolet (UV) region. When excited by UV light, the sample shows bright green emission at 535 nm, which corresponds to the distinctive transition of Mn2+ (4 T1 →6 A1 ). Moreover, the quantum efficiency of Sr2 ZnGe2 O7 :Mn2+ could reach 67.6%. Finally, a high-performance white-light-emitting diode (WLED) with a low correlated colour temperature of 4632 K and a high colour rendering index (CRI) of 92.3 were packaged by coating commercial blue and red phosphors with an optimized Sr2 ZnGe2 O7 :Mn2+ sample on a 310 nm UV chip. This indicated that Sr2 ZnGe2 O7 :Mn2+ has the potential application as a green component in the WLED lighting field.

The Spotlight Based on the Solid-State Laser Light Source

The spotlight development on the solid-state laser light source is considered in this scientific article. The light sources characteristics are as close as possible to the characteristics and parameters of modern LED light sources. The main aim is to reach the luminous flux value of 3000 lm. That is analogues with the luminous flux of modern LED searchlights. As well as the photometric and electrical parameters, values and determination of the measures to improve the design of the spotlight are of the interest. The spotlight sample has been tested. And the test results show that after the value of 3000 lm reached the main failing of light source is the low value of its luminous efficacy, equal to 57 lm/W. In order to increase the light output of the searchlight, there are the ways of modernization of its construction suggested in the article. The previous results show that the measures suggested will allow us to increase the value of luminous efficacy to 100 lm/W. Besides that, such parameters and characteristics of the spotlight as the correlated colour temperature (CCT), colour rendering index (CRI), wattage, luminous intensity and spectral light distribution are measured and submitted in the article. The obtained energetic characteristics of the sample allow us to conclude that application of such light sources is approved in special conditions. Absence of electronic components in the distant radiation source of white light allows increasing the light source reliability substantially. Therefore, the laser spotlights are acceptable for application in the hard-to-reach places for installation of the lighting equipment, for example, on high places where the equipment demount used for repairing works is too difficult. It is actually to use also the developed light sources at the explosive industrial facilities having the current-transmitting elements of construction, especially having the open contacts. That allows reducing the safety of facility operation significantly.

Zero-Dimensional Halides with ns2 Electron (Sb3+) Activation to Generate Broad Photoluminescence.

Organic-inorganic metal halides (OIMHs) have various crystal structures and offer excellent semiconducting properties. Here, we report three novel OIMHs, (PPA)6InBr9 (PPA = [C6H5(CH2)3NH3]+), (PBA)2SbBr5, and (PBA)2SbI6 (PBA = [C6H5(CH2)4NH3]+), showing typical zero-dimensional (0D) structure, octahedra dimers, and corner-sharing one-dimensional chains and crystallized in the monoclinic system with P21, P21/c, and C2/c space groups, respectively. (PPA)6InBr9, (PBA)2SbBr5, and (PBA)2SbI6 have experimental optical band gaps of ∼3.16, ∼2.24, and 1.48 eV, respectively. (PPA)6InBr9 exhibits bright-orange light emission centered at 642 nm with a full-width at half-maximum of 179 nm (0.51 eV) and a Stokes shift of 277 nm (1.46 eV). After Sb3+ doping, the peak position did not change, and the photoluminescence quantum yield increased significantly from 9.2 to 53.0%. The efficient emission of Sb:(PPA)6InBr9 stems from the isolated ns2 luminescent center and strong electron-phonon coupling, making the spin-forbidden 3P1-1S0 observable. By combining commercial blue and green phosphors with orange-red-light-emitting (PPA)6In0.99Sb0.01Br9, a white-light-emitting diode was constructed, with the color-rendering index reaching up to 92.3. Our work highlights three novel 0D OIMHs, with chemical doping of Sb3+ shown to significantly enhance the luminescence properties, demonstrating their potential applications in solid-state lighting.