Collision Energy Research Articles

Observation of geometric phase effect through backward angular oscillations in the H + HD → H2 + D reaction

Quantum interference between reaction pathways around a conical intersection (CI) is an ultrasensitive probe of detailed chemical reaction dynamics. Yet, for the hydrogen exchange reaction, the difference between contributions of the two reaction pathways increases substantially as the energy decreases, making the experimental observation of interference features at low energy exceedingly challenging. We report in this paper a combined experimental and theoretical study on the H + HD → H2 + D reaction at the collision energy of 1.72 eV. Although the roaming insertion pathway constitutes only a small fraction (0.088%) of the overall contribution, angular oscillatory patterns arising from the interference of reaction pathways were clearly observed in the backward scattering direction, providing direct evidence of the geometric phase effect at an energy of 0.81 eV below the CI. Furthermore, theoretical analysis reveals that the backward interference patterns are mainly contributed by two distinct groups of partial waves (J ~ 10 and J ~ 19). The well-separated partial waves and the geometric phase collectively influence the quantum reaction dynamics.

Design optimization of the bamboo-inspired foam-filled tube for high-speed train collision energy absorption

This study first developed a novel bamboo-inspired foam-filled tube (BFFT) for potential application in high-speed trains, considering the practical use conditions. The BFFT was initially designed by mimicking the macro and micro characteristics of bamboo culms and understanding their axial crushing mechanical behavior. The key bionic parameters are drawn based on the crashworthiness indices of natural bamboos with various geometric sizes and growth ages. The numerical simulation model of the BFFT under axial impact load was established and verified using simplified super folding element (SSFE) theory and drop-weight experiments. A multi-objective optimization on the BFFT was conducted to find the optimal parameter alternative, integrating experimental design method of the optimal Latin hypercube, the response surface agent model and the non-dominated sorting genetic algorithm (NSGA-II). The crashworthiness performance of the optimized BFFT was compared with the initial design scheme, a conventional circular tube and other existing energy absorbers of rail vehicles. The results indicated that the EA, SEA and IPCF values of the optimized BFFT can be improved by 150.2 %, 63.3 %, and 48.5 %, respectively, when considering the single target requirement. In comparison to the initial design scheme and conventional circular tube, the SEA value of the final optimized BFFT increased by 44.7 % and 53.0 %, respectively. The proposed novel BFFT demonstrated a superior crashworthiness, providing inspiration for enhancing and optimizing passive safety performance of high-speed trains.

Fine-Scale Characterization of Plant Diterpene Glycosides Using Energy-Resolved Untargeted LC-MS/MS Metabolomics Analysis.

Plant diterpene glycosides are essential for diverse physiological processes. Comprehensive structural characterization proved to be a challenge due to variations in glycosylation patterns, diverse aglycone structures, and the absence of comprehensive reference databases. In this study, a method for fine-scale characterization was proposed based on energy-resolved (ER) untargeted LC-MS/MS metabolomics analysis using steviol glycosides as a demonstration. Energy-dependent fragmentation patterns were unveiled by a series of model compounds. Distinct glycosylation sites were discerned by leveraging varying fragmentation energies for the precursor ions. The sugar moiety linkage at C19OOH (R1) exhibited facile and intact cleavage at low collision energies, while the sugar moiety at C13-OH (R2) demonstrated consecutive cleavage with increasing energy. Aglycone ions exhibited a higher relative intensity at NCE 50, with relative intensities ranging from 95% to 100%. Subsequently, aglycone candidates, R1 sugar composition, and R2 sugar sequence were deduced through ER-MS/MS analysis. The developed method was applied to Stevia rebaudiana leaves. A total of 91 diterpene glycosides were unambiguously identified, including 16 steviol glycosides with novel acetylglycosylation patterns. This method offers a rapid alternative for glycan analysis and the structural differentiation of isomers. The developed method enhances the understanding of diterpene glycosides in plants, providing a reliable tool for the in-depth characterization of complex metabolite profiles.

Probing valence quark width of the proton in deeply virtual Compton scattering at high energies* *Supported by the National Natural Science Foundation of China (12165004), the Basic and Applied Basic Research Project of Guangzhou Science and Technology Bureau (202201011324), the Education Department of Guizhou Province, China (QJJ[2022]016) and the National Key Research and Development Program of China (2018YFE0104700, CCNU18ZDPY04)

We use the refined hot spot model to study the valence quark shape of the proton with the deeply virtual Compton scattering at high energies in the color glass condensate framework. To investigate the individual valence quark shape, a novel treatment of the valence quark width is employed. We calculate the cross-sections for coherent and incoherent deeply virtual Compton scattering using, for the first time, different widths ( and ) for the profile density distributions of the up and down quarks instead of using the same width as in the literature. We find that the cross-sections calculated with at each collision energy are consistent with each other, which is in agreement with theoretical expectations, whereas those computed with show some discrepancies. This outcome implies that the up quark might emit more gluons than the down quark, leading to at high energy. The impact of energy on the outcome is estimated. Our results show that as the collision energy increases, the aforementioned discrepancies are not only significantly broadened, but also shift to a relatively smaller momentum transfer range at the future Electron-Ion Collider (EIC) and Large Hadron Electron Collider (LHeC) energies, which indicates that the EIC and LHeC can provide an unprecedented chance to access the shape of the valence quark of the proton.

Chemical freeze-out parameters via a functional renormalization group approach

We study the freeze-out parameters in a QCD-assisted effective theory that accurately captures the quantum and in-medium effects of QCD at low energies. The functional renormalization group approach is implemented in our work to incorporate the nonperturbative quantum, thermal, and density fluctuations. By analyzing the calculated baryon number susceptibility ratios χ2B/χ1B and χ3B/χ2B, we determine the chemical freeze-out temperatures and baryon chemical potentials in cases of hard thermal or dense loop improved μ-dependent gluon potential and μ-independent gluon potential. We calculate the χ4B/χ2B(κσ2) and χ6B/χ2B along the freeze-out line for both cases. It is found that κσ2 exhibits a nonmonotonic behavior in a low collision energy region and approaches one for lower collision energy. χ6B/χ2B shows a similar complicated behavior in our calculation. Published by the American Physical Society 2024

Momentum correlation of light nuclei in Au + Au collisions at [formula omitted] GeV

Within the Ultra-relativistic Quantum Molecular Dynamics model (UrQMD) coupled with nucleon coalescence model and Mini-Spanning-Tree model, the yields of light nuclei have been stimulated in Au + Au collisions over an energy range of sNN=2.0∼7.7GeV and the momentum correlation functions of light nuclei pairs have been calculated by both the Lednický-Lyuboshitz and the Correlation After Burner methods. We compare the yields of light nuclei and their momentum correlation functions at midrapidity in this energy region with experimental data. It is found that there are differences between the results of the two models, and the coalescence method seems less valid at low collision energy. Furthermore, both the peak values of proton-proton correlation functions and the transition point of elliptic flows from out-of-plane to in-plane emission show a turning point around 3-4 GeV, which suggests that there is a relation between momentum correlation function and collective flow of particles.

Enantioselective Reduction of Noncovalent Complexes of Amino Acids with CuII via Resonant Collision-Induced Dissociation: Collision Energy, Activation Duration Effects, and RRKM Modeling.

Formation of noncovalent complexes is one of the approaches to perform chiral analysis with mass spectrometry. Enantiomeric distinction of amino acids (AAs) based on the relative rate constants of competitive fragmentations of quaternary copper complexes is an efficient method for chiral differentiation. Here, we studied the complex [CuII,(Phe,PhG,Pro-H)]+ (m/z 493) under resonant collision-induced dissociation conditions while varying the activation time. The precursor ion can yield two main fragments through the loss of the non-natural AA phenylglycine (PhG): the expected product ion [CuII,(Phe,Pro-H)]+ (m/z 342) and the reduced product ion [CuI,(Phe,Pro)]+ (m/z 343). Enantioselective reduction describes the difference in relative abundance of these ions, which depends on the chirality of the precursor ion: the formation of the reduced ion m/z 343 is favored in homochiral complexes (DDD) compared to heterochiral complexes (such as LDD). Energy-resolved mass spectrometry data show that reduction, which arises from rearrangement, is favored at a low collision energy (CE) and long activation time (ActT), whereas direct cleavage preferentially occurs at a high CE and short ActT. These results were confirmed with kinetic modeling based on RRKM theory. For this modeling, it was necessary to set a pre-exponential factor as a reference, so that the E0 values obtained are relative values. Interestingly, these simulations showed that the critical energy E0 required to form the reduced ion is comparable in both homochiral and heterochiral complexes. However, the formation of product ion m/z 342 through direct cleavage is associated with a lower E0 in heterochiral complexes. Consequently, enantioselectivity would not be caused by enhanced reduction in homochiral complexes but rather by direct cleavage being favored in heterochiral complexes.

Mid-Infrared Generated Laser-Induced Grating Signals in Methane-Containing Gas Mixtures as Indicators of Composition, Pressure, and Temperature.

The present work is aimed at studying how spatially periodic modulations of the refractive index of the medium, i.e., laser-induced gratings (LIGs), generated in a gas mixture containing methane (CH4) by nanosecond pulses of resonant mid-infrared laser radiation, can be used to measure various gas parameters. It is investigated to what extent the temporal profiles of the LIG signals, recorded as the power of the diffracted by LIGs continuous wave probe radiation, are specific to the composition, pressure, and temperature of a selected buffer gas. This specificity is illustrated by the LIG signal profiles recorded in the experiments in different gas mixtures under various conditions. Experimental data show that large LIG signals can be obtained even in mixtures with CH4 concentrations as low as ∼100 parts per million due to the strong absorption of the excitation light and subsequent rapid, highly exothermic, and partner-dependent collisional energy exchange of the laser-excited molecules with the environment. These two factors ensure high LIG generation efficiency by a small number of CH4 molecules and high sensitivity of signal strength and profile to variations of gas parameters.

Time evolution of natural orbitals in abinitio molecular dynamics.

This work combines for the first time abinitio molecular dynamics (AIMD) within the Born-Oppenheimer approximation with a global natural orbital functional (GNOF), an approximate functional of the one-particle reduced density matrix. The most prominent feature of GNOF-AIMD is its ability to display the real-time evolution of natural orbitals, providing detailed information on the time-dependent electronic structure of complex systems and processes, including reactive collisions. The quartet ground-state reaction N(4S) + H2(1Σ) → NH(3Σ) + H(2S) is taken as a validation test. Collision energy influences on integral cross sections for different initial rovibrational states of H2 and rotational-state distributions of the NH product are discussed, showing a good agreement with previous high-quality theoretical results.

Coupled 3D (J ≥ 0) Time-Dependent Wave Packet Calculation for the F + H2 Reaction on Accurate Ab Initio Multi-State Diabatic Potential Energy Surfaces.

We had calculated adiabatic potential energy surfaces (PESs), nonadiabatic, and spin-orbit (SO) coupling terms among the lowest three electronic states (12A', 22A', and 12A″) of the F + H2 system using the multireference configuration interaction (MRCI) level of theory, and the adiabatic-to-diabatic transformation equations were solved to formulate the diabatic Hamiltonian matrix [J. Chem. Phys. 2020, 153, 174301] for the entire region of the nuclear configuration space. The accuracy of such diabatic PESs is explored by performing scattering calculations to evaluate integral cross sections (ICSs) and rate constants. The nonadiabatic and SO effects are studied by utilizing coupled 3D time-dependent wave packet formalism with zero and nonzero total angular momentum on multiple adiabatic/diabatic surfaces calculation. We depict the convergence profiles of reaction probabilities for the reactive as well as nonreactive processes on various electronic states at different collision energies with respect to total angular momentum including all helicity quantum numbers. Finally, total ICSs are calculated as functions of collision energies for the initial rovibrational state (v = 0, j = 0) of the H2 molecule along with the temperature-dependent rate coefficient, where those quantities are compared with previous theoretical and experimental results.

Automated potential energy surface development and comprehensive dynamics for the F + CH3NH2 reaction.

This work is an extensive investigation of the F + CH3NH2 reaction dynamics using a newly-developed potential energy surface (PES). The full-dimensional spin-orbit (SO) corrected (MRCI+Q/aug-cc-pwCVDZ) PES is developed by the Robosurfer program package and the ManyHF method is used in order to fix the Hartree-Fock (HF) convergence issues in the entrance channel. On the surface, retrieved by the fitting of the iteratively extended set of the ManyHF-CCSD(T)-F12a/triple-zeta-quality and SO-corrected energy points, quasi-classical trajectory (QCT) simulations are run. By analyzing the opacity functions and integral cross sections (ICSs) of six reaction channels, the dynamics of the two most reactive hydrogen-abstraction reactions resulting in HF + CH2NH2/CH3NH products are selected for a thorough examination. Despite the statistically and thermodynamically expected results, the kinetically preferred amino hydrogen-abstraction is the dominant mechanism at low collision energies. The initial attack angle and scattering angle distributions are investigated as well. The post-reaction energy distributions show that the collision energy mostly converts into the translational energy of the products, while the reaction energy excites the vibration of the products. The computed vibrationally resolved rotational distributions and vibrational state distributions of the HF product are compared to experimental data, and the theory and experiment are found to be in good agreement.

Investigating the crash-box-structure’s ability to absorb energy

Protection under external loads often requires the use of energy absorbers. They are designed to absorb impact energy in a controlled way protecting the structures, as well as their possible occupants. This study examines the crushing performances of thin structures, made in sheet metal, as their shape and thickness vary. Three crash-box-structures were considered for their geometries (i.e. rectangular, rectangular with two inclined walls, and truncated pyramidal structures) with two variations in thicknesses (i.e. s = 1 and 2 mm). Their elastic-plastic behaviour under low-speed compression was analysed by experiments and simulations. The collision force reduction and energy absorption were compared. Based on outcomes a new absorber was developed and used for improving safety in the case of an innovative ultra-light solar racing vehicle.

Reactivity of the Ethenium Cation (C2H5+) with Ethyne (C2H2): A Combined Experimental and Theoretical Study.

The gas-phase reaction between the ethyl cation (C2H5+) and ethyne (C2H2) is re-investigated by measuring absolute reactive cross sections (CSs) and branching ratios (BRs) as a function of collision energy, in the thermal and hyperthermal energy range, via tandem-guided ion beam mass spectrometry under single collision conditions. Dissociative photoionization of C2H5Br using tuneable VUV radiation in the range 10.5-14.0 eV is employed to generate C2H5+, which has also allowed us to explore the impact of increasing (vibrational) excitation on the reactivity. Reactivity experiments are complemented by theoretical calculations, at the G4 level of theory, of the relative energies and structures of the most relevant stationary points on the reactive potential energy hypersurface (PES) and by mass-analyzed ion kinetic energy (MIKE) spectrometry experiments to probe the metastable decomposition from the [C4H7]+ PES and elucidate the underlying reaction mechanisms. Two main product channels have been identified at a centre-of-mass collision energy of ∼0.1 eV: (a) C3H3++CH4, with BR = 0.76±0.05 and (b) C4H5++H2, with BR = 0.22±0.02. A third channel giving C2H3+ in association with C2H4 is shown to emerge at both high internal excitation of C2H5+ and high collision energies. From CS measurements, energy-dependent total rate constants in the range 4.3×10-11-5.2×10-10 cm3·molecule-1·s-1 have been obtained. Theoretical calculations indicate that both channels stem from a common covalently bound intermediate, CH3CH2CHCH+, from which barrierless and exothermic pathways exist for the production of both cyclic c-C3H3+ and linear H2CCCH+ isomers of the main product channel. For the minor C4H5+ product, two isomers are energetically accessible: the three-member cyclic isomer c-C3H2(CH3)+ and the higher energy linear structure CH2CHCCH2+, but their formation requires multiple isomerization steps and passages via transition states lying only 0.11 eV below the reagents' energy, thus explaining the smaller BR. Results have implications for the modeling of hydrocarbon chemistry in the interstellar medium and the atmospheres of planets and satellites as well as in laboratory plasmas (e.g., plasma-enhanced chemical vapor deposition of carbon nanotubes and diamond-like carbon films).

A strategy of combining energy‐resolved mass spectrometry and density functional theory for the recognition of forsythoside isomers

RationaleIsomerism is very common in nature, and the mass spectrometry (MS) behavior of isomers is highly similar, making their spectral analysis and identification difficult. Computational chemistry can effectively assist the study of MS spectra and molecule structures. Herein, three isomers of forsythoside (For‐A, For‐H, and For‐I) were successfully identified using energy‐resolved MS combined with density functional theory (DFT).MethodsThe MS scan spectra of the isomers were collected in electrospray ionization MS. The possible positive/negative ion adduct sites were investigated using the DFT method, and the molecular formation energy of each precursor ion was obtained. In the multireaction monitoring mode, the spectra of the common precursor ion → product ion pair of the three isomers were acquired under different collision energy, and the optimal collision energy (OCE) and maximum relative intensity (MRI) of each product ion were obtained. The energy of the broken chemical bond was calculated.ResultsThe experimental data showed that the product ions of [M + H]+ of the three isomers have the greatest differences in OCE and MRI and were the most suitable to distinguish the three isomers. The DFT data showed that there was a good positive correlation between the bond fragmentation energy calculated by the quasi‐molecular ion model and OCE. The results indicated that the energy of precursor ions and corresponding fragments could be correlated with their experimental spectra.ConclusionsA strategy of combining energy‐resolved MS and DFT was implemented on the recognition of forsythoside isomers, and this strategy was expected to be applied to the identification of more isomers.

Collisions of red giants in galactic nuclei

ABSTRACT In stellar-dense environments, stars can collide with each other. For collisions close to a supermassive black hole (SMBH), the collisional kinetic energy can be so large that the colliding stars can be destroyed, potentially releasing an amount of energy comparable to that of a supernova. These black hole-driven disruptive collisions have been examined mostly analytically, with the non-linear hydrodynamical effects being left largely unstudied. Using the moving-mesh hydrodynamics code arepo, we investigate high-velocity (>103 km s−1) collisions between 1 M⊙ giants with varying radii, impact parameters, and initial approaching velocities, and estimate their observables. Very strong shocks across the collision surface efficiently convert ${\gtrsim} 10~{{\ \rm per\ cent}}$ of the initial kinetic energy into radiation energy. The outcome is a gas cloud expanding supersonically, homologously, and quasi-spherically, generating a flare with a peak luminosity ≃1041–1044 erg s−1 in the extreme ultraviolet band (≃10 eV). The luminosity decreases approximately following a power law of t−0.7 initially, then t−0.4 after t ≃ 10 d at which point it would be bright in the optical band (≲1eV). Subsequent, and possibly even brighter, emission would be generated due to the accretion of the gas cloud on to the nearby SMBH, possibly lasting up to multiyear time-scales. This inevitable BH–collision product interaction can contribute to the growth of BHs at all mass scales, in particular, seed BHs at high redshifts. Furthermore, the proximity of the events to the central BH makes them a potential tool for probing the existence of dormant BHs, even very massive ones which cannot be probed by tidal disruption events.

Collision Energy Analysis within the Vertical Shaft Impact Crusher Based on the Computational Fluid Dynamics-Discrete Element Method.

Particles in the vertical shaft impact crusher absorb and dissipate collision energy in the impact breakage. The distribution of the collision energy determines the breakage rate of materials and breakage energy consumption of the entire system. In this paper, the gas-solid coupling method is used to explore the regional distribution of collision energy, collision frequency, and collision energy spectrum of the material particle groups. Hence, a theoretical basis is provided for the efficient and energy-saving design of the crusher. First, a coupling mathematical model of the computational fluid dynamics and discrete element method is established to describe the interaction between material and fluid in the crushing chamber. Moreover, the experiment is carried out using a PL8500 VSI crusher and compared with the simulation results to verify the model's reliability. Finally, the effects of different working conditions on the energy dissipation distribution and energy spectrum are explored. The results show that the collision energy within the crushing chamber can be accurately predicted by using the fluid-solid coupling model. Moreover, increasing the rotational speed can effectively transform low-energy collision events into high-energy collisions and increase the collision frequency with energy dissipation above the threshold energy. Thus, the probability of material breakage is increased. Last, increasing the feed rate minorly affects the material breakage rate, while the specific energy of the entire system is reduced.

Strategy strengthens structural identification through hyphenating full collision energy ramp-MS2 and full exciting energy ramp-MS3 spectra: An application for metabolites identification of rosmarinic acid

“MS/MS spectrum to structure” analysis is the most challenging task for MS/MS-relied qualitative characterization. The conventional database- and computation-assisted strategies cannot reach confirmative identification, notably for isomers. Hence, an advanced strategy was proposed here through tackling the two determinant obstacles such as the transformation from elemental compositions to fragment ion structures and the linkage style amongst substructures. As typical conjugated structures, esters were measured for strategy illustration, and metabolite identification of a famous natural antioxidant namely rosmarinic acid (RosA) in rat was undertaken for applicability justification. Through programming online energy-resolved (ER)-MS for the first collision cell of Qtrap-MS device, full collision energy ramp (FCER)-MS2 spectrum was configured for [M−H]− ion of each ester to provide optimal collision energies (OCEs) for all concerned diagnostic fragment ions (DFIs), i.e. a-, b-, c-, y-, and z-type ions. The linear correlations between masses and OCEs were built for each ion type to facilitate DFIs recognition from chaotic MS2 spectrum. To identify 1st-generation fragment ions, full exciting energy ramp (FEER)-MS3 spectra were configured for key DFIs via programming the second ER-MS in the latter collision chamber. FEER-MS3 spectrum of 1st-generation fragment ion for ester was demonstrated to be identical with FEER-MS2 spectrum of certain hydrolysis product when sharing the same structure. After applying the advanced strategy to recognize DFIs and identify 1st-generation fragment ions, a total of forty metabolites (M1−M40), resulted from hydrolysis, methylation, sulfation, and glucuronidation, were unambiguously identified for RosA after oral administration. Together, the advanced bottom-up strategy hyphenating FCER-MS2 and FEER-MS3 spectra, is meaningful to strengthen “MS/MS spectrum to structure” analysis through recognizing and identifying fragment ions.

Design and Experiment of a Harvesting Header for Wide–Narrow-Row Corn

Aiming to solve the problems of the large harvesting loss and low harvesting efficiency of wide- and narrow-row corn harvesting header in China, a method for the side installation of a header is proposed. A wide–narrow-row corn harvesting header with high working efficiency and low harvesting loss was designed. The collision energy balance equation of corn ears was established. The analysis shows that the kinetic energy change before and after the collision between the ear and the picking plate is the main cause of the shedding of and damage to corn kernels. Based on this, the main structural parameters of the corn harvesting header were designed. Based on the principle of Box–Behnken test, the response surface test was designed. The effects of the plant feeding speed, feeding angle, and rotation speed of a stem pulling roller on harvesting performance were analyzed. The best combination of working parameters was determined: The plant feeding speed was 1.08 m/s, the feeding angle was 52.46°, and the rotation speed of the stem pulling roller was 835.25 r/min. At this time, the grain damage rate was 1.09% and the grain loss rate was 0.14%. The corresponding parameters are verified by experiments. The results show that the grain damage rate was 1.12% and the grain loss rate was 0.14%. The optimization results are essentially consistent with the verification results, which meet the requirements of corn harvesting performance.

High-resolution Tandem Mass Spectrometry for Studying Chemical Constituents of Gynura bicolor DC.

The separation and analysis of the desired chemical components are important subjects for the fundamental research of traditional Chinese medicine (TCM). Ultra-high-performance liquid chromatography quadrupole time-of-flight tandem mass spectrometry (UPLC-Q-TOF-MS/MS) has gradually become a leading technology for the identification of TCM ingredients. Gynura bicolor DC. (BFH), a perennial stemless herb used for medicine and food in China has medicinal effects such as clearing heat, moistening the lung, relieving cough, dispersing stasis, and relieving swelling. Polyphenols and flavonoids contain numerous isomers, which hinder the identification of the complex compounds in BFH. This paper presents a systematic protocol for studying chemical constituents of BFH based on solvent extraction and integrated data via UPLC-Q-TOF-MS. The method described here includes systematic protocols for sample pretreatment, MS calibration, MS acquisition, data processing, and analysis of results. Sample pretreatment includes collection, cleaning, drying, crushing, and extraction. MS calibration consists of multipoint and single-point correction. Data processing includes data importing, method establishment, analysis processing, and result presentation. Representative results of the typical fragmentation pattern of phenolic acids, esters, and glycosides in Gynura bicolor DC. (BFH) are presented in this paper. In addition, organic solvent selection, extraction, data integration, collision energy selection, and method improvement are discussed in detail. This universal protocol can be widely used to identify complex compounds in TCM.

Exploring anisotropic flow via the Boltzmann transport equation employing the Tsallis blast wave description at LHC energies

Anisotropic flows i.e. azimuthal anisotropies in the particle production are one of the important probes in characterizing the properties of the strongly interacting matter created in the relativistic heavy-ion collisions. These observables are sensitive to both the transport properties as well as the equation of state of the quantum chromodynamics matter. We have adopted the Boltzmann transport equation (BTE) in the relaxation time approximation to describe the experimental data for harmonic flows such as elliptic flow (v 2), triangular flow (v 3), quadrangular flow (v 4) obtained in heavy-ion collisions at large hadron collider (LHC) energies. In this analysis, we have used Tsallis statistics as an initial distribution and the Tsallis blast wave description is used as the equilibrium distribution function while describing the evolution of the particle production in BTE. We have fitted the transverse momentum spectra, v 2, v 3, and v 4 of identified hadrons such as pion, kaon, and proton for Pb–Pb and Xe–Xe collisions at the LHC energies of sNN = 5.02 TeV and sNN = 5.44 TeV, respectively for various centralities. Our study offers the comparative analysis between the two distinct collision systems operating at comparable collision energies. The present formulation successfully fits the experimental data for p T - spectra upto p T = 8 GeV and effectively explains the anisotropic flows data upto p T = 10 GeV with a very favourable χ 2/ndf. We observe that the average transverse flow velocity (〈β〉) and the kinetic freeze-out temperature (T) extracted in our analysis decrease as we go towards the peripheral collisions. Non-extensive parameters (q AA and q pp ) exhibit an ascending trend from central to peripheral collisions, signifying an almost thermalized system in the most central collisions and a non-equilibrium state in peripheral ones. The azimuthal modulation amplitudes (ρ a ) for v 2, v 3, and v 4 exhibit an increasing pattern as one moves from the most central to peripheral collisions in both the Pb–Pb and Xe–Xe nuclei interactions.