Collector Surface Research Articles

Thermodynamics, Adhesion, and Wetting at Li/Cu(-Oxide) Interfaces: Relevance for Anode-Free Lithium-Metal Batteries.

A rechargeable battery that employs a Li metal anode requires that Li be plated in a uniform fashion during charging. In "anode-free" configurations, this plating will occur on the surface of the Cu current collector (CC) during the initial cycle and in any subsequent cycle where the capacity of the cell is fully accessed. Experimental measurements have shown that the plating of Li on Cu can be inhomogeneous, which can lower the efficiency of plating and foster the formation of Li dendrites. The present study employs a combination of first-principles calculations and sessile drop experiments to characterize the thermodynamics and adhesive (i.e., wetting) properties of interfaces involving Li and other phases present on or near the CC. Interfaces between Li and Cu, Cu2O, and Li2O are considered. The calculations predict that both Cu and Cu2O surfaces are lithiophilic. However, sessile drop measurements reveal that Li wetting occurs readily only on pristine Cu. This apparent discrepancy is explained by the occurrence of a spontaneous conversion reaction, 2 Li + Cu2O → Li2O + 2 Cu, that generates Li2O as one of its products. Calculations and sessile drop measurements show that Li does not wet (newly formed) Li2O. Hence, Li that is deposited on a Cu CC where surface oxide species are present will encounter a compositionally heterogeneous substrate comprising lithiophillic (Cu) and lithiophobic (Li2O) regions. These initial heterogeneities have the potential to influence the longer-term behavior of the anode under cycling. In sum, the present study provides insights into the early stage processes associated with Li plating in anode-free batteries and describes mechanisms that contribute to inefficiencies in their operation.

Numerical simulation and experimental study on seafloor sampling of an anchor-type mud collector based on SPH-FEM coupling method

Marine sediments are important for research in scientific fields such as marine geology, environmental testing of waters, marine biology and seabed resource exploration. Among them, mud miner is an important way to obtain sediments. However, due to the complexity of the marine environment, the seabed sampling operation is a relatively difficult and complicated project. The structural design of the sampler, the operation mode, and the interaction between the sampler and the sediment affect the sampling effect, which leads to the low efficiency of the sampler operation. In order to investigate the main factors affecting the drag force of the sampler during seafloor sampling, this paper takes a simple and portable anchor-type mud collector surface sediment sampler as a study. This paper introduces the mechanical structure and working principle of an anchor-type mud collector, establishes a mechanical model of the mud collector seafloor sampling process and derives the main factors affecting the dragging force: internal friction angle; the horizontal angle of the bi-directional shaft rod; undercut angle [Formula: see text] of bottom cover and dragging speed. A FEM-SPH method based on the coupling of the finite element method (FEM) and the smooth particle hydrodynamics method (SPH) was proposed to simulate the dynamic process of mud collector subsea sampling, and the mechanical data of fine sand and clay were obtained through land-based experiments. Based on the comparison between experimental data and numerical simulation data, the simulation validity of the FEM-SPH method was verified. The results show that the drag force of the clay was greater than that of the fine sand in the experiment of cutting the lower cover of the mud collector into the fine sand and clay, the internal friction angle of the clay is greater than that of the fine sand; with the increase in horizontal inclination angle and the decrease in undercut angle, the dragging force gradually increased; The dragging speed ranged from 0.2 to 0.6 m/s, with an increase in the mass of clay and fine sand collected with increasing speed, resulting in a gradual increase in dragging force. This paper provides a new method to study the force of the mud collector, provides a theoretical method to reduce the intensity and difficulty of manual work in the sampling process and increase the efficiency of sampling.

Dual roles of goethite coating on the transport of plastic nanoparticles in heterogeneous porous media: The significance of collector surface roughness

This study systematically examines the roles of positive goethite on the retention and release of negative plastic nanoparticles (PSNPs) with different surface functional groups (Blank, -COOH, and -NH2). It provides the first evidence for the dual roles of goethite coatings on colloid transport; e.g., increased transport caused by surface morphology modification or decreased transport due to increased surface roughness and charge heterogeneity. Although previous work has shown that goethite-coated sand increases the retention of negative colloids, this work demonstrates that collector surface roughness can also reduce the retention of PSNPs due to increased interaction energy profiles. Nonmonotonic retention of all the different functionalized PSNPs was observed in goethite-coated rough sand, and the magnitude of variations was contingent on the PSNP functionalization, the solution ionic strength (IS), and the goethite coating. The release of PSNPs with IS decrease (phase I) and pH increase (phase II) varied significantly due to differences in energy barriers to detachment, e.g., release in phase I was inhibited in both goethite-coated sands, whereas release in phase II was enhanced in coated smooth sand but completely inhibited in rough sand. The findings of this study provide innovative insight into transport mechanisms for colloidal and colloid-associated contaminants.

Recent Progress of the Application of Electropolymerization in Batteries and Supercapacitors: Specific Design of Functions in Electrodes

AbstractElectrochemical energy storage devices play a vital role in human life, and the requirements for their sustainability and environmental friendliness have been increasing in recent years. Electropolymerization, as a convenient method for polymer synthesis, has attracted increasing attentions in applications in the field of energy storage and conversion. It is not only commonly employed for the fabrication of various self‐supporting electrodes, but also is one of the most promising preparation strategies for organic electrode materials, internal interlayers within electrodes, functional protective layers, and current collector surface modifications. Previously published works have confirmed that the introduction of electropolymerization can effectively improve the electrochemical performance of various energy storage devices. However, there are still challenges in the universality of the synthesis route, in‐depth understanding of interface chemical behavior, and scaled‐up production. This mini review summarizes the main components in electropolymerization, material synthesis mechanisms, and their application principles in batteries and supercapacitors. Additionally, the current challenges and future development directions of electropolymerization have been discussed, offering some perspectives for further exploration.

Mechanisms of Pore-Clogging Using a High-Resolution CFD-DEM Colloid Transport Model

Colloidal transport and clogging in porous media is a phenomenon of critical importance in many branches of applied sciences and engineering. It involves multiple types of interactions that span from the sub-colloid scale (electrochemical interactions) up to the pore-scale (bridging), thus challenging the development of representative modelling. So far published simulation results of colloidal or particulate transport are based on either reduced set of forces or spatial dimensions. Here we present an approach enabling to overcome both computational and physical limitations posed by a problem of 3D colloidal transport in porous media. An adaptive octree mesh is introduced to a coupled CFD and DEM method while enabling tracking of individual colloids. Flow fields are calculated at a coarser scale throughout the domain, and at fine-scale around colloids. The approach accounts for all major interactions in such a system: elastic, electrostatic, and hydrodynamic forces acting between colloids, as well as colloids and the collector surface. The method is demonstrated for a single throat model made of four spherical segments, and the impact of clogging is reported in terms of the evolution of the critical path diameter for percolation and permeability. We identified four stages of clogging development depending on position and time of individual colloid entrapment, which in turn correlates to a cluster evolution and local transport.

Plasma Surface Treatment of Cu Current Collectors for Improving the Electrochemical Performance of Si Anodes.

The practical utilization of Si electrodes is hindered by their substantial volume expansion during alloying and dealloying processes, which causes mechanical damage and separation from Cu current collectors. To alleviate the problem of Si composite detachment from Cu current collectors, the surface of the Cu current collectors is modified using atmospheric oxygen plasma. Plasma treatment improves the wetting ability of the Cu current collectors and, consequently, the coating quality of the Si electrodes. The uniform distribution of the Si electrode components reduces the sheet resistance and improves the adhesion properties of the Si electrodes containing surface-modified Cu current collectors. As a result, the volume expansion of Si during alloying and dealloying is reduced; this results in an excellent rate capability of 1584 mA h g-1 at a current density of 3.6 A g-1 (135% that of bare Cu) and excellent cycle performance of 1545 mA h g-1 after 300 cycles (Si electrodes with bare Cu exhibit 930 mA h g-1). Therefore, the developed plasma treatment method for Cu current collectors is expected to be an economical and efficient approach for improving the Li-ion battery performance.

Binder-free Cu1.9Bi0.1Se@SWCNT hybrid anodes for lithium-ion and sodium-ion batteries

The rapid growth of portable electronic devices, electric vehicles, and grid-scale energy storage systems has accelerated the demand for enhancing existing materials and innovating new materials in rechargeable battery technologies. Li-ion batteries have dominated the energy storage field among the various battery systems. Na-ion batteries have emerged as promising candidates due to their similarities to Li-ion battery chemistry, low cost, and environmental sustainability. This study explores the potential advantages of synthesizing the binder-free Cu1.9Bi0.1Se@SWCNT heterostructure directly on the copper collector surface. A crucial aspect of this research is the intentional use of nanostructuring during synthesis. This technique capitalizes on the benefits of greater surface area, enhanced electron transport, and superior ionic conductivity. The synthesis method not only ensures excellent electrical and mechanical contact with the collector but also omits the need for a binder, offering a potential for improved overall performance in Li-ion and Na-ion batteries. The electrodes were synthesized using a simple and cost-effective physical vapor deposition method. The structural, morphological, and electrochemical properties of the electrodes were characterized. The binder-free Cu1.9Bi0.1Se@SWCNT electrode with 25 % SWCNT content exhibits excellent performance in Li-ion half cells, maintaining a high energy capacity of 556 mAh g−1 at 0.1 A g−1 over 100 cycles and 244 mAh g−1 at 0.5 A g−1 over 750 cycles. However, in the Na-ion battery system, the performance is notably poorer, revealing challenges and limitations. Most likely, the larger size of sodium ions posed difficulties in intercalation within the anode material structure.

Effect of Distance between Double Glazing on the Performance of a Solar Thermal Collector

In this research paper, an attempt has been made to come across the effect of distance between double glazing on the efficiency of a solar thermal collector. Experiments were carried out on an active solar energy demonstration system (ET 200). Commercial glass pane of 3 mm thick having the same dimensions as that of the apparatus was placed above the collector at a distance of 2 cm, 4 cm and 6 cm. Tests were done with and without the added glass. Experiments were performed for double glazing with two positions of the light meter. In one position, it was placed in the middle of the collector surface. While, in the other, the light meter was placed in the middle of the added glass. To study the effect of double glazing on the performance of the solar collector ET200, the correct position of the light meter was to place it exactly in the middle of the additional pane under the lamp. Double glazing doesn’t enhance the performance of the solar collector because of the high resistance of the system glass air glass. The efficiency of double glazing solar collector decreases with increasing the distance separating the two glasses.

Energy and Exergy Analysis of Forced Convection Solar Drying of Allium Sativum With and With Out Sensible Heat Storage

In this article the energy & exergy analysis of forced convection solar dryer for drying of garlic has been investigated. The exergy parameter, air velocity has been taken to conduct the experiments and its effect on thermal efficiency. Forced draft fans were used in all the two working conditions. During the two conditions, with and without sensible heat storage system, the average air-velocities were 4.5, 9.5 and 11.4 m/s selected as ideal and subsequently its entire effect on thermal efficiency and outlet. The ambient temperatures were between (17-25) °C during the month of October and November. A DC fan is directly connected to the photovoltaic cell in the solar dryer. The thermal energy storage bed was packed with gravels with 1.5 in of thickness up to the surface of flat plate collector, the storage system becomes space-efficient. The average thermal efficiency with sensible heat storage materials was high as compared to system without sensible heat storage. The highest thermal efficiency of 61% was achieved. The maximum collector temperature obtained was 55 °C, with a mean temperature of 42 °C in the drying chamber. The collector’s greatest exergy loss was 30.38 kJ/kg and highest exergy efficiency was 70%.

Optimization of geometrical parameters of the heat receiver of a solar air heating collector

The article presents the optimization of the radiant surface of the solar air heating collector (SAH). As a radiation-receiving surface of the SAH, a surface is used, which is a system of metal drainage shavings and a V-shaped surface. Based on the study of the heat transfer process, an effective scheme of heat removal from the radiation-receiving surface of the SAH is presented. When optimizing the radiation-sensing surface of the SAH, the process of radiation-sensing of the surface, which depends on the geometric shape of the chips, is taken as the target function of the maximum. A formula is proposed for calculating the determination of the transmitted amount of the radiant flux of the sun to the unit of the frontal surface through the shape of the metal shavings from the value of the opening step angle in different thicknesses of the metal shavings. It has been confirmed that the solar radiant flux passing to the unit of the frontal surface through the metal chip shape reaches its maximum value in the following cases: when the chips are 0,002 m thick, they have an optimal angle φ = 58°, the transmitted energy of the radiant flux through the chip shape is E = 31%; with a chip thickness of 0,0005 m, the optimal angle is φ = 42°, the transmitted energy of the radiant flux through the chip shape is E = 41%; with a thickness of 0,001 m, the optimal angle is φ = 50°, the transmitted energy of the radiant flux through the chip shape is.

Renewable lignocellulose based binders for advanced battery systems

The research potential and challenges of using lignocellulose and its derivatives as binder materials in advanced battery systems are summarized and forecast.

Interface Design for High‐Performance All‐Solid‐State Lithium Batteries

AbstractAll‐solid‐state batteries suffer from high interface resistance and lithium dendrite growth leading to low Li plating/stripping Coulombic efficiency (CE) of <90% and low critical current density at high capacity. Here, simultaneously addresses both challenges are simultaneously addressed and the Li plating/stripping CE is significantly increased to 99.6% at 0.2 mA cm−2/0.2 mAh cm−2, and critical current density (CCD) of > 3.0 mA cm−2/3.0 mAh cm−2 by inserting a mixed ionic‐electronic conductive (MIEC) and lithiophobic LiF‐C‐Li3N‐Bi nanocomposite interlayer between Li6PS5Cl electrolyte and Li anode. The highly lithiophobic LiF‐C‐Li3N‐Bi interlayer with high ionic conductivity (10−5 S cm−1) and low electronic conductivity (3.4×10−7 S cm−1) enables Li to plate on the current collector (CC) surface rather than on Li6PS5Cl surface avoiding Li6PS5Cl electrolyte reduction. During initial Li plating on CC, Li penetrates into porous LiF‐C‐Li3N‐Bi interlayer and lithiates Bi nanoparticles into Li3Bi. The lithiophilic Li3Bi and Li3N nanoparticles in LiF‐C‐Li3N‐Li3Bi sub‐interlayer will move to CC along with plated Li, forming LiF‐C/Li3N‐Li3Bi lithiophobic/lithiophilic sublayer during the following Li stripping. This interlayer enables Co0.1Fe0.9S2/Li6PS5Cl/Li cell with an areal capacity of 1.4 mAh cm−2 to achieve a cycle life of >850 cycles at 150 mA g−1. The lithiophobic/lithiophilic interlayer enables solid‐state metal batteries to simultaneously achieve high energy and long cycle life.

Challenges and Breakthroughs Towards the Development and Optimisation of a Zero Excess Li-S Battery

There is currently a large demand to produce batteries and energy storage devices offering both improved volumetric and gravimetric energy densities to help prevent the catastrophic effects of climate change. One promising candidate is the lithium-sulfur (Li-S) chemistry due to the high theoretical capacity and abundance of sulfur. However, current designs require a 1000% excess of Li metal which impedes their commercialisation. An area gaining momentum is the development of “anode-free” or zero excess lithium (ZEL) cells which minimise inactive materials and mitigate the challenges of handling Li metal foils during fabrication. So far, most studies involving anode-free have been based on the Li-ion chemistry and there are significantly fewer systematic studies concerning ZEL Li-S cell fabrication and optimisation. However, nearly all fall short of targets required for commercialisation.Here we present the development of an Li2S ZEL cell composed of a Li2S/C65/SBR positive electrode material paired with a metallic current collector. The design allows for a Li-limited LiS battery where Li-ions are reversibly plated and stripped to a metallic current collector surface. We initially investigate the effects of electrolyte volume :Li2S mg (ES) ratio, conductive carbon loading, C-rate capacity dependency, various current collector materials and positive electrode substrates. The optimised cell achieves good capacity retention with a Coulombic efficiency of over 98% after 50 cycles, and a final capacity of 400 mAh g-1.Previous studies have shown difficulties in achieving consistent results and are often distorted by a large volume of conductive carbon present in the cathode substrate [1, 2]. Therefore, investigations into capacity losses stemming from the cathode are presented using a range of air-tight characterisation techniques. The performance is also closely correlated to the efficiency of reversible Li deposition onto the metallic current collector, as evaluated by comparison to the use of Li negative electrodes. In the ZEL set up, losses from dead Li formation and SEI instability result in permanent loss of Li inventory with no reservoir to replenish. To counter this, initial investigations attempting to apply an ionically conductive coating to the metal current collector surface are shown.[1]. S. Nanda, A. Gupta and A. Manthiram, Adv. Energy Mater., 2018, 8, 2–7.[2]. S. Nanda, A. Bhargav and A. Manthiram, Joule, 2020, 4, 1121–1135.

Preparation and surface nanostructural characterization of multi-emitter sources based on superionic conductor CsAg4Br3-xI2+x (x=0.25)

Since the fabrication of micro-/nano-electronic devices is approaching nanoscales and demanding low energy, high dose ion beam processing with controlled area and dense patterns to meet the current semiconductor industry demands, continuous advancement is needed in terms of material design and ion beam techniques. In this perspective, development of new ion sources may provide advanced technologies useful in the manufacture of high-performance devices. Silver ion beams have salient features including simple generating process, nanoscale beam spot size and high intensity ion current. In this paper, we have developed a solid electrolyte multi emitter ion source (SEIS) with CsAg4Br3-xI2+x (x = 0.25) films deposited on silver tips. Ag+ ion emission is significantly enhanced with the added number of emitters and the ion current of 1.95 μA (with four emitter tips) has been obtained at 168 °C temperature and 20 kV accelerating voltage. The stability and cooling/heating curves of the multi-emitter ion beam are measured, and the interrelation between ion current intensity and mechanism of shape geometry of the emitter tips are discussed. Finally, both the solid electrolyte multi-tip emitters and the collector surfaces are analyzed, with an attempt to precisely control of formation of the nanoparticles (NPs) including their size and height through the control of the ion implantation parameters.

Experimental Study for the Enhancement of Thermal Efficiency and Development of Nusselt Number Correlation for the Roughened Collector of Solar Air Heater

Abstract The solar air heater’s thermal efficiency is relatively poor owing to the flat collector surface. This article’s primary objective is to increase the collectors’ thermal efficiency of rectangular ducts of solar air heater by adopting a novel V-shaped twisted rib element with staggering orientation. Experimentations are performed for various flow Reynolds numbers ranging from 3 k to 21 k, roughness pitch-to-rib height ratio ranging from 7 to 11, and staggering distance-to-rib height ratio between 2 and 6. Dispersion of Nusselt number over the collector surface is achieved through the liquid crystal thermography technique. Among the varied rib and flow constraints, it is observed that a maximum thermal performance enhancement index of 2.69 is observed, with the optimum value of the roughness parameter at a rib pitch-to-height ratio of 9 and a staggering distance-to-height ratio of 4. Mathematical correlation has also been developed using a regression model to estimate the Nusselt number in terms of non-dimensional roughness parameters. The percentage deviation between the Nusselt number attained from established relationships and the investigational results is found to be giving very satisfactory outcomes. The thermal efficiency of the smooth surface is recognized at 41.64% which increases for the roughened surface of twisted V-ribs to 73.63%. Hence employing twisted V-ribs as an artificial roughness element no doubt increases the Nusselt number, thermohydraulic performance enhancement index, and thermal efficiency, but it also exerts less frictional power of solar air heater.

Spider Silk-Inspired Binder Design for Flexible Lithium-Ion Battery with High Durability.

The development of flexible lithium-ion batteries (LIBs) imposes demands on energy density and high mechanical durability simultaneously. Due to the limited deformability of electrodes, as well as the flat and smooth surface of the metal current collectors, stable/durable/reliable contact between electrode materials and the current collectors remains a challenge, in particular, for electrodes with high loading mass and heavily deformed batteries. Binders play an essential role in binding particles of electrode materials and adhering them to current collectors. Herein, inspired by spider silk, a binder for flexible LIBs is developed, which equips a cross-linked supramolecular poly(urethane-urea) to the polyacrylic acid. The binder imparts super high elastic restorability originating from the meticulously engineered hydrogen-bonding segments as well as extraordinary adhesion. The developed binder provides excellent flexibility and intact electrode morphologies without disintegration even when the electrode is largely deformed, enabling a stable cycling and voltage output even when the batteries are put under tough dynamic deformation tests. The flexible LIBs exhibit a high energy density of 420WhL-1 , which is remarkably higher than reported numbers. The unique binder design is greatly promising and offers a valuable material solution for LIBs with high-loading mass and flexible designs.

Impact of Morphological Dimensions in Carbon‐Based Interlayers on Lithium Metal Anode Stabilization

AbstractLithium metal batteries (LMBs) offer high energy density and promise as a future technology. Yet, their adoption is hindered by safety concerns and cycle life stability, arising from Li dendrite formation, solid electrolyte interphase instability, and volume changes during cycling. In response to these challenges, carbon‐based materials have been utilized as an artificial interface layer for modifying the surface of copper current collector in LMBs. Among the diverse carbon‐based materials, 0D carbon, with its high specific surface area, is advantageous for enhancing Li ion transport rates and ensuring uniform current distribution. 1D carbon structures foster a network that facilitates Li ion diffusion, while 2D carbon establishes a protective layer, mitigating side reactions. 3D carbon structures promote Li deposition within their internal cavities, effectively controlling volume fluctuations. With this understanding, this review delves into the latest advancements in carbon‐based materials for modifying copper current collectors. It offers a detailed exploration of how each dimension of carbon‐based materials contributes to regulating Li deposition. Furthermore, the ongoing challenges and potential avenues in the development of carbon‐modified copper current collectors for LMBs are spotlighted, aiming to provide insightful guidance for the design of anode‐free Li metal batteries.

Chitin and cellulose as constituents of efficient, sustainable, and flexible zinc-ion hybrid supercapacitors

A zinc-ion hybrid supercapacitor (ZIHS) is a prospective energy storage device featuring cost-effectiveness, operational safety, environmental friendliness, high-power performance, and satisfied energy density. The sustainability of this ZIHS technology is even improved by introducing biopolymer constituents into the cell construction. Herein, efficient, sustainable, and flexible ZIHSs employing polysaccharide (chitin- or cellulose-based) components are developed. Using green ionic liquid solvents, biopolymer-bound, activated carbon-based cathode materials and hydrogel biopolymer electrolytes containing conductive zinc salts are obtained. According to systematical characterization results, the prepared materials possess favorable functional properties. Biopolymer binders provide homogeneity and integrity within the electrode network and high adhesion to the surface of the current collector. Depending on the type of zinc salt, hydrogel biopolymer electrolytes display high ionic conductivity (up to 46 mS cm−1), expanded electrochemical stability window (up to ca. 2.8 V), and zinc dendrites growth suppression. Biopolymer components assembled with zinc foil electrodes operate efficiently in both coin and pouch ZIHS cell configurations, providing satisfactory energy (45–50 Wh kg−1) and high power (10–20 kW kg−1) density combined with excellent cycle stability. Moreover, these ZIHS pouch-type devices exhibit superior durability and flexibility, withstanding mechanical stress up to 150° bending states with at least 90% of capacitance retention. It suggests a prospect for their application in wearable electronics.

Novel insights into the microstructure of Al-BHA on the surface of ilmenite

In the process of flotation recovery of metal oxide ore, the complexes obtained by premixing metal ions with benzohydroxamic acid are often used as collectors. The study of aluminum (III) -benzohydroxamic acid (Al-BHA) system is not perfect. In order to study the chemical properties, microstructure and adsorption mechanism of Al-BHA on mineral surface, Fourier transform infrared spectroscopy (FTIR), atomic force microscopy (AFM) and density functional theory (DFT) were used. The analysis of FTIR confirmed the chemisorption of Al-BHA onto the ilmenite. AFM results show that the coverage of Al-BHA on the surface of ilmenite is obviously better than that of BHA. According to Fukui function and frontier orbital theory, the chemical activities of Al-BHA are greater than those of BHA. In addition, aluminum atom is the active center of Al-BHA. The bonding model of the collector and (104) ilmenite surface showed that the vacuum adsorption energy of Al-BHA was higher than that of BHA, and the bridge site adsorption form is the most stable. Overall, it is possible to apply Al-BHA with higher activity to ilmenite flotation.

Investigation of the corrosion behavior influence of carbon interlayer on aluminum collector in lithium-sulfur battery system

Due to the shuttle effect brought by polysulfides, the commercialization of lithium-sulfur batteries still faces significant difficulties. Carbon interlayer is introduced to enhance the electrochemical performance of lithium-sulfur batteries, while the drawback that the interlayer will reversely affect the performance of the current collector was ignored. The current collector has a significant influence and contribution to the cycle stability of lithium-sulfur batteries. In this study, we looked into the electrochemical stability and corrosion situation of standard aluminum foil collectors in lithium-sulfur batteries with carbon interlayer. The results show that the introduction of carbon interlayer into the lithium-sulfur batteries will make aluminum foil and carbon paper form an electronic conduction path and galvanic corrosion occurs, accelerating the corrosion of aluminum foil. Therefore, we propose a new corrosion model. During the cycle, the surface of the aluminum collector becomes a non-dense passivation film and lithium polysulfide terminal (ST−1). Then, under the action of the carbon interlayer, the passivation film peels off and the oxide film is attacked by the electrolyte, thiosulfate and polythionate, resulting in pitting holes and ultimately accelerating the corrosion of the aluminum foil collector. This research has some guiding significance for the commercial application of lithium-sulfur batteries.