COD Mass Balance Research Articles

Synergism of floated paperboard sludge cake /sewage sludge for maximizing biomethane yield and biochar recovery from digestate: A step towards circular economy

Anaerobic digestion of floated paperboard sludge (PS) cake suffers from volatile fatty acids (VFAs) accumulation, nutrient unbalanced condition, and generation of digestate with a risk of secondary pollution. To overcome these drawbacks, sewage sludge (SS) was added to PS cake for biogas recovery improvement under a co-digestion process followed by the thermal treatment of solid fraction of digestate for biochar production. Batch experimental assays were conducted at different SS:PS mixing ratios of 70:30, 50:50, 30:70, and 20:80 (w/w), and their anaerobic co-digestion performances were compared to the mono-digestion systems at 35 ± 0.2 °C for 45 days. The highest methane yield (MY) of 241.68 ± 14.81 mL/g CODremoved was obtained at the optimum SS:PS ratio of 50:50 (w/w). This experimental condition was accompanied by protein, carbohydrate, and VFA conversion efficiencies of 47.3 ± 3.2%, 46.8 ± 3.2%, and 56.3 ± 3.8%, respectively. The synergistic effect of SS and PS cake encouraged the dominance of Bacteroidota (23.19%), Proteobacteria (49.65%), Patescibacteria (8.12%), and Acidovorax (12.60%) responsible for hydrolyzing the complex organic compounds and converting the VFAs into biomethane. Further, the solid fraction of digestate was subjected to thermal treatment at a temperature of 500 °C for 2.0 h, under an oxygen-limited condition. The obtained biochar had a yield of 0.48 g/g dry digestate, and its oxygen-to-carbon (O/C), carbon-to-nitrogen (C/N), and carbon-to-phosphorous (C/P) ratios were 0.55, 10.23, and 16.42, respectively. A combined anaerobic co-digestion/pyrolysis system (capacity 50 m3/d) was designed based on the COD mass balance experimental data and biogenic CO2 market price of 22 USD/ton. This project could earn profits from biogas (12,565 USD/yr), biochar (6641 USD/yr), carbon credit (8014 USD/yr), and COD shadow price (6932 USD/yr). The proposed project could maintain a payback period of 6.60 yr. However, further studies are required to determine the associated life cycle cost model that is useful to validate the batch experiment assumptions.

Calcium peroxide mediated sustainable microalgal-bacterial consortium system: Role and significance of configured anaerobic fermentation

Microalgal-bacterial consortium (MBC) is an effective way to meet increasingly stringent standards in wastewater treatment, with advantages in nutrient removal, resource recovery, and energy conservation. The efficient and stable operation of the MBC sewage treatment system is generally limited by the insufficient and unstable carbon source in the influent. In this study, a calcium peroxide-mediated anaerobic fermenter was configured to transfer the MBC sludge into the preferred carbon source, short-chain fatty acids (SCFAs) in-situ, to alleviate the limitations. Experimental results showed that after 4-day 0.15 g/g VS calcium peroxide mediated anaerobic fermentation, the production of SCFAs and the proportion of acetic acid reached 514.8 mg COD/g VS and 59 %, respectively. Scanning electron microscopy, COD mass balance analysis, and lactate dehydrogenase assays jointly showed that calcium peroxide effectively promoted the breakdown of MBC sludge cells, which led to the release of large amounts of organic matter and could be attributed to the released OH–, ·OH and ·O2– from calcium peroxide, thereby providing more bioavailable substrates for SCFAs production. Microbial community analysis indicated that the anaerobes associated with hydrolysis and degradation of refractory organic matters were enriched in the mediated fermenter and had positive correlation with SCFAs production. Using such fermentation liquid as an additional carbon source for influent sewage, the MBC process performance was significantly promoted, with phosphorus and COD removal and sludge settleability reaching 84.7 %, 96.1 %, and 33 %, respectively. Configuring calcium peroxide-mediated anaerobic fermentation may thus become a sustainable strategy to strengthen the MBC sewage treatment system, thus providing new ideas for wastewater treatment to reduce inputs and improve performance.

Zero-Valent Iron and Activated Carbon Coupled to Enhance Anaerobic Digestion of Food Waste: Alleviating Acid Inhibition at High Loads

Anaerobic digestion (AD) has the advantages of utilizing complex substrates and producing renewable energy and is currently one of the mainstream technologies for food waste (FW) resourcing. However, at high organic loads and low inoculum-to-substrate ratios (ISRs), AD with FW as substrate is prone to acid accumulation, resulting in a drastic decrease in gas production and system collapse. This study investigated the effect of the coupled addition of zero-valent iron (ZVI) and activated carbon (AC) on the AD of FW at three low ISRs of 0.715, 0.625, and 0.5. The results showed that the control group acidified and stopped producing biogas when the ISR decreased to 0.625 and 0.5, but ZVI coupled with AC alleviated the acidification and increased the cumulative biogas yield. Especially at ISR = 0.5, the cumulative biogas yield for the ZVI + AC group was 31.5%, 99.5%, and 11.43 times higher than that of the ZVI, AC, and control groups, respectively. ZVI coupled with AC also increased the degradation of volatile fatty acids (70.5–84.4%) and soluble chemical oxygen demand (50.0–72.9%) while decreasing propionate concentration and improving the stability of the AD system. COD mass balance analyses indicated that the coupled addition of ZVI and AC promoted the conversion of particulate organic matter to soluble organic matter and increased the conversion of carbon sources to methane.

Process characteristics and energy self-sufficient operation of a low-fouling anaerobic dynamic membrane bioreactor for up-concentrated municipal wastewater treatment

Up-concentration of municipal wastewater using physico-chemical methods can effectively enrich organic matter, facilitating subsequent anaerobic digestion of up-concentrated wastewater for enhanced methanogenesis at reduced energy consumption. An anaerobic dynamic membrane bioreactor (AnDMBR) assisted with biogas-sparging was developed to treat up-concentrated municipal wastewater, focusing on the effects of operating temperature and hydraulic retention time (HRT) as well as COD mass balance and energy balance. The COD removal stabilized at about 98 % over the experimental period, while gaseous and dissolved methane contributed 43–49 % and 2–3 % to the influent COD reducing greenhouse gas emissions. The formed dynamic membrane exists mainly as a heterogeneous cake layer with a uneven distribution feature, ensuring the stable effluent quality. Without adopting any physico-chemical cleaning, the transmembrane pressure (TMP) maintained at a low range (2.7 to 14.67 kPa) with the average TMP increasing rate of 0.089 kPa/d showing a long-term low-fouling operation. Increasing the concentration ratio, the methane production rate decreased from 0.18 to 0.15 L CH4/gCOD likely due to the accumulation of particulate organics. Microbial community analysis indicated the predominant methanogenic pathway shifted from hydrogenotrophic to acetoclastic methanogenesis in response to the temperature change. Net energy balance (0.003–0.600 kWh/m3) can be achieved only under room temperature (25 °C) rather than mesophilic conditions (36 °C).

Enhancing the performance of thermophilic anaerobic digestion of food waste by introducing a hybrid anaerobic membrane bioreactor

The thermophilic anaerobic digestion of food waste was a long-term challenge for maintaining process stability. A hybrid submerged anaerobic membrane bioreactor (AnMBR), integrating 27%(v/v) polyurethane sponge as fixed carriers were therefore investigated at (50 ± 2) °C. The organics removal efficiencies, COD mass balance, and membrane filtration performance were investigated in a 75-days continuously operated experiment. The results showed that methane production reached 0.31 L/(kg·COD) under an organic loading rate of 7.3 kg·COD/(m3·d). The low concentration of total volatile fatty acids of 247 ~ 274 mg/L and a high proportion of Methanosarcina (>97%) represented the high stability of the thermophilic process. Approximately 21% of biomass grew on the carriers in the hybrid AnMBR and induced a much lower suspended solids concentration and viscosity of bulk sludge. Noticeable lower trans-membrane pressure was consequently observed. The affecting factors identified by PCA analysis proved the advantages of the hybrid AnMBR for alleviating membrane fouling formation.

Dual production of hydrogen and biochar from industrial effluent containing phenolic compounds

Black liquor (BL) rich phenolic and complex compounds is generated from pulp and paper mill manufacturing processes which should be treated before reaching the environment. The potential of achieving several sustainable development goals (SDGs) by recovering energy and valuable by-products from BL was extensively investigated. Results revealed that under a dark-fermentation process, the organic content in BL was effectively bio-degraded by anaerobes to achieve a hydrogen yield (HY) of 0.62 ± 0.04 mol/molglucose. Fortunately, the HY was significantly increased up to 1.41 ± 0.13 mol/molglucose by immobilizing the anaerobes onto magnetite nanoparticles (MN). α-amylase, xylanase, CM-cellulase, polygalacturinase, and protease enzymes activities were increased by 2.3, 23.7, 2.7, 26.8, and 31.1 folds with supplementation of MN. Moreover, the conversion efficiencies of protein and carbohydrate were improved by values of 36 and 113.3% and total phenolic compounds (TPC) were enhanced by 23.5% compared with the control test. Electron-equivalent and COD mass balances were estimated to comprehensively describe the effect of Mn supplementation on the HY performance and fermentation pathways. Digestate generated from the fermentation process was utilized to produce biochar, having C (58.2%), O (32.4%), Na (4.7%), and P (1.1%). The study outputs were interlinked to bio-energy generation, pollution minimization, biochar as a soil amendment, nanoparticles and paper manufacturing industrialization, meeting environmental, economic, and social related SDGs.

Bioenergy recovery from methanogenic co-digestion of food waste and sewage sludge by a high-solid anaerobic membrane bioreactor (AnMBR): mass balance and energy potential

To support smart city in terms of municipal waste management and bioenergy recovery, a high-solid anaerobic membrane bioreactor (AnMBR) was developed for sewage sludge (SeS) and food waste (FW) treatment in this study. COD mass balance showed that 54.1%, 66.9%, 73.5%, 91.4% and 93.5% of the COD input was converted into methane at the FW ratio of 0, 25%, 50%, 75% and 100%, respectively. The corresponding net energy balance was 13.6, 14.1, 17.1, 22.9 and 27.4 kJ/g-VS, respectively. An important finding of this investigation was that, for the first time, the relationship between net energy balance and carbon to nitrogen (C/N) ratio was revealed and the established sigmoid-type function was shown to be capable of predicting energy balance at different C/N ratios regardless of the region. The outcomes of this study show the potential of high-solid AnMBRs in SeS and FW treatment for supporting smart cities in the future.

Part A: Advances in tools and techniques for estimating biogas production and treatment in anaerobic-based STPs Technical Note 2 - Software for estimation of biogas production in UASB reactors - ProBio 2.0

The use of biogas energy has highlighted as a promising alternative for reducing the operating costs of sewage treatment plants (STPs). However, in order to validate this practice, it is necessary to know, at a minimum, the amount of biogas available for use and, subsequently, compare it with the amount required for a given energy recovery system. In a sense, the analysis of measurements is extremely relevant to the decision making process of the energy use of biogas in STPs. However, these analyzes are often not feasible due to the high cost of measurement equipment. In these cases, decisions need to be based on mathematical models of estimates. Thus, this technical note aims to present a software for estimating biogas production in UASB reactors - ProBio 2.0. Therefore, the following topics of interest were highlighted: (i) mathematical model used as a basis for the estimate; (ii) input data to be considered in the software; (iii) COD mass balance; (iv) unit relationships for the production of methane, biogas and energy; (v) scenarios of biogas energy use and (vi) example of ProBio 2.0 application.

ALBA: A comprehensive growth model to optimize algae-bacteria wastewater treatment in raceway ponds

This paper proposes a new model describing the algae-bacteria ecosystem evolution in an outdoor raceway for wastewater treatment. The ALBA model is based on mass balances of COD, C, N and P, but also H and O. It describes growth and interactions among algae, heterotrophic and nitrifying bacteria, while local climate drives light and temperature. Relevant chemical/physical processes are also included. The minimum-law was used as ground principle to describe the multi-limitation kinetics. The model was set-up and calibrated with an original data set recorded on a 56 m2 raceway located in the South of France, continuously treating synthetic wastewater. The main process variables were daily measured along 443 days of operations and dissolved O2 and pH were on-line recorded. A sub-dataset was used for calibration and the model was successfully validated, along the different seasons over a period of 414 days. The model proved to be effective in reproducing both the short term nycthemeral dynamics and the long-term seasonal ones. The analysis of different scenarios reveals the fate of nitrogen and the key role played by oxygen and CO2 in the interactions between the different players of the ecosystem. On average, the process turns out to be CO2 neutral, as compared to a standard activated sludge where approximately half of the influent carbon will end up in the atmosphere. The ALBA model revealed that a suboptimal regulation of the paddle wheel can bring to several detrimental impacts. At high velocity, the strong aeration will reduce the available oxygen provided by photo-oxygenation, while very low aeration can rapidly lead to oxygen inhibition of the photosynthetic process. On the other hand, during night, the paddle wheel is fundamental to ensure enough oxygen in the system to support algal-bacteria respiration. The model can be used to support advanced control strategies, including smart regulation of the paddle wheel velocity to more efficiently balance the mixing, aeration and degassing effects.

Co-digestion of municipal wastewater and microalgae biomass in an upflow anaerobic sludge blanket reactor

Upflow anaerobic sludge blanket reactors associated in series with photobioreactors offers an efficient and low cost solution for the wastewater treatment in small communities. However, there is little information about the performance of such anaerobic process fed with microalgae biomass from high rate algal ponds. This study aimed to evaluate the performance of a 3.78 m3 working volume pilot scale upflow anaerobic sludge blanket reactor during anaerobic co-digestion of municipal wastewater and microalgae biomass from high rate algal ponds (13.7 m3 each) during 365 days. To establish a basis for comparison, in the first research phase the anaerobic process was fed exclusively with municipal wastewater and, in the second phase, with a mixture of municipal wastewater and microalgae biomass. Similar organic and hydraulic loading rates were provided to the process in both research phases. The results showed a great removal of organic matter (COD) and suspended solids (TSS) in anaerobic process during the first phase (61% COD and 74% TSS) and second phase (63% COD and 74% TSS), the latter in anaerobic co-digestion. No sign of toxicity due to excess of ammoniacal, nitrogen or sulfur compounds was found. However, COD mass balance showed an increase of 54% on COD sludge retained and indicated that most of the microalgae biomass was not converted into methane. It was also observed a significant decrease in biogas production and a washout of microalgae cells to the upflow anaerobic sludge blanket reactor effluent in the second phase. The presence of intact microalgae cells retained in the sludge at all levels of this process also evidenced the incomplete anaerobic digestion of the microalgae biomass. These findings prove that an auxiliary pretreatment of the microalgae biomass is essential to improve its conversion into methane in the upflow anaerobic sludge blanket reactor.

Robustness of granular activated carbon-synergized anaerobic membrane bioreactor for pilot-scale application over a wide seasonal temperature change

A novel granular activated carbon-synergized anaerobic membrane bioreactor (GAC-AnMBR), consisted of four expanded bed anaerobic bioreactors with GAC carriers and a membrane tank, was established in pilot scale (10 m3/d) to treat real municipal wastewater (MWW) at ambient temperature seasonally fluctuating from 35 to 5 °C. It showed sound organic removal over 86% with the permeate COD less than 50 mg/L even at extremely low temperatures below 10 °C. COD mass balance analysis revealed that membrane rejection (with a contribution rate of 10%-20%) guaranteed the stable organic removal, particularly at psychrophilic temperature. The methane yield was over 0.24 L CH4 (STP)/g COD removed at mesophilic temperature and 0.21 L CH4 (STP)/g COD removed at 5–15 °C. Pyrosequencing of microbial communities suggested that lower temperature reduced the abundance of the methane producing bacteria, but the methane production was enhanced by selectively enriched Methanosaeta, syntrophic Syntrophobacter and Smithella and exoelectrogenic Geobacter for direct interspecies electron transfer (DIET) on the additive GAC. Compared with previously reported pilot-scale AnMBRs, the GAC-AnMBR in this study showed better overall performance and higher stability in a wide temperature range of 5–35 °C. The synergistic effect of GAC on AnMBR guaranteed the robustness of GAC-AnMBR against temperature, which highlighted the applicational potential of GAC-AnMBR, especially in cold and temperate climate regions.

Large pilot-scale submerged anaerobic membrane bioreactor for the treatment of municipal wastewater and biogas production at 25 °C

The aim of this work was to demonstrate the operation of a large pilot-scale submerged anaerobic membrane bioreactor (5.0 m3) for biogas production from municipal wastewater at ambient temperature of 25 °C. To the best of our knowledge, this is the largest one-stage submerged AnMBR that has ever been reported. This AnMBR realized a hydraulic retention time (HRT) of 6 h and a treatment capacity of 20 m3 d-1, obtaining excellent effluent quality with COD removal efficiency over 90% and BOD5 removal over 95%. The biogas yield of the AnMBR was 0.25–0.27 L g−1 removed COD and 0.09–0.10 L L-1 raw wastewater. The methane content of the biogas was at the range of 75%-81%. The COD and nitrogen mass balance were also identified based on long-term operation. The hollow-fiber membrane module realized a flux of 2.75–17.83 LMH. An online backwash chemical cleaning system helped to lower the transmembrane pressure timely.

Optimization of Energy Recovery from Cellulosic Wastewater Using Mesophilic Single-Stage Bioreactor

The efficiency of single-stage biohythane production from synthetic cellulosic wastewater under mesophilic temperature was investigated. A lab-scale continuously stirred tank reactor was conducted at a hydraulic retention time of 10 days using mixed microflora without pretreatment. The experimental results show that a stable methane and hydrogen yields of 18.2 ± 0.16 and 5.6 ± 0.31 L/kg VS were maintained for 240 days, respectively with acetate/butyrate ratio of 0.39 as the main byproducts. Based on COD mass balance, more than 45% of the decomposed COD converted to bio-hythane, which means that the setting temperature 37 °C and pH improved the conditions of degradation efficiency. The energy recovery calculations indicated that the total net energy was 4.54 MJ/m3 of cellulosic wastewater. This work contributes to the limited knowledge on continuous cellulosic-hythane conversion into a safe and clean form of energy.

Packed-bed biofilm reactor for semi-continuous anaerobic digestion of olive mill wastewater: performances and COD mass balance analysis

ABSTRACT In the present study, the treatability of olive mill wastewater (OMWW) using an anaerobic fixed bed biofilm reactor packed with granular activated carbon (GAC) and inoculated with non-acclimated biomass was performed in a semi-continuous mode under mesophilic conditions. Three organic loading rates (OLR) varied from 0.94 to 2.81 g COD/(L d) were applied. The results of batch adsorption tests on GAC and the experimental data from PBBR-GAC operation were used to set up a COD mass balance in order to investigate the effect of adsorption on the COD removal during the three anaerobic treatment steps. Despite the slight accumulation of volatile fatty acids (VFAs) during the second and the third steps, between 735 and 1135 mg COD/L (as acetic acid), a stable environment for methanogens was maintained for a period of 104 days. During the three steps, degradation levels were up to 80% of COD and 85% of phenolic compounds. An averaged specific biogas production of 1.77 LN/d and a methane (CH4) concentration of about 60%, corresponding to a CH4 yield of 0.31 L CH4produced/g CODdepleted, were reached at an OLR of 2.81 g COD/(L d). The results show that the COD mass balance was not closed during the first two steps, while in the third step, it could be around 96%. This finding suggests that the adsorption of organic substances on activated carbon occur just during the two first steps, while at 2.81 g COD/(L d) OLR no adsorption is occurring and the introduced COD becomes completely available for CH4 production.

Operation performance of an A/O process combined sewage sludge treatment and phosphorus recovery using human urine

A novel sewage sludge treatment process is developed in which sludge anaerobically phosphorus (P) released with the temperature control/ultrasonic treatment and recovery with human urine are incorporated to a conventional anaerobic/aerobic (A/O) process. The results showed that temperature affected the anaerobic P release and the maximum orthophosphate (PO4 3-P) release rate was 21.68 mg PO4 3-P/(g MLVSS.h) at 20 °C. The optimal specific energy of ultrasonic treatment was 15,000 kJ/kg TS, at which the solubilization degree of soluble chemical oxygen demand (SCOD) was 37.93%, which verified that the anaerobic sludge flocs were broken and the organic matter was obviously released. Human urine and P-rich sludge stream could be verified as a feasible way of P recovery in the form of struvite. The output of P in the combined A/O treatment process consisted of three pathways (i.e., effluent wastewater, sewage sludge, and P recovery). The influent P could be recovered by 22.84% and about 1.48 g/d potential struvite could be recovered from the anaerobic sludge flow using 0.27 L/d-human urine. The mass balances of COD and nitrogen (N) indicated that the combined A/O process also improved the organic mineralization and the removal of N.

Impact of water characteristics on the bioenergy recovery from sewage treatment by anaerobic membrane bioreactor via a comprehensive study on the response of microbial community and methanogenic activity

Effect of wastewater characteristics on bioenergy recovery in sewage treatment by anaerobic membrane bioreactor (AnMBR) was investigated. Based on COD removal, sludge concentration change and COD mass balance, nonionic surfactant or operation at 20–25 °C had no effect on the energy recovery with COD conversion of 72–79%. The anaerobic microbes can cope with the characteristic by releasing more SMP/EPS or changing its community structure. Compared with Control (6.99 × 107 kJ/d, HRT 12 h), with suspended solid or operation at 15 °C and 10 °C, the captured energy was only 5.90 × 107 kJ/d, 6.0 × 107 kJ/d and 3.10 × 107 kJ/d, respectively while the energy in dissolved methane was 1.08 × 107 kJ/d, 0.98 × 107 kJ/d and 1.26 × 107 kJ/d. Hence, the recovery efficiency was decreased by 15.6%, 14.2% and 55.7%. The recovery also decreased by 26% (5.17 × 107 kJ/d) in the presence of anionic surfactant. The toxicity of anionic surfactant to the anaerobic microbes and lower growth rate of microorganism at psychrophilic temperatures were responsible to the decrease of bioenergy recovery efficiency. SS accumulation will finally increase the loading rate of sludge and decrease the bioenergy recovery from the long-term view.

Biohydrogen production from sugarcane bagasse hydrolysate: effects of pH, S/X, Fe2+, and magnetite nanoparticles

Batch dark fermentation experiments were conducted to investigate the effects of initial pH, substrate-to-biomass (S/X) ratio, and concentrations of Fe2+ and magnetite nanoparticles on biohydrogen production from sugarcane bagasse (SCB) hydrolysate. By applying the response surface methodology, the optimum condition of steam-acid hydrolysis was 0.64% (v/v) H2SO4 for 55.7min, which obtained a sugar yield of 274mgg-1. The maximum hydrogen yield (HY) of 0.874mol (mol glucose-1) was detected at the optimum pH of 5.0 and S/X ratio of 0.5g chemical oxygen demand (COD, gVSS-1). The addition of Fe2+ 200mgL-1 and magnetite nanoparticles 200mgL-1 to the inoculum enhanced the HY by 62.1% and 69.6%, respectively. The kinetics of hydrogen production was estimated by fitting the experimental data to the modified Gompertz model. The inhibitory effects of adding Fe2+ and magnetite nanoparticles to the fermentative hydrogen production were examined by applying Andrew's inhibition model. COD mass balance and full stoichiometric reactions, including soluble metabolic products, cell synthesis, and H2 production, indicated the reliability of the experimental results. A qPCR-based analysis was conducted to assess the microbial community structure using Enterobacteriaceae, Clostridium spp., and hydrogenase-specific gene activity. Results from the microbial analysis revealed the dominance of hydrogen producers in the inoculum immobilized on magnetite nanoparticles, followed by the inoculum supplemented with Fe2+ concentration. Graphical abstract ᅟ.

Comparison of single-stage and temperature-phased two-stage anaerobic digestion of oily food waste

Anaerobic digestion is an effective technology to recover energy from oily food waste. A single-stage system and temperature-phased two-stage systems with and without recycle for anaerobic digestion of oily food waste were constructed to compare the operation performances. The synchronous operation indicated the similar ability to produce methane in the three systems, with a methane yield of 0.44L/g VSadded. The pH drop to less than 4.0 in the first stage of two-stage system without recycle resulted in poor hydrolysis, and methane or hydrogen was not produced in this stage. Alkalinity supplement from the second stage of two-stage system with recycle improved pH in the first stage to 5.4. Consequently, 35.3% of the particulate COD in the influent was reduced in the first stage of two-stage system with recycle according to a COD mass balance, and hydrogen was produced with a percentage of 31.7%, accordingly. Similar solids and organic matter were removed in the single-stage system and two-stage system without recycle. More lipid degradation and the conversion of long-chain fatty acids were achieved in the single-stage system. Recycling was proved to be effective in promoting the conversion of unsaturated long-chain fatty acids into saturated fatty acids in the two-stage system.

Anaerobic dynamic membrane bioreactor for wastewater treatment at ambient temperature

A bench-scale dynamic membrane (DM) bioreactor was operated to evaluate the anaerobic treatment of a synthetic municipal wastewater at ambient temperature. The DM was developed over a large pore size (200μm) mesh in order to improve sludge filterability and reduce energy consumption. The system achieved average organic removals higher than 80% and 90% for total COD and filtered COD, respectively. Results also demonstrated that the biofilm, which the DM is made of, played a significant part in obtaining the overall organic removal efficiency. The large pore size of the mesh allowed for high membrane fluxes (approximately 15–20Lm−2h−1) applying low TMP (usually lower than 50–100mbar). Fluxes higher than 20Lm−2h−1 produced low solid removal efficiency indicating deterioration of the DM. COD mass balance suggests that the low hydraulic retention times applied to the system caused methane loss through the effluent due to oversaturation.

Defining full-scale Anaerobic Digestion Stability: The Case of Central Weber Sewer Improvement District

A full-scale anaerobic digester receiving a mixture of primary and secondary sludge was monitored for one hundred days. A chemical oxygen demand, COD, and volatile solids (VS), and mass balance were conducted to evaluate the stability of the digester and its capability of producing methane gas. The COD mass balance could account for nearly 90% of the methane gas produced while the VS mass balance showed that 91% of the organic matter removed resulted in biogas formation. Other parameters monitored included: pH, alkalinity, VFA, and propionic acid. The values of these parameters showed that steady state had occurred. At mesophilic temperature and at steady state performance, the anaerobic digester stability was defined as a constant rate of methane produced per substrate of ?VS (average rate=0.40 L/g). This constant rate can be used as the stability index to determine the anaerobic digester stability in an easy and inexpensive way.