Coastal Basins Research Articles

Hybrid rainfall–runoff model with continuous infiltration experiments: a Mediterranean coastal basin of Madjez Ressoul in Algeria

Hybrid rainfall–runoff model with continuous infiltration experiments: a Mediterranean coastal basin of Madjez Ressoul in Algeria

Near future flash flood prediction in an arid region under climate change

Flash floods represent a significant threat, triggering severe natural disasters and leading to extensive damage to properties and infrastructure, which in turn results in the loss of lives and significant economic damages. In this study, a comprehensive statistical approach was applied to future flood predictions in the coastal basin of North Al-Abatinah, Oman. In this context, the initial step involves analyzing eighteen General Circulation Models (GCMs) to identify the most suitable one. Subsequently, we assessed four CMIP6 scenarios for future rainfall analysis. Next, different Machine Learning (ML) algorithms were employed through H2O-AutoML to identify the best model for downscaling future rainfall predictions. Forty distribution functions were then fitted to the future daily rainfall, and the best-fit model was selected to project future Intensity-Duration-Frequency (IDF) curves. Finally, the Soil and Water Assessment Tool (SWAT) model was utilized with sub-daily time steps to make accurate flash flood predictions in the study area. The findings reveal that IITM-ESM is the most effective among GCM models. Additionally, the application of stacked ensemble ML model proved to be the most reliable in downscaling future rainfall. Furthermore, this study highlighted that floods entering urbanized areas could reach 20.33 and 20.70 m³/s under pessimistic scenarios during rainfall events with 100 and 200-year return periods, respectively. This hierarchical comprehensive approach provides reliable results by utilizing the most effective model at each step, offering in-depth insight into future flash flood prediction.

Assessing hydrodynamic impacts of tidal range energy impoundments in UK coastal waters

Tidal range energy comprises a vast theoretical resource of 9,220 TWh per year, globally, with advantageous characteristics of predictability, generation flexibility and reliability. Approximately 13% of this resource lies within the United Kingdom’s (UK) coastal waters, where it could supply up to 12% of annual electricity demand. Tidal range energy conversion traditionally involves constructing and operating large-scale coastal or offshore impoundments (O10-100 km2), which will redefine near and far-field water levels and flow patterns. The relationship between the scale of the impoundment area and hydrodynamic impact has not been investigated for UK sites. To address this, we develop a two-dimensional (depth-averaged) TELEMAC model of the Irish Sea, and simulate six scenarios involving tidal range schemes of increasing basin area, from 25 to 150 km2, located on the North Wales coast in an open coastal basin setting. Results indicate that far-field (30−150 km) changes to the amplitude of the semi-diurnal (M2) tidal constituent exhibit a linear relationship with impoundment area and volume (correlation coefficient R=0.95 and R=0.96, respectively). The largest impoundment (150 km2) caused far-field changes in maximum surface elevation (2<ηmax<3 cm); near-field surface elevation was reduced (ηmax>3 cm).

Description of the Late Holocene South‐east Saline Everglades, Florida palustrine depositional environment with comparisons to other Holocene environments

AbstractA transgressive palustrine depositional model is described for the South‐east Saline Everglades, Florida. The origin, development and termination of freshwater carbonate mud (marl) deposition along the very low gradient Late Pleistocene carbonate ramp are responses to changing rates of rising sea level during the Late Holocene. The onset of the Late Holocene is defined by a decrease in the rate of sea‐level rise from between 2 and 3 to &lt;1 mm year−1. Freshwater marl deposition began with this decrease ca 3165 ± 187 year BP, in a shallow (&lt;0.3 m deep), ephemeral wetland that developed landward of a fringing mangrove forest and is maintained by seasonal Everglades water delivery. Sedimentation kept pace with sea‐level rise forming a 1.2 m thick wedge shaped, landward thinning deposit. The rate of global sea‐level rise began to accelerate ca 1900, the Anthropocene Marine Transgression, and presently the regional rate is 9.4 mm year−1. Saltwater encroachment rates &gt;80 m year−1 are driven by sea‐level rise. Saltwater encroachment resulted in retreat and transformation of coastal communities and their biogenic facies, resulting in a decrease in freshwater wetlands and marl production. Inundation ponding, mangrove overstep and the beginning of submergence are the responses to the accelerating rate of sea‐level rise, however, small scale topographic and tidal ingress differences create considerable variability between Biscayne Bay and Florida Bay coastal basins. The freshwater marl producing habitat will probably be lost within 55 years, and submergence within the next century at the present rate of sea‐level rise. The unique South‐east Saline Everglades depositional environment is compared to other Holocene palustrine depositional environments.

Comparative Phenotypic Traits and Performances of Native Sheep in Naikhongchhari Hilly Area of Bangladesh

Background: Many studies have been conducted to investigate the performance of native sheep in plains and coastal regions, but no studies have been conducted in hilly regions of Bangladesh. Considering this fact, Coastal, Barind and Jamuna River Basin sheep were evaluated for their phenotypic traits, productive and reproductive abilities to gain insights into their performance in the hilly region. Methods: The Coastal, Barind and Jamuna River Basin sheep were collected from Bangladesh Livestock Research Institute (BLRI), Savar, Dhaka for the first time to Regional Station, Naikhongchhari, BLRI and separated based on their phenotypic characteristics. A breeding program was established to ensure purity, using independent culling levels and selection indexes. Ewes were allowed to lamb throughout the year, mated with rams in a 15-20 to 1 ratio. The sheep were kept in a semi-intensive system. Result: The highest lamb birth weight was observed in coastal Region sheep, both male (1.43 kg) and female (1.22 kg), followed by Barind males (1.36 kg) and females (1.15 kg), respectively. The highest average daily gain was found in coastal region sheep (41.87 g/d), which was significantly higher compared to others. The lowest age at first heat, gestation length, age at first lambing, post-partum heat period, days open, lambing interval was observed in Barind sheep. Finally, the study offers valuable insights into the potentialities of native sheep in hilly regions, guiding future research and extension efforts for sheep farming in these areas.

Richness, types, and thermal maturation of organic matter of Jurassic to Eocene rocks of the offshore Coastal Basin, Tanzania

Richness, types, and thermal maturation of organic matter of Jurassic to Eocene rocks of the offshore Coastal Basin, Tanzania

Seasonal euxinia in a coastal basin: Impact on sedimentary molybdenum enrichments and isotope signatures

Eutrophication and global warming are leading to increased deoxygenation of coastal waters worldwide. To predict future trajectories of oxygen loss, insight into the intensity and temporal dynamics of past coastal deoxygenation is essential. Here, we assess the use of sedimentary molybdenum (Mo) enrichments and isotopic signatures (δ98Mo) as redox proxies in sediments of a seasonally euxinic coastal basin (Scharendijke, Lake Grevelingen, the Netherlands). Strong drawdown of dissolved Mo (from ∼100 to ∼60 nmol L−1) was observed in the euxinic bottom waters from July to September in 2021, coinciding with sedimentary enrichment of Mo (with peak values up to 19 ppm). A mass balance for Mo indicates that both deposition of Mo in the form of particles and diffusion of dissolved Mo into the sediment account for this Mo enrichment. The δ98Mo composition of suspended matter in the euxinic waters (0.30 to −1.95 ‰) is in line with isotopic fractionation during formation of thiomolybdates, and removal of Mo by sulfur- and/or iron-rich particles. The δ98Mo composition of the bottom water increases from 2.42 to 3.16 ‰ throughout the euxinic period, thereby further supporting preferential uptake of light Mo isotopes during sulfidation in the water column and near the sediment-water interface. The exceptionally high sedimentation rate at this site (>13 cm yr−1) allows seasonal variations in sedimentary enrichments to be preserved in the sedimentary record. Notably, sediment δ98Mo values peak during the summer euxinic period, reaching 1.28 ‰ in 2021 and as high as 2.15 ‰ in 2020. The 2020 value is close to the mean ocean value of 2.3 ‰, implying that sediments overlain by seasonally and permanently euxinic bottom waters can record the same isotopic signatures for Mo. Further work is needed to determine the potential role of diagenesis in altering δ98Mo records on time scales of months to several years.

Delineation of Groundwater Storage and Recharge Potential Zones Using Multi-Influencing Factors (MIF) Method: Application in Synclinal Coastal Basin of Essaouira (Western High Atlas of Morocco)

Unpredictable rainfall caused by climate change and pollution directly impacts groundwater demand, making the exploitation of groundwater reserves necessary. To achieve this, a study in the synclinal basin of Essaouira (Western High Atlas) used GIS, remote sensing, and the Multi-Influencing Factors (MIF) method, to identify areas ideal for the installation of productive wells. An overlay analysis created a groundwater potential zone (GWPZ) map, showing 30% of the basin with high potential, 51% with moderate potential, and 19% with low to very low potential. The groundwater potential zone map was validated using geophysical surveys, piezometric data, and well water levels, showing a 69.3% prediction accuracy with the ROC curve.

Using environmental DNA to assess the response of steelhead/Rainbow Trout and Coastrange Sculpin populations to postfire debris flows in coastal streams of Big Sur, California

AbstractObjectiveDebris flows are among the most extreme disturbances to streams and are predicted to become more frequent under climate change. We assessed the response of steelhead Oncorhynchus mykiss (anadromous Rainbow Trout)/Rainbow Trout (hereafter, collectively referred to as O. mykiss) and Coastrange Sculpin Cottus aleuticus populations to major postfire debris flows in two small coastal basins of California using noninvasive environmental DNA (eDNA) sampling.MethodsWe analyzed water samples from disturbed reaches for eDNA in the first two summers after debris flows. In Big Creek, all Coastrange Sculpin habitat was disturbed by debris flows, but a major tributary occupied by O. mykiss was not affected. In Mill Creek, all available habitat for both species was disturbed. We also sampled two unburned basins as undisturbed reference streams.ResultIn Big Creek, O. mykiss eDNA was detected in all water samples during both years, and concentrations in some samples approached the lowest concentrations in the reference streams. Coastrange Sculpin eDNA was detected only in a single water sample in the first year and was not detected in the second year. In Mill Creek, neither species was detected in the first year, but during the second year, O. mykiss eDNA was detected at very low concentrations in 40% of samples and Coastrange Sculpin eDNA was detected in a single sample.ConclusionOur results indicate that O. mykiss and Coastrange Sculpins either survived in or quickly reoccupied the disturbed reaches from within the basins. However, the detection rates for cases in which all habitat for a species in a basin was affected by debris flows indicate that abundances were very low, suggesting that persistence may be uncertain unless there is successful reproduction or immigration. Finally, eDNA appears to be effective for monitoring sensitive fish populations after a major disturbance; however, detection rates in individual samples may be low and require appropriate sampling designs to achieve the desired detection probability.

Flow-weighted sourcing of freshwater runoff from Pacific-draining continental and coastal basins in south-western Patagonia (41-56° S): characterizing regional inputs to Chilean fjords

Global estimates of the supply of dissolved and suspended materials to the ocean, in order to be relevant at either political or ecological scales, belie a finer-scale analysis necessary for understanding specific terrestrial-marine interactions. This is especially true for continental runoff to the marine critical zone of inland fjords and channels, where mechanisms, drivers, and predictions need to be elaborated in the context of changing land use and shifting climate forcing. In fjords in south-western Patagonia, runoff from small coastal and large continental basins (~310 x103 km2), sourced from a diverse geography and wide climatic gradient (&amp;lt;150 – 6,000+ mm/year), correspond with a very low density of hydrological and water quality observations. Based on the recently developed regional runoff model (FLOW), we estimated the coastal freshwater discharges and characterized flow-weighted sourcing (land use-cover type, climate, glaciers/geology, and soil province) for Pacific drainages from 41° to 56° south latitude. An estimated 692 km3/year (mean across 1979-2018), or 2% of worldwide total, is more than 85% of previous estimates for the much larger Pacific South American input. Based on limited water quality observations and inference from runoff sourcing, we predict general patterns of export for four groups of continental resources important for marine productivity, including: significant regional variation in flow seasonality, a N-S gradient in declining input of silicic acid and increased glacial input of sediment and iron, and potential shift in dissolved organic matter input sources from rainforest (potentially labile) to peatlands (refractory). Finally, we emphasize the temporal and spatial consequences of near-reference condition river runoff for marine ecosystem productivity and function in the Patagonian fjords, with specific recommendations for water quality standards and sustained monitoring for coupled river and marine ecosystems.

Ebullition drives high methane emissions from a eutrophic coastal basin

The production of methane in coastal sediments and its release to the water column is intensified by anthropogenic eutrophication and bottom water hypoxia, and it is still uncertain whether methane emissions to the atmosphere will be enhanced. Here, we assess seasonal variations in methane dynamics in a eutrophic, seasonally euxinic coastal basin (Scharendijke, Lake Grevelingen). In-situ benthic chamber incubations reveal high rates of methane release from the sediment to the water column (74–163 mmol m−2 d−1) during monthly measurements between March and October 2021. Comparison of these in-situ total benthic methane fluxes and calculated diffusive fluxes point towards a major role for ebullition. In spring and fall, when the water column was oxic, microbial removal of dissolved methane occurred aerobically in the bottom water. In summer, in contrast, dissolved methane accumulated to concentrations of up to 67 μmol L−1 below the oxycline. Shifts in δ13C–CH4 and δD-CH4 towards higher values and the abundant presence of methane oxidizing bacteria point towards removal of methane around the oxycline, likely through both aerobic and anaerobic pathways, with the latter possibly linked to iron oxide reduction. Shifts in δ13C–CH4 and δD-CH4 to lower values above the oxycline indicate that bubble dissolution contributed to dissolved methane. Methane emissions to the atmosphere were observed in all seasons with the highest, in-situ measured diffusive fluxes (1.2 mmol m−2 d−1) upon the onset of water column mixing at the end of summer. Methane release events during the measurement of in-situ water-air fluxes and model calculations point towards a flux of methane to the atmosphere in the form of bubbles, which bypass the microbial methane filter. The model calculations suggest a potential year-round ebullitive methane flux between 30 and 120 mmol m−2 d−1. We conclude that methane emissions from eutrophic coastal systems may be much higher than previously thought because of ebullition.

The frequency distribution and stochastic analysis of the hydrological drought in northern Algeria

The objective of this study was to examine drought using the Streamflow Drought Index (SDI) at various time scales and its temporal evolution using monthly streamflow data from 1973 to 2009. Streamflow records were collected from a network of 14 hydrometric stations distributed throughout the study area. The Akaike Information Criterion (AIC) and the Bayesian Information Criterion (BIC) were used to assess the quality of the adjustment. According to these criteria, the gamma law better suited the time scales of 3, 6, and 12 months, whereas the log-normal law was better suited to the scale of 9 months. The analysis of the Streamflow Drought Index in the three study basins (Middle and Upper Cheliff, Lower Cheliff, and the Mina) revealed that different classes of drought among 3, 6, 9, and 12-month time scales in the period of 1973 to 2009 had occurred, notably beginning in 1980. The frequency of 19 to 54% was found at all stations and in years marked by a mild drought. The moderate years had a frequency of 6 to 19%, while the severe and extreme years had a lower percentage (about 3 to 6%) in the study area. Two consecutive years of drought (D-D) were more likely in the Middle and Upper Cheliff basins (&gt; 60%) for the 6, 9, and 12-month time scales, according to the transition of probability of first-order non-stationary Markov chain. On a three-month time scale, the transition probabilities (D-D) were greater than 50% in the Coastal basin and Lower Cheliff basin, as well as the Mina basin, and less than 50% in the Middle and Upper Cheliff basins.

Trait Composition and Assemblage Structure Analyses of Lacustrine Fishes: Synthesizing a Proposal for Better Fishing Practices

Fish provide ecosystem services and contribute to human well-being through fishing. In Chile, subsistence fishing provides food to local communities, whereas recreational fishing contributes to economic income via tourism. In the Lanalhue coastal lake basin, unregulated subsistence fishing and formal recreational fishing primarily target large fish species to ensure satisfactory catches and food provision. However, the development of unplanned fishing activities and lack of scientific knowledge can lead to socioecological conflicts and tension between users. To address this issue, this study focuses on improving fishing practices through the analysis of fish assemblages of the Lanalhue lake basin. The life cycle traits of each fish species were analyzed, as well as their abundance and biomass in each habitat. Twelve fish species were identified, and their distribution and abundance explain the differences in fish assemblage composition and structure among habitats. To promote better fishing practices, we propose four target species and specific management actions. These include defining fishing seasons, delineating fishing sites, and establishing fishing quotas. This approach, considering both community structure and functional aspects of fish assemblages, can serve as a valuable guide for developing sustainable fishing practices in the Lanalhue coastal lake basin.

OPTIMIZATION OF MIB-02 WELL BY CONVERTING THE ACTIVATION MODE USING PROSPER SOFTWARE

Mibale oil field considered a mature oil field, located offshore in the coastal basin of the DR Congo and discovered in 1973, has seen an evolution in its production since it began operation in 1976, starting from an initial rate of 10,000 BOPD with 3 producing wells to the current production of 5,905 BOPD from 14 wells. In 2021, the field had 393 MMstb of oil reserves in the reservoir. A thorough study of the production system was carried out, focusing on the five best producing wells, including well MIB-02. Despite traversing layers of the reservoir with high oil potential, the well is underperforming with a respective flow rate of 351 BOPD and a 60% WOR using an electric submersible pump. Following this low production, various studies were conducted, including the study on converting the activation method by proceeding with nodal analysis technique. The use of nodal analysis proved crucial in identifying the shortcomings of the production system, combining field history with analysis of production, well test, pressure, and completion data. The IPM Prosper software enabled a thorough analysis, revealing that MIB-02 had a production potential greater than its current performance. This performance was revealed after evaluation and interpretation of IPR, VLP curves and sensitivities of variables such as water cut and pressure at the first node. After interpreting these curves, the MIB-02 well had the production capacity of 4100.62 BOPD and 12463.9 BWPD. By converting the submersible electric pump activation mode to gas-lift and exploring various scenarios, production was improved with an oil flow rate of 1244.9 BOPD, water flow of 2539 BWPD, to a gas flow of 0.37346 MMscf/day and 67.1% water cut. Despite these improvements, excessive water production remains a challenge while also highlighting the complexity of the production system and the limitations of the analysis technique. Therefore, further studies can be envisaged by modeling and simulating the reservoir, considering well interventions and quantifying the remaining reserves today. This more comprehensive approach will enable a clearer vision and help decide the best optimization strategies for the Mibale field production system.

Mid to Late-Holocene environmental dynamics recorded in Lake Pup Lagoon, East Antarctica: Insights from environmental magnetism and biogeochemical proxies

Paleoenvironmental archives in East Antarctica have revealed significant changes during the Holocene, marked by ice sheet retreat leading to the isolation of submarine basins. These basins offer valuable insights into past climate, glaciology, and oceanography shifts that impact sedimentary processes. In this study, environmental magnetism and biogeochemical proxies to investigate the Mid-to-Late-Holocene transitions in Pup Lagoon, a coastal isolation basin is presented. Our findings reveal distinct stratigraphic zones reflecting shifts from marine to lacustrine environments. The results reveal predominant mechanical weathering in the Stornes region, producing coarse-grained “soft” ferrimagnetic minerals. Notably, a period of warm oceanographic conditions between 6000 and 4722 cal. yr BP was characterized by mixed magnetic grain sizes and ultrafine superparamagnetic grains, indicating relatively oxic open waters in the basin. Subsequent shifts to reducing conditions coincide with persistent marine sea ice cover from 4722 to 2634 cal. yr BP, favoring the retention of coarse-grained ferrimagnets. Finer magnetic grain sizes between 2634 and 2185 cal. yr BP was attributed to the increased freshwater inputs associated with the Mid-Holocene Hypsithermal. Further, diagenetic changes under persistent sea ice cover between 2185 and 1970 cal. yr BP led to the selective dissolution of fine-grained ferrimagnets. Transitioning to freshwater isolated basin conditions between 1970 and 588 cal. yr BP, fine ferrimagnet precipitation indicate oxic to suboxic conditions alongside drier conditions. Biogenic productivity increased post-isolation, which was reflected in increased (Total Organic Carbon) TOC and (Total Nitrogen) TN percentages. Additionally, the presence of greigite in the isolated phase sediment indicates reducing conditions owing to organic matter decomposition. Notably, χfd% exhibits an inverse trend to sea ice concentration, potentially indicating anoxic-dysoxic conditions due to the presence of sea ice. These observations align with broader regional sea ice concentration changes, emphasizing the interconnected behavior of local and regional factors shaping Antarctic coastal environments.

Understanding land subsidence in the Pearl River Delta region of China based on InSAR observations

Land subsidence occurs in river delta areas. A comprehensive understanding of the factors contributing to land subsidence is crucial for effective geohazard mitigation and land planning. This study investigates the distribution characteristics and spatiotemporal evolution pattern of the land subsidence in the Pearl River Delta based on the InSAR-derived ground deformation data spanning 2016 to 2021; and, the effects of the influencing factors, including the Quaternary sediment thickness, land use classification, land reclamation, and subway construction and operation, on the subsidence are analyzed. The results unveil the presence of four major subsidence zones and several minor coastal subsidence bowls in the research area, with a total area of about 1100 km, all of which exhibit prolonged and intense subsidence. In the remaining regions, land subsidence predominantly exhibits weak and short-term occurrences. The subsidence in the study area follows a distinct linear evolutionary pattern with a slight rebound, potentially linked to the rise of groundwater levels. Regions with Quaternary sediment thickness surpassing 20 m, engaging in aquaculture or agricultural activities, and featuring reclaimed land are predisposed to prolonged and intense ground subsidence. In addition, the construction and operation of subway lines may induce ground subsidence, especially in geologically vulnerable areas. This study provides valuable insights into land subsidence research in delta regions.

The response of non-point source pollution to climate change in an orchard-dominant coastal watershed

China is the largest global orchard distribution area, where high fertilization rates, complex terrain, and uncertainties associated with future climate change present challenges in managing non-point source pollution (NPSP) in orchard-dominant growing areas (ODGA). Given the complex processes of climate, hydrology, and soil nutrient loss, this study utilized an enhanced Soil and Water Assessment Tool model (SWAT-CO2) to investigate the impact of future climate on NPSP in ODGA in a coastal basin of North China. Our investigation focused on climate-induced variations in hydrology, nitrogen (N), and phosphorus (P) losses in soil, considering three Coupled Model Intercomparison Project phase 6 (CMIP6) climate scenarios: SSP1-2.6, SSP2-4.5, and SSP5-8.5. Research results indicated that continuous changes in CO2 levels significantly influenced evapotranspiration (ET) and water yield in ODGA. Influenced by sandy soils, nitrate leaching through percolation was the principal pathway for N loss in the ODGA. Surface runoff was identified as the primary pathway for P loss. Compared to the reference period (1971–2000), under three future climate scenarios, the increase in precipitation of ODGA ranged from 15% to 28%, while the growth rates of P loss and surface runoff were the most significant, both exceeding 120%. Orchards in the northwest basin proved susceptible to nitrate leaching, while others were more sensitive to N and P losses via surface runoff. Implementing targeted strategies, such as augmenting organic fertilizer usage and constructing terraced fields, based on ODGA's response characteristics to future climate, could effectively improve the basin's environment.

Exploring the Spatial Distribution of Coastal Drainage Basins in Turkey

Coastal regions are vital areas globally, serving as hubs for human habitation and economic activities. Water, being the fundamental resource for life, plays a crucial role in sustaining ecosystems and shaping coastal landscapes. The convergence of river systems in coastal zones underscores their significance in the hydrological cycle and aquatic biodiversity. However, managing these valuable yet vulnerable regions presents multifaceted challenges, necessitating robust management frameworks supported by monitoring and assessment tools. In Türkiye, a country with limited freshwater resources, the management of coastal zones is particularly complex due to increasing pressure on resources and land. This study examines the distribution and characteristics of river and coastal basins in Türkiye. Through spatial analyses on Geographical Information System and basin delineations with watershed modelling program, the study clarifies the regional differences and obstacles encountered by coastal provinces spanning the entirety of Türkiye's coastal borders. The results offer valuable understanding regarding the spatial dynamics of Türkiye's coastal areas with particular emphasis on the significance of Black Sea coastal basins and all coastal provinces. Firstly, river basin systems draining into the Black Sea constitute the majority of Türkiye's surface area. Although the Black Sea region covers only 14% of the total area, more than half of the country's surface area, excluding transboundary and endorheic basins, drains into the Black Sea. Similarly, the analysis of basin types reveals that coastal basins constitute approximately 18% of the drainage areas associated with our coastal waters, nearly one-fifth. This distinction between coastal basin and river basin boundaries differs from the traditional zoning approach in river basin management and coastal area management plans in Türkiye. Consequently, it is anticipated that this spatial evaluation, which has brought a new perspective, will significantly contribute to addressing management challenges, especially the studies that will be evaluated together with population and resource use.

Seasonal euxinia in a coastal basin: Impact on sedimentary molybdenum enrichments and isotope signatures

Eutrophication and global warming are leading to increased deoxygenation of coastal waters worldwide. To predict future trajectories of oxygen loss, insight into the intensity and temporal dynamics of past coastal deoxygenation is essential. Here, we assess the use of sedimentary molybdenum (Mo) enrichments and isotopic signatures (δ98Mo) as redox proxies in sediments of a seasonally euxinic coastal basin (Scharendijke, Lake Grevelingen, the Netherlands). Strong drawdown of dissolved Mo (from ~100 to ~60 nmol L−1) was observed in the euxinic bottom waters from July to September in 2021, coinciding with sedimentary enrichment of Mo (with peak values up to 19 ppm). A mass balance for Mo indicates that both deposition of Mo in the form of particles and diffusion of dissolved Mo into the sediment account for this Mo enrichment. The δ98Mo composition of suspended matter in the euxinic waters (0.30 to −1.95 ‰) is in line with isotopic fractionation during formation of thiomolybdates, and removal of Mo by sulfur- and/or iron-rich particles. The δ98Mo composition of the bottom water increases from 2.42 to 3.16 ‰ throughout the euxinic period, thereby further supporting preferential uptake of light Mo isotopes during sulfidation in the water column and near the sediment-water interface. The high sedimentation rate at this site (>13 cm yr−1) allows seasonal variations in sedimentary enrichments to be preserved in the sedimentary record. Notably, sediment δ98Mo values peak during the summer euxinic period, reaching 1.28 ‰ in 2021 and as high as 2.15 ‰ in 2020. The 2020 value is close to the mean ocean value of 2.3 ‰, implying that sediments overlain by seasonal and permanently euxinic bottom waters can record the same isotopic signatures for Mo. Further work is needed to determine the potential role of diagenesis in altering δ98Mo records on time scales of months to several years.

Microfacies Characterization of Calcareous Crusts and Pleistocene Moghrebian Strata in the Coastal Basin of Tarfaya (Morocco): Paleoclimatic and Paleoenvironmental Implications

Microfacies Characterization of Calcareous Crusts and Pleistocene Moghrebian Strata in the Coastal Basin of Tarfaya (Morocco): Paleoclimatic and Paleoenvironmental Implications