In view of the low water flux and fluoride ion (F−) retention rate of forward osmosis emergency water bags in coal mine emergency rescue, sulfonated graphene oxide (SGO) is selected to modify the polysulfone-polyamide forward osmosis (FO) membrane to obtain high water flux and F−retention rate in this work. The results show that the crosslinking of m-phenylenediamine (MPD) improves the sulfonated graphene oxide (SGO) dispersion of the polyamide layer in the interfacial polymerization (IP) reaction, and the polyamide active layer with more hydrophilic and more water flux is obtained, and the increase in water flux is up to 6 times. Furthermore, the negatively charged SGO reduces the surface potential of the polyamide membrane, which significantly improves the F−retention effect of the high water flux FO membrane to 83.2 %. At the same time, the existence of Donnan's law leads to differences in the retention performance of different anions. Therefore, SGO-modified polysulfone-polyamide FO membrane presents excellent permeability performance, which provides a new combination of materials and technologies for fluorine-containing wastewater environmental emergency rescue and high-fluorine wastewater treatment.