CoFe-layered Double Hydroxide Research Articles

FeCo Bimetallic ZIF Derivatives decorated with CoFe-LDH to Promote Bifunctional Oxygen Electrocatalysis Activation.

Reasonably screening the targeted oxygen reduction reaction (ORR)/oxygen evolution reaction (OER) constituents and constructing high-efficiency and stabilized ORR/OER bifunctional electrocatalysts are pivotal for the advancement of rechargeable zinc-air batteries (ZABs). Here, CoFe layered double hydroxide (CoFe-LDH) nanosheets are deposited on nitrogen-doped graphite-carbon polyhedra with FeCo alloy nanoparticles (FeCo/LDH-NGCP). Due to the synergic effect between FeCo-NGCP, CoFe-LDH and FeCo/LDH-NGCP, the electrocatalyst with the abundant and accessible active sites can provide good charge/mass transfer, and thus shows wonderful ORR and OER bifunctional electrocatalytic performance. In ORR tests, FeCo/LDH-NGCP catalyst displays larger half-wave potential (E1/2, 0.89 V vs. 0.85 V), higher limiting current density (JL, 5.91 mA/cm2 vs. 5.14 mA/cm2) and better stability than commercial Pt/C. As for OER, FeCo/LDH-NGCP possesses a smaller overpotential (η) of 299.6 mV at a current density of 10 mA/cm2 and more durable stability than commercial RuO2 (330.6 mV). Furthermore, in ZAB tests, the cycling stability of ZAB-FeCo/LDH-NGCP (over 470 h) outperforms the ZAB-Pt/C+RuO2 (92 h) with commercial electrocatalyst (Pt/C+RuO2). Therefore, the FeCo/LDH-NGCP catalyst offers a new perspective to construct ZABs bifunctional catalysts and their commercial application in ZABs.

CoFe-LDHs were grown on Co-layered hydroxides to achieve 3D-hierarchical flower like architecture for efficient oxygen evolution reaction

In this work, we have successfully synthesized an efficient and cost-effective electrocatalyst for alkaline oxygen evolution (OER) using a solvothermal method combined with an ion exchange strategy. Firstly, single Co-layer hydroxides (Co-LHs) were synthesized by a one-step solvothermal method. Subsequently, [Fe(C2O4)3]3- was introduced onto the Co-LHs surface to facilitate ion exchange, and a further CoFe-layered double hydroxides (CoFe-LDHs) layer was grown on the Co-LHs material surface to finally obtain the nanoflower-like Co-LHs@CoFe-LDHs composite. Related material characterization results showed that C2O42- was successfully inserted into the interlayer structure of the LDHs, resulting in an increase in interlayer spacing. In situ Raman spectroscopy revealed that the active site of the OER reaction in the Co-LHs@CoFe-LDHs material was CoOx. Thanks to the double structure of the LDHs improving charge transfer ability and the synergy between cobalt and iron species, Co-LHs@CoFe-LDHs showed significantly enhanced OER performance. This study provides new insights and methods for the development of novel LDHs structural electrocatalysts.

Guided Heterostructure Growth of CoFe LDH on Ti3C2Tx MXene for Durably High Oxygen Evolution Activity.

Heterostructures of layered double hydroxides (LDHs) and MXenes have shown great promise for oxygen evolution reaction (OER) catalysts, owing to their complementary physical properties. Coupling LDHs with MXenes can potentially enhance their conductivity, stability, and OER activity. In this work, a scalable and straightforward in situ guided growth of CoFeLDH on Ti3C2Tx is introduced, where the surface chemistry of Ti3C2Tx dominates the resulting heterostructures, allowing tunable crystal domain sizes of LDHs. Combined simulation results of Monte Carlo and density functional theory (DFT) validate this guided growth mechanism. Through this way, the optimized heterostructures allow the highest OER activity of the overpotential = 301mV and Tafel slope = 43mV dec-1 at 10mA cm-2, and a considerably durable stability of 0.1% decay over 200h use, remarkably outperforming all reported LDHs-MXenes materials. DFT calculations indicate that the charge transfer in heterostructures can decrease the rate-limiting energy barrier for OER, facilitating OER activity. The combined experimental and theoretical efforts identify the participation role of MXene in heterostructures for OER reactions, providing insights into designing advanced heterostructures for robust OER electrocatalysis.

Bifunctional Bismuth-Based Layered Double Hydroxide Sonosensitizer for Magnetic Resonance Imaging-Guided Sonodynamic Cancer Therapy.

Novel inorganic sonosensitizers with excellent reactive oxygen species (ROS) generation activity and multifunctionality are appealing in sonodynamic therapy (SDT). Herein, amorphous bismuth (Bi)-doped CoFe-layered double hydroxide (a-CoBiFe-LDH) nanosheets are proposed via crystalline-to-amorphous phase transformation strategy as a new type of bifunctional sonosensitizer, which allows ultrasound (US) to trigger ROS generation for magnetic resonance imaging (MRI)-guided SDT. Importantly, a-CoBiFe-LDH nanosheets exhibit much higher ROS generation activity (≈6.9 times) than that of traditional TiO2 sonosensitizer under US irradiation, which can be attributed to the acid etching-induced narrow band gap, high electron (e-)/hole (h+) separation efficiency and inhibited e-/h+ recombination. In addition, the paramagnetic properties of Fe ion endow a-CoBiFe-LDH with excellent MRI contrast ability, making it a promising contrast agent for T2-weighted MRI. After modification with polyethylene glycol, a-CoBiFe-LDH nanosheets can function as a high-efficiency sonosensitizer to activate p53, MAPK, oxidative phosphorylation, and apoptosis-related signaling pathways, ultimately inducing cell apoptosis in vitro and tumor ablation in vivo under US irradiation, which shows great potential for clinical cancer treatment.

Trace ruthenium dioxide stabilize active center of CoFe-LDH for efficient water electrolysis

It is immensely meaningful to design efficient electrolysis for water electrolysis and realize green hydrogen production. Herein, a ruthenium dioxide modified CoFe-Layered double hydroxides (LDHs) catalyst (RuO2/CoFe-LDH/NF) was synthesized by combining the advantages of RuO2 and CoFe-LDHs for driving alkaline water and seawater. RuO2/CoFe-LDH/NF display impressive activity and stability at 10 mA cm−2, which only need an overpotential of 59 and 270 mV for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) respectively. Meaningfully, the catalyst only required a small cell voltage of 1.58 V as a bifunctional catalyst, what is superior to commercial RuO2/NF||Pt/C/NF (1.66 V). In addition, RuO2/CoFe-LDH/NF exhibited excellent HER and OER performance with overpotentials of 119 and 260 mv in alkaline seawater at 10 mA cm−2, respectively. Additionally, RuO2/CoFe-LDH/NF displays a larger corrosion potential, smaller corrosion and improved oxygen evolution capacity than CoFe-LDH/NF. Moreover, there is electron transfer between Ru and Co or Fe, which can improve the micro-coordination environment and enhance the stability for RuO2/CoFe-LDH/NF. The method with integration of RuO2 and CoFe-LDH could be broadened to explore other robust bifunctional catalysts for water/seawater electrolysis.

Constructing core-shell structured Mott–Schottky heterojunction towards remarkable hydrogen production from water/seawater splitting

Green hydrogen production through electrocatalytic water/seawater splitting has recently received significant attention. However, the practical utilization for this technique is still limited due to the poor performance and stability of electrocatalysts. Herein, a heterogeneous core-shell hybrid, containing Ni3S2 nanorod arrays and CoFe layered double hydroxide (LDH) nanosheets, has been fabricated via a developed two-step hydrothermal and electrodeposition method. The build-in electronic field in the as-formed Mott–Schottky barrier endows the efficient electron transfer from CoFe LDH to Ni3S2, subsequently enhancing the reaction kinetics. The as-prepared Ni3S2@CoFe catalyst exhibits exceptional performance for oxygen evolution reaction (OER, η10 = 222 and 237 mV) and hydrogen evolution reaction (HER, η10 = 83 and 109 mV) in 1 M KOH as well as alkaline seawater environments, respectively. Notably, it only requires a cell voltage of 1.51 and 1.55 V to achieve a current density of 10 mA cm2 for overall seawater and water splitting, respectively, outperforming the commercial benchmark Pt/C||RuO2 (1.56 V). This work paves a solid way for construction of Mott–Schottky catalysts for green hydrogen production and its beyond.

Flexible and hydrophobic CoFe-LDH @Co MOF @biomass-derived carbon fabrics for effective near-infrared photothermal conversion and electromagnetic attenuation

Near-infrared (NIR) laser countermeasures firing systems and electromagnetic wave shielding are extremely important in military warfare. Herein, a series of biomass-derived carbon flexible textiles with NIR photothermal conversion and microwave absorption capabilities were created by pyrolysis at temperatures ranging from 700 to 1000 °C. A hydrothermal approach was employed to create 2D CoFe-layered double hydroxides (CoFe-LDH), whose positively charged characteristics were securely attached to the hydroxide clusters on the surface of cotton fibers via electrostatic interaction. Subsequently, the adjustable layer spacing of LDH provides ideal in situ growth sites for metal ions and organic ligands of Co MOF. CoFe-LDH@Co MOF@PDMS cotton-derived carbon textiles (CoFe@PCCF) were successfully made using high-temperature pyrolysis, annealed carbonization, and polydimethylsiloxane curing. The intrinsic light absorption of the interwoven and entangled carbon fibers, combined with the plasmonic resonance of its surface metal particles, promotes photothermal conversion of the material, reduces density, and increases absorption during multiple reflections of electromagnetic waves. Furthermore, its qualities can be optimized and modified by modifying parameters like as carbonization temperature and thickness. As a result, CoFe@PCCF-900 shows the minimum reflection loss (RLmin) of −23.03 dB at 1.6 mm thickness and an effective absorption bandwidth (EAB) of 4.53 GHz. The surface temperature of CoFe@PCCF-1000 reaches 74.5 ℃ after 3 seconds of NIR (980 nm, 200 mW) light, indicating quick and stable photothermal conversion. This work provides an opportunity for laser shooting and electromagnetic attenuation low-cost materials.

A high-flux atomically dispersed MIL-100 (Fe) incorporated PMS-based LDH catalytic membrane for the removal of micropollutants from secondary effluent wastewater

This study fabricated a CoFe layered double hydroxide (CoFeLDH) membrane incorporating the metal–organic framework (MOF) MIL(100)Fe, tailored for a peroxymonosulfate (PMS) based system. Among various combinations of MOF and LDH nanosheets on a PVDF substrate, the highest water flux, reaching 1900 L/m2/hr/bar, was achieved with an LDH/MOF ratio of 5:1 and an MOF concentration of 0.025 M. The optimized membrane exhibited exceptional performance, achieving 99 % degradation of ranitidine at 0.1 mM PMS. The LDH MOF catalytic membrane exhibited excellent treatment performance in real water matrices and demonstrated long-term operational efficiency. The effective removal of ranitidine by this catalytic membrane was attributed to a synergistic combination of radical (SO4− and OH) and non-radical (singlet 1O2 and electron transfer O2) oxidation pathways, with SO4− and singlet 1O2 playing a predominant role. Post-activation, 40 % of surface Co2+ and 65 % of Fe2+ in the LDH MOF membrane were found in the + III oxidation state, highlighting the significance of metal catalytic sites and the reusability potential of the membrane. The durability of the membrane was evident through 10 cycles, achieving a flux recovery ratio of 95 % in the first cycle and sustaining efficient performance across pH variations (3 to 9) and exposure to various anions. Importantly, negligible metal leaching was observed for the real water samples, ensuring suitability for large-scale applications.

CoFe Layered Double Hydroxide Supported on Fe-Doped BiVO4 Nanoparticles as Photoanode for Photoelectrochemical Water Splitting

CoFe Layered Double Hydroxide Supported on Fe-Doped BiVO₄ Nanoparticles as Photoanode for Photoelectrochemical Water Splitting

Exploiting calcinated CoFe-layered double hydroxide for the photo-persulfate catalytic degradation of sulfamethoxazole

This study synthesized CoFe-layered double oxide (CoFe-LDO) from CoFe-layered double hydroxide (CoFe-LDH) via simple calcination. The resulting CoFe-LDO material was characterized and first employed as a heterogeneous catalyst for sulfamethoxazole (SMX) degradation. The synergic activation of persulfate (PS) by CoFe-LDO in the presence of UV light was demonstrated in a degradation study. The UV/CoFe-LDO/PS system (pronounced as photo-PS system) achieved approximately 98 % SMX removal within 60 min with 0.1 g/L catalyst and 5 mM PS concentration. Compared with the control experiments, the PS was effectively activated by the CoFe-LDO, which degrades SMX in the presence of UV light. The effects of catalyst dosage and PS concentrations were examined, and 0.1 g/L CoFe-LDO and 5 mM PS were determined to be optimal for achieving complete SMX degradation within 60 min. Furthermore, the CoFe-LDO catalyst exhibited superior catalytic activity under weakly acidic pH conditions (i.e., pH 5–6). Reactive oxygen species were identified by scavenging experiments and electron spin resonance, suggesting that SO4•− and •OH radicals as well as 1O2 contributed to the SMX degradation. This finding proposed a plausible mechanism for SMX degradation in the UV/CoFe-LDO/PS system. Furthermore, nine by-products after the photo-PS process were identified, which were supposed to be generated through radical and non-radical pathways. This work offers a simple strategy for developing a sustainable, efficient, and effective catalyst for degrading persistent organic pollutants from water.

Molybdate intercalated CoFe-layered double hydroxides for overall water splitting

The exploration of bifunctional electrocatalysts with abundant resources and excellent catalytic performances is currently one of the fundamental conditions for the development and promotion of hydrogen energy technology. In this work, an extremely simple one-step hydrothermal strategy was proposed for the preparation of CoFe-layered double hydroxide nanosheets intercalated with molybdate (CoFe-LDH-MoO42-). The well-designed electrocatalyst exhibits outstanding catalytic activity due to the adjustability of two-dimensional layered materials, synergistic effects of Co and Fe, as well as expanded inter-layer distance, which necessitates overpotential of 74 and 92 mV at 10 mA cm−2 for HER and OER, respectively. When the CoFe-LDH-MoO42- is assembled in a two-electrode system, it requires a cell voltage of 1.50 V to drive 10 mA cm−2. The innovative exploration of this work offers a novel approach to construct multifunctional electrocatalysts for efficient and stable total water splitting.

Degradation of Tetracycline through peroxymonosulfate activation with Co/Fe-LDH modified magnetic hydrochar: Synergistic effect and low toxicity

In this work, 2LDH-CoFe2O4@BHC catalyst was prepared by modifying magnetic corncob-based hydrochar (CoFe2O4@BHC) with Co/Fe layered double hydroxide (Co/Fe-LDH), which was used to activate peroxymonosulfate (PMS) for tetracycline (TC) degradation. 2LDH-CoFe2O4@BHC demonstrated effective activation of PMS and rapid removal of TC (100 %) within 10 min by leveraging structural modulation and synergistic interactions among multiple components. In contrast, BHC (26.02 %), CoFe2O4 (59.25 %), and CoFe2O4@BHC (61.88 %) presented poor removal efficiency. Furthermore, it was shown that both the free radicals (SO4•-) and non-free radicals (1O2) were essential in the degradation process, and the catalytic mechanism was revealed to be a synergistic process with the characterization results from in-situ Raman, electrochemical characterization, and X-ray photoelectron spectroscopy (XPS). The catalytic performance of 2LDH-CoFe2O4@BHC was also evaluated using a self-developed fixed-bed reactor, demonstrating its strong stability and resistance to interference during long-term operation. The potential degradation pathway of TC in the 2LDH-CoFe2O4@BHC + PMS system was suggested based on the quadrupole time-of-flight mass spectrometry (QTOF/MS) findings. It was found that the toxicity of the intermediates produced by TC degradation significantly reduced. This study presented an insight for the decomposition of organic pollutants by synthetic biochar-loaded catalysts.

Efficient bimetallic activation of sulfite by CoFe-LDH for bisphenol A removal: Critical role of Co/Fe ratio on ROS generation

The sulfite (S(IV))-based advanced oxidation process is an emerging approach for the treatment of phenolic pollution. In this study, CoFe-layered double hydroxides (CoFe-LDHs), showing superior physicochemical properties as catalysts, were applied to activate S(IV) for bisphenol A (BPA) degradation. The results show that the Co/Fe molar ratios play a crucial role in regulating the physicochemical properties, degradation capacity, and activation mechanism of the catalysts, with Co3Fe1-LDH exhibiting the best performance in BPA degradation. The degradation of BPA is significantly influenced by pH and dissolved oxygen, and proceeds through bimetallic synergism and both radical and non-radical pathways. However, with increasing Co/Fe ratio, SO4•− gradually assumes a more prominent role in degradation by the system, and the contributions from high-valent metals and HO• gradually diminish. Additionally, the system brought about a substantial reduction in toxicity after degradation, and the catalyst demonstrated promise in consecutive recycling experiments, the degradation of other organics, and tests in actual water bodies.

Reactive layered hydroxide membrane for advanced water treatment: Micropollutant degradation and antifouling potential

The effective removal of micropollutants by water treatment technologies remains a significant challenge. Herein, we develop a CoFe layered double hydroxide (CoFeLDH) catalytic membrane for peroxymonosulfate (PMS) activation to achieve efficient micropollutant removal with improved mass transfer rate and reaction kinetics. This study found that the CoFeLDH membrane/PMS system achieved an impressive above 98% degradation of the probe chemical ranitidine at 0.1 mM of PMS including five more micropollutants (Sulfamethoxazole, Ciprofloxacin, Carbamazepine, Acetaminophen and Bisphenol A) at satisfactory level (above 80%). Moreover, significant improvements in water flux and antifouling properties were observed, marking the membrane as a specific advancement in the removal of membrane fouling in water purification technology. The membrane demonstrated consistent degradation efficiency for several micropollutants and across a range of pH (4–9) as well as different anionic environments, thereby showing it suitability for scale-up application. The key role of reactive species such as SO4•–, and O2• − radicals in the degradation process was elucidated. This is followed by the confirmation of the occurrence of redox cycling between Co and Fe, and the presence of CoOH+ that promotes PMS activation. Over the ten cycles, the membrane could be operated with a flux recovery of up to 99.8% and maintained efficient performance over 24 h continuous operation. Finally, the efficiency in degrading micropollutants, coupled with reduced metal leaching, makes the CoFeLDH membrane as a promising technology for application in water treatment.

Cellulose-based Co[sbnd]Fe LDH composite as a nano-adsorbent for sulfamethoxazole and cefixime residues: Evaluation of performance, green metrics and cytotoxicity

The increase in antibiotic residues poses a serious threat to ecological and aquatic environments, necessitating the development of cost-effective, convenient, and recyclable adsorbents. In our study, we used cellulose-based layered double hydroxide (LDH) as an efficient adsorbent and nanocarrier for both sulfamethoxazole (SMX) and cefixime (CFX) residues due to their biodegradability and biocompatibility. Chemical processes are measured according to green chemistry metrics to identify which features adhere to the principles. A GREEnness Assessment (ESA), Analytical GREEnness Preparation (AGREEprep), and Analytical Eco-Scale Assessments (ESA) were used to assess the suitability of the proposed analytical method. We extensively analyzed the synthesized CoFe LDH/cellulose before and after the adsorption processes using XRD, FTIR, and SEM. We investigated the factors affecting the adsorption process, such as pH, adsorbent dose, concentrations of SMX and CFX and time. We studied six nonlinear adsorption isotherm models at pH 5 using CoFe LDH, which showed maximum adsorption capacities (qmax) of 272.13 mg/g for SMX and 208.00 mg/g for CFX. Kinetic studies were also conducted. The 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl-2H-tetrazolium bromide (MTT) assay was performed on Vero cells in direct contact with LDH nanocomposites to evaluate the cytotoxicity and side effects of cellulose-based CoFe LDH. The cellulose-based CoFe LDH nanocomposite demonstrated excellent cytocompatibility and less cytotoxic effects on the tested cell line. These results validate the potential use of these unique LDH-based cellulose cytocompatible biomaterials for water treatment applications. The cost of the prepared adsorbents was investigated.

Understanding highly active and durable Fe-decorated Co(OH)2 catalysts in alkaline oxygen evolution reaction by in situ XANES studies

The activation and degradation mechanisms of CoFe layered double hydroxide (CoFe-LDH) and Fe-decorated Co(OH)2 (Fe-Co(OH)2) have been investigated using in situ X-ray absorption spectroscopy coupled with cyclic voltammetry (CV) in 0–0.9 V (vs Hg/HgO). A series of CoFe-LDH samples have been prepared by co-electrodeposition with varying Co/Fe ratios. Fe-decorating on Co(OH)2 has been applied using 10 ppm of Fe in 1.0 M KOH. Electrochemical impedance spectroscopy (EIS) and CV cycles confirm the degradation of Co(OH)2 and CoFe-LDH due to the irreversible redox of Co(OH)2/CoOOH, and Fe extraction. In contrast, Fe-decorated Co(OH)2 shows high activity and stability in the OER. In situ XANES analysis suggests that the Fe-decorating allows the Co(OH)2 to remain as γ-CoOOH even under potential fluctuations.

Application of cobalt-cerium-iron ternary layered double hydroxide for extraction of perfluorooctane sulfonate followed by HPLC-MS/MS analysis

Herein, Ce-doped CoFe layered double hydroxide (LDH), noted as CoCeFe ternary LDH, was prepared using the co-precipitation route. Prosperous synthesis of CoFe LDH and successful partial replacement of iron cations with cerium cations in CoCeFe ternary LDH were confirmed by X-ray diffraction patterns, energy-dispersive X-ray spectroscopy, and elemental dot-mapping images. Nanosheet morphology was recognized for both CoFe LDH and CoCeFe ternary LDH from scanning electron microscopy and transmission electron microscopy micrographs. In the following, a dispersive solid phase extraction (DSPE) method was developed using the synthesized CoCeFe ternary LDH as a sorbent for extracting perfluorooctanesulfonic acid (PFOS) from wastewater samples. For the selective analysis of PFOS, high-performance liquid chromatography-tandem mass spectroscopy (HPLC-MS/MS) in multiple reaction monitoring mode was used. Analytical parameters such as the limit of detection equal to 0.02 μg/L, with a linear range of 0.05–300 μg/L, the limit of quantification equal to 0.05 μg/L, and an enrichment factor equal to 23.3 were achieved for PFOS at the optimized condition (sorbent: 5 mg of CoCeFe ternary LDH, eluent type and volume: 150 μL mobile phase, pH: 3, adsorption time: 3 min, and desorption time: 5 min). The developed strategy for the analysis of PFOS was tested in real wastewater samples, including copper mine and petrochemical wastewater. The amount of analytes in real samples was calculated using the standard addition method, and good relative recovery in the range of 86%–105% was obtained. The main novelty of this research is the application of CoCeFe ternary LDH to extract the PFOS from wastewater using the DSPE method for determination by HPLC-MS/MS.

Cu3P Nanoarrays Fabricated on Copper Foam Substrates Followed by Coating with CoFe Layered Double Hydroxide Nanosheets as Electrocatalysts for Water Splitting

Cu₃P Nanoarrays Fabricated on Copper Foam Substrates Followed by Coating with CoFe Layered Double Hydroxide Nanosheets as Electrocatalysts for Water Splitting

Enhanced photocatalytic performance of MXene-Modified cation-exchanged CoFe-LDH/CoFeCrO4 heterostructure for Antibiotic degradation and hydrogen production through synergistic charge dynamics

Systemizing an effective charge-transfer channel across a junction interface replete with ample active sites for enhancing the photocatalytic activity of semiconducting materials presents a formidable challenge. Here, we present a novel approach based on an in situ hydrothermal method for synthesizing CoFe-Layered Double Hydroxide (LDH)/CoFeCrO4 heterojunction materials that were partially derived from CoFe-LDH. These materials synergistically interact with Ti3C2 MXene nanosheets facilitating multi-interface interactions. Indeed, the highest tetracycline hydrochloride degradation rate of nearly 92% in 2 h was achieved because of the intense synergy between the CoFe-LDH/CoFeCrO4 heterojunction material optimized with 7.5 wt% of MXene nanosheets (CMC-7.5). This degradation performance was 3.1 times greater than that of the original CoFe-LDH. Further, CMC-7.5 produces the highest H2 gas of 458.79 μmol h−1g−1 from a photocatalytic water splitting reaction. The formation of a Schottky energy barrier between the partially derived CoFe-LDH/CoFeCrO4 unit and MXene promoted the fast transfer of photogenerated electrons from CoFe-LDH/CoFeCrO4 to the surface of MXene, thereby providing a plethora of active sites for photocatalytic reactions. Photoelectrochemical assessments using transient and linear sweep voltammetry along with electrochemical impedance spectroscopy confirmed efficient charge carrier transfer. Moreover, the optimized CMC-7.5 photoelectrode has a superior integral area and exhibited excellent stability over 100 cycles. Finally, the study outlines the construction of several advanced materials with multi-interface heterojunctions involving cation-exchanged LDH derivatives with high photogenerated charge carrier separation efficiency and minimal interfacial migration resistance to serve as stability benchmarks for practical applications.

CoFe-Layered Double Hydroxide Needles on MoS2/Ni3S2 Nanoarrays for Applications as Catalysts for Hydrogen Evolution and Oxidation of Organic Chemicals

CoFe-Layered Double Hydroxide Needles on MoS₂/Ni₃S₂ Nanoarrays for Applications as Catalysts for Hydrogen Evolution and Oxidation of Organic Chemicals