The basic national condition that is dominated by coal will not alter in the foreseeable future. Coal-fired boiler is the main equipment for coal utilization, and cyclone burner is a practical type of burner. There is a cyclone formation, a primary air duct inside the center air duct, and a secondary air duct. Introducing a small stream of pulverized coal gas or oil mist stream or gas directly into the reflux zone in the center duct ignites first a stable combustion and a small fluctuation of ignition pressure. In this paper, the variation of furnace temperature for cyclone pulverized coal burner corresponding to different excess air factors and the composition of gases such as O2, CO, CO2, and NOX produced by combustion were investigated using fluent software. A single cyclone pulverized coal burner from an actual coal-fired boiler is used, and a combustion zone applicable to the study of a single pulverized coal burner is established to study the actual operation of a single pulverized coal burner at different excess air coefficients. The findings indicate that the ignition position of pulverized coal combustion advances with decreasing α (Excess Air Factors); however, the length of the produced high-temperature flame gets shorter. As the value of α decreases, the burnout in the furnace decreases and the CO emission concentration increases, with a maximum CO mole fraction of 0.38% at α = 1.2 and a maximum CO mole fraction of 3.13% at the axial position when α decreases to 0.8. The furnace’s concentration of NOX, the NOX emission level decreases significantly with decreasing α. The NOX mole mass increases gradually with increasing α, and in the bottom portion of the primary combustion zone, more NOX is produced. The concentration of NOX in the chamber changes significantly after α exceeds 1.0, and the NOX at the outlet surges from 417.25 ppm to 801.07 ppm, which is attributed to the increase in the average temperature of the chamber, which promotes the generation of thermophilic NOX. The distribution pattern of O2 mole fraction along the furnace height cross-section at different excess air factors is basically the same, with a maximum at the burner inlet and a gradual decrease in the O2 content as it enters the combustion chamber to react with the pulverized coal in a combustion reaction. The value of α = 0.8 when the air supply is obviously insufficient, the fuel cannot be fully combusted, and only a small amount of CO2 is produced.