Clear-sky Retrievals Research Articles

A Near-Real-Time Method for Estimating Volcanic Ash Emissions Using Satellite Retrievals

We present a Bayesian inversion method for estimating volcanic ash emissions using satellite retrievals of ash column load and an atmospheric dispersion model. An a priori description of the emissions is used based on observations of the rise height of the volcanic plume and a stochastic model of the possible emissions. Satellite data are processed to give column loads where ash is detected and to give information on where we have high confidence that there is negligible ash. An atmospheric dispersion model is used to relate emissions and column loads. Gaussian distributions are assumed for the a priori emissions and for the errors in the satellite retrievals. The optimal emissions estimate is obtained by finding the peak of the a posteriori probability density under the constraint that the emissions are non-negative. We apply this inversion method within a framework designed for use during an eruption with the emission estimates (for any given emission time) being revised over time as more information becomes available. We demonstrate the approach for the 2010 Eyjafjallajökull and 2011 Grímsvötn eruptions. We apply the approach in two ways, using only the ash retrievals and using both the ash and clear sky retrievals. For Eyjafjallajökull we have compared with an independent dataset not used in the inversion and have found that the inversion-derived emissions lead to improved predictions.

Detection of carbon monoxide pollution from cities and wildfires on regional and urban scales: the benefit of CO column retrievals from SCIAMACHY 2.3 µm measurements under cloudy conditions

Abstract. In the perspective of the upcoming TROPOMI Sentinel-5 Precursor carbon monoxide data product, we discuss the benefit of using CO total column retrievals from cloud-contaminated SCIAMACHY 2.3 µm shortwave infrared spectra to detect atmospheric CO enhancements on regional and urban scales due to emissions from cities and wildfires. The study uses the operational Sentinel-5 Precursor algorithm SICOR, which infers the vertically integrated CO column together with effective cloud parameters. We investigate its capability to detect localized CO enhancements distinguishing between clear-sky observations and observations with low (< 1.5 km) and medium–high clouds (1.5–5 km). As an example, we analyse CO enhancements over the cities Paris, Los Angeles and Tehran as well as the wildfire events in Mexico–Guatemala 2005 and Alaska–Canada 2004. The CO average of the SCIAMACHY full-mission data set of clear-sky observations can detect weak CO enhancements of less than 10 ppb due to air pollution in these cities. For low-cloud conditions, the CO data product performs similarly well. For medium–high clouds, the observations show a reduced CO signal both over Tehran and Los Angeles, while for Paris no significant CO enhancement can be detected. This indicates that information about the vertical distribution of CO can be obtained from the SCIAMACHY measurements. Moreover, for the Mexico–Guatemala fires, the low-cloud CO data captures a strong outflow of CO over the Gulf of Mexico and the Pacific Ocean and so provides complementary information to clear-sky retrievals, which can only be obtained over land. For both burning events, enhanced CO values are even detectable with medium–high-cloud retrievals, confirming a distinct vertical extension of the pollution. The larger number of additional measurements, and hence the better spatial coverage, significantly improve the detection of wildfire pollution using both the clear-sky and cloudy CO retrievals. Due to the improved instrument performance of the TROPOMI instrument with respect to its precursor SCIAMACHY, the upcoming Sentinel-5 Precursor CO data product will allow improved detection of CO emissions and their vertical extension over cities and fires, making new research applications possible.

An Accurate Estimate of Monthly Mean Land Surface Temperatures from MODIS Clear-Sky Retrievals

Abstract MODIS thermal sensors can provide us with global land surface temperature (LST) several times each day, but have difficulty in obtaining information from the land surface in cloudy situations. As a result, the monthly day or night LST products [Terra monthly day LST (TMD), Terra monthly night LST (TMN), Aqua monthly day LST (AMD), and Aqua monthly night LST (AMN)] are the average LST values calculated over a variable number of clear-sky days in a month. Is it possible to derive an accurate estimate of monthly mean LST based on averaging of the multidaily overpasses of MODIS sensors? In situ ground measurements and ERA-Interim reanalyses data, both of which provide continuous information in either clear or cloudy conditions, have been used to validate the approach. Using LST measurements from 156 ground flux towers, it was found that the three mean values , , and (mean biases of 0.19, 0.59, and 0.40 K, respectively) can all provide a reliable estimate of all-sky monthly mean LST. Of the three means, we recommend the use of for monthly mean LST in climate studies as it provides the most complete coverage. When retrievals from either Terra or Aqua are not available, then either or may be used to fill the gaps. The intrinsic error in the MODIS monthly mean LST cannot be explained from monthly mean view time, view angle, and clear-sky ratio. MODIS monthly LST calculated using this approach (RMSE = 2.65, mean bias < ±1 K) will have wide applicability for climate studies and numerical model evaluation.

Carbon monoxide column retrieval for clear-sky and cloudy atmospheres: a full-mission data set from SCIAMACHY 2.3 µm reflectance measurements

Abstract. We discuss the retrieval of carbon monoxide (CO) vertical column densities from clear-sky and cloud contaminated 2311–2338 nm reflectance spectra measured by the Scanning Imaging Absorption Spectrometer for Atmospheric Chartography (SCIAMACHY) from January 2003 until the end of the mission in April 2012. These data were processed with the Shortwave Infrared CO Retrieval algorithm (SICOR) that we developed for the operational data processing of the Tropospheric Monitoring Instrument (TROPOMI) that will be launched on ESA's Sentinel-5 Precursor (S5P) mission. This study complements previous work that was limited to clear-sky observations over land. Over the oceans, CO is estimated from cloudy-sky measurements only, which is an important addition to the SCIAMACHY clear-sky CO data set as shown by NDACC and TCCON measurements at coastal sites. For Ny-Ålesund, Lauder, Mauna Loa and Reunion, a validation of SCIAMACHY clear-sky retrievals is not meaningful because of the high retrieval noise and the few collocations at these sites. The situation improves significantly when considering cloudy-sky observations, where we find a low mean bias b = ±6. 0 ppb and a strong correlation between the validation and the SCIAMACHY results with a mean Pearson correlation coefficient r = 0. 7. Also for land observations, cloudy-sky CO retrievals present an interesting complement to the clear-sky data set. For example, at the cities Tehran and Beijing the agreement of SCIAMACHY clear-sky CO observations with MOZAIC/IAGOS airborne measurements is poor with a mean bias of b = 171. 2 ppb and 57.9 ppb because of local CO pollution, which cannot be captured by SCIAMACHY. For cloudy-sky retrievals, the validation improves significantly. Here the retrieved column is mainly sensitive to CO above the cloud and so not affected by the strong local surface emissions. Adjusting the MOZAIC/IAGOS measurements to the vertical sensitivity of the retrieval, the mean bias adds up to b = 52. 3 ppb and 5.0 ppb for Tehran and Beijing. At the less urbanised region around the airport Windhoek, local CO pollution is less prominent and so MOZAIC/IAGOS measurements agree well with SCIAMACHY clear-sky retrievals with a mean bias of b = 15. 5 ppb, but can be even further improved for cloudy SCIAMACHY observations with a mean bias of b = 0. 2 ppb. Overall the cloudy-sky CO retrievals from SCIAMACHY short-wave infrared measurements present a major extension of the clear-sky-only data set, which more than triples the amount of data and adds unique observations over the oceans. Moreover, the study represents the first application of the S5P algorithm for operational CO data processing on cloudy observations prior to the launch of the S5P mission.

Testing the Two-Layer Model for Correcting Near Cloud Reflectance Enhancement Using LES/SHDOM Simulated Radiances.

A transition zone exists between cloudy skies and clear sky, such that clouds scatter solar radiation into clear sky regions. From a satellite perspective, it appears that clouds enhance the radiation nearby. We seek a simple method to estimate this enhancement, since it is so computationally expensive to account for all 3-dimensional (3D) scattering processes. In previous studies, we developed a simple two-layer model (2LM) that estimated the radiation scattered via cloud-molecular interactions. Here we have developed a new model to accounts for cloud-surface interaction (CSI). We test the models by comparing to calculations provided by full 3D radiative transfer simulations of realistic cloud scenes. For these scenes, the MODIS-like radiance fields were computed from the Spherical Harmonic Discrete Ordinate Method (SHDOM), based on a large number of cumulus fields simulated by the UCLA Large Eddy Simulation (LES) model. We find that the original 2LM model that estimates cloud-air molecule interactions accounts for 64% of the total reflectance enhancement, and the new model (2LM+CSI) that also includes cloud-surface interactions accounts for nearly 80%. We discuss the possibility of accounting for cloud-aerosol radiative interactions in 3D cloud induced reflectance enhancement, which may explain the remaining 20% of enhancements. Because these are simple models, these corrections can be applied to global satellite observations (e.g. MODIS) and help to reduce biases in aerosol and other clear-sky retrievals.

The potential of clear-sky carbon dioxide satellite retrievals

Abstract. Since the launch of the Greenhouse Gases Observing Satellite (GOSAT) in 2009, retrieval algorithms designed to infer the column-averaged dry-air mole fraction of carbon dioxide (XCO2) from hyperspectral near-infrared observations of reflected sunlight have been greatly improved. They now generally include the scattering effects of clouds and aerosols, as early work found that absorption-only retrievals, which neglected these effects, often incurred unacceptably large errors, even for scenes with optically thin cloud or aerosol layers. However, these “full-physics” retrievals tend to be computationally expensive and may incur biases from trying to deduce the properties of clouds and aerosols when there are none present. Additionally, algorithms are now available that can quickly and effectively identify and remove most scenes in which cloud or aerosol scattering plays a significant role. In this work, we test the hypothesis that non-scattering, or “clear-sky”, retrievals may perform as well as full-physics retrievals for sufficiently clear scenes. Clear-sky retrievals could potentially avoid errors and biases brought about by trying to infer properties of clouds and aerosols when none are present. Clear-sky retrievals are also desirable because they are orders of magnitude faster than full-physics retrievals. Here we use a simplified version of the Atmospheric Carbon Observations from Space (ACOS) XCO2 retrieval algorithm that does not include the scattering and absorption effects of clouds or aerosols. It was found that for simulated Orbiting Carbon Observatory-2 (OCO-2) measurements, the clear-sky retrieval had errors comparable to those of the full-physics retrieval. For real GOSAT data, the clear-sky retrieval had errors 0–20 % larger than the full-physics retrieval over land and errors roughly 20–35 % larger over ocean, depending on filtration level. In general, the clear-sky retrieval had XCO2 root-mean-square errors (RMSEs) of less than 2.0 ppm, relative to Total Carbon Column Observing Network (TCCON) measurements and a suite of CO2 models, when adequately filtered through the use of a custom genetic algorithm filtering system. These results imply that non-scattering XCO2 retrievals are potentially more useful than previous literature suggests, as the filtering methods we employ are able to remove measurements in which scattering can cause significant errors. Additionally, the computational benefits of non-scattering retrievals means they may be useful for certain applications that require large amounts of data but have less stringent error requirements.

Simulated retrievals for the remote sensing of CO<sub>2</sub>, CH<sub>4</sub>, CO, and H<sub>2</sub>O from geostationary orbit

Abstract. The Geostationary Fourier Transform Spectrometer (GeoFTS) is designed to measure high-resolution spectra of reflected sunlight in three near-infrared bands centered around 0.76, 1.6, and 2.3 μm and to deliver simultaneous retrievals of column-averaged dry air mole fractions of CO2, CH4, CO, and H2O (denoted XCO2, XCH4, XCO, and XH2O, respectively) at different times of day over North America. In this study, we perform radiative transfer simulations over both clear-sky and all-sky scenes expected to be observed by GeoFTS and estimate the prospective performance of retrievals based on results from Bayesian error analysis and characterization. We find that, for simulated clear-sky retrievals, the average retrieval biases and single-measurement precisions are < 0.2 % for XCO2, XCH4, and XH2O, and < 2 % for XCO, when the a priori values have a bias of 3 % and an uncertainty of 3 %. In addition, an increase in the amount of aerosols and ice clouds leads to a notable increase in the retrieval biases and slight worsening of the retrieval precisions. Furthermore, retrieval precision is a strong function of signal-to-noise ratio and spectral resolution. This simulation study can help guide decisions on the design of the GeoFTS observing system, which can result in cost-effective measurement strategies while achieving satisfactory levels of retrieval precisions and biases. The simultaneous retrievals at different times of day will be important for more accurate estimation of carbon sources and sinks on fine spatiotemporal scales and for studies related to the atmospheric component of the water cycle.

Validating IASI Temperature and Moisture Sounding Retrievals over East Asia Using Radiosonde Observations

Abstract Temperature and moisture profiles retrieved from Infrared Atmospheric Sounding Interferometer (IASI) data are evaluated using collocated radiosonde data from September 2008 to August 2009 over East Asia. The level-2 products used in this study were provided by the National Oceanic and Atmospheric Administration/National Environmental Satellite, Data, and Information Service. By using radiosonde observations as a reference, the bias and root-mean-square error (RMSE) of the temperature and water vapor profiles are obtained to examine the performance of the IASI retrievals depending on surface types and the degree of atmospheric moisture. Overall, retrievals over the land or under drier atmospheric conditions show degraded performance for both the temperature and the moisture, especially for the boundary layer temperature. It is further shown that the vertical distributions of the RMSEs and the biases of the IASI retrievals resemble the variability pattern of the radiosonde observations from the mean profiles. These retrieval aspects are thought to be related to the surface emissivity effect on the IASI retrieval and the difficulties of accounting for large atmospheric variability in the retrieval process. Although the retrieval performance appears to degrade under cloudy conditions, cloudy- and clear-sky retrievals show similar statistical behaviors varying with surface type and atmospheric moisture. Furthermore, the similar statistical behaviors between first guess and final retrievals suggest that error characteristics inherent to the first guess were not sufficiently resolved by the physical retrieval process, leaving a need to improve the first guess for the better retrieval.