Bridge decks are the surface of bridges that carry the weight of the vehicles and pedestrians crossing over them. The design of bridge decks varies depending on the span, traffic volume, and material availability. But nowadays, the need for a sustainable approach is required. So, use of a sustainable material for construction and retrofitting purposes is the need of the hour. In the present study, a novel synthetic material polyurethane has been used in bridges. The study deals with the variation in skew angles to determine the response of the bridge deck. The response of natural frequencies on the bridge deck due to the variation in skewness and thickness of steel are analysed under simply supported and clamped boundary conditions. Further, the bridge deck is sandwiched using steel and polyurethane having different thicknesses, and the responses are recorded. Afterwards, a bridge deck is modelled using polyurethane as a special case, to pursue sustainability and justify the RRR (reduce, reuse, and recycle) concept of waste management. A comparative study is also performed between the isotropic steel deck and sandwiched deck by varying the skewness. The skew angle is varied from 0° to 60° with a difference of 10°, i.e., 0°, 10°, 20°, 30°, 40°, 50°, and 60°. The frequencies of the isotropic steel and sandwiched decks are increasing when the skewness is increased. Also, the decks may be modelled in a way to enhances the vibration behaviour by sandwiching the existing steel decks. The free vibration frequencies of the sandwiched decks are comparable to the steel deck of similar thickness, which shows the use of polyurethane as the core material does not affect the vibrational characteristics of the deck, while at the same time reducing the cost significantly. The research lays the groundwork for the creation of engineering recommendations that practitioners can use.