Knowledge of heat transfer conditions in large-scale circulating fluidised bed reactors plays an essential role in their proper design and optimization of theirs. This work presents an evaluation of the heat transfer conditions taking into account the coordinate height of the furnace chamber and the fluidised bed flow regime in the reactor. Experimental tests used method and measurement technique that provides reliable temperature data. The vertical and horizontal temperature profiles were obtained at different 966MWth fluidised bed reactor operating conditions. Four characteristic areas can be distinguished in the furnace chamber: the bottom region with a high-temperature gradient from 10.6 °C/m to 22.7 °C/m; the dense region with a medium temperature gradient from 4.7 °C/m to 7.3 °C/m; the dilute area with the lowest temperature gradient from 0.7 °C/m to 3.1 °C/m and the exit region with a temperature gradient (4.3 °C ≤ grad T ≤ 9.6 °C) similar to dense region. The horizontal temperature profiles confirmed a core-annular flow structure inside the furnace chamber. At the pressure drop below 5 kPa, the low variation of average temperature (from ±0.7 °C to ±4.2 °C) inside the furnace chamber of the CFB reactor was observed. As a result of fly ash recirculation of 3.86 kg/s, the lowest temperature gradient 0.2 °C/m was achieved in the bottom region of the furnace chamber. In the range of bed material circulation rates of 32 to 68 were registered temperature fluctuations 115 °C. The experimental results also showed the variation of the bed temperature was small and kept at a very low level of ±13 °C whereas the fluidised bed reactor was operated with a fluidisation velocity range of 1.8 to 2.4. Obtained findings provide unique data on heat transfer conditions in industrial facilities and thus fill the gap in literature data for CFB reactors. Based on main tests carried out in a large-scale CFB reactor, it can be concluded that detailed experimental data on thermal conditions provide important information to validate guidelines and for verifying empirical relationships, which are used in the design, optimization, and scaling of heat transfer surfaces in commercial fluidised bed reactors.