Chiral Topological Superconductivity Research Articles

Interface-induced superconductivity in magnetic topological insulators

The interface between two different materials can show unexpected quantum phenomena. In this study, we used molecular beam epitaxy to synthesize heterostructures formed by stacking together two magnetic materials, a ferromagnetic topological insulator (TI) and an antiferromagnetic iron chalcogenide (FeTe). We observed emergent interface-induced superconductivity in these heterostructures and demonstrated the co-occurrence of superconductivity, ferromagnetism, and topological band structure in the magnetic TI layer—the three essential ingredients of chiral topological superconductivity (TSC). The unusual coexistence of ferromagnetism and superconductivity is accompanied by a high upper critical magnetic field that exceeds the Pauli paramagnetic limit for conventional superconductors at low temperatures. These magnetic TI/FeTe heterostructures with robust superconductivity and atomically sharp interfaces provide an ideal wafer-scale platform for the exploration of chiral TSC and Majorana physics.

Topological superconductor candidates PdBi2Te4 and PdBi2Te5 from a generic ab initio strategy

Superconducting topological metals (SCTMs) have recently emerged as a promising platform of topological superconductivity (TSC) and Majorana zero modes for quantum computation. Despite their importance in both fundamental research and applications, SCTMs are very rare in nature. Here, we propose a strategy to design SCTMs by intercalating the superconducting units into the topological insulators. A program that characterizes the superconducting BdG Chern number of 2D BdG Hamiltonian from ab initio calculations is also developed. Following this strategy, PdBi2Te5 and PdBi2Te4 are found to be experimentally synthesizable and ideal SCTMs. Chiral TSC could be realized in such SCTMs by incorporating topological surface states with Zeeman effect, which can be realized by an external magnetic field or in proximity to ferromagnetic insulator. Our strategy provides a new method for identifying the SCTMs and TSC candidates, and the program makes it possible to design and modulate the TSC candidates from ab initio calculations.

Topological superconductivity from forward phonon scatterings

Searching for topological superconductors with non-Abelian states has been attracting broad interest. The most commonly used recipe for building topological superconductors utilizes the proximity effect, which significantly limits the working temperature. Here, we propose a mechanism to attain topological superconductivity via forward phonon scatterings. Our crucial observation is that electron-phonon interactions with small momentum transfers favor spin-triplet Cooper pairing under an applied magnetic field. This process facilitates the formation of chiral topological superconductivity even without Rashba spin-orbit coupling. As a proof of concept, we propose an experimentally feasible heterostructure to systematically study the entangled relationship among forward-phonon scatterings, Rashba spin-orbit coupling, pairing symmetries, and the topological property of the superconducting state. This theory not only deepens our understanding of the superconductivity induced by the electron-phonon interaction but also sheds light on the critical role of the electron-phonon coupling in pursuing non-Abelian Majorana quasiparticles.

Unconventional self-similar Hofstadter superconductivity from repulsive interactions

Fractal Hofstadter bands have become widely accessible with the advent of moiré superlattices, opening the door to studies of the effect of interactions in these systems. In this work we employ a renormalization group (RG) analysis to demonstrate that the combination of repulsive interactions with the presence of a tunable manifold of Van Hove singularities provides a new mechanism for driving unconventional superconductivity in Hofstadter bands. Specifically, the number of Van Hove singularities at the Fermi energy can be controlled by varying the flux per unit cell and the electronic filling, leading to instabilities toward nodal superconductivity and chiral topological superconductivity with Chern number {{{{{{{mathcal{C}}}}}}}}=pm 6. The latter is characterized by a self-similar fixed trajectory of the RG flow and an emerging self-similarity symmetry of the order parameter. Our results establish Hofstadter quantum materials such as moiré heterostructures as promising platforms for realizing novel reentrant Hofstadter superconductors.

Chiral Majorana modes via proximity to a twisted cuprate bilayer

We propose a novel heterostructure to achieve chiral topological superconductivity in two dimensions. A substrate with a large Rashba spin-orbit coupling energy is brought in proximity to a twisted bilayer of thin films exfoliated from a high-temperature cuprate superconductor. The combined system is then exposed to an out-of-plane magnetic field. The rare $d+id$ pairing symmetry expected to occur in such a system allows for nontrivial topology; specifically, in contrast to the case of the twisted bilayer in isolation, the substrate induces an odd Chern number. The resulting phase is characterized by the presence of a Majorana zero mode in each vortex.

Engineering chiral topological superconductivity in twisted Ising superconductors

Van der Waals materials like NbSe$_2$ or TaS$_2$ have demonstrated Ising superconductivity down to atomically thin layers. Due to the spin-orbit coupling, these superconductors have the in-plane upper critical magnetic field far beyond the Pauli limit. We theoretically demonstrate that, twisted bilayer Ising superconductors separated by a ferromagnetic buffer layer can naturally host chiral topological superconductivity with Chern numbers, which can be realized in heterostructures like $\mathrm{NbSe_2/CrCl_3/NbSe_2}$. Under appropriate experimental conditions the topological superconducting gap can reach $>0.1$ meV, leading to readily observable signatures such as the quantized thermal Hall transport at low temperatures.

Twisted multilayer nodal superconductors

Twisted bilayers of nodal superconductors were recently proposed as a promising platform to host superconducting phases that spontaneously break time-reversal symmetry. Here we extend this analysis to twisted multilayers, focusing on two high-symmetry stackings with alternating ($\pm \theta$) and constant ($\theta$) twist angles. In analogy to alternating-twist multilayer graphene, the former can be mapped to twisted bilayers with renormalized interlayer couplings, along with a remnant gapless monolayer when the number of layers $L$ is odd. In contrast, the latter exhibits physics beyond twisted bilayers, including the occurrence of `magic angles' characterized by cubic band crossings when $L \mod 4 = 3$. Owing to their power-law divergent density of states, such multilayers are highly susceptible to secondary instabilities. Within a BCS mean-field theory, defined in the continuum and on a lattice, we find that both stackings host chiral topological superconductivity in extended regions of their phase diagrams.

Anomalous Floquet Chiral Topological Superconductivity in a Topological Insulator Sandwich Structure.

We show that Floquet chiral topological superconductivity arises naturally in Josephson junctions made of magnetic topological insulator-superconductor sandwich structures. The Josephson phase modulation associated with an applied bias voltage across the junction drives the system into the anomalous Floquet chiral topological superconductor hosting chiral Majorana edge modes in the quasienergy spectrum, with the bulk Floquet bands carrying zero Chern numbers. The bias voltage acts as a tuning parameter enabling novel Floquet topological quantum phase transitions driving the system into a myriad of exotic Majorana-carrying Floquet topological superconducting phases. Our theory establishes a new paradigm for realizing Floquet chiral topological superconductivity in solid-state systems, which should be experimentally directly accessible.

Chiral topological superconducting state with Chern number C = −2 in Pb3Bi/Ge(111)

Materials realization of chiral topological superconductivity is a crucial condition for observing and manipulating Majorana fermions in condensed matter physics. Here we develop a tight-binding description of Pb$_3$Bi/Ge(111), identified recently as an appealing candidate system for realizing chiral $p$-wave topological superconductivity [Nat. Phys. 15, 796 (2019)]. We first show that our phenomenological model can capture the two main features of the electronic band structures obtained from first-principles calculations, namely, the giant Rashba splitting and type-II van Hove singularity. Next, when the $s$-wave superconducting property of the parent Pb system is explicitly considered, we find the alloyed system can be tuned into a chiral topological superconductor with Chern number $\mathcal{C} = -2$, resulting from the synergistic effect of a sufficiently strong Zeeman field and the inherently large Rashba spin-orbit coupling. The nontrivial topology with $\mathcal{C} = -2$ is further shown to be detectable as two chiral Majorana edge modes propagating along the same direction of the system with proper boundaries. We finally discuss the physically realistic conditions to establish the predicted topological superconductivity and observe the corresponding Majorana edge modes, including the influence of the superconducting gap, Land\'{e} $g$-factor, and critical magnetic field. The present study provides useful guides in searching for effective $p$-wave superconductivity and Majorana fermions in two-dimensional or related interfacial systems.

Chiral topological superconductivity in Josephson junctions

We consider a heterostructure of semiconductor layers sandwiched between two superconductors, forming a two-dimensional Josephson junction. Applying a Zeeman field perpendicular to the junction can render a topological superconducting phase with chiral Majorana edge mode. We show that the phase difference between two superconductors can efficiently reduce the magnetic field required to achieve the chiral topological superconductivity, providing an experimentally feasible setup to realize chiral Majorana edge modes. We also construct a lattice Hamiltonian of the setup to demonstrate the chiral Majorana edge mode and the Majorana bound state localized in vortices.

Emergence of Van Hove singularity and topological states in Pb3Bi/Ge(111) Rashba systems

It has been shown recently that the coexistence of Van Hove singularity and geometric phase in ${\mathrm{Pb}}_{3}\mathrm{Bi}\text{/}\mathrm{Ge}(111)$ as a prototypical Rashba system can result in chiral topological superconductivity [W. Qin, L. Li, and Z. Y. Zhang, Nat. Phys. 15, 796 (2019)]. Here, we use first-principles calculations to systematically investigate the structural, electronic, and topological properties of the ${\mathrm{Pb}}_{3}\mathrm{Bi}\text{/}\mathrm{Ge}(111)$ alloyed systems by considering not only the configuration that harbors topological superconductivity considered previously (labeled as the ${\mathrm{T}}_{1}$ phase) but also two other energetically nearly degenerate configurations with high symmetries (labeled as ${\mathrm{H}}_{3}$ and ${\mathrm{T}}_{4}$). We first show that all the three structural configurations have giant Rashba-type spin splittings, resulting from the strong spin-orbit coupling effect of the heavy elements (Pb, Bi) together with inversion symmetry breaking. Next, we demonstrate that each of the saddle- or paraboliclike band dispersions can lead to the emergence of Van Hove singularities, whose positions can be substantially tuned by the giant Rashba effect to the vicinity of the Fermi level. Furthermore, we reveal the existence of topological states in both the ${\mathrm{H}}_{3}$ and ${\mathrm{T}}_{4}$ phases, and the corresponding Rashba-induced band gaps are given by 25 and 50 meV, respectively. Given the energetic affinity of the three phases, these findings suggest the feasibility of realizing quantum phase transitions between quantum spin Hall effect and topological superconductivity within the same materials platform. The present study is expected to give new insights in searching for topological quantum states including 2D topological superconductivity based on Rashba systems.

Vortex-lattice structure and topological superconductivity in the quantum Hall regime

Chiral topological superconductors are expected to appear as intermediate states when a quantum anomalous Hall system is proximity coupled to an s-wave superconductor and the magnetization direction is reversed. In this paper we address the edge state properties of ordinary quantum Hall systems proximity coupled to s-wave superconductors, accounting explicitly for Landau quantization. We find that the appearance of topological superconducting phases with an odd number of Majorana edge modes is dependent on the structure of the system's vortex lattice. More precisely, vortex lattices containing odd number of superconducting flux quanta per unit cell, always support an even number of chiral edge channels and are therefore adiabatically connected to normal quantum Hall insulators. We discuss strategies to engineer chiral topological superconductivity in proximity-coupled quantum Hall systems by manipulating vortex lattice structure.

Stability of disordered topological superconducting phases in magnet-superconductor hybrid systems

Magnet-superconductor hybrid heterostructures constitute a promising candidate system for the quantum engineering of chiral topological superconductivity. Here, we investigate the stability of their topological phases in the presence of various types of potential and magnetic disorder. In particular we consider magnetic disorder in the coupling strength and spin-orientation, as well as percolation type disorder representing missing magnetic moments. We show that potential disorder leads to the weakest suppression of topological phases, while percolation disorder leads to their strongest suppression. In addition, we demonstrate that in the case of correlated potential disorder, the spatial structure of the disorder potential is correlated not only with the particle number density, but also the Chern number density. Finally, we demonstrate how the disorder-induced destruction of topological superconductivity is reflected in the spatial structure and distribution of the Chern number density.

Correlation-Driven Charge Order in a Frustrated Two-Dimensional Atom Lattice.

We thoroughly examine the ground state of the triangular lattice of Pb on Si(111) using scanning tunneling microscopy and spectroscopy. We detect electronic charge order, and disentangle this contribution from the atomic configuration which we find to be 1-down-2-up, contrary to previous predictions from density functional theory. Applying an extended variational cluster approach we map out the phase diagram as a function of local and nonlocal Coulomb interactions. Comparing the experimental data with the theoretical modeling leads us to conclude that electron correlations are the driving force of the charge-ordered state in Pb/Si(111). These results resolve the discussion about the origin of the well-known 3×3 reconstruction. By exploiting the tunability of correlation strength, hopping parameters, and band filling, this material class represents a promising platform to search for exotic states of matter, in particular, for chiral topological superconductivity.

Chiral topological superconductivity arising from the interplay of geometric phase and electron correlation

In modern theory of solids, many-electron correlations can give rise to superconductivity, while the Berry or geometric phase is responsible for non-trivial topology. So far, these two physical ingredients have been taken into account only in a simple additive manner. Here, we carry out a systematic study of the interplay between geometric phase and electron correlation as well as their combined effects on topological and superconducting properties. Based on first-principles studies of Pb3Bi/Ge(111) as a prototypical system, we develop a generic two-dimensional effective formalism that respects hexagonal symmetry with Rashba spin–orbit coupling, displays a van Hove singularity and includes geometric phase-decorated electron correlations. Our functional renormalization group analysis shows that superconductivity dominates the competing orders in the weak interaction regime, with two consequences. First, the renormalized geometric phase flows to three stable fixed points, favouring chiral (px ± ipy)-wave and f-wave superconducting states. Second, the corresponding superconductivity can be substantially enhanced. We construct the phase diagram of the topological quantum states, and identify hole-doped Pb3Bi/Ge(111) as an appealing platform for realizing chiral topological superconductivity in two-dimensional systems that are highly desirable for detecting and braiding Majorana fermions. Renormalization group calculations incorporate band structure and interaction effects on an equal footing. Applying this methodology to Ge-doped Pb3Bi shows that this material is a chiral topological superconductor and hosts Majorana fermions.

Unconventional superconductivity in the extended Hubbard model: Weak-coupling renormalization group

We employ the weak-coupling renormalization group approach to study unconventional superconducting phases emerging in the extended, repulsive Hubbard model on paradigmatic two-dimensional lattices. Repulsive interactions usually lead to higher-angular momentum Cooper pairing. By considering not only longer-ranged hoppings, but also non-local electron-electron interactions, we are able to find superconducting solutions for all irreducible representations on the square and hexagonal lattices, including extended regions of chiral topological superconductivity. For the square, triangular and honeycomb lattices, we provide detailed superconducting phase diagrams as well as the coupling strengths which quantify the corresponding critical temperatures depending on the bandstructure parameters, band filling, and interaction parameters. We discuss the sensitivity of the method with respect to the numerical resolution of the integration grid and the patching scheme. Eventually we show how to efficiently reach a high numerical accuracy.

Observation of the Superconducting Proximity Effect in the Surface State ofSmB6Thin Films

The proximity effect at the interface between a topological insulator (TI) and a superconductor is predicted to give rise to chiral topological superconductivity and Majorana fermion excitations. In most TIs studied to date, however, the conducting bulk states have overwhelmed the transport properties and precluded the investigation of the interplay of the topological surface state and Cooper pairs. Here, we demonstrate the superconducting proximity effect in the surface state of SmB6 thin films which display bulk insulation at low temperatures. The Fermi velocity in the surface state deduced from the proximity effect is found to be as large as 10^5 m/s, in good agreement with the value obtained from a separate transport measurement. We show that high transparency between the TI and a superconductor is crucial for the proximity effect. The finding here opens the door to investigation of exotic quantum phenomena using all-thin-film multilayers with high-transparency interfaces.

Two-dimensional chiral topological superconductivity in Shiba lattices.

The chiral p-wave superconductor is the archetypal example of a state of matter that supports non-Abelian anyons, a highly desired type of exotic quasiparticle. With this, it is foundational for the distant goal of building a topological quantum computer. While some candidate materials for bulk chiral superconductors exist, they are subject of an ongoing debate about their actual paring state. Here we propose an alternative route to chiral superconductivity, consisting of the surface of an ordinary superconductor decorated with a two-dimensional lattice of magnetic impurities. We furthermore identify a promising experimental platform to realize this proposal.

Equivalence of topological mirror superconductivity and chiral superconductivity in one dimension

Recently it has been proposed that a unitary topological mirror symmetry can stabilize multiple zero energy Majorana fermion modes in one-dimensional (1D) time-reversal (TR) invariant topological superconductors. Here we establish an exact equivalence between 1D ``topological mirror superconductivity'' and chiral topological superconductivity in the BDI class which can also stabilize multiple Majorana-Kramers pairs in 1D TR invariant topological superconductors. The equivalence proves that topological mirror superconductivity can be understood as chiral superconductivity in the BDI symmetry class coexisting with time-reversal symmetry. Furthermore, we show that the mirror Berry phase coincides with the chiral winding invariant of the BDI symmetry class, which is independent of the presence of the time-reversal symmetry. Thus, the time-reversal invariant topological mirror superconducting state may be viewed as a special case of the BDI symmetry class in the well-known Altland-Zirnbauer periodic table of free fermionic phases. We illustrate the results with the examples of 1D spin-orbit coupled quantum wires in the presence of nodeless ${s}_{\ifmmode\pm\else\textpm\fi{}}$ superconductivity and the recently discussed experimental system of ferromagnetic atom (Fe) chains embedded on a lead (Pb) superconductor.