Space Charge Research Articles

A method for calculating space charge distribution in ultra-high voltage direct current transmission lines based on the transport of diluted species theory

The occurrence of corona discharge in ultra-high-voltage direct current transmission lines results in the generation of space charge, which significantly affects the nearby electromagnetic environment. To investigate the micro-physical mechanisms of discharge and provide better guidance for the calculation of the ground ion current density and total electric field, a method based on the theory of the transport of diluted species is proposed. This method enables the visualization and analysis of the movement process of space charge in air medium, as well as the calculation of the total electric field below the transmission lines. To validate the effectiveness of this algorithm, experimental tests of the total electric field are conducted on actual transmission lines. The experimental results demonstrate that the algorithm not only highlights the evident differences in the transient microscopic processes between positive and negative corona discharges but also accurately calculates the total electric field below the transmission lines. In addition, considering the weather conditions in the Chongqing region, relevant recommendations are provided under the influence of wind speed, aiming to offer protection guidelines for individuals engaged in activities near transmission lines.

Theoretical study of the ϒ2-graphyne p-n junction diode devices

Due to the tunable bandgap of ϒ2-graphyne, there is an expectation that this structure is a favorable candidate for p-n junction diode devices. The characteristic of the pure and hydrogenated ϒ2-graphyne nanoribbon structures is modeled and investigated from the electrostatic point of view. The charge distribution is approximated in one and two dimensions. The space charge region wide, electric field and the potential along with the current density are calculated for different donor and acceptor doping amounts. Our survey includes various simulated hydrogenated and Oxygenated molecular devices with different unit cell numbers, and their density of states, transmission spectrum, and current voltage diagrams were obtained using VNL Quantum wise ATK software. The results indicate the reduction of the depletion region and the creation of new energy levels in the band gap of the system. The interaction and bending effects of these new levels with the intrinsic levels are also observed.

Expulsion of hydrogen negative ions by the anode layer of negative space charge from Penning discharge with metal hydride cathodes

The method of expulsion of hydrogen negative ions in the axial direction by a negative space charge formed in the plasma of Penning discharge with metal hydride cathodes is discussed. The plasma is produced on hydrogen, which is stored in metal hydride cathodes and injected locally into the discharge cell without any external gas supply due to ion current impact from plasma. The process of nonequilibrium desorption resulted in high vibrational excitation of H2 molecules, which greatly increases the efficiency of H− ion production. The method of efficient expulsion of H− ions depends on the external magnetic field. At a high magnetic field, it is performed by the supply of negative electric bias of the opposite cathode, but at a low one, H− ions are pushed out by the negative space charge of the anode layer, which expands toward the axis. The impact of both methods is considered in the case of DC discharge and in pulsating regime implementation.

Precise synthesis of three-arm star polymethacrylates with high emission efficiency both in solution and in the solid state

Organic/polymeric fluorescent materials with bright emission both in solution and in the solid state have garnered growing interest in biological and optoelectronic fields. Herein, triphenylamine-derived boron ketoimine (TPA-BKI-3Br) was utilized as the initiator for atom transfer radical polymerization (ATRP) to prepare dual-state emission three-arm star polymethacrylates. Due to the intramolecular charge transfer (ICT) effect and highly distorted structure of the TPA-BKI unit, as well as the polymer arms constraining intramolecular motions, the resultant polymers displayed significant emission in solution. In the aggregated and solid states, the photophysical characteristics of the resultant polymethacrylates were notably impacted by the space charge transfer between the TPA-BKI unit and polymer chains. In addition, the TPA-BKI-based poly(2-(dimethylamino)ethyl methacrylate) (TPA-BKI-(PDMAEMA)3) exhibited fluorescence responses to temperature variations owing to the presence of dimethylamino group. This study presents an approach for the advancement of dual-state emission polymeric materials.

Effect of sintering temperature on microstructure and electrical properties of Na0.5Bi0.47Sr0.02TiO3-δ ceramics

In this investigation, a series of Na0.5Bi0.47Sr0.02TiO3-δ samples, sintered from 1000 to 1100 °C, were synthesized utilizing the solid-state method. The XRD results indicate that all samples exhibit a perovskite phase, with the exception of those sintered at 1100 °C, which display no discernible impurity peaks. The SEM results indicate that the average grain size exhibits an increase proportionate to the sintering temperature, which attributes to the variations in the actual Na/Bi ratio. From the study of grain conductivity we can obtain that the dominant factor affecting grain conductivity is the activation energy. At 1100 °C, the oxygen vacancy concentration emerges as the primary determinant of grain conductivity. It should be noticed that the phase transition temperature of the sample increases (350 °C→400 °C) with the increase of sintering temperature, which is due to the local A-site disorder aggravated by high temperature sintering. Therefore, reducing the sintering temperature is beneficial to improve the grain conductivity. The grain boundary conductivity initially rises, then diminishes with increasing sintering temperature. It is evident that the enhanced macroscopic grain boundary conductivity stems from a marked reduction in space charge potential within the 1000–1025 °C temperature range. Within the 1050 °C−1100 °C temperature range, the space charge potential barely changed, the significant decrease of intrinsic grain boundary conductivity can be attributed to the surge in the coverage ratio of grain boundary impurities and the number of grain boundary impurities increased caused by the rapid reduction of grain boundary area and thermal evaporation. The research on electrical performance of NBT-based oxygen-ion conductors will promote the application of NBT-based oxygen ion conductors in solid oxide fuel cells, oxygen sensors and other fields.

Numerical Evaluation Methodology for Power Electronic Transformer Insulation Based on Space Charge Characteristics Under Combined HF Electrothermal Stress

Numerical Evaluation Methodology for Power Electronic Transformer Insulation Based on Space Charge Characteristics Under Combined HF Electrothermal Stress

Prototype of a 2.45 GHz cylindrical ceramic dielectric antenna surface wave plasma source for flood gun

In modern ion implanters, plasma flood gun (PFG) is used to neutralize wafer charge during doping process, preventing the breakdown damage of floating wafers caused by the space charge accumulation. Surface wave (SW) plasma source is a potential choice for PFG, because of its no metal pollution, simple structure, high current intensity and low cost for ion implanters. At Peking University (PKU), a 2.45 GHz surface wave PFG (SW-PFG) with a cylindrical dielectric antenna was designed and tested recently. It aims to obtain plasma at the gas pressure of several 10−3 Pa and below which is strictly required by the ion implanter. A two-dimensional discharge model was established to optimize the cylindrical dielectric antenna structure. Through optimization of operation parameters, the electron current intensity of 88 mA was obtained with RF power 500 W and gas pressure 5.0 × 10−3 Pa in the experiments, which meets the requirement of ion implanters. Further, through optimization of operation parameters, the electron current intensity could reach 140 mA. In addition, by setting the graphite liner to isolate the metal cavity wall and plasma, the improvement in the long-term operation stability has been confirmed, which laid a solid foundation for the industrial application of the SW-PFG.

Study of Space Charge Potential for Propagation of Plasma-Assisted Electron Beam

Study of Space Charge Potential for Propagation of Plasma-Assisted Electron Beam

The Child Langmuir Illusion

A Particle in Cell (PIC) model of ion beam extraction from a plasma provides strong evidence that the origin of the observed V(3/2) relationship between the applied extraction voltage and beam current is caused by meniscus shape and collimation on the extraction electrode, not by space charge limited extraction. Excellent correlation between the PIC model, a gun code and experiment is shown for 100 µA Ar+ beams. The s-shape in the emittance phase space is shown to be caused by the radial electric field created by the external edge of the plasma electrode.

Structural, Microstructural, and Electrical Properties Study of Pb(Sn0.45Ti0.55)O3 Ceramics

We undertook a comprehensive investigation of the the structural, dielectric, and electrical characteristics of Pb(Sn0.45Ti0.55)O3 ceramics prepared using the conventional solid-state route. A meticulous preparation protocol, involving solvating various precursors, was followed by extensive characterization employing X-ray diffraction, scanning electron microscopy, and dielectric studies. The synthesized sample features a single-phase tetragonal structure with P4mm symmetry. Using impedance spectroscopy, electrical transport properties of the polycrystalline Pb(Sn0.45Ti0.55)O3(PST) ceramic were studied in detail. Relaxation and conduction mechanisms of the material were inferred using complex impedance, complex electric modulus, and frequency dependent ac conductivity analysis. Impedance spectroscopy results reveal the range of frequencies in which the grain, grain boundary, and electrode effects are dominant. Above certain temperatures, the imaginary component of impedance (Z//) exhibits some resonant type peaks at different frequencies indicating relaxor nature of the sample. The activation energy obtained for both the relaxation and conduction process indicates the role of doubly-ionized oxygen vacancy in the conduction mechanism of the sample. The dielectric relaxation occurring at low frequency and high temperatures is related to the space charges associated with the ionized oxygen vacancies being trapped at the grain boundaries. The Cole-Cole plots confirm the poly-dispersive nature of dielectric relaxation in the sample.

Molecular Dynamics Simulations on Epoxy Resin Composite via Grafting Acryloyl-chloride to Inhibit Electron Transport and Improve Thermal-mechanical Properties

Electrical, thermal, and mechanical properties of cross-linked epoxy resin (EP) modified by the chemical grafting of acryloyl chloride (AC) were studied to explore the trapping mechanism of charge transport inhibition. The bound state traps deriving from grafted molecules were analyzed by first-principles calculations combined with electron transmission spectra to study the underlying mechanism of the electrical properties. In contrast to pure EP, the EP-graft-AC (EP-g-AC) represents significantly depressed conductivity due to the electron scattering from polar-groups of the grafted AC molecule. The substantial deep traps are generated in EP-g-AC molecules by the polar group of grafted AC and accordingly decrease charge mobility and raise the charge injection barrier, consequently suppressing space charge accumulation and charge carrier transport. EP-g-AC polymer acquires a significant amelioration in thermal and mechanical properties, as indicated by the higher cohesive energy density, glass transition temperature, and decomposition temperature in consistence with the lower thermal vibrations compared with pure EP polymer, except that the resulting higher fractional free volume is not preferable, which is attributed to the mixing incompatibility of the grafted AC molecules with EP molecular-chains.

Design and Experiment of a Slotted Antenna Surface Wave Plasma Flood Gun

In a modern ion implanter, plasma flood gun (PFG) is used to neutralize wafer charge during doping process, preventing the breakdown of floating wafers caused by the space charge accumulation. In order to obtain the PFG which can produce ribbon electron beams with the characteristics of high stability, high plasma density, no metal pollution and long life, studies at Peking University (PKU) are focused on surface wave plasma flood gun (SW-PFG) recently. A 2.45 GHz SW-PFG with a quartz plate and a series of metal slotted antenna arrays was designed and tested. Theoretical studies are carried out to optimize the SW-PFG structural parameters. The quartz plate thickness is determined as 15 mm. The size of the plasma chamber is 280 mm×150 mm×40 mm with a 280 mm×2 mm extraction slit. In the experiment, a relatively uniform argon plasma is obtained under the condition of gas flow rate of 2 sccm and input power of 800 W. In this case, the plasma distribution is studied by emission spectrum diagnosis and 73 mA ribbon electron beam is measured.

Influence of the Capillary Design and Conditions upon the Transmission Efficiency of a Portable Ion Trap Mass Spectrometer

The capillary is a widely used atmospheric pressure interface in mass spectrometers that may be heated to enhance the desolvation of ions. In this study, the ion transmission efficiency of a portable ion trap mass spectrometer was investigated using capillaries with different inner diameters and temperatures, different vacuum pressures, and different ion optics designs. Due to the incomplete desolvation and the space charge effect inside the miniature ion funnel, the increase of ion intensities with the inner diameter of the capillary leveled off when the inner diameter of the capillary was larger than 0.37 mm. With the increase of capillary temperature, the ion intensities first increase due to better desolvation and then decrease due to greater diffusion loss. The optimal temperature of the capillary increases with the inner diameter of the capillary and the mass-to-charge ratio of ion. In addition, the pressures of different vacuum stages also exerted remarkable effects on the sensitivity of the portable mass spectrometer. From the perspective of instrument miniaturization, optimal transmission efficiency can be obtained when the first-stage vacuum pressure is maintained from 4 to 6 mbar. For a capillary with an inner diameter of 0.37 mm, the background of mass spectrum can be significantly reduced by replacing the pinhole behind the ion funnel with an off-axis skimmer.

Electrostatic discharge mechanisms and dynamic characteristics of different polarity powders in the Silo

Electrostatic discharge in powder silos poses a significant safety hazard due to the risk of fire or explosion. However, the underlying discharge mechanisms are not fully understood. This study aims to improve the comprehension of electrostatic discharge dynamics and mechanisms by introducing a fluid discharge model for charged powder silos. The model validation is carried out by examining discharge patterns and electric field variations. The investigation of the electrostatic field and potential distribution prior to discharge helps to comprehend the discharge conditions. The discharge modes and evolution laws of different polarity powders are explored to reveal disparities in discharge phenomena. These disparities are further scrutinized in relation to electron density, space charge, electric field, and potential. To elucidate the discharge mechanism, the electric field distortion caused by space charge, electron existence time, and migration law are analyzed. The electrostatic and diffusion effects are the main reasons for the discharge differences.

Charge interaction behaviors at interfacial domains in DC GIL insulators

Long-term operation of high voltage direct current at elevated temperatures can result in the accumulation of surface charges in DC gas-insulated transmission line (GIL) insulators. Such a phenomenon leads to localized electric field distortion, increasing the risk of surface discharge. The analysis of interaction behaviors between surface charge and space charge at interfacial domains of GIL insulators is a complex task, which requires a comprehensive understanding of physical mechanisms of the gas–solid interface charging. In this work, a two-dimensional bipolar charge transport and interaction (2D BCTI) model is established, with the consideration of both surface and space charge dynamics. Pulsed electroacoustic tests and surface potential measurements are conducted on DC GIL insulator materials under different electrical-thermal coupling conditions. Experimental results exhibit great consistency with the predictions from the 2D BCTI model. The local accumulation of space charge near interfaces has certain effects on surface potential distribution, which in turn influences charge injection behavior from electrodes. In comparison to traditional surface charge simulation models, the consideration of space charge–surface charge interaction behaviors proves to be essential for estimating the polarity and amplitude of surface potential distribution. This model holds promise for assessing charge characteristics in electrical equipment where direct measurement is challenging.

Photodetector array for measuring the spatial–temporal distribution characteristics of electric field in oil–pressboard insulation based on the Kerr electro‐optic effect

AbstractAccurate measurement and effective analysis of the space electric field and charge characteristics within the oil–pressboard insulation structure of converter transformer are essential for achieving precise insulation structure design. Presently, most electric field measurement methods relying on the Kerr electro‐optical effect are limited to single‐point measurements. Given the complexity of converter transformer insulation structures, including their large scale and the use of various materials, existing technologies and findings struggle to provide comprehensive electric field observations within the oil–pressboard region. After leveraging the Kerr electro‐optic effect, a high‐precision 32‐unit photodetector array has been developed to achieve regional measurements of spatial‐temporal electric field in oil–pressboard insulation. The array boasts a measurement spatial resolution of 1.4 mm2 and a sensitivity of 0.15 kV/mm, ensuring measurement accuracy exceeding 96.50%. Through practical measurements of the spatial electric field distribution within the oil–pressboard insulation under direct current voltage, the non‐uniform distribution of the electric field is effectively captured in oil. Notably, the maximum deviation in field strength at different positions within the transformer oil can reach 18.5%. Moreover, as the applied voltage increases, the unevenness coefficient of the field strength gradually rises, peaking at 1.19, which signifies a progressive expansion in the area affected by electric field distortion. By conducting tests to assess the dispersion of volume resistivity in samples from various positions within large sheets of pressboard, the variation in volume resistivity of materials is posited as one of the contributing factors to the non‐uniform distribution of electric field within the oil. The detailed accomplishments aim to provide essential technical and theoretical support for optimising insulation structure design of converter transformers.

Modeling and Bulk Characterization of 4HSIC Radiation Detector in Sentaurus TCAD Simulation Environment

This paper gives an insight into the need for radiation detection and the most commonly flexible and efficient radiation detector. It also examines bulk characteristics of 4H-SiC semiconductor radiation detector with Ni and Ti as metals for the contact. Bulk characterization of the device, including: doping concentration, electrons and holes behaviors, space charge and current densities were carried out. The modeling is conducted using Sentaurus Technology Computer Aided Design (TCAD) to examine charge transport in bulk 4HSiC material. Data obtained were further analyzed through Sentaurus visual, sentaurus Techplot and Excel to clearly determine the characteristics of the device. It is observed that when the semiconductor and metal are in contact, the Fermi-level is established where the doping concentration varied with either magnitude of the doping concentration or nature of the dopant. Similarly, Schottky and ohmic contacts and temperature effect were observed from the device characteristics which demonstrate that, the detector can withstand a temperature from the range of 100K to 700K in no fluctuating state.

Matched phase sweep method for the optimization of bunching factor in dual rf systems of high-intensity hadron synchrotrons

The scheme of multiturn painting beam injection in a dual harmonic rf system is widely employed in high-intensity proton or heavy ion synchrotrons to alleviate space charge effects. With a momentum offset of the injected beams, a large bunching factor can be achieved at the end of multiturn painting injection process. However, the momentum offset can increase the instantaneous beam peak current during the first 1/4 synchrotron period, causing a reduced bunching factor during the beam injection process. To address this issue, a matched phase sweep method is developed. By matching the synchrotron oscillation frequency and beam injection period, an optimal curve for phase sweeping can be directly obtained. The effectiveness of the method has been checked via simulations and machine study, which are in good agreement. The matched phase sweep method is employed for the increase of the beam power in the upcoming upgrade project of the China Spallation Neutron Source and can also be generally applied for the operation in the presence of dual harmonic rf system in high-intensity hadron synchrotrons. Published by the American Physical Society 2024

In Situ Polymerization Inhibiting Electron Localization in Hybrid Electrolyte for Room‐Temperature Solid‐State Lithium Metal Batteries

AbstractHybrid solid electrolytes (HSEs) have attracted much attention due to their advantages as both inorganic and organic polymer electrolytes. However, the organic/inorganic interfacial space charge layer has a great barrier to the transport of Li+ in the HSE. Here, an in situ polymerization layer is proposed on garnet‐type particles, working as the coherent region to eliminate the space charge layer at the organic/inorganic interfaces by inhibiting electron localization. The conjugate hybridization of fillers weakens the aggregation of particles, induces the dissociation of Li salt, and provides high‐throughput Li+ transport pathways at the ceramics/polymer interface. Furthermore, the continuous Li+ conduction networks are connected by the coherent region between inorganic fillers and polymer chains. The fabricated HSE exhibits a high ionic conductivity of 0.47 mS cm−1 and ion migration numbers of 0.78 at room temperature. The 3D Li//Li systematic battery assembled with the HSE delivers a high critical current density (CCD) of 2.0 mA cm−2. Meanwhile, the 4.5 V NCM811//Li batteries achieve a prolonged operation of 500 cycles at 0.5 C. The Li//LiFePO4 batteries demonstrate superior capacity retention of 96.4% at 1 C after 500 cycles.

Temperature and frequency dependence of conductivity, density of states, and dielectric permittivity of ternary metal chalcogenide PbSnSe2 flake

The mechanically cleaved flake of ternary metal chalcogenide PbSnSe2 was transferred onto the interdigitated electrodes to form electrical contacts. The temperature dependent (180 K–250 K) electrical properties were then analyzed employing complex impedance spectroscopy from 2 kHz to 2 MHz. A detailed analysis of Nyquist plots proposed the space charge dependent behavior and negative temperature coefficient of PbSnSe2 flake. The AC conductivity followed Jonscher's power law with s-parameter value being less than unity. The values of s-parameter increased with rise in temperature suggesting the presence of non-overlapping small polaron tunneling (NSPT) in the PbSnSe2 flake. From this NSPT model, tunneling distance, hopping energy, and density of states (DOS) were estimated at temperatures from 180 K–250 K. The dielectric permittivity showed dispersion at lower frequencies and the tangent loss was also found to be directly related to temperature. A single semicircular arc in complex modulus analysis showed the dominance of bulk effect in the material.