Chesapeake Bay Impact Structure Research Articles

2022 Joint Barringer Medal for Kai Wünnemann and Gareth S. Collins

2022 Joint Barringer Medal for Kai Wünnemann and Gareth S. Collins

The remanent magnetisation recorded in the Chesapeake Bay impact crater, Virginia

During impact events, planetary crusts experience high pressures that can impart rocks with shock remanent magnetisation (SRM) if an ambient magnetic field or demagnetise rocks if a field is absent. If rocks experience substantial impact heating or are pressurised above ~40 GPa (inducing melting and recrystallisation) they may instead record a thermo-viscous remanent magnetisation (TVRM) as they cool below their Curie temperatures. Understanding impact re-magnetisation is crucial for studying terrestrial impact craters, but also unraveling the history of long-lived core dynamo fields on other planetary bodies. In this research we studied impact-related re-magnetisation recorded in natural rock samples from the Chesapeake Bay impact crater, Virginia. As a case study, here we discuss the natural remanent magnetisation (NRM) of two samples of different rock types: a suevite (sample I9-UI, depth 1.40 km beneath the ground) and a schist (sample S32, depth 1.67 km beneath the ground) using thermal and alternating field demagnetisation. The suevite represents a sample that contains material that experience impact remelting, whereas the schist represents an unmelted rock. From the NRM spectra, we found that the sample ITH9-UI was remagnetised by TVRM due to impact-related heating, while the sample STH32 shows the indication of shock deformation of magnetic minerals.

Origin and evolution of the Haustoriidae (Amphipoda): a eulogy for the Haustoriidira

Abstract Haustoriid amphipods have received little recent attention and their systematics and phylogenetics are largely unresolved. Some efforts have been made at classifying the family within the broader Amphipoda, but there is persistent incongruence in its placement among different authors and techniques. Furthermore, there exists no phylogenetic hypothesis of intrafamilial relationships. In this work, we evaluate the competing hypotheses on the phylogenetic position of the Haustoriidae within Amphipoda by examining new and previously published sequences of nearly 100 species across 38 families. We find strong support for the Haustoriidae as basal gammarids, and that other families placed within the parvorder ‘Haustoriidira’ are spread across Amphipoda. The radiation began during the Eocene and may have been driven in North America by the rapid filling of a coastal niche opened by the Chesapeake Bay impact crater. Unlike previous work, we find that the Pacific-endemic genus Eohaustorius is the most basal haustoriid, and that it separated from the rest of the family ~31 Mya. Finally, we provide taxonomic recommendations for relationships within Haustoriidae, including the elevation of a new genus, Cryptohaustorius gen. nov.. We conclude by recommending that the ‘Haustoriidira’ be abandoned.

ExoMars Raman Laser Spectrometer: A Tool for the Potential Recognition of Wet-Target Craters on Mars.

In the present work, near-infrared, laser-induced breakdown spectroscopy, Raman, and X-ray diffractometer techniques have been complementarily used to carry out a comprehensive characterization of a terrestrial analogue selected from the Chesapeake Bay impact structure (CBIS). The obtained data clearly highlight the key role of Raman spectroscopy in the detection of minor and trace compounds, through which inferences about geological processes occurred in the CBIS can be extrapolated. Beside the use of commercial systems, further Raman analyses were performed by the Raman laser spectrometer (RLS) ExoMars Simulator. This instrument represents the most reliable tool to effectively predict the scientific capabilities of the ExoMars/Raman system that will be deployed on Mars in 2021. By emulating the analytical procedures and operational restrictions established by the ExoMars mission rover design, it was proved that the RLS ExoMars Simulator can detect the amorphization of quartz, which constitutes an analytical clue of the impact origin of craters. Beside amorphized minerals, the detection of barite and siderite, compounds crystallizing under hydrothermal conditions, helps indirectly to confirm the presence of water in impact targets. Furthermore, the RLS ExoMars Simulator capability of performing smart molecular mappings was successfully evaluated.

(U‐Th)/He zircon dating of Chesapeake Bay distal impact ejecta from ODP site 1073

AbstractSingle crystal (U‐Th)/He dating has been undertaken on 21 detrital zircon grains extracted from a core sample from Ocean Drilling Project (ODP) site 1073, which is located ~390 km northeast of the center of the Chesapeake Bay impact structure. Optical and electron imaging in combination with energy dispersive X‐ray microanalysis (EDS) of zircon grains from this late Eocene sediment shows clear evidence of shock metamorphism in some zircon grains, which suggests that these shocked zircon crystals are distal ejecta from the formation of the ~40 km diameter Chesapeake Bay impact structure. (U‐Th/He) dates for zircon crystals from this sediment range from 33.49 ± 0.94 to 305.1 ± 8.6 Ma (2σ), implying crystal‐to‐crystal variability in the degree of impact‐related resetting of (U‐Th)/He systematics and a range of different possible sources. The two youngest zircon grains yield an inverse‐variance weighted mean (U‐Th)/He age of 33.99 ± 0.71 Ma (2σ uncertainties n = 2; mean square weighted deviation = 2.6; probability [P] = 11%), which is interpreted to be the (U‐Th)/He age of formation of the Chesapeake Bay impact structure. This age is in agreement with K/Ar, 40Ar/39Ar, and fission track dates for tektites from the North American strewn field, which have been interpreted as associated with the Chesapeake Bay impact event.

40Ar-39Ar step heating ages of North American tektites and of impact melt rock samples from the Chesapeake Bay impact structure

Abstract This study presents 40Ar-39Ar step heating ages of four North American tektites (three bediasites and one georgiaite) and of two groundmass samples extracted at different depths from clast-rich impact melt rocks (CB-W61 and CB-W84) recovered by the USGS-ICDP Eyreville B drill-core about 9 km from the centre of the Chesapeake Bay impact structure. Radiometric age determination on both North American tektites and impact melt rocks from within Chesapeake Bay crater offers the first possibility to confirm the origin of these tektites. For this aim, argon isotopic data from 13 samples/aliquots of tektite rims, cores and bulk, and 4 samples/aliquots from two impact melt rocks were obtained over 15 to 26 step heating extractions. Age spectra of all tektite samples show plateaux comprising 62–98% of the 39Ar release over consecutive intermediate and high temperature heating steps. Few low temperature extractions indicate excess 40Ar. Inverse isochron 40Ar/36Ar intercepts of tektite samples are indistinguishable from air (295.5). However, impact melt rock spectra presented complex Ar-release affecting primarily the low temperature heating-steps. Inverse isochrones indicate excess argon from which the 40Ar/36Ar intercept was used to correct the age calculation. CB-W61 and CB-W61-2 40Ar/36Ar intercepts are 354.5 ± 2.5 and 327.2 ± 6.3, respectively, and those for CB-W84 and CB-W84-2 are 332.0 ± 7.3 and 329.6 ± 5.6, respectively. The inverse isochron weighted mean age (according to currently suggested K-decay constants revisions by Schwarz et al. (2011) and Renne et al. (2011)) for all four tektites is 34.86 ± 0.25 Ma (MSWD = 0.96, P = 0.41; n = 4) and for the two impact melt rocks is 37.16 ± 3.65 Ma (MSWD = 0.83, P = 0.36). The combined tektite and impact melt rocks isochron mean age of 34.86 ± 0.23 (0.32) Ma (MSWD = 0.87, P = 0.43) is slightly – though not significantly – higher than the plateau mean age of 34.55 ± 0.27 (0.36) Ma (MSWD = 0.66, P = 0.62). Placing this age in the Global Stratotype Section and Point (GSSP) marine section exposed at Massignano, Italy, it falls below the Eocene/Oligocene (E/O) boundary overlapping with the 10.28 m Ir-anomaly. These results agree within errors with previously reported ages of 35.20 ± 0.54 Ma, especially those derived from K-Ar and Ar-Ar total fusion analysis. An age of 34.86 ± 0.32 Ma sets the Chesapeake Bay impact event close to the youngest of the three Ir anomalies at ∼35.0 Ma in the case the impactor was Ir-rich (e.g, a chondrite, primitive achondrite, stony-iron or iron meteorite). The concordance with the E/O boundary at ∼33.9 Ma seems only marginally possible, and only if the Ir contribution from the ejecta were, potentially, due either to its small amount becoming diluted in the geologic record or the impactor being Ir poor, e.g., of differentiated achondritic composition. This study also brings to front the need to re-establish the stratigraphic and palaeo-magnetic correlations across the globe for the Ir-anomalies and the magneto-stratigraphy during the mid- to late-Eocene and early-Oligocene, and the need to re-evaluate the markers for the Eocene-Oligocene boundary.

2018 Barringer Medal for Thomas Kenkmann

2018 Barringer Medal for Thomas Kenkmann

Coesite in suevites from the Chesapeake Bay impact structure

AbstractThe occurrence of coesite in suevites from the Chesapeake Bay impact structure is confirmed within a variety of textural domains in situ by Raman spectroscopy for the first time and in mechanically separated grains by X‐ray diffraction. Microtextures of coesite identified in situ investigated under transmitted light and by scanning electron microscope reveal coesite as micrometer‐sized grains (1–3 μm) within amorphous silica of impact‐melt clasts and as submicrometer‐sized grains and polycrystalline aggregates within shocked quartz grains. Coesite‐bearing quartz grains are present both idiomorphically with original grain margins intact and as highly strained grains that underwent shock‐produced plastic deformation. Coesite commonly occurs in plastically deformed quartz grains within domains that appear brown (toasted) in transmitted light and rarely within quartz of spheroidal texture. The coesite likely developed by a mechanism of solid‐state transformation from precursor quartz. Raman spectroscopy also showed a series of unidentified peaks associated with shocked quartz grains that likely represent unidentified silica phases, possibly including a moganite‐like phase that has not previously been associated with coesite.

Dual strike hints at chaos in the asteroid belt

Sometime between the demise of the dinosaurs and the rise of primates, Earth suffered a one-two punch from two unrelated asteroids. The double whammy could signify chaos in the inner solar system, triggering a cascade of events that perhaps plunged Earth into the recent ice age. The impacts that made the Popigai crater in Siberia and the Chesapeake Bay crater on the US East Coast were two of the largest asteroid strikes since the one that killed the dinosaurs, so big that their dust left thin layers of debris all over the globe. But when Birger Schmitz of Lund University in Sweden examined sediment from a site in central Italy containing debris from both impacts, he found two distinct types of meteoritic grains. Those from the part of the deposit associated with Popigai were rich in iron; those from the part associated with Chesapeake Bay were iron-poor. So the pair can't be explained by a single body breakup--they must be from two separate asteroids.

Post-impact depositional environments as a proxy for crater morphology, Late Devonian Alamo impact, Nevada

Marine facies of carbonate and siliciclastic sediments deposited on top of the upper Devonian Alamo Breccia Member identify the shape and size of the Alamo impact crater in south-central Nevada (western USA). There are 13 measured sections that record peritidal to deep-subtidal deposition across the impacted platform, and these are correlated to three regional depositional sequences above the Alamo Breccia Member. Facies and accommodation patterns identify a concave seafloor that we interpret as the post-impact legacy of the Alamo crater. Together with isopach and lithostratigraphic trends in the underlying Alamo Breccia Member, a new map of the Alamo crater is presented showing the eastern outer rim fault and the annular trough. Size estimates were made using the newly defined crater features and linear scaling relationships from other marine-target complex craters. Revised dimensions of the Alamo crater place its transient diameter between 37 and 65 km, and its apparent diameter between 111 and 150 km. These estimates are more than double previous estimates based on the biostratigraphy of the Alamo Breccia Member. If correct, these new estimates place the Alamo crater as one of the largest marine impacts of the Phanerozoic, and conservatively larger than the well-studied Eocene Chesapeake Bay crater.

Evidence for high salinity of Early Cretaceous sea water from the Chesapeake Bay crater

High-salinity groundwater more than 1,000 metres deep in the Atlantic coastal plain of the USA has been documented in several locations, most recently within the 35-million-year-old Chesapeake Bay impact crater. Suggestions for the origin of increased salinity in the crater have included evaporite dissolution, osmosis and evaporation from heating associated with the bolide impact. Here we present chemical, isotopic and physical evidence that together indicate that groundwater in the Chesapeake crater is remnant Early Cretaceous North Atlantic (ECNA) sea water. We find that the sea water is probably 100-145 million years old and that it has an average salinity of about 70 per mil, which is twice that of modern sea water and consistent with the nearly closed ECNA basin. Previous evidence for temperature and salinity levels of ancient oceans have been estimated indirectly from geochemical, isotopic and palaeontological analyses of solid materials in deep sediment cores. In contrast, our study identifies ancient sea water in situ and provides a direct estimate of its age and salinity. Moreover, we suggest that it is likely that remnants of ECNA sea water persist in deep sediments at many locations along the Atlantic margin.

Origin of two Verwey transitions in different generations of magnetite from the Chesapeake Bay impact structure, USA

AbstractWe observed two different Verwey transition temperatures in fragments of crystalline basement rocks and impact sediments from the Chesapeake Bay impact structure, USA. Our study aims to the question if this feature can be used as shock indicator in impact craters. We distinguished three generations of magnetite. (1) Primary magnetite in crystalline basement rocks has average grain sizes up to several hundreds of micrometers and shows a regular TV at ≈ 121 K. (2) Shocked magnetite occurs in fragments of crystalline basement rocks and also in the suevite and impact breccia. These magnetites show two Verwey transitions—a regular one and a “low‐temperature transition” (LTV) at around 89 K. LTV is related to a small grain size fraction, whereas a larger grain size fraction (some hundreds of micrometers) causes the regular TV. The small grain size fraction contains a distinctly higher amount of superficially oxidized material due to the high surface/volume ratio, which causes a decrease of the Verwey transition temperature (LTV). (3) A secondary magnetite generation shows also two Verwey transition temperatures, one at 121 K and a LTV range between 91 and 105 K. The LTV in this generation is also linked to thin oxidized surface layers. This study shows that especially the Verwey transition temperature of small magnetite grains reacts very sensitively to surface oxidation and can therefore not be used as a reliable pressure indicator for impact structures on Earth.

Dinocyst taphonomy, impact craters, cyst ghosts and the Paleocene–Eocene thermal maximum (PETM)

Dinocysts recovered from sediments related to the Chesapeake Bay impact structure in Virginia and the earliest Eocene suboxic environment in Maryland show strange and intriguing details of preservation. Features such as curled processes, opaque debris, breakage, microborings and cyst ghosts, among others, invite speculation about catastrophic depositional processes, rapid burial and biological and chemical decay. Selected specimens from seven cores taken in the coastal plain of Virginia and Maryland show abnormal preservation features in various combinations that merit illustration, description, discussion and further study. Although the depositional environments described are extreme, many of the features discussed are known from, or could be found in, other environments. These environments will show both similarities to and differences from the extreme environments here.

Impact Disruption and Recovery of the Deep Subsurface Biosphere

Although a large fraction of the world's biomass resides in the subsurface, there has been no study of the effects of catastrophic disturbance on the deep biosphere and the rate of its subsequent recovery. We carried out an investigation of the microbiology of a 1.76 km drill core obtained from the ∼35 million-year-old Chesapeake Bay impact structure, USA, with robust contamination control. Microbial enumerations displayed a logarithmic downward decline, but the different gradient, when compared to previously studied sites, and the scatter of the data are consistent with a microbiota influenced by the geological disturbances caused by the impact. Microbial abundance is low in buried crater-fill, ocean-resurge, and avalanche deposits despite the presence of redox couples for growth. Coupled with the low hydraulic conductivity, the data suggest the microbial community has not yet recovered from the impact ∼35 million years ago. Microbial enumerations, molecular analysis of microbial enrichment cultures, and geochemical analysis showed recolonization of a deep region of impact-fractured rock that was heated to above the upper temperature limit for life at the time of impact. These results show how, by fracturing subsurface rocks, impacts can extend the depth of the biosphere. This phenomenon would have provided deep refugia for life on the more heavily bombarded early Earth, and it shows that the deeply fractured regions of impact craters are promising targets to study the past and present habitability of Mars.

Iron deficiency in pyrrhotite of suevites from the Chesapeake Bay impact crater, USA—A consequence of shock metamorphism?

Abstract– Pyrrhotite from suevite of the 35 Ma Chesapeake Bay impact structure (CBIS) shows a shock metamorphism and we report on several mineralogical and magnetic features. Pyrrhotite shows strong brittle deformation with a high density of stacking faults, twinning parallel to the hexagonal (001) planes and average fault distances in the order of 10 nm. Although the determination of a superstructure was not possible due to the lattice defects, the reflections of the NiAs subcell, which is typical of all pyrrhotite modifications, were clearly detected. This phase is ferrimagnetic with a Curie temperature (TC) between 350 and 365 °C, and suevite with this phase does not show the 34 K transition. The most peculiar feature is the low metal/sulfur ratio of 0.81, which indicates a distinctly higher vacancy concentration than for 4C pyrrhotite and a composition close to smythite (Fe9S11). This phase carries a stable natural remanent magnetization and is relatively hard magnetic. Steep inclinations of the natural remanent magnetization vector, however, suggest that this phase has been remagnetized by the drilling process. A possible explanation is the magnetic domain size of faultless areas of about 10 nm in diameter, which is at the lower limit of the single domain size near the threshold, below which superparamagnetic behavior occurs. The low thermal stability of this phase excludes postshock heating above 300 °C for the suevite of the CBIS. Our results imply that the iron‐deficient pyrrhotite is produced by shock metamorphism, although an iron loss due to shock has never been reported before for pyrrhotite.

Foraminiferal repopulation of the Late Eocene Chesapeake Bay Impact Crater

The Chickahominy Formation is the initial postimpact deposit in the 85km-diameter Chesapeake Bay impact crater, which is centered under the town of Cape Charles, Virginia, USA. The formation comprises dominantly microfossil-rich, silty, marine clay, which accumulated during the final ~1.6myr of late Eocene time. At cored sites, the Chickahominy Formation is 16.8-93.7m thick, and fills a series of small troughs and subbasins, which subdivide the larger Chickahominy basin. Nine coreholes drilled through the Chickahominy Formation (five inside the crater, two near the cratermargin, and two ~3km outside the crater) record the stratigraphic and paleoecologic succession of 301 indigenous species of benthic foraminifera, as well as associated planktonic foraminifera and bolboformids. Two hundred twenty of these benthic species are described herein, and illustrated with scanning electron photomicrographs. The Chickahominy Formation can be categorized as a single benthic foraminiferal biozone (Cibicidoides pippeni Biozone), subdivided into five subzones, in stratigraphic order from bottom to top: Bulimina jacksonensis Subzone; Lagenoglandulina virginiana Subzone; Uvigerina dumblei Subzone; Bolivina tectiformis Subzone, and; Siphonina jacksonensis Subzone. Two planktonic datums and four benthic datums provide a biochronostratigraphic framework in which to estimate the duration and temporal distribution patterns of discrete microfossil assemblages. Apaleoseral succession from pioneer to equilibrium paleocommunities reflects the temporal and spatial evolution from early unstable benthic paleoenvironments to later stable benthic paleoenvironments. Initial reoccupation of the newly formed crater basin is marked by a dramatic immigration of 32 indigenous species, which replaced the sparse, entirely reworked (allochthonous) foraminiferal assemblages of a preceding inhospitable dead zone. At all nine core sites, attainment of benthic paleoenvironmental equilibrium (29-190kyr postimpact) is signaled by a notable reduction in the number of new immigrant species arriving in the Chickahominy basin. In addition, at five sites inside the crater, early unstable benthic paleoenvironments can be differentiated from later stable benthic paleoenvironments by the presence of an agglutinated Psammosiphonella biofacies in basalChickahominy strata and a shift from short-term to long-term benthic foraminiferal generic dominance facies. Restriction of the dead zone and Psammosiphonella biofacies to intracrater sites indicates unusual benthic paleoenvironmental conditions (warm, saline bottomwater and porewater) derived from the impact,which lasted as long as ~350kyr postimpact at one site.Absence of key planktonic foraminiferal and Bolboforma species in early Chickahominy sediments indicates that detrimental effects of the impact also disturbed the upper oceanic water column for at least 80-100kyr postimpact. Nine genera (Bolivina, Uvigerina, Gyroidinoides, Globocassidulina, Angulogerina, Nuttallides, Cibicidina, Caucasina, Epistominella) and two generic groups (buliminids, stilostomellids) are the most abundant taxa among 17 generic dominance facies that characterize Chickahominy core sites. Most dominant taxa were epifaunal or shallow infaunal opportunists, which thrived under conditions of oxygen depletion (dysoxia) and high organic flux rates. After an average of ~73kyr of stressed, rapidly fluctuating paleoenvironments,which were destabilized by after-effects of the impact,most of the cored Chickahominy subbasins maintained stable, nutrient-rich, low-oxygen bottom waters and interstitial microhabitats for the remaining ~1.3myr of late Eocene time.

Jared R. Morrow (October 8, 1959-October 7, 2010)

Jared R. Morrow (October 8, 1959-October 7, 2010)

Shock metamorphism investigations of quartz grains in clasts from impact breccia of the Eyreville B drill core, Chesapeake Bay impact structure, USA

Abstract– The Chesapeake Bay impact structure, approximately 85 km in diameter, has been drilled in 2005–2006 at Eyreville (Virginia, USA), to a total depth of 1766 m. In the drill cores, the abundance of shock metamorphosed material is very variable with depth. Shocked mineral and lithic clasts, as well as melt particles, are most abundant in suevitic impact breccia section (1397–1451 m depth). Shocked quartz (i.e., quartz grains with planar fractures and/or planar deformation features) and melt particles, although rare, are also dispersed in the Exmore Formation unit (444–867 m depth). Other lithologies in the Eyreville drill cores show no clear evidence of shock metamorphism. Here, we report on the investigations of 40 samples from the impact breccia section. A total of more than 27,000 quartz grains were examined in about 200 clasts. The abundance of highly shocked clasts tends to decrease with increasing depth. Crystalline clasts derived from the crystalline basement are commonly only slightly shocked (contain generally <10 rel% of shocked quartz grains). The clasts of metamorphosed sediments show a low proportion of shocked quartz grains (mostly <10 rel%). Sedimentary clasts show a wide range of proportions of shocked quartz grains, with several of them being highly shocked clasts (most values between 0 and 40 rel%). Conglomerates show the highest proportion of shocked quartz grains of all types of clasts (up to 83 rel%). Polycrystalline quartz clasts are also commonly highly shocked (contain mostly between 10 and 40 rel% of shocked quartz grains). These hard nonporous clasts are possibly more liable to show evidence of shock. The investigations suggest that the intensity of shock metamorphism is the result of several parameters, such as original position in the target (both horizontal and vertical) and the properties of each lithology (e.g., grain size, porosity, and amount of matrix). According to the universal‐stage investigations, the dominant orientations of planar deformation features in quartz are , , and also .

Melt in the impact breccias from the Eyreville drill cores, Chesapeake Bay impact structure, USA

– The center of the 35.3 Ma Chesapeake Bay impact structure (85 km diameter) was drilled during 2005/2006 in an ICDP–USGS drilling project. The Eyreville drill cores include polymict impact breccias and associated rocks (1397–1551 m depth). Tens of melt particles from these impactites were studied by optical and electron microscopy, electron microprobe, and microRaman spectroscopy, and classified into six groups: m1—clear or brownish melt, m2—brownish melt altered to phyllosilicates, m3—colorless silica melt, m4—melt with pyroxene and plagioclase crystallites, m5—dark brown melt, and m6—melt with globular texture. These melt types have partly overlapping major element abundances, and large compositional variations due to the presence of schlieren, poorly mixed melt phases, partly digested clasts, and variable crystallization and alteration. The different melt types also vary in their abundance with depth in the drill core. Based on the chemical data, mixing calculations were performed to determine possible precursors of these melt particles. The calculations suggest that most melt types formed mainly from the thick sedimentary section of the target sequence (mainly the Potomac Formation), but an additional crystalline basement (schist/gneiss) precursor is likely for the most abundant melt types m2 and m5. Sedimentary rocks with compositions similar to those of the melt particles are present among the Eyreville core samples. Therefore, sedimentary target rocks were the main precursor of the Eyreville melt particles. However, the composition of the melt particles is not only the result of the precursor composition but also the result of changes during melting and solidification, as well as postimpact alteration, which must also be considered. The variability of the melt particle compositions reflects the variety of target rocks and indicates that there was no uniform melt source. Original heterogeneities, resulting from melting of different target rocks, may be preserved in impactites of some large impact structures that formed in volatile-rich targets, because no large melt body exists, in which homogenization would have taken place.

Monoclinic tridymite in clast-rich impact melt rock from the Chesapeake Bay impact structure

X-ray diffraction and Raman spectroscopy confirm a rare terrestrial occurrence of monoclinic tridymite in clast-rich impact melt rock from the Eyreville B drill core in the Chesapeake Bay impact structure. The monoclinic tridymite occurs with quartz paramorphs after tridymite and K-feldspar in a microcrystalline groundmass of devitrified glass and Fe-rich smectite. Electron-microprobe analyses revealed that the tridymite and quartz paramorphs after tridymite contain different amounts of chemical impurities. Inspection by SEM showed that the tridymite crystal surfaces are smooth, whereas the quartz paramorphs contain irregular tabular voids. These voids may represent microporosity formed by volume decrease in the presence of fluid during transformation from tridymite to quartz, or skeletal growth in the original tridymite. Cristobalite locally rims spherulites within the same drill core interval. The occurrences of tridymite and cristobalite appear to be restricted to the thickest clast-rich impact melt body in the core at 1402.02-1407.49 m depth. Their formation and preservation in an alkali-rich, high-silica melt rock suggest initially high temperatures followed by rapid cooling.