Heat Reaction Research Articles

STUDYING THE THERMOCHEMICAL CHARACTERISTICS OF SINTERING WITH ALKALI CONCENTRATE FROM WASTE COPPER TAILINGS

A long period of deposit development leads to a reduction in the volume of balance reserves of ores, while the volume of accumulation of waste (tailings) from mining and processing production increases. In connection with this, an urgent problem is the processing of waste tailings, which can serve as an additional source of commercial products of non-ferrous metals. The set objectives can be achieved by implementing comprehensive extraction of valuable components, reducing fuel, and energy costs at the stage of low-temperature sintering to produce white soot (grade BS-100). In order to determine the amount of heat of chemical reactions during sintering of rough copper concentrate with sodium hydroxide, thermochemical calculations were carried out. For the research, we used rough copper concentrate with a copper content of 4.40% and silver of 77.03 g/t. An equation has been obtained for calculating the heat of chemical reactions of rough concentrate sintering. According to this equation, the greatest contribution to the heat release is provided by the iron content (60%), three times less and equally (19%) - copper and silicon and about 0.2% is absorbed by aluminum. The thermal effect of sintering will be -920.45 kW·h/t of concentrate. From the heat balance of sintering it follows that with an alkali consumption of up to 200% of the mass of the concentrate. The heat of chemical reactions will be sufficient for the autogeneity of the process. Research has been carried out on sintering the concentrate with alkali in the temperature range of 250-500 °C and obtaining white soot from a productive leaching solution with the extraction of 60% silicon. White soot (mSiO2·nH2O) was isolated by two-stage carbonization of a silicate solution with carbon dioxide in a recirculation system with further washing of the precipitate with a solution of sulfuric acid. For citation: Karimova L.M., Kairalapov Ye.T., Makascheva G.K., Kharchenko Ye.M. Studying the thermochemical characteristics of sintering with alkali concentrate from waste copper tailings. ChemChemTech [Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol.]. 2024. V. 67. N 7. P. 72-79. DOI: 10.6060/ivkkt.20246707.7004.

Dynamics of the ohmic heating and chemically reactive time-dependent flow of magnetized Casson fluid inside a rectangular pipe

Chemical reaction and ohmic heating can significantly influence the flow behavior and heat transfer characteristics in industrial processes involving non-Newtonian fluids. These processes include polymer processing, food processing, and manufacturing processes where non-Newtonian fluids are commonly encountered. Therefore, the impacts of chemical reaction and ohmic heating on the unsteady flow of an incompressible magnetized non-Newtonian Casson liquid through a rectangular pipe with a variable pressure gradient is scrutinized in this article. The impacts of heat generation/absorption and viscous dissipation are also incorporated through the energy equation. The numerical simulations of partial differential equations (PDEs) are acquired utilizing the finite difference method with the incorporating relaxation (SOR) algorithm. The impacts of dissimilar imperative parameters on various flow fields are scrutinized through graphs. Outcomes indicate that liquid velocity decreases with enhancing values of the Casson parameter. Furthermore, the liquid temperature has an enhancing behavior with the impact of the heat source/sink parameter. Comparisons of numerical results with previously published results show an excellent agreement. This kind of research may find specific industrial and medical utilizations such as glass manufacturing, crude oil purification, lubrication, paper production, blood transport study in cardiovascular design, etc.

Harvesting Energy Via Water Movement and Surface Ionics in Microfibrous Ceramic Wools

Due to the push for carbon neutrality in various human activities, the development of methods for producing electricity without relying on chemical reaction processes or heat sources has become highly significant. Also, the challenge lies in achieving microwatt‐scale outputs due to the inherent conductivity of the materials and diverting electric currents. To address this challenge, our research has concentrated on utilizing nonconductive mediums for water‐based low‐cost microfibrous ceramic wools in conjunction with a NaCl aqueous solution for power generation. The main source of electricity originates from the directed movement of water molecules and surface ions through densely packed microfibrous ceramic wools due to the effect of dynamic electric double layer. This occurrence bears resemblance to the natural water transpiration in plants, thereby presenting a fresh and straightforward approach for producing electricity in an ecofriendly manner. The generator module demonstrated in this study, measuring 12 × 6 cm2, exhibited a noteworthy open‐circuit voltage of 0.35 V, coupled with a short‐circuit current of 0.51 mA. Such low‐cost ceramic wools are suitable for ubiquitous, permanent energy sources and hold potential for use as self‐powered sensors and systems, eliminating the requirement for external energy sources such as sunlight or heat.

Математическое моделирование пиролиза резиновых отходов в горизонтальном цилиндрическом реакторе

Recycling of cushioned rubber products is an important environmental and technical-economic issue. Among the various methods of processing such waste, one of the most effective is the pyrolysis process, since it allows us to obtain fuel and energy, and provides the possibility of secondary use of carbon black and metal. Mathematical modeling of this process is necessary to solve problems of optimization and automated control. Thus, the purpose of this study is to simulate the pyrolysis process in a horizontal cylindrical batch reactor, which is currently becoming increasingly widespread. To mathematically describe the process, a model with distributed parameters is used in the form of a two-dimensional thermal conductivity equation and a system of equations of chemical kinetics of polymer thermal destruction reactions. The problem is solved numerically using the finite element method. As a result of the numerical solution of the equations of the mathematical model, non-stationary distributions of temperature and degree of conversion over the cross section of the reactor with non-uniform filling have been obtained. The authors have studied the kinetics of the reaction of polymer thermal destruction in reactors of different diameters. The results obtained can be used to predict the kinetics of material destruction under given reactor heating conditions, which can be useful when we design reactors and automate pyrolysis process control.

Assessing the Potential of Teff Husk for Biochar Production through Slow Pyrolysis: Effect of Pyrolysis Temperature on Biochar Yield

Environmental restoration and sustainable energy solutions require effective management and utilization of agricultural crop residues to reduce greenhouse gas emissions. Biowastes are a valuable resource that can be converted into biofuels and their byproducts, solving the energy crisis and reducing environmental impact. In this study, teff husk, primarily generated in Ethiopia during the production of teff within the agro-industrial sector, is used as a feedstock for slow pyrolysis. Ethiopia generates an estimated annual production of over 1.75 million tons of teff husk, a significant portion of which is incinerated, resulting in significant pollution of the environment. This study focuses on assessing teff husk as a potential material for slow pyrolysis, a crucial stage in biochar production, to tap into its biochar-producing potential. To identify the composition of biomass, the teff husk underwent an initial analysis using thermogravimetry. The significant presence of fixed carbon indicates that teff husk is a viable candidate for pyrolytic conversion into biochar particles. The process of slow pyrolysis took place at three temperatures—specifically, 400, 450, and 500 °C. The maximum biochar yield was achieved by optimizing slow pyrolysis parameters including reaction time, temperature, and heating rate. The optimized reaction time, temperature, and heating rate of 120 min, 400 °C, and 4.2 °C/min, respectively, resulted in the highest biochar yield of 43.4 wt.%. Furthermore, biochar’s physicochemical, SEM-EDX, FTIR, and TGA characterization were performed. As the temperature of biochar increases, its carbon content and thermal stability increases as well. Unlike fuel recovery, the results suggest that teff-husk can be used as a feedstock for biochar production.

Preparation of Ultrafine Co- and Ni-Coated (Ti,W,Mo,Ta)(C,N) Powders and Their Influence on the Microstructure of Ti(C,N)-Based Cermets.

The use of metal-coated ceramic powders not only effectively enhances the wettability of the metal-ceramic interface but also promotes a more uniform microstructure in Ti(C,N)-based cermets, which is advantageous for improving their mechanical properties. In this study, ultrafine Co- and Ni-coated (Ti,W,Mo,Ta)(C,N) powders were synthesized via the spray-drying-in-situ carbothermal reduction method. Subsequently, Ti(C,N)-based cermets were effectively fabricated using the as-prepared ultrafine Co- and Ni-coated (Ti,W,Mo,Ta)(C,N) powders. The impact of reaction temperature, heating rate, and isothermal time on the phase and microstructure of prepared powders was analyzed using X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Additionally, the microstructure of the as-sintered cermets was experimentally investigated. The findings reveal that the complete reduction of Co and Ni metal salts, pre-coated on the surface of (Ti,W,Mo,Ta)(C,N) particles, can be achieved through rapid heating (10 °C/min) in a specific temperature range (600-1000 °C) with an isothermal time of 3 h at a lower reduction temperature (1000 °C). The synthesized powders have only two phases: the (Ti,W,Mo,Ta)(C,N) phase and Co/Ni phase, and no other heterogeneous phases were observed with an oxygen content of 0.261 wt.%. Notably, the conventional core-rim structure was not dominant in the cermets obtained from the prepared Co- and Ni-coated (Ti,W,Mo,Ta)(C,N) powders. Moreover, the heterogeneous segregation effect of the Co/Ni coating on the ultrafine powder particles resulted in a finer microstructure than the traditional cermets with the same composition. However, the grain size is mainly in the range of 0.5-0.8 μm. The weaker residual stresses at the core and rim interfaces and the finer particle distributions could theoretically enhance the toughness of Ti(C,N)-based cermets, simultaneously.

Reaction Pattern and Mechanistic Aspects of Iodine and Iodine-Based Reagents in Selenylation of Aliphatic, Aromatic, and (Hetero)Cyclic Systems.

Organoselenium compounds have been the subject of extensive research since the discovery of the biologically active compound ebselen. Ebselen has recently been found to show activity against the main protease of the virus responsible for COVID-19. Other organoselenium compounds are also well-known for their diverse biological activities, with such compounds exhibiting interesting physical properties relevant to the fields of electronics, materials, and polymer chemistry. In addition, the incorporation of selenium into various organic molecules has garnered significant attention due to the potential of selenium to enhance the biological activity of these molecules, particularly in conjunction with bioactive heterocycles. Iodine and iodine-based reagents play a prominent role in the synthesis of organoselenium compounds, being valued for their cost-effectiveness, non-toxicity, and ease of handling. These reagents efficiently selenylate a broad range of organic substrates, encompassing alkenes, alkynes, and cyclic, aromatic, and heterocyclic molecules. They serve as catalysts, additives, inducers, and oxidizing agents, facilitating the introduction of different functional groups at alternate positions in the molecules, thereby allowing for regioselective and stereoselective approaches. Specific iodine reagents and their combinations can be tailored to follow the desired reaction pathways. Here, we present a comprehensive review of the progress in the selenylation of organic molecules using iodine reagents over the past decade, with a focus on reaction patterns, solvent effects, heating, microwave, and ultrasonic conditions. Detailed discussions on mechanistic aspects, such as electrophilic, nucleophilic, radical, electrochemical, and ring expansion reactions via selenylation, multiselenylation, and difunctionalization, are included. The review also highlights the formation of various cyclic, heterocyclic, and heteroarenes resulting from the in situ generation of selenium intermediates, encompassing cyclic ketones, cyclic ethers, cyclic lactones, selenophenes, chromones, pyrazolines, pyrrolidines, piperidines, indolines, oxazolines, isooxazolines, lactones, dihydrofurans, and isoxazolidines. To enhance the reader's interest, the review is structured into different sections covering the selenylation of aliphatic sp2/sp carbon and cyclic sp2 carbon, and then is further subdivided into various heterocyclic molecules.

Factors affecting reduction efficiency in industrial retorts for Mg production by aluminothermic process

Industrial experiments were carried out for Mg production by aluminothermic process in industrial retorts and the factors affecting the reduction efficiency were analyzed. The results show that the main factors reducing the reduction ratio are oxidation and combustion of crystallized magnesium and uneven mixing of raw materials. The latter could result in raw material regions with low Al concentration and MgO redundance, which can promote the formation of 12CaO·7Al2O3 and CaO·Al2O3. For raw material regions with higher Al concentration, both MgO and CaO can be reduced to form the Mg2Ca phase. Radiation and chemical reaction heat are the key factors affecting the reaction rate. Increasing the heating temperature can rapidly increase the bed temperature and obtain sufficient reaction ratio. The higher the magnesium content in the pellets is, the longer the reduction time is required.

Enhancing Intrinsic Electrocatalytic Activity of Pt/C Nanoparticles for Oxygen Reduction Reaction in Acidic Media by Microwave-Assisted Synthesis

Abstract: This study is focused on the enhancement of the intrinsic electrocatalytic activity of Pt nano-particles supported on C (Pt/C NPs) towards Oxygen Reduction Reaction (ORR) in acidic media. The goal was to investigate the effect of microwave-assisted synthesis on the electrocatalytic performance of Pt/C NPs towards ORR. Thus, Pt/C NPs were synthesized using a microwave-assisted method and by a conventional heating method; structural and morphological characteristics were analyzed by X-ray dif-fraction (XRD) and transmission electron microscopy (TEM). Electrochemical studies were performed using the rotating disk electrode technique to evaluate the ORR performance. Microwave-assisted syn-thesis produced Pt/C NPs with a smaller particle size (6.3 ± 0.2 nm) than conventionally synthesized nanoparticles (8.6 ± 0.3 nm). Electrochemical analysis showed that the microwave-synthesized Pt/C NPs exhibited higher mass activity (4.6 ± 0.8 mA･g-1Pt) for ORR compared to conventionally synthesized nanoparticles (1.9 ± 0.4 mA･mA･g-1Pt). These results demonstrate that microwave-assisted synthesis en-hances the intrinsic electrocatalytic activity of Pt/C NPs for ORR in acidic media. These findings have important implications for the development of efficient electrocatalysts for fuel cell applications. Background: The synthesis and characterization of platinum nanoparticles on C are crucial for advancing electrocatalysis, particularly in the context of potential applications in fuel cells. This study builds on previous research, focusing on two distinct synthesis methods to enhance our understanding of their im-pact on nanoparticle properties and electrocatalytic performance. Objective: To investigate the synthesis efficiency, structural characteristics, and electrocatalytic activities of platinum nanoparticles on C using microwave-assisted heating and conventional synthesis reactor heating. The objective is to discern any significant differences in particle size, structure, and electrocata-lytic performance between the two synthesis methods. Methods: The synthesis involved a comparative analysis of platinum nanoparticles using microwave-assisted and conventional heating methods. Chemical composition analysis verified the synthesis efficiency, and structural and morphological characterizations were performed using X-ray Diffraction and Transmission Electron Microscopy. Electrochemical studies employed the rotating disk electrode technique, with activation and evaluation conducted through cyclic voltammetry, and the oxygen reduction reaction studied via linear sweep voltammetry in an acidic media (0.5 mol⋅L-1 H2SO4). Results: Well-supported platinum nanoparticles with a face-centered cubic structure were obtained on C using both synthesis methods. However, microwave-synthesized particles (6.3 ± 0.2 nm) exhibited a smaller size compared to conventionally synthesized particles (8.6 ± 0.3 nm). Electrochemical assess-ment revealed superior mass activity for microwave-synthesized material (4.6 ± 0.8 mA･g-1Pt), outper-forming commercial Pt nanoparticles (3.0 ± 0.3 mA･g-1Pt) and conventionally synthesized material (1.9 ± 0.4 mA･mA･g-1Pt). Conclusion: This study concludes that microwave-assisted synthesis yields platinum nanoparticles on C with enhanced electrocatalytic performance, as evidenced by the smaller particle size and superior mass activity compared to conventionally synthesized material and commercial Pt nanoparticles. These findings highlight the potential of microwave-synthesized Pt nanoparticles for applications in fuel cells.

Effect of the reactor heating rate on bio-crude yield and quality from hydrothermal liquefaction of different sludge

This study scrutinizes the effect of the heating rate obtained in two reactors of different volume (10 mL and 500 mL) on the production of bio-crude during the hydrothermal liquefaction (HTL) process applied to sludges of different nature: a municipal, a paper mill and an agricultural sludge. The effect of the reactor scale on the chemical composition of the bio-crude and the solid residue (co-product of HTL process) is also evaluated by elemental, GC–MS and FT-IR analysis. Results suggest that different heating rates along HTL exert an almost negligible influence on the bio-crude yield and limited effect on the chemical composition when the reaction time under the isothermal conditions is kept at 10 min. In fact, regardless of the heating rate, the bio-crude yields on dry basis from municipal, paper mill and agricultural sludges are equal to 21 %, 21 % and 12 %, respectively. These results could be explained with the different reactive pathway and kinetics of the sludges macro-components.

Photothermal heating of cell-free reactions for on-site production of recombinant proteins

Photothermal heating of cell-free reactions for on-site production of recombinant proteins

Analytical simulation of Darcy–Forchheimer flow of hybrid nanofluid through cone with nonlinear heat source and chemical reaction

This paper intends to discuss the hybrid nanofluid flow through a cone in a Darcy–Forchheimer porous media, containing base fluid Methanol (CH3OH), nanoparticles of titanium oxide (TiO2) and copper (Cu). We have examined the flow under the influences of mixed convection, viscous dissipation, chemical reaction, and nonlinear heat source. In hybrid nanofluid flow, viscous dissipation and mixed convection play a crucial role in heat exchangers. By accounting for both mixed convection and viscous dissipation, the addition of nanoparticles into a base fluid improves the transfer of heat and optimizes the performance of the cooling system. Using the laws of conservation, governing equations have been constructed. The flow model is converted using the appropriate similarity transformations from partial differential equations to ordinary differential equations. The homotopy analysis method is used to solve the updated system of equations. When Forchheimer inertial drag parameter is increased, the velocity profile decreases, but it rises when the Darcy number is increased. As the value of exponential heat source parameter rises, the temperature profile increases as well. The result exposes that with an increment in nanoparticle volume fraction, temperature profile also rises but velocity profile decreases.

The significance of chemical reaction, thermal buoyancy, and external heat source to optimization of heat transfer across the dynamics of Maxwell nanofluid via stretched surface

Energy loss during the transportation of energy is the main concern of researchers and industrialists. The primary cause of heat exchange gadget inefficiency during transportation was applied to traditional fluids with weak heat transfer characteristics. Instead, thermal devices worked much better when the fluids were changed to nanofluids that had good thermal transfer properties. A diverse range of nanoparticles were implemented on account of their elevated thermal conductivity. This research addresses the significance of MHD Maxwell nanofluid for heat transfer flow. The flow model comprised continuity, momentum, energy transport, and concentration equations in the form of PDEs. The developed model was converted into ODEs by using workable similarities. Numerical simulations in the MATLAB environment were employed to find the outcomes of velocity, thermal transportation, and concentration profiles. The effects of many parameters, such as Hartman, Deborah, buoyancy, the intensity of an external heat source, chemical reactions, and many others, were also evaluated. The presence of nanoparticles enhances temperature conduction. Also, the findings are compared with previously published research. In addition, the Nusselt number and skin friction increase as the variables associated with the Hartman number and buoyancy parameter grow. The respective transfer rates of heat are 28.26%\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\%$$\\end{document} and 38.19%\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\%$$\\end{document} respectively. As a result, the rate of heat transmission increased by 14.23%\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\%$$\\end{document}. The velocity profiles enhanced while temperature profiles declined for higher values of the Maxwell fluid parameter. As the external heat source increases, the temperature profile rises. Conversely, buoyancy parameters increase as it descends. This type of problem is applicable in many fields such as heat exchangers, cooling of electronic devices, and automotive cooling systems.

Optimizing the Vanillin-Acid Sulfuric Method to Total Saponin Content in Leaves of Yerba Mate Clones.

Yerba mate (Ilex paraguariensis) is a forest species consumed in the form of non-alcoholic beverages in South America, with applications in foods, cosmetics, and pharmaceutical industries. The species leaves are globally recognized for their important bioactive compounds, including, saponins. We adjusted the vanillin-acid sulfuric method for determining spectrophotometrically the total saponin in yerba mate leaves. Seeking to maximize the extraction of saponins from leaves, a Doehlert design combined with Response Surface Methodology (RSM) was used, considering ethanol:water ratios and ultrasound times. In addition, the same methodology was used for the analysis of times and temperatures in the vanillin-sulfuric acid reaction heating. The contents of total saponin in mature leaves were compared in four yerba mate clones. The extraction was maximized using 40 % ethanol:60 % water and 60 minutes of ultrasound assisted extraction (UAE) without heating. For the reaction conditions, 70 °C for 10 minutes heating is recommended, and UV/Vis reading from 460 to 680 nm. Using the optimized methodology, total saponin contents ranged from 28.43 to 53.09 mg g-1 in the four yerba mate clones. The significant difference in saponin contents between clones indicate great genetic diversity and potential for clones' selection and extraction of these compounds from yerba mate leaves.

GASIFICATION TECHNOLOGY AND ITS FUTURE: A REVIEW

Gasification technology has the potential to revolutionise the energy industry by providing a clean and efficient way to produce energy from a variety of raw materials. This technology have the ability to produce synthesis gas from raw materials based on negative or low carbon values such as high sulphur fuel oil, petroleum coke, coal, domestic wastes, industrial and biomass wastes. The gas produced from the process is used to replace natural gas, to generate electricity, or as a basic raw material to produce chemicals and liquid fuels. Gasification is a process that uses heat, pressure, and steam to convert substances directly into gases, such as carbon monoxide and hydrogen. Gasification technology has differences in various aspects but there are four engineering factors that are the core of the gasification system such as atmospheric gasification reactor (level of oxygen or air content), internal and external heating, reactor design and operating temperature. The raw material used, prepared and introduced in dry form and small particles to the reactor chamber are called gasification. Raw materials experience heat, pressure and an environment rich or low in oxygen content in the gasification. There are three main products from the gasification process which are hydrocarbon gas (also called syngas), hydrocarbon liquid (oil) and coal (carbon black and ash). Syngas can be used as a fuel to produce electricity or steam or as a based material for many types of chemicals. When mixed with air, syngas can be used in petrol or diesel engines as a vehicle fuel with minor modifications to the engine. Gasification technology has several advantages over traditional fossil fuel-based energy production methods. It is able to produce energy from a wide range of raw materials, including waste, which reduces the need for landfills and incineration. Additionally, gasification can reduce greenhouse gas emissions by producing energy from low or negative carbon value raw materials.

Vat photopolymerization additive manufacturing process modeling: a thermal-chemical coupling approach informed by in-situ and ex-situ characterization data

Vat photopolymerization (VPP) is one of the most widely used additive manufacturing methods. The VPP process temperature and material curing reaction interplay with each other to critically determine the final product quality. Insights about the time-varying process temperature and degree of conversion (DoC) is desired for VPP process control but difficult to attain due to lacking effective operando characterization technologies. This work reports a new method to create a thermal-chemical model of the VPP process by solving an inverse heat conduction problem (IHCP) based on in-situ observable temperature measurement to estimate the chemistry reaction-induced heat source that is a function of DoC. Ex-situ photo differential scanning calorimetry (Photo-DSC) characterization is used to initialize the chemistry reaction model parameters so that DoC can be calculated. Specifically, vat substrate temperature is measured using an in-situ infrared thermal camera and used as input to solve an IHCP for estimating exothermic heat generation rate for the internal heat generation component at the curing part. Overall, the newly developed VPP modeling framework combines an IHCP that is optimized by in-situ thermal monitoring with a chemical reaction heat generation and conduction model that is educated by Photo-DSC characterization. The model predictions of temperature and DoC are experimentally validated by comparing against in-situ temperature measurement and ex-situ spectroscopy measurement of prints at different exposure times.

Influence of the catalyst precursor for cobalt on activated carbon applied in ammonia decomposition

Ammonia is a key compound for storing and transporting green hydrogen. However, the efficient release of stored hydrogen through thermocatalytic ammonia decomposition is achievable only at temperatures around 600 °C, particularly with non-noble metal-based catalysts, which prove to be both ecologically and economically more feasible. In this study, electrically conductive activated carbon was selected as the catalyst support, chosen specifically for its suitability in achieving more energy-efficient direct reactor heating through the ohmic resistance of the catalysts. Cobalt salts were wet impregnated on activated carbon investigating the influence of different precursors (cobalt nitrate and cobalt acetate) and pyrolysis temperatures (400 °C and 600 °C) under N2 flow on the cobalt particle size and the incorporation of cobalt into the carbon matrix. TEM imaging and CO-chemisorption revealed well dispersed cobalt particles with sizes below 10 nm for the catalysts synthesized from the cobalt nitrate precursor. On the other hand, cobalt acetate led to about nine times larger Co agglomerates, which were partially detached from the carbon matrix. Moreover, this substantial difference in the Co particle size results in a significantly higher ammonia conversion for cobalt nitrate-based catalysts, achieving 94 % of ammonia conversion at 600 °C. Furthermore, the long-term stability test of the cobalt nitrate-based catalyst resulted in a slight deactivation of only 2 % ammonia conversion at 500 °C.

Research on the Influence of Negative KERMA Factors on the Power Distribution of a Lead-Cooled Fast Reactor

The accurate calculation of reactor core heating is vital for the design and safety analysis of reactor physics. However, negative KERMA factors may be produced when processing and evaluating libraries of the nuclear data files ENDF/B-VII.1 and ENDF/B-VIII.0 with the NJOY2016 code, and the continuous-energy neutron cross-section library ENDF71x with MCNP also has the same problem. Negative KERMA factors may lead to an unreasonable reactor heating rate. Therefore, it is important to investigate the influence of negative KERMA factors on the calculation of the heating rate. It was also found that negative KERMA factors can be avoided with the CENDL-3.2 library for some nuclides. Many negative KERMA nuclides are found for structural materials; there are many non-fuel regions in fast reactors, and these negative KERMA factors may have a more important impact on the power distribution in non-fuel regions. In this study, the impact of negative KERMA factors on power calculation was analyzed by using the RBEC-M benchmark and replacing the neutron cross-section library containing negative KERMA factors with one containing normal KERMA factors that were generated based on CENDL-3.2. For the RBEC-M benchmark, the deviation in the maximum neutron heating rate between the negative KERMA library and the normal library was 6.46%, and this appeared in the reflector region. In the core region, negative KERMA factors had little influence on the heating rate, and the deviations in the heating rate in most assemblies were within 1% because the heating was mainly caused by fission. However, in the reflector zone, where gamma heating was dominant, the total heating rate varied on account of the gamma heating rate. Therefore, negative KERMA factors for neutrons have little influence on the calculation of fast reactor heating according to the RBEC-M benchmark.

A computational ascertainment of Hall and ion slip implications over a stretched regime with chemical reaction and internal heat source

This study is inspired by the emerging importance of micropolar fluids in a variety of scientific and technical fields due to varied uses and effective thermal activities. Potential applications of these fluids include cancer treatment, magnetic refrigeration, drug delivery and magnetic resonance imaging. Hall and ion repercussions on unstable magneto micropolar liquid beyond a stretched sheet are described in this article. By using the bvp4c, the resulting non-sequential coupled PDEs are transfigured into a system of coupled non-consecutive ODEs, which are remedied by a numerical procedure. An impact of various governing non-dimensional factors on velocity, angular momentum, temperature, concentration, wall friction, couple stress, local Nusselt and Sherwood numbers, is indicated graphically. The main finding specifies that Hall and Ion impacts influence velocity and with increased Hall and Ion effects, velocity raised as well as thermal boundary layer reduced. When compared to previous findings in the literature, the current findings indicate a splendid agreement. The predominant uses of this issue are in solar cell systems, such as solar water pumps, manufacturing and production processes, motion in plasmas, furnace design, nuclear power plants, and solar aircraft wings.

On thermal distribution of MHD mixed convective flow of a Casson hybrid nanofluid over an exponentially stretching surface with impact of chemical reaction and ohmic heating

On thermal distribution of MHD mixed convective flow of a Casson hybrid nanofluid over an exponentially stretching surface with impact of chemical reaction and ohmic heating