Polypyrrole has a unique place among conducting polymers discovered so far, due to its advantageous properties such as low-cost synthesis, stable electrical conductivity, non-toxicity, environmentally benign nature, etc. In this study, the polymerization of polypyrrole is carried out inside the porous structure of the polyvinylidene fluoride (PVDF) matrix using the chemical oxidation method to prepare flexible and rollable conducting films. The resistivity measurement of these flexible and rollable Polypyrrole-PVDF films were carried out using a standard four-point probe method in the temperature range of 320–10 K. The room temperature dc electrical conductivity of the film was found to be ∼ 50 S/m. To understand the charge transport mechanism in these films the experimental data were analyzed in the light of Mott’s variable range hopping model and Fluctuation assisted tunneling model. It was found that experimental data follows the three-dimensional variable range hopping behavior from 320 K to 90 K and below 90 K a crossover from hopping to fluctuation-assisted tunneling was observed. Mott’s parameters were measured in the temperature range of 320–90 K and the corresponding values for density of states at the Fermi level N(EF), average hopping distance (R), and average hopping energy (W) were found to be 5.54 × 1029m-3eV−1, 2.94 Å and 17.7 meV respectively.