Units of modern cars require an uninterrupted supply of electricity of the required quality, therefore, the prompt determination of the technical condition of the power supply system (SE) is an urgent task. During the operation of the car, there is a dynamic redistribution of electricity consumed for the needs of consumers between the car generator and the storage battery (AKB). The efficiency of the balance of electricity on board the car is influenced not only by the power of consumers, the mode of movement of the car, weather and climatic factors, but also by the technical condition of the generator and battery, however, insufficient attention has been paid to this. It has been established that the currents of the generator, the field winding and the battery, as well as the voltage of the on-board network, can serve as indicators of the technical condition of the vehicle’s ESS. The purpose of the article is to develop typical loading modes of a vehicle’s solar cell and a technique for their modeling in laboratory conditions. The leading method for solving this problem is fixing the ESS parameters using an analog data recorder with variations in the load current and the generator rotor speed. In the course of the experiment, the loading modes were changed in the order of increasing the generator rotor speed. The nature of the change in the parameters of the solar cell in the case of a working generator and a charged battery has been determined. The efficiency of the solar cell can be indirectly estimated by the ratio of the areas limited by the charging and discharging currents of the battery of the dynamic characteristic curve. With a load current of 10 A, the energy supplied by the battery generator exceeds the energy consumed for the work of consumers. When the load current increases to 15 A, the energy balance shifts towards the discharge part. The experimentally established dependences of the change in the parameters of the solar cell with variations in the load and speed modes of operation can be considered a scientific novelty. The practical significance of the research carried out is to increase the reliability of diagnosing SE based on the analysis of indicators of its technical condition. Further research will be aimed at determining changes in the parameters of the vehicle’s ESS in the process of occurrence and development of generator and battery malfunctions.