In this paper, we present a proof-of-principle of the formation of pure maximally entangled states from the Greenberger-Horne-Zeilinger class, in the experimental context of charged quantum dots. Each qubit must be identified as a pair of quantum dots, sharing an excess electron, coupled by tunneling. The electron-electron interaction is accounted for and is responsible for the coupling between the qubits. The interplay between coherent tunneling events and many-body interaction gives rise to the formation of highly entangled states. We begin by treating the problem of encoding three-qubits in a system with three pairs of quantum dots, and the numerical analysis of the exact quantum dynamics to find the conditions for the generation of the GHZ states. An effective two-level model sheds light on the role of a high-order tunneling process behind the dynamics. The action of the main decoherence process, the charge dephasing, is quantified in the process. We then evaluate the physical requirements for the dynamical generation of GHZ states in a $N$ qubit scenario, and its challenges.
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