Characterization Of Materials Research Articles

In situ acoustic characterization of a perforated panel on a cavity by means of PU measurement and model fitting

The in situ characterization of materials is a crucial challenge in room acoustics, as laboratories measurement cannot always be applied in consultancy practices. In particular, there is a lack of method to characterize in situ systems with perforated facings, which are commonly encountered systems in room acoustics. In this paper, the in situ characterization of a rigidly-backed porous material behind a rigid perforated facing by means of pressure–velocity measurements is presented. The method includes an inverse impedance model fitting based on measurement in a limited frequency range. The applicability of this method was studied by measuring a variety of perforated facings, whether in front of an air cavity or backed by a porous layer, and comparing the obtained impedance model parameters to reference values. Good agreement was observed between the retrieved parameters and the references, with the errors in all retrieved parameters moving mass, facing thickness, cavity depth, porous layer thickness and porous layer flow resistivity not exceeding 15%.

Decellularized Biohybrid Nerve Promotes Motor Axon Projections.

Developing nerve grafts with intact mesostructures, superior conductivity, minimal immunogenicity, and improved tissue integration is essential for the treatment and restoration of neurological dysfunctions. A key factor is promoting directed axon growth into the grafts. To achieve this, biohybrid nerves are developed using decellularized rat sciatic nerve modified by in situ polymerization of poly(3,4-ethylenedioxythiophene) (PEDOT). Nine biohybrid nerves are compared with varying polymerization conditions and cycles, selecting the best candidate through material characterization. These results show that a 1:1 ratio of FeCl3 oxidant to ethylenedioxythiophene (EDOT) monomer, cycled twice, provides superior conductivity (>0.2mScm-1), mechanical alignment, intact mesostructures, and high compatibility with cells and blood. To test the biohybrid nerve's effectiveness in promoting motor axon growth, human Spinal Cord Spheroids (hSCSs) derived from HUES 3 Hb9:GFP cells are used, with motor axons labeled with green fluorescent protein (GFP). Seeding hSCS onto one end of the conduit allows motor axon outgrowth into the biohybrid nerve. The construct effectively promotes directed motor axon growth, which improves significantly after seeding the grafts with Schwann cells. This study presents a promising approach for reconstructing axonal tracts in humans.

Broadband acoustic waves in plate-like structures for acoustic material characterisation

Abstract Guided acoustic waves can be used for a multitude of different testing and material characterisation purposes. The options for evaluation are especially plentiful if a method for broadband excitation, e.g. thermoelastic excitation using focused, pulsed laser radiation, is used, and if the distance between excitation and detection of the acoustic waves can be varied. In this contribution, methods to infer different quantitative material properties from the recorded spatiotemporal measurement data are presented, ranging from isotropic elastic properties to parameters describing absorption for complex absorption models.

Zeolite functionalized with macroalgae as novel material for Fe and Mn removal from real acid mine drainage

The treatment of heavy metals such as Fe and manganese Mn remains a critical global issue, necessitating solutions that are not only effective and efficient but also cost- effective and easy to implement. Adsorption has been identified as one of the most efficient techniques for removing heavy metals. This study investigates adsorption method applied to real AMD, characterized by high levels of heavy metal contamination and low pH. Key parameters analyzed include adsorption performance, isotherm and kinetic models, thermodynamic properties, and adsorption characteristics. The adsorbent used was zeolite functionalized with carboxyl, hydroxyl, and sulfate groups derived from macroalgae. Material characterization was conducted using SEM, XRD, and FTIR. The results indicate that zeolite functionalized with carboxyl, hydroxyl, and sulfate groups from macroalgae effectively reduced Fe and Mn concentrations by up to 99 % within just five minutes. Furthermore, the adsorption process followed a pseudo-second-order kinetic model and conformed to the Langmuir isotherm model.

Experimental review and accuracy of etchants used for phase analysis of SAF2507 Super Duplex Stainless Steel

The mechanical and corrosion properties of duplex stainless steels (DSS) depend on the distribution of ferrite and austenite as well as the presence of secondary phases. It is therefore necessary to accurately determine both the distribution of the phases and their morphology. The aim of this research is to define a standard method for the determination of the volume fraction of the phases present in a SAF2507 SDSS by analysing images acquired by light microscope. To do this, the material is heat-treated at 850 °C for 5 min, 15 min, 30 min, 1h, 5h to stimulate the formation of the σ-phase. The metallographic etchant capable of maximising phase contrast is then identified. Micrographic analyses are performed using different reagents at different holding times and temperatures, in order to find the best combination. A standard procedure is then defined for the image analysis. The data obtained were are processed to calculate the phase distribution. The results are compared with the quantitative analysis performed using X-ray diffraction as reference.The research evidence that Kalling's reagent is best etchant for fully solubilised materials, as it accurately estimates ferrite and austenite content. On the other hand, Marble's reagent should be preferred for the detection of σ-phase. For comprehensive analysis of all phases, Murakami's reagent is recommended.The approach defined in this paper not only improves the understanding of the microstructure of DSS, but also provides an important tool for industrial quality control and material characterisation.

Nafion/ZrO2 Modified NiTi Orthodontic Wire: Preparation, Material Characterization, and Corrosion Studies

Background: Nickel-titanium (NiTi) orthodontic wires are widely used in dental corrective procedures due to their high mechanical properties and cost-effectiveness. However, they are prone to oral corrosion, leading to mechanical deterioration, aesthetic issues, and potential health concerns. Objective: This study aims to improve the corrosion resistance and durability of NiTi orthodontic wires by employing zirconium dioxide (ZrO2) and Nafion coating with the goal of enhancing wire performance. Methods: Two types of NiTi wires were evaluated: a standard, unmodified wire as a control and another wire treated with electrodeposited ZrO2 film and Nafion (Naf) coating. Surface analysis was conducted using various techniques, including Field Emission Scanning Electron Microscopy (FESEM) and Energy Dispersive X-ray Spectroscopy (EDX) analysis. Results: The uncoated NiTi wire exhibited a corrosion rate of 4.436× 10-1 mm/year, whereas the Naf/ZrO2-coated NiTi wire showed a corrosion rate of 4.068× 10-1 mm/year, indicating that the Naf/ZrO2 coating acted as a protective layer. Additionally, the ZrO2 layer provided poor electrical conductivity, resulting in slightly higher impedance compared to bare NiTi. The coating served as a barrier, which significantly enhanced corrosion resistance and improved the wire lifespan. Conclusion: Electro-modification through ZrO2 deposition and Nafion coating significantly improved the corrosion resistance and overall durability of NiTi orthodontic wires, offering a promising advancement for their use in dental orthodontics. This study underscores the potential of ZrO2 and Nafion coating to enhance the corrosion resistance and longevity of NiTi orthodontic wires.

Visceral pleura mechanics: Characterization of human, pig, and rat lung material properties

Pulmonary air leaks are amongst the most common complications in lung surgery. Lung sealants are applied to the organ surface and need to synchronously stretch with the visceral pleura, the layer of tissue which encompasses the lung parenchymal tissue. These adhesives are commonly tested on pig and rat lungs, but applied to human lungs. However, the unknown mechanics of human lung visceral pleura undermines the clinical translatability of such animal-tested sealants and the absence of how pig and rat lung visceral pleura compare to human tissues is necessary to address. Here we quantify the biaxial planar tensile mechanics of visceral pleura from healthy transplant-eligible and smoker human lungs for the first time, and further compare the material behaviors to pig and rat lung visceral pleura. Initial and final stiffness moduli, maximum stress, low-to-high strain transition, and stress relaxation are analyzed and compared between and within groups, further considering regional and directional dependencies. Visceral pleura tissue from all species behave isotropically, and pig and human visceral pleura exhibits regional heterogeneity (i.e. upper versus lower lobe differences). We find that pig visceral pleura exhibits similar initial stiffness moduli and regional trends compared to human visceral pleura, suggesting pig tissue may serve as a viable animal model candidate for lung sealant testing. The outcomes and mechanical characterization of these scarce tissues enables future development of biomimetic lung sealants for improved surgical applications. Statement of significanceSurgical lung sealants must synchronously deform with the underlying tissue and with each breath to minimize post-operative air leaks, which remain the most frequent complications of pulmonary intervention. These adhesives are often tested on pig and rat lungs, but applied to humans; however, the material properties of human lung visceral pleura were previously unexplored. Here, for the first time, the mechanics of human visceral pleura tissue are investigated, further contrasting rarely acquired donated lungs from healthy and smoking individuals, and additionally, comparing biaxial planar material characterizations to animal models often employed for pulmonary sealant development. This fundamental material characterization addresses key hindrances in the advancement of biomimetic sealants and evaluates the translatability of animal model experiments for clinical applications.

A circularly polarized graphene based wideband 1 × 2 array antenna for terahertz spectrum applications

A graphene-based 1 × 2 array antenna with circular polarization for terahertz applications is prescribed in this article. Initially, a novel concept of a folded quarter wave impedance transformer is utilized in the design process of a single element for minimizing the overall antenna size. The opposite corners of the patches have been truncated and structural modifications are performed with the insertion of four flower-shaped slots along with an additional circular slot for achieving a much-improved reflection coefficient and better impedance bandwidth. It also shows a much wider 3 dB axial ratio bandwidth, confirming circular polarization due to the suggested modifications in its geometry. Then, an array antenna has been formed to provide better gain. The configured patches are fed by a magic-T power divider to attain the required impedance matching. The results of the CP antenna array have been analyzed using the HFSS and CST simulators. The propounded 1 × 2 array antenna shows circular polarization with a 3 dB AR bandwidth of 205 GHz (2.345–2.55 THz) and wide spectral coverage of 210 GHz (2.345 − 2.555 THz) along with a maximum gain of 8.65 dB and 99.8 % radiation efficiency with a total size of 53.5 × 102 × 1.56 μm3. It could be utilized for high-speed data transmission, material characterization, terahertz spectroscopy, terahertz imaging, etc. applications.

Sulfuric Acid Leaching of Carbonatite ore with High Calcite Content in Lugiin Gol under Ambient Condition

AbstractCarbonatite bearing rare earth elements are rich sources of rare earth elements and play a critical role in the global supply chain. While carbonatite deposits are less accessible compared to ion adsorption clays, their mineral composition makes them essential for rare earth element extraction. Extraction of rare earth elements from carbonatite ore involves acid leaching, a process that we aim to explore in this study using the carbonatite ore from Lugiin gol. Characterization of the raw material and solid residue post‐leaching was conducted using X‐ray diffractometry, inductively coupled plasma optical emission spectroscopy, and a zeta potential analyzer. These analytical techniques were utilized for kinetic modeling, assessing the influencing factors of leaching, and determining metal recovery in the pregnant solution. The results of the study highlight the significant role of surface charge formation on target particles during milling in the acidic leaching process. This finding shed light on the importance of understanding the surface properties of the particles in the extraction of rare earth elements from carbonatite ores. The surface of particles in the supernatant of rare earth elements’ ore was negatively charged, with the median zeta potential of the 0.025 mm fraction being at its minimum of −60.6 mV.

Enhanced Antimicrobial Properties of Polymeric Denture Materials Modified with Zein-Coated Inorganic Nanoparticles.

Polymeric denture materials can be susceptible to colonization by oral microorganisms. Zein-coated magnesium oxide nanoparticles (zMgO NPs) demonstrate antimicrobial activity. The aim of this study was to investigate the antimicrobial effect and adherence of different oral microorganisms on hybrid polymeric denture materials incorporated with zMgO NPs. Five types of polymeric denture materials were used. A total of 480 disc-shaped specimens were divided by material type (n=96/grp), then subdivided by zMgO NPs concentration: control with no nanoparticles and other groups with zMgO NPs concentrations of 0.3%, 0.5% and 1% by weight. Characterization of the polymeric denture materials incorporating zMgO NPs was done, and the antimicrobial activity of all groups was tested against four types of microorganisms: 1) Streptococcus mutans, 2) Staphylococcus aureus, 3) Enterococcus faecalis and 4) Candida albicans. The samples underwent an adherence test and an agar diffusion test. Experiments were done in triplicates. The characterization of the hybrid samples revealed variation in the molecular composition, as well as a uniform distribution of the zMgO NPs in the polymeric denture materials. All hybrid polymeric denture materials groups induced a statistically significant antimicrobial activity, while the control groups showed the least antimicrobial activity. The agar diffusion test revealed no release of the zMgO NPs from the hybrid samples, indicating the NPs did not seep out of the matrix. The zMgO NPs were effective in reducing the adherence of the tested microorganisms and enhancing the antimicrobial activity of the polymeric denture materials. This antimicrobial effect with the polymeric dentures could aid in resisting microbial issues such as denture stomatitis.

Fabrication and characterization of a composite material from polymer matrix using citrus limetta fiber

Natural fibers, known for their excellent mechanical properties, non-abrasiveness, affordability, high specific strength, environmental friendliness, and biodegradability, are increasingly being considered as potential replacements for synthetic fibers like glass and carbon. This study investigates the use of Citrus limetta peel fibers to develop and characterize a polymer matrix composite. The fibers were extracted, purified, and coated with epoxy resin, then developed into composites using the hand layup method and cured in an oven. Mechanical tests, including hardness, impact, tensile strength, and compression strength, were conducted to assess the composites. The results showed that fiber reinforcement significantly enhanced mechanical stability, with compression strength and ultimate tensile strength reaching 231.39 MPa and 22.68 MPa, respectively. Microstructural analysis using scanning electron microscopy (SEM) and moisture absorption tests were also performed. Additionally, Ansys workbench software was utilized for further analysis. The study concludes that Citrus limetta peel fibers are a viable reinforcement material for polymer matrix composites, offering enhanced mechanical properties. This research is relevant for applications in industries seeking sustainable and high-performance composite materials.

Towards Simpler Modelling Expressions for the Mechanical Characterization of Soft Materials

Aims: The aim of this paper is to develop a new, simple equation for deep spherical indentations. Background: The Hertzian theory is the most widely applied mathematical tool when testing soft materials because it provides an elementary equation that can be used to fit force-indentation data and determine the mechanical properties of the sample (i.e., its Young’s modulus). However, the Hertz equation is only valid for parabolic or spherical indenters at low indentation depths. For large indentation depths, Sneddon’s extension of the Hertzian theory offers accurate force-indentation equations, while alternative approaches have also been developed. Despite ongoing mathematical efforts to derive new accurate equations for deep spherical indentations, the Hertz equation is still commonly used in most cases due to its simplicity in data processing. Objective: The main objective of this paper is to simplify the data processing for deep spherical indentations, primarily by providing an accurate equation that can be easily fitted to force-indentation data, similar to the Hertzian equation Methods: A simple power-law equation is derived by considering the equal work done by the indenter using the actual equation. Results: The mentioned power-law equation was tested on simulated force-indentation data created using both spherical and sphero-conical indenters. Furthermore, it was applied to experimental force-indentation data obtained from agarose gels, demonstrating remarkable accuracy. Conclusion: A new elementary power-law equation for accurately determining Young’s modulus in deep spherical indentation has been derived.

Mechanical heterogeneity characterization of coal materials based on nano-indentation experiments

Mechanical heterogeneity characterization of coal materials based on nano-indentation experiments

Effect of experimental parameters on X-ray Micro-CT imaging for Spectral CT applications

Computed tomography (CT) is recognized as a reliable method for structural characterization of different materials. Recently, Spectral CT methods have emerged as a tool to describe the sample composition through assessment of mass density (ρ) and effective atomic number (Zeff) assessment from CT results. These techniques depend on measuring the linear attenuation of a set of standards samples. However, besides ρ and Zeff, these results are influenced by factors such as X-ray energy and may be affected by experimental factors not accounted for in the foundational equation. Thus, in this study, we propose to quantify the effects of two factors: uniaxial compression and image pixel size on measurements of linear attenuation assessed through the registered mean gray value and its standard deviation. Initially, a group of metallic oxides pellets were compressed under different pressures and scanned at various magnification factors. Subsequently, based on factorial design theory, Yates’ method was applied to evaluate the significant effects of the factors. In a second phase, using a group of known samples, a Dual-Energy CT (DECT) measurement of a validation sample was conducted to verify the quantified effects. As expected initially, we observed that uniaxial compression positively influences attenuation, as it directly affects mass density. However, we found that an increase in image pixel size leads to a decrease in registered attenuation as it reduces the relationship between radiation attenuation and detected photons. Indeed, for the leveraged variation, the linear effect of pixel size variation proved to be the most influential on the registered mean gray value. When considering these effects in DECT application, no statistical difference was observed between loose powder and pellet measurements. Furthermore, no trend was observed in the results regarding image pixel size. However, it is possible that more significant changes in these factors may yield different results, and therefore, operators applying Spectral CT methods must ensure that the same experimental conditions are applied to both the standard sample set and the sample under investigation.

Terahertz Components by Additive Manufacturing: Material and Fabrication Characterizations Realized Through Bragg Structures

Terahertz Components by Additive Manufacturing: Material and Fabrication Characterizations Realized Through Bragg Structures

Assessment of photovoltaic efficacy in antimony-based cesium halide perovskite utilizing transition metal chalcogenide

Antimony-based perovskites have been recognized for their distinctive optoelectronic attributes, standard fabrication methodologies, reduced toxicity, and enhanced stability. The objective of this study is to systematically investigate and enhance the performance of all-inorganic solar cell architectures by integrating Cs3Sb2I9, a perovskite-analogous material, with WS2—a promising transition metal dichalcogenide—used as the electron transport layer (ETL), and Cu2O serving as the hole transport layer (HTL). This comprehensive assessment extends beyond the mere characterization of material attributes such as layer thickness, doping levels, and defect densities, to include a thorough investigation of interfacial defect effects within the structure. Optimal efficiency was observed when the Cs3Sb2I9 absorber layer thickness was maintained within the 600-700 nm range. The defect tolerance for the absorber layer was identified at 1×1015/cm3, with the ETL and HTL layers exhibiting significant defect tolerance at 1×1016/cm3 and 1×1017/cm3, respectively. Furthermore, this study calculated the minority carrier lifetime and diffusion length, establishing a strong correlation with defect density; a minority carrier lifetime of approximately 1 µs was noted for a defect density of1×1014/cm3 in the absorber layer. A noteworthy finding pertains to the balance between the high work function of the back contact and the incorporation of p-type back surface field layers, revealing that interposing a highly doped p+ layer between the Cu2O and the metal back contact can elevate the efficiency to 21.60%. This approach also provides the freedom to select metals with lower work functions, offering a cost-effective advantage for commercial-scale applications.

Preface

Dear Readers, I am pleased to announce the successful conclusion of the 2023 International Congress on Ultrasonics in Beijing (the 2023 ICU BEIJING), organized and hosted by the International Congress on Ultrasonics (ICU), the Institute of Acoustics in the Chinese Academy of Sciences (IACAS), and the Acoustical Society of China (ASC) in September 2023. The 2023 ICU Beijing aimed to bring together professionals and experts from academia and industry across all disciplines of ultrasonics, encompassing fundamental science and applications such as engineering material characterization and quality inspection, chemical and biological US-based monitoring, medical imaging, and therapy, among others. This congress offered more than 830 presentations covering various domains of ultrasonics and their applications. The program included 7 keynote presentations from world experts, 63 invited lectures, 547 oral contributions, and around 220 posters. For further information, please visit https://www.2021icu.org.cn/. As usual, there will be a proceeding of the 2023 ICU BEIJING after the congress. Through collaborations with the International Organization Committee and the Scientific Committee of the 2023 ICU Beijing, etc., we have selected 800 peer-reviewed abstracts that were presented at the congress. These presentations reflected the state-of-the-art scientific advancements and technological progress in ultrasonic scientific research and applications in recent years. Due to the impact of COVID-19, there is still much high-quality research work not included. After the completion of the congress, we selected 202 submitted papers by our peer reviewers and scientific committee which will be published in the Journal of Physics Conference Series (JPCS) as the proceeding of the 2023 ICU BEIJING. On behalf of the Organizing Committee, the Scientific Committee of the 2023 ICU BEIJING, and the ICU Board Members, I would like to extend my heartfelt appreciation to our Session Organizers, Plenary speakers, Session invited speakers, peer reviewers, IOP Publishers of the JPCS, as well as all those who have contributed to this proceeding. It is your participation and support that make the proceeding available. Yours sincerely, Xiuming Wang President of the 2023 ICU BEIJING Chair of the International Congress on Ultrasonics List of Scientific Committee Members of the Proceeding of 2023 ICU BEIJING are available in this Pdf.

Comparative Study of UPV and IE Results on Concrete Cores from Existing Structures

Dynamic non-destructive methods (NDT) are particularly attractive owing to their time and cost efficiency when compared to conventional uniaxial compressive strength tests. However, the results of these methods are highly scattered; therefore, they are primarily used for qualitative material characterization. One of the most important NDT results is the calculation of the dynamic Young’s modulus, which is associated to the uniaxial compressive strength (UCS) of concrete. The ultrasonic pulse velocity (UPV) is the most commonly used NDT. The limitation of this method is that it directly depends on knowledge of the Poisson’s ratio, and an assumption of its value must be made. This assumption results in highly scattered results. In contrast, the impact echo method (IE) can result in a dynamic Young’s modulus calculation without knowing the Poisson’s ratio. The limitation of this method is that it is dependent on the specimen’s slenderness, which in turn depends on the Poisson’s ratio. This study investigates the IE method’s applicability to short cylinders. A comparison of the UPV and IE methods is made, and the error in the dynamic Young’s modulus value derived by assuming Poisson’s ratio value in the UPV method is calculated. The authors conducted a numerical analysis and recently proposed the use of a shape correction factor (SCF) to apply the IE results for short cylinders, considering the influence of the slenderness (L/D) of the samples. For the first time worldwide, an extensive experimental study on 232 concrete samples with L/D ≈ 1.0 confirmed the wide spread of UPV test results and showed that it can lead to an error on Young’s Modulus determination by up to 50% owing to the adoption of an arbitrary Poisson’s ratio value. In contrast, using the SCF yields IE results with a ±2% error. A new methodology, ultrasonic pulse impact echo synergy (UPIES), is proposed by performing both UPV and IE tests on the specimens and using the SCF. The Poisson’s ratio and, consequently, the Young’s modulus can be accurately determined. Doi: 10.28991/CEJ-2024-010-09-03 Full Text: PDF

Photodegradation of Methylene Blue Dye Using BiVO₄/g-C₃N₄ Composites under Visible Light Irradiation

This study evaluates the degradation of methylene blue through photocatalysis using BiVO4/g-C3N4 material with the help of visible light. Material characterization was conducted using X-ray diffraction, scanning electron microscopy, and UV-Vis diffuse reflectance spectroscopy data. The characterization results show that the crystal structure of BiVO4/g-C3N4 is a heterojunction between monoclinic BiVO4 and hexagonal g-C3N4, with a crystal size of about 10.16 nm and a band gap energy value of about 2.16 eV. The morphology formed is a combination of sheet and rod-like. This study optimized the photocatalytic activity of the composite by analyzing the variation of g-C3N4 concentration, degradation time, and methylene blue pH. The results show that the BiVO4/g-C3N4 sample has optimal photocatalytic and adsorption properties in sample B (1:3) with pH 7 and a degradation time of 150 minutes. Under these conditions, the BiVO4/g-C3N4 composite successfully degraded methylene blue by 94.14%. The rate kinetics of the photocatalytic reaction followed first order, with *OH species playing the most role in the degradation mechanism. These findings highlight the potential of BiVO4/g-C3N4 as an effective photocatalyst material for organic pollutant degradation applications, offering a sustainable solution for wastewater treatment.

Investigation of the Effect of Temperature on the Biofuel Performance of Hydrochar Obtained from Kidney Bean Shell

In this study, hydrochar products were obtained from kidney bean shell (KBS) biomass at different temperatures using the hydrothermal carbonization (HTC) method. Hydrochar products were produced at three different temperatures (200, 220 and 240 C) and a holding time of 90 minutes. Biomass/water ratio was taken as 1:10. Analysis techniques such as Thermogravimetric analysis (TG), Ultimate analysis and Fourier Transform Infrared Spectroscopy (FTIR) were used in the characterization of raw materials and hydrochar products. In addition, the fuel properties (high heating value, energy yield and energy densification ratio) of raw KBS and hydrochar products were also investigated. As the HTC temperature increases, the high heating value of hydrochar products increases. Among hydrochar products, the highest high heating value belongs to the product obtained at 240 C. The combustion behavior of raw and hydrochar a product was examined using the thermogravimetric analysis method and combustion parameters (Ti, Tb and Tm) were determined. As a result, this study has shown that the hydrochar product produced from KBS by hydrothermal carbonization method can be used as a biofuel material.