AbstractMicroscopic scrutiny aids in alkali-activated materials’ (AAM) application in construction industry. This study delves into the pore structure and properties of one-part alkali-activated slag (AAS) mortar modified by carbon black (CB) and recycled carbon fiber (rCF). The additives enhanced flexural strength by 51.82% (12.16 MPa) with lower water absorption (10.24%). Refinement of pore size and reduction of connectivity are key factors in improving properties. The densification effect of CB and the strong interface between rCF and gel were observed. Furthermore, AAS mortars exhibited multifractal characteristics within the range of micropores and capillary pores. Despite altering fractal regions, the additives did not affect its size dependence. The backbone fractal dimension increases with the addition of CB and rCF, exhibiting strong correlations with various macro properties, thus serving as a comprehensive parameter to characterize pore shape and distribution. This study deepens understanding of AAM composites, facilitating their adoption of low-carbon building materials.