The Ti–Si–C coatings with metallic Cr addition were plasma-sprayed using the Ti–Si–C–Cr powder aggregates with different molar ratios. The influence of metallic Cr addition on the phase structure and mechanical properties of the coating were studied. The outcomes illustrate that Ti–Si–C–Cr coatings contained binary TiC and Ti5Si3, ternary Ti3SiC2 phase, metallic Cr, and small amounts of residual Si and graphite phases. The fracture toughness of the 3Ti–Si–2C-1.0Cr coating had an ~35% improvement compared to that of the 3Ti–Si–2C coating, while its micro-hardness only had ~4% decrease. The wear loss of 3Ti–Si–2C-0.2Cr coating was only ~39% of that observed for the 3Ti–Si–2C coating, indicating that the addition of metallic Cr improved the wear resistance. The coating worn surfaces primarily showed the characteristics of adhesive and abrasive wear.
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