Changes In Surface Microstructure Research Articles

Research Progress towards the Machining of Titanium Alloy Using CNC Milling: A Technical Review

Because of their extraordinary qualities, titanium alloys are very sought-after materials that can be applied to a wide range of sectors. Excellent mechanical and chemical qualities, including a high strength-to-weight ratio and resistance to corrosion, are present in it. The special properties of these alloys make machining them extremely difficult. As frequent tool wear occurs throughout the machining process, Computer Numerical Control (CNC) milling has become a potential method for machining titanium alloys due to its precision and versatility. This review article provides a comprehensive overview of the development of titanium alloy CNC milling, with an emphasis on the effects of cutting tool geometries and materials on machining efficiency. The process examines several aspects of cutting circumstances, including depth of cut, speed, feed rate, and lubrication techniques, and optimizes machining parameters and procedures to achieve the best results. Surface integrity and quality, surface roughness, residual stresses, and microstructural changes brought about by CNC milling are the main points of evaluation.

Investigation of wettability and icing on the steel surface using laser surface treatment

Icing impairs normal functionality for a variety of industries and applications. Research on hydrophobic surfaces is being conducted to solve the icing problem. In this study, a hydrophobic surface was fabricated on SM490A using a nanosecond laser. The change in surface microstructure was observed. Hydrophilicity was immediately observed right after laser irradiation, and the contact angle increased over time, resulting in hydrophobicity. To explain the wettability conversion, X-Ray Photoelectron Spectroscopy (XPS) was used to observe changes in surface chemical composition and element bonding. It was observed that the level of and increased immediately after laser irradiation, resulting in surface oxidation. Since the presence of oxides has high surface energies, they contribute to super hydrophilic surfaces. Since the bond has low surface energy and the content of nonpolar bonds and increased over time, the contact angle subsequently increases over time. When the ice shape was observed after dropping a droplet on the surface, the higher contact angle specimen reduced the attached area. Therefore, the surface treatment using a nanosecond laser can produce a hydrophobic surface on the SM490A specimens so that it may solve ice adhesion problems.

Comprehensive study on physicochemical properties of materials based on titanium suboxides

This study focuses on the surface structures and microstructural changes of titanium dioxide nanotubes, when electrochemically coated with platinum and/or palladium. Ti samples anodized in a fluorine-containing electrolyte exhibit self-organized nanotubes of varying diameters with open pores. Annealing at 773 K led to compaction of the porous layer, the formation of cracks, and the appearance of corrugation in the nanotubes. The deposition of platinum produced a transition from a nanotubular surface structure to a microcrystalline structure consisting of rutile crystallites. The palladium-coated samples showed fused blocks characteristic of titanium suboxides. The tubular structure was preserved, even after crystallization. SEM images revealed a comb-like pattern in coatings with varying metal content. XRPD analysis confirmed the presence of anatase and elemental titanium. PdO was detected on the surface of the thermally treated samples. For samples co-treated with Pd and Pt, mutual diffusion of the two metals took place during the heat treatment. The findings reveal surface characteristics, metal deposition effects, and phase composition of titania nanotubes, providing valuable insights for further research.

Study of the Characteristics of Ba0.6Sr0.4Ti1-xMnxO3-Film Resistance Random Access Memory Devices.

In this study, Ba0.6Sr0.4Ti1-xMnxO3 ceramics were fabricated by a novel ball milling technique followed by spin-coating to produce thin-film resistive memories. Measurements were made using field emission scanning electron microscopes, atomic force microscopes, X-ray diffractometers, and precision power meters to observe, analyze, and calculate surface microstructures, roughness, crystalline phases, half-height widths, and memory characteristics. Firstly, the effect of different sintering methods with different substitution ratios of Mn4+ for Ti4+ was studied. The surface microstructural changes of the films prepared by the one-time sintering method were compared with those of the solid-state reaction method, and the effects of substituting a small amount of Ti4+ with Mn4+ on the physical properties were analyzed. Finally, the optimal parameters obtained in the first part of the experiment were used for the fabrication of the thin-film resistive memory devices. The voltage and current characteristics, continuous operation times, conduction mechanisms, activation energies, and hopping distances of two types of thin-film resistive memory devices, BST and BSTM, were measured and studied under different compliance currents.

Thermostatic microwave-assisted pretreatment of corn stover at atmospheric pressure to enhance saccharification

A large amount of corn stover waste is produced from processing industries. In this study, the thermostatic microwave-assisted alkali pretreatment (TMAAP) of corn stover at atmospheric pressure was investigated to improve the utilization rate. The optimized conditions include pretreated time, NaOH concentration, temperature, initial power, and solid-liquid ratio. The pretreated corn stover samples for the enzymatic hydrolysis were studied on the crystallinity, surface microstructural changes, functional group changes and compositional analysis. The results showed cellulose recovery and lignin removal in the solid residue reached 87.39 % and 87.59 %, respectively when the corn stover was subjected for 45 min at a microwave reactor with an initial 600 W, 100 °C and 5 % NaOH. After TMAAP, the enzyme hydrolysis efficiency of the corn stove reached 85.40 %, which was higher than that of the untreated (59.96 %). The experiment can be carried out at atmospheric pressure without strict conditions. The techno-economic analysis predicts revenue of 22.82 USD by processing 100 kg of waste corn stover combined with enzyme cost analysis. To conclude, glucose (26.37 kg) and xylose (1.19 kg) were produced from corn stover (100 kg, 39.31 % glucan, 17.34 % xylan, 23.60 % lignin). The results can give insights into establishing an efficient alkali pretreatment of corn stove waste to produce glucose.

New Generation of Orthodontic Elastomeric Ligature to Prevent Enamel Demineralization In Vivo.

This study aimed to synthesize a novel elastomeric ligature with dimethylaminohexadecyl methacrylate (DMAHDM) grafted, providing a new strategy for improving the issue of enamel demineralization during fixed orthodontics. DMAHDM was incorporated into elastomeric ligatures at different mass fractions using ultraviolet photochemical grafting. The antibacterial properties were evaluated and the optimal DMAHDM amount was determined based on cytotoxicity assays. Moreover, tests were conducted to evaluate the in vivo changes in the mechanical properties of the elastomeric ligatures. To assess the actual in vivo effectiveness in preventing enamel demineralization, a rat demineralization model was established, with analyses focusing on changes in surface microstructure, elemental composition, and nanomechanical properties. Elastomeric ligatures with 2% DMAHDM showed excellent biocompatibility and the best antibacterial properties, reducing lactic acid production by 65.3% and biofilm bacteria by 50.0% within 24 h, without significant mechanical property differences from the control group (p > 0.05). Most importantly, they effectively prevented enamel demineralization in vivo, enhancing elastic modulus by 73.2% and hardness by 204.8%. Elastomeric ligatures incorporating DMAHDM have shown great potential for application in preventing enamel demineralization, providing a new strategy to solve this issue during fixed orthodontics.

Effect of Different Modification Techniques on Mechanical and Physical Properties of E-Max CAD Substrate

The world's best-selling glass-ceramic is IPS E.Max CAD. It is known for its versatile applications and is appropriate for the effective manufacturing of comprehensive dental restorations. This experimental study aimed to evaluate the morphological changes, surface roughness, and micro-hardness after modification techniques with KHF2 and NH4HF2 acid etching on e-max cad substrate. Materials and Methods: Forty disc shape of E.Max CAD specimens (thickness 3mm and diameter 10mm) were fabricated and divided into four groups according modification techniques (control group, sandblasting by 70µm of Al2O3, etching with 70 mg of KHF2 and etching with 70mg of NH4HF2),10 samples for each group. Surface roughness, micro-hardness, and microstructure changes of e-max CAD substrate have been measured. Results: The higher mean value for the surface roughness (Ra) was in the group (ECNH4HF2), followed by (ECKHF2) whereas the lowest mean value of surface roughness was in the group (ECC) followed by (ECSB). While for the micro-hardness test, the (ECKHF2) group demonstrated the highest mean value in comparison with other treated groups. Finally, SEM results for both untreated and sandblasted groups revealed there is a smooth and no deep morphological change for their surfaces. While the SEM analysis revealed that the e-max cad surfaces after KHF2 and NH4HF2 showed rough morphology with fine grains result and random porosities. Conclusions: Etching with KHF2 and NH4HF2 yielded higher microstructure changes and roughness than other techniques. While KHF2 etchant was more effective on E.Max CAD surface micro-hardness in comparison with other treated groups.

Surface Fluorination of Nuclear Graphite Exposed to Molten 2LiF-BeF2 (FLiBe) Salt and Its Cover Gas at 700 °C.

This study demonstrates that the reaction of Li2BeF4 (FLiBe) with graphite both in the liquid phase and the gas phase of the molten salt leads to the formation of covalent and semi-ionic carbon-fluorine bonds at the graphite surface and is accompanied by surface microstructural changes, removal of C-O groups, and deposition of metallic beryllium, based on XPS, Raman, and glow discharge mass spectroscopy characterization. At 700 °C, the observed surface density of C-F is higher after 240 h than after 12 h of exposure to molten FLiBe salt; the kinetics of covalent C-F formation is slower than that of semi-ionic C-F formation, and the relative amount of semi-ionic C-F content increases with depth. The graphite sample exposed to the cover gas exhibits less surface fluorination than the salt-exposed sample, with predominantly semi-ionic C-F. Based on these observations and the observed LiF/BeF2 ratio by surface XPS, the hypotheses that fluorination of the salt-exposed graphite occurs via a gas-phase mechanism or that it requires salt intrusion are refuted; future studies are warranted on the transport of C-F semi-ionic and covalent species in graphite at high temperatures.

Changes in mechanical properties and surface microstructure of shale organic matter after coupling supercritical carbon dioxide with water

Supercritical carbon dioxide (ScCO2) fracturing technology has been increasingly emphasized in the development of unconventional oil and gas resources due to its advantages of anhydrous fabrication of complex seam networks and geological sequestration of CO2. However, previous studies have mostly focused on the geometry, number, and type of inorganic mineral fractures, and rarely paid attention to the changes in the seepage structure within organic matter (OM). To characterize the nanoscale microstructural changes of OM induced by H2O-ScCO2, this study obtained the variation rule of mechanical properties of OM with adsorbed water saturation based on nanoindentation test, and the continuous change of elastic modulus and morphology of the OM in the same region after dry, water-wet, and water-ScCO2 treatments was compared by atomic force microscopy (AFM). Elastic modulus and hardness of OM were calculated by Oliver-Pharr and Hertz methods, and the average roughness, root mean square roughness, and kurtosis were obtained based on 3D morphology. The results showed that elastic modulus and hardness were negatively and nonlinearly correlated with water saturation. Although the AFM-measured elastic modulus of OM microphases of the dry, water-wet, and water-ScCO2-treated shale were all highly discrete and non-homogeneous, they were generally normally distributed, and the mean values of the elastic modulus decreased sequentially. It is determined that water-ScCO2 coupling make OM matrix undergo superimposed dissolution. It is shown that ScCO2 and water synergistically change the microstructure of shale OM, and the weakening of mechanical properties and the increase of surface roughness are very favorable for geological sequestration and long-term storage of CO2.

Leaching and cytotoxicity of bismuth oxide in ProRoot MTA - A laboratory investigation.

The present study examined the leaching and cytotoxicity of bismuth from ProRoot MTA and aimed to identify whether bismuth leaching was affected by the cement base and the immersion regime used. The leaching profile of bismuth was examined from ProRoot MTA and compared with hydroxyapatite containing 20% bismuth oxide as well as hydroxyapatite and tricalcium silicate to investigate whether bismuth release changed depending on the cement base. Bismuth leaching was determined after 30 and 180 days of ageing immersed in Dulbecco's modified Eagle's medium (DMEM) using mass spectroscopy (ICP-MS). The media were either unchanged or regularly replenished. The pH, surface microstructure and phase changes of aged materials were assessed. Wistar rat femoral bone marrow stromal cells (BMSCs) and cutaneous fibroblasts were isolated, cultured and seeded for cell counting (trypan blue live/dead) after exposure to non-aged, 30- and 180-days-aged samples in regularly replenished DMEM. Aged DMEM in contact with materials was also used to culture BMSCs to investigate the effect of material leachates on the cells. Gene expression analysis was also carried out after direct exposure of cells to non-aged materials. Differences between groups were statistically tested at a significance level of 5%. All materials exhibited alterations after immersion in DMEM and this increased with longer exposure times. The bismuth leached from ProRoot MTA as detected by ICP-MS. Aged ProRoot MTA samples exhibited a black discolouration and surface calcium carbonate deposition. ProRoot MTA influenced cell counts after direct exposure and its 180-days leachates reduced BMSC viability. After direct BMSC contact with non-aged ProRoot MTA an upregulation of metallothionein (MT1 and MT2A) expression and down-regulation of collagen-1a (Col-1a) and bone sialoprotein (BSP) expression was identified. Bismuth leaching was observed throughout 180-days observation period from all materials containing bismuth oxide. This negatively influenced cell viability and gene expression associated with bismuth exposure. This is the first study to report that metallothionein gene expression was influenced by exposure to ProRoot MTA.

Effect of Electrolytic Plasma Polishing on Surface Properties of Titanium Alloy

Electrolytic plasma polishing (EPPo) is an advanced metal surface finishing technology with high quality and environmental protection that has broad application prospects in the biomedical field. However, the effect of EPPo on surface properties such as corrosion resistance and the wettability of biomedical titanium alloys remains to be investigated. This paper investigated the changes in surface roughness, surface morphology, microstructure, and chemical composition of Ti6Al4V alloy by EPPo and their effects on surface corrosion resistance, wettability, and residual stress. The results showed that Ra decreased from 0.3899 to 0.0577 μm after EPPo. The surface crystallinity was improved, and the average grain size increased from 251 nm to more than 800 nm. The oxidation behavior of EPPo leads to an increase in surface oxygen content and the formation of TiO2 and Al2O3 oxide layers. EPPo can significantly improve the corrosion resistance and wettability of titanium alloy in simulated body fluid and eliminate the residual stress on the sample surface. The surface properties are enhanced not only by the reduction in surface roughness but also by the formation of a denser oxide film on the surface, changes in the microstructure, an increase in surface free energy, and the annealing effect developed during EPPo. This study can provide guidance and references for applying EPPo to biomedical titanium alloy parts.

Microwave humidity sensor based on shorted split ring resonator with interdigital capacitance and α-Al2O3 nanoflakes/chitosan sensitive film for respiration monitoring

A microwave relative humidity (RH) sensor based on shorted split ring resonator with interdigital capacitance (SSRR-IDC) as a test platform and α-Al2O3 nanoflakes/chitosan (CS) composite as sensitive film is proposed for the detection of human respiration. The SSRR-IDC was designed by optimizing the finger spacing and width of the IDC. Electromagnetic simulation of the designed SSRR-IDC confirms a strong electric field distribution and high dielectric sensitivity in the IDC region. The porous α-Al2O3 nanoflakes/CS composite was coated onto the IDC region of the SSRR to obtain a microwave humidity sensor. Abundant hydrophilic groups and large specific surface area of the α-Al2O3 nanoflakes/CS contribute to the adsorption of water molecules. The proposed microwave humidity sensor shows excellent sensitivity in wide RH range, especially at high humidity condition. The working principle and the sensitivity enhancement mechanism of the proposed microwave sensor were explained by combining a circuit model analysis and the dielectric property and surface microstructure changes of the sensitive materials. Furthermore, the microwave sensor also demonstrates short response/recover time and outstanding repeatability, long-term stability, temperature stability, and selectivity. Additionally, the prepared microwave humidity sensor successfully records respiratory data from different volunteers. Changes in respiratory depth before and after drinking water of the volunteers can also be distinguished by this sensor.

Thermo-mechanical aging of carbon-black reinforced styrene-butadiene rubber under cyclic-loading

PurposeThe research aims to investigate the impact of thermo-mechanical aging on SBR under cyclic-loading. By conducting experimental analyses and developing a 3D finite element analysis (FEA) model, it seeks to understand chemical and physical changes during aging processes. This research provides insights into nonlinear mechanical behavior, stress softening and microstructural alterations in SBR compounds, improving material performance and guiding future strategies.Design/methodology/approachThis study combines experimental analyses, including cyclic tensile loading, attenuated total reflection (ATR), spectroscopy and energy-dispersive X-ray spectroscopy (EDS) line scans, to investigate the effects of thermo-mechanical aging (TMA) on carbon-black (CB) reinforced styrene-butadiene rubber (SBR). It employs a 3D FEA model using the Abaqus/Implicit code to comprehend the nonlinear behavior and stress softening response, offering a holistic understanding of aging processes and mechanical behavior under cyclic-loading.FindingsThis study reveals significant insights into SBR behavior during thermo-mechanical aging. Findings include surface roughness variations, chemical alterations and microstructural changes. Notably, a partial recovery of stiffness was observed as a function of CB volume fraction. The developed 3D FEA model accurately depicts nonlinear behavior, stress softening and strain fields around CB particles in unstressed states, predicting hysteresis and energy dissipation in aged SBRs.Originality/valueThis research offers novel insights by comprehensively investigating the impact of thermo-mechanical aging on CB-reinforced-SBR. The fusion of experimental techniques with FEA simulations reveals time-dependent mechanical behavior and microstructural changes in SBR materials. The model serves as a valuable tool for predicting material responses under various conditions, advancing the design and engineering of SBR-based products across industries.

Surface topography and microstructure changes of ultrafine-grained graphite prepared from filler of onion-like carbon spheres by Xe ions irradiation

Onion-like carbon spheres (OLC) were doped into the traditional graphite raw material system to decrease the pore diameter to ∼400 nm, with potential for use in molten salt reactors. The obtained graphite (OLCG) prepared from OLC was subjected to 7 MeV Xe26+ irradiation in this work, and a systematic investigation was conducted to verify its irradiation behavior. The surface morphology and microstructural evolution in graphite samples under different irradiation conditions were studied with different characterization methods. The surface roughness of OLCG increased and the hill appeared at lower irradiation doses, which was similar to that of IG-110, but the filler particles of OLCG gradually become spherical at 2.5 dpa. The analysis by X-ray diffraction reveals that OLCG's graphitization degree is approaching but slightly worse compared to IG-110. Raman studies indicate that the irradiation causes an increase in defect density and in-plane disorder both in graphite. The OLC filler exhibits a greater sensitivity to radiation, leading to OLCG being slightly sensitive to radiation as compared to IG-110. Neutron irradiation of the resulting graphite should be continued as OLCG showed good irradiation resistance at low irradiation doses and had a much smaller pore diameter.

Improved corrosion and cavitation erosion resistance of laser-based powder bed fusion produced Ti-6Al-4V alloy by pulsed magnetic field treatment

The application of pulsed magnetic field (PMF) treatment demonstrated enhanced corrosion resistance in saline solution and prolonged resistance to cavitation erosion in deionised water for Ti-6AI-4V alloy manufactured by laser-based powder bed fusion (LPBF) and conventional wrought processing methods. The observed outcomes were attributed to the formation of a denser protective surface oxide layer and microstructural changes, resulting in a reduction of the α' phase by 0.13% and an increase in the presence of dislocations at the surface. Consequently, this led to an increase in the compressive residual stresses. Additionally, the application of this treatment resulted in the formation of highly refined and uniform precipitates, leading to a notable enhancement in microhardness by 5.73% and 5.85% for the conventionally manufactured (CM) and LPBF samples, respectively.

Influence of bond thermal and mechanical properties on the additively manufactured grinding wheels performance: Mechanical, wear, surface integrity, and topography analysis

It is always a great challenge to fabricate customized grinding wheels using diverse bonding materials to determine their impacts on the cutting ability and grinding performance. Additive Manufacturing methods offer tremendous advantages for customized and prototype production to reduce the cost as well as increase speed to market. This work aims to extend the grinding operation knowledge by examining acrylate base resin bonds with different mechanical and thermal characteristics to print the grinding wheels. Extensive experiments are conducted to investigate their performance in metal grinding, with hardness ranging from soft to super hard. A remarkable improvement in grinding performance has been established by using high-temperature resistance bond material, which was more prominent in the case of aluminium and hardened steel. It was discovered that utilizing the bond material with a higher mechanical and thermal characteristic could provide high grain retention under elevated temperatures, which participated in less grinding force (up to 58 % and 18 % in the case of soft and hard metals, respectively). Employing bond material with improved mechanical and thermal properties to fabricate grinding wheels significantly prolonged the tool life, for example, by up to 80 % for hardened steel at maximum, along with promoting dimensional accuracy. Nevertheless, however, using high-temperature resistance resin brought slight improvement in tool life for the hard metals grinding due to the intensely aggressive grinding condition, which could not be largely compensated by using modified resin. The surface roughness of the ground part represented considerable improvements through using high-temperature resistance resin by representing 33 % and 30 % roughness values reduction for Al and hard metal, respectively, compared to those ground with lower temperature resistance resin. Moreover, the ground surface's microhardness examination indicated meaningful surface microstructure change by applying different grinding parameters and bond material types. Furthermore, the microtopography of the grinding wheels before and after the grinding operation revealed that employing the higher temperature resistance resin could bring about notably less chip loading and grain loss.

Potential impact of surface microstructure change on reduction of emission current in tungsten filament

When a helium beam is extracted, a significant decrease in arc current is observed in the filament arc ion source of the Neutral Beam Injector. Microstructural changes in the tungsten filament surface of the ion source are observed by electron microscopy to investigate the cause of the reduction of arc current. Helium bubbles with 100–800nm diameters appear immediately beneath the surface within 1μm, and the bubbles develop into surface hole structures with surface erosion by sputtering. The decrease in arc current with helium beam extraction can be explained by a reduced effective surface area, due to the increase in hole porosity. It has been shown that the reduction of the arc current can be recovered by removing the helium-irradiation-affected layer by sputtering with argon discharge.

Dupilumab-Associated Blepharoconjunctivitis: Clinical and Morphological Aspects.

To describe the clinical and morphologic changes in the ocular surface microstructure of patients affected with moderate-to-severe Atopic Dermatitis (AD) before and during Dupilumab treatment. This is a monocentric observational study on thirty-three patients affected with AD before and during Dupilumab treatment. All patients underwent a slit-lamp examination: complete clinical assessment, Break Up Time test (BUT), Schirmer test, and corneal staining grading (Oxford scale) were performed. Meibomian Glands Dysfunction (MGD) evaluation (Meibography), Non-invasive Keratograph Break Up Time test (NIKBUT), Tear Meniscus Height (TMH), and ocular Redness Score (RS) have been investigated using an OCULUS Keratograph. In vivo images of the conjunctiva, cornea, and meibomian glands have been acquired by confocal microscopy. Sixty-six eyes were included in our study: twenty-two eyes of 11 naive patients with indication for treatment but not in therapy yet (Group 1) and forty-four eyes of 22 patients treated with Dupilumab for at least 4 months (subcutaneous administration of 300 mg every 2 weeks) (Group 2). Either patients treated with Dupilumab or naive patients with moderate-to-severe forms of AD had a tear film instability (TBUT and NIKBUT reduced), whereas the quantity of the tear film was overall normal (Schirmer test and TMH), without statistically significant differences between the two groups. When Meibography was performed with the Keratograph, the difference between Group 1 and Group 2 was statistically significant in terms of Meiboscore (p = 0.0043 and p = 0.0242, respectively), as well as the difference in terms of mean RS. These results paired well with the confocal microscopy results in which we found a decrease in the goblet cell population in the conjunctival epithelium in the treated group (5.2 cells/mm), along with inflammatory cells that were more concentrated around the adenoid lumina of the meibomian glands. In recent years, the use of Dupilumab has been increasing, but mild-to-severe conjunctivitis is a common side effect. Our major results demonstrate a loss of meibomian glands at the Keratograph examination: we can assume a reduced meibum secretion and an evaporative dry eye with MGD. We suggest that the inflammation of the ocular surface may involve not only the cornea and the conjunctiva, but also the meibomian glands, and Dupilumab may play a role. However, the frequency of clear conjunctivitis is not as common as reported in the literature.

Air-frying of meat analog based parfried frozen batter coated foods

Air-frying (AF) is a novel method of producing low-fat containing fried foods using hot-air. This study investigated the effects of AF parameters on mass-transfer, texture, surface microstructure and color changes during air frying of meat-analog based batter coated parfried frozen products, and mathematically modeled their kinetics. Wheat and rice flour-based batters were used to coat a meat-analog model. Coated products were partially-fried at 180 °C for 1 min in canola oil and subsequently frozen at −18 °C for 7 days. Frozen-products were fried for different time (0, 5, 10, 15, 20 min) by hot-air of different temperature (160, 170, 180, 190 °C). Mass-transfer, texture and color development during AF of parfried-frozen coated products were dependent on both AF parameter and batter-formulations. At varied temperature, moisture content of frozen-products declined with AF time. Non-linear regression analysis outcome (R2, sum square error) showed that Newton, Page, modified Page, and Henderson & Pabis model satisfactorily predicted moisture-loss of parfried-frozen products. Zero-order kinetic model satisfactorily characterized the changes in textural (hardness, brittleness, crispiness) and color (L, a*,b*, ΔE) traits. Rate-constant (min−1) of moisture, texture and color changes were positively correlated with AF temperature. Arrhenius model sufficiently characterized the temperature-dependency of rate constants. Higher moisture diffusivity (Deff, m2/min) and rate constant (k, min−1) of textural changes were estimated for rice-flour based batter coated products, whereas higher rate of total color change (ΔE) and activation energy (Ea, kJ/mol) were estimated for wheat-flour based batter coated products. Surface microstructure (openings, roughness) of air-fried products were impacted by batter-formulation and parameters of AF. Overall, batter formulations and AF parameters are the key to customize both macro and micro quality attributes of meat-analog based batter coated product.

Molecular dynamics study on wetting behavior of aluminum plates with different surface energies by microstructure difference

Wettability is the main factor that affects the self-cleaning and corrosion resistance of metal surfaces. The main factor that affects wettability is the change of surface microstructure and surface energy of metal material. When modifying metals, it is necessary to master their wetting behavior to obtain the required performance surface. In this paper, the wetting behavior of liquid droplets on smooth, square, papillary and nail-shaped surfaces with different surface energies was studied systematically by molecular dynamics simulation. The results show that the solid–liquid interaction factor is negatively correlated with the surface contact angle of aluminum plate. When the solid–liquid interaction factor is greater than the droplet potential energy parameter, the nail-shaped surface has the largest solid–liquid contact area and droplet centroid displacement rate due to its large roughness, and the surface hydrophilicity is the best; When the solid–liquid interaction factor is close to the droplet potential energy parameter, the nail-shaped surface has the smallest solid–liquid contact area and droplet centroid displacement rate due to its large roughness, and realizes the transition from neutral to hydrophobic; When the solid–liquid interaction factor is less than the droplet potential energy parameter, the papillary surface has the smallest solid–liquid contact area and droplet centroid displacement rate due to its small solid–liquid area fraction, thus realizing the transition from hydrophobicity to superhydrophobicity. The simulation results of this study are consistent with the classical theoretical calculation and experimental results, which reveals the interaction between metal surface wettability and surface energy and surface morphology.