Energy Change Research Articles

Machine learning-assisted design of transition metal-doped 2D WSn₂N₄ electrocatalysts for enhanced hydrogen evolution reaction

Hydrogen energy is characterized as environmentally friendly and resourceful. The hydrogen evolution reaction (HER) is a crucial process for hydrogen production and is essential for achieving a transition to sustainable and clean energy. In this work, we conducted a systematic investigation into the hydrogen catalytic activity of two-dimensional WSn2N4 materials. The transition metal atoms (Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn) were substituted at the N and Sn sites in WSn2N4, respectively. The catalyst's performance was evaluated to verify its catalytic activity for the HER. The results indicate that the Gibbs free energy changes (ΔGH∗) of Ti@W–WSn2N4, V@W–WSn2N4, Fe@W–WSn2N4, Co@W–WSn2N4, and Ni@W–WSn2N4 are close to zero. Among the structures examined, Ti@W–WSn2N4 exhibited the lowest Gibbs free energy change (ΔGH∗ = −0.01 eV), indicating a high degree of catalytic activity. Through machine learning analysis, key features affecting catalytic activity could be directly identified, and a framework for rapid screening was established. This study lays a solid foundation for the design and development of potential HER catalysts in the future.

Local Strain Effects on Lattice Defect Dynamics and Interstitial Dislocation Loop Formation in Irradiated Tungsten-Molybdenum Alloys: A Molecular Dynamics Study.

In this study, molecular dynamics (MD) simulations were used to investigate how alloying tungsten (W) with molybdenum (Mo) and local strain affect the primary defect formation and interstitial dislocation loops (IDLs) in W-Mo alloys. While the number of Frenkel pairs (FPs) in the W-Mo alloy is similar to pure W, it is half that of pure Mo. The W-20% Mo alloy, chosen for further analysis, showed minimal FP variance after collision cascades induced by primary knock-on atoms (PKAs) at 10 to 80 keV. The research examined hydrostatic strains from -1.4% to 1.6%, finding that higher strains correlated with increased FP counts and cluster formation, including IDLs. The following two types of IDLs were identified: majority ½ <111> loops as well as <100> IDLs that formed within the initial picoseconds of the simulations under higher tensile strain (1.6%) and larger PKA energies (80 keV). The strain effects also correlated with changes in threshold displacement energy (TDE), with higher FP formation under tensile strain. This study highlights the impact of strain and alloying on radiation damage, particularly in low-temperature, high-energy environments.

Experimental study of the energy and exergy performance of a solar parabolic dish concentrator integrated with thermal energy storage

Concentrating solar power is rapidly becoming a mainstay of solar energy systems, with the parabolic dish concentrator being a common and high-performing option for medium-temperature applications. This study investigates the thermal performance of a parabolic dish concentrator integrated with phase change material based thermal energy storage. Energy and exergy efficiencies are compared for a water-based storage tank in thermosyphon circulation mode, both with and without phase change materials encapsulation. Various phase change materials capsules were strategically positioned within the tank in a certain position, which satisfies the melting temperature of the studied phase change materials. Steam generation was also measured and correlated with solar irradiation intensity. This study aims to address the changes in energy and exergy efficiencies for the system integrated with latent heat storage encapsulation. Results show the highest overall energy efficiency 46.7% was achieved with copper cylindrical capsules, while the base case without phase change materials yielded the highest overall exergy efficiency 5.23%, closely followed by the copper cylindrical capsule 4.94%. Peak energy and exergy efficiencies reached 79.37% and 11.12%, respectively. The copper cylindrical capsules provided the optimal balance between thermal and storage performance without compromising efficiency.

Sparkling Synergy: Enhancing Hydrogen Evolution with a Mesoporous CoP/FeP Interface.

The reaction kinetics is predominantly determined by the surface and interface engineering of electrocatalysts. Herein, we demonstrate the growth of cobalt monophosphide and iron monophosphide (CoP/FeP) with an effective solid interface. The surface of CoP/FeP is mesoporous, which is obtained by phosphidizing mesoporous CoFe2O4. The CoP/FeP electrode exhibits substantially superior hydrogen evolution reaction (HER) performance compared to CoP and FeP. The overpotentials (η) required to generate 10 mA cm-2 are determined to be around 98 mVRHE (CoP/FeP), 220 mVRHE (FeP), and 265 mVRHE (CoP) in an acidic electrolyte. The exchange current density and Tafel slopes suggest that CoP/FeP has better redox properties and kinetic abilities compared to FeP and CoP. Furthermore, the CoP/FeP electrode exhibits reduced electrochemical impedance and superior surface charge transport characteristics in comparison to both the CoP and FeP electrodes. In addition to having a greater number of catalytically active sites, the turnover frequency of CoP/FeP is approximately 2 and 5 times higher than that of FeP and CoP, respectively. The CoP/FeP electrode maintains a consistent current density of around 25 mA cm-2 for a continuous period of 24 h during the HER, attesting to the excellent durability of the CoP/FeP electrode. In addition, a relationship between differential hydrogen adsorption energy (ΔEH), the corresponding Gibbs free energy change (ΔGH), and the hydrogen coverage on distinct surfaces, namely, CoP, FeP, and CoP/FeP, is established. The calculation findings show that the CoP/FeP surface, which is predominantly exposed with CoP, exhibits the highest catalytic potential for the HER. The estimation of the specific HER activity of the electrodes, normalized to the electrochemically active surface area, corroborates the calculation findings.

Ligand-Coupled Conformational Changes in a Cyclic Nucleotide-Gated Ion Channel Revealed by Time-Resolved Transition Metal Ion FRET.

Cyclic nucleotide-binding domain (CNBD) ion channels play crucial roles in cellular-signaling and excitability and are regulated by the direct binding of cyclic adenosine- or guanosine-monophosphate (cAMP, cGMP). However, the precise allosteric mechanism governing channel activation upon ligand binding, particularly the energetic changes within domains, remains poorly understood. The prokaryotic CNBD channel SthK offers a valuable model for investigating this allosteric mechanism. In this study, we investigated the conformational dynamics and energetics of the SthK C-terminal region using a combination of steady-state and time-resolved transition metal ion Förster resonance energy transfer (tmFRET) experiments. We engineered donor-acceptor pairs at specific sites within a SthK C-terminal fragment by incorporating a fluorescent noncanonical amino acid donor and metal ion acceptors. Measuring tmFRET with fluorescence lifetimes, we determined intramolecular distance distributions in the absence and presence of cAMP or cGMP. The probability distributions between conformational states without and with ligand were used to calculate the changes in free energy ( ) and differences in free energy change ( ) in the context of a simple four-state model. Our findings reveal that cAMP binding produces large structural changes, with a very favorable . In contrast to cAMP, cGMP behaved as a partial agonist and only weakly promoted the active state. Furthermore, we assessed the impact of protein oligomerization and ionic strength on the structure and energetics of the conformational states. This study demonstrates the effectiveness of time-resolved tmFRET in determining the conformational states and the ligand-dependent energetics of the SthK C-terminal region.

Drop Test Simulation of Packaging for Dangerous Goods: An Investigation of Appropriate Drop Height Adjustment in Case of Deviating Packaging Gross Mass

ABSTRACTIn the approval process of dangerous goods packagings, drop tests onto a flat, essentially unyielding surface are used to assess resistance against mechanical damage. International adopted regulations like ADR and RID define filling good dependent drop heights and filling degrees whilst the user needs to define the maximum gross mass to be tested and approved. Maximum packaging gross mass is defined conservatively and not reached in practice. To meet the defined gross mass in testing, using additives is permitted. However, in some cases, additives are not desirable due to packaging design or filling substance properties. This leads to deviations from the initial gross mass definition. Hence, a certain drop height adjustment is necessary to achieve the required impact loading. Laboratories frequently adjust drop height assuming a perfectly elastic collision that is inaccurate. Appropriate adjustment is not trivial due to energy conversion processes, for example, plastic deformation. In this work, a test stand is developed for measuring the change in kinetic energy of different packaging designs and filling substances in regulative drop tests. The experimental results are used to validate finite‐element (FE) models so that packaging properties can be varied in simulated drop test scenarios. The findings intend to describe the appropriate drop height adjustment of the respective packaging with same design but deviating gross mass to produce comparable mechanical response. The results are highly beneficial for testing laboratories, approval issuing authorities and packaging institutes confronted with the problem of testing packages with gross masses other than those to be approved.

Long-term casual analysis of the energy-food price relationship

The energy price index is a key economic measure that tracks changes in the prices of energy commodities, such as petroleum, electricity, and gas. This study aims to explore how the energy price index influences the food price index, as both have significant impacts on the economy. The relationship between energy and food prices is complex and affected by various factors. The novelty of this research lies in identifying the time period during which increases in energy prices impact food prices due to inflation. A statistical approach is applied to investigate this effect, using data from Pakistan's energy and food price indices for the period between January 2019 and May 2023. The Augmented Dickey-Fuller (ADF) test is employed to assess whether the time series is stationary, followed by the Granger causality test to determine if the energy price index can be used to predict changes in the food price index. The Engle-Granger cointegration test is used to identify long-term relationships between non-stationary time series. Additionally, various lag tests are conducted to determine the minimum time period within which changes in energy prices influence food prices. This research has practical implications for policymakers. Government agencies can use the findings to predict potential changes in food prices, and the study may also be relevant to the United Nations' Sustainable Development Goals (SDGs), as shifts in food prices could directly or indirectly affect several SDGs.

The Influence of Filler Particle Size on the Strength Properties and Mechanical Energy Dissipation Capacity of Biopoly(Ethylene Terephthalate) BioPET/Eggshell Biocomposites

This work aims to evaluate how the particle size of a waste filler in the form of eggshells changes the mechanical properties of biopoly(ethylene terephthalate) (bioPET). BioPET was modified with three different waste fractions: 1.60–3 mm—large particles; 1.60–1 mm—medium particles; 1 mm–200 μm—small particles. Waste filler was added to the biopolymer matrix in the amount of 10 wt.%. Static tensile tests, as well as bending and impact tests, were carried out to assess the strength properties of the waste-enriched materials. Dissipation energy changes and relaxation processes were observed and evaluated by means of a low-cycle dynamic test. Waste particles were shown to be an effective modifier of bioPET by increasing its stiffness (all particle sizes) and strength (the smallest ones). Studies of the wetting angle and mechanical energy dissipation in the first hysteresis loops indicate the better adhesion of small particles to the biopolymer and their greater ability to dissipate mechanical energy.

DNA and hemoglobin binding activities: Investigation of coumarin-thiosemicarbazone hybrids

Coumarin and coumarin-thiosemicarbazone hybrids were synthesized and characterized by various techniques such as FT-IR, 1H NMR, 13C NMR, MALDI-TOF-MS spectroscopy, and single crystal X-Ray diffractometer (XRD). The photochemical and photophysical properties of the compounds, such as solvatochromism, solubility, and chemical reactivity, were analyzed using UV–vis spectroscopy in different solvents. Due to the potential biological activities of the synthesized compounds, their binding affinity and mechanisms with calf thymus DNA (ct-DNA) and bovine hemoglobin (BHb) were determined using several useful spectrophotometric and theoretical approaches such as UV–vis absorption and fluorescence spectroscopy, molecular docking, and density functional theory (DFT). The experimental results showed that the compounds exhibited strong binding interactions with DNA and BHb. Additionally, the compounds demonstrated predominantly binding modes, such as intercalation and groove binding with DNA and π–π stacking interactions with BHb.To better understand the thermodynamics of these interactions, quenching constants, binding constants, and Gibbs free energy changes (ΔG°) were calculated. Molecular docking and DFT results supported the experimental data regarding the binding affinity and mechanisms of the compounds to DNA and BHb. Overall, this comprehensive study on coumarin and coumarin-thiosemicarbazone hybrids provides valuable insights into their interaction mechanisms with critical biomolecules, highlighting their potential in therapeutic applications as multifunctional agents.

Efficient As(V) removal by NiFe-LDHs and NiFe2O4 in situ growth on 3D porous carbon foam fabricated from waste melamine–formaldehyde foam

The utilization of waste melamine-formaldehyde foam to produce value-added carbon foam has been identified as a promising approach to polymer recycling. Nickel-Iron layered double hydroxides (NiFe-LDHs) and its complex oxides (NiFe2O4) were synthesized in this study through a hydrothermal method, growing in situ on the above-mentioned carbon foam substrate. Comparative analysis revealed that CF@NiFe2O4 exhibited superior removal efficiency compared to CF@NiFe-LDHs. Furthermore, arsenate adsorption on CF@NiFe-LDHs and CF@NiFe2O4 conformed more to the pseudo-second-order model; meanwhile, the isothermal adsorption characteristic fitted the Langmuir isothermal model better. The negative ΔG (free energy changes, <−37.68 kJ/mol) and positive ΔH (enthalpy change, 7.64 kJ/mol) indicate that it is spontaneous and endothermic for As(V) to adsorb on CF@NiFe2O4. Potential mechanisms such as surface complexation, electrostatic interaction, and hydrogen bonding were suggested. This innovative approach offers a novel method for utilizing LDHs-based adsorption materials and recycling waste polymers.

Design and Performance Analysis of a Hybrid Solar Photovoltaic System With Battery Energy Storage in a Government School of Indian Village

ABSTRACTIn India, energy security and electrification of rural area remains significant challenges. In addressing energy changes, solar photovoltaic (SPV) systems will play a major role, particularly in remote and rural areas. This research presents the design and performance assessment of a hybrid SPV plant integrated with battery energy storage system (BESS) at a government school within an Indian village. This hybrid SPV system is designed to utilize grid electricity when available, switch to solar power during the day when it is available, and use stored battery power at night time. The designed SPV system is of 1785 Wp, capacity coupled with a 560 Ah battery pack. The performance metrics, energy production, and storage efficiency, are analyzed using simulation data from PVsyst software. The results shows that system produces an annual energy of 2149.28 kWh/year and shows a performance ratio (PR) of 72.75% and a solar fraction (SF) of 98.31%. This proposed hybrid SPV system ensures continuous power supply, reduces dependency on the grid, and significantly lowers CO₂ emissions.

Screening Transition-Metal-Incorporated β-AgVO3 for Augmented Oxygen Reduction Activity.

Exploring cost-effective alternatives to Pt-based catalysts for the oxygen reduction reaction (ORR) in fuel cells is crucial for their large-scale deployment in green energy applications. Silver vanadate (AgVO3) is a well-studied material for photocatalytic applications. Here, we investigate the electrocatalytic ORR activity of the thermodynamically stable β phase of AgVO3 through computational modeling based on DFT. It is found that β-AgVO3 exhibits weak catalytic activity for the ORR, with vanadium being the preferable active site. Incorporating single atoms of transition metals at surface-level vacancies in β-AgVO3 significantly modifies the ORR activity. We study the scaling of free energy changes for the ORR intermediates *OOH, *OH, and *O for various transition metals incorporated, which leads to an optimal overpotential for the system. The optimal overpotential thus obtained is remarkably lower than that of pristine β-AgVO3. For the transition metal atoms we consider here, Co-incorporated β-AgVO3 exhibits the best ORR catalytic activity due to its optimal binding of ORR species to the vanadium site. It is also observed that some of the transition metals considered like Re, Rh, Os, or Mn show weak activity, either due to strong or weak binding. Analysis of the electronic structure of the adsorbate-catalyst interface shows a strong correlation between optimal activity and evolution of midgap states in β-AgVO3, due to transition metal incorporation. Our study concludes that the ORR activity of a stable mixed transition metal oxide like β-AgVO3 can be enhanced with a minimal loading of transition metals, which could help in developing a novel series of ORR catalysts.

Model for atomization droplet size and energy distribution ratio at the distal end of an electrostatic nozzle

Electrostatic atomization minimum quantity lubrication (EMQL) employs the synergistic effect of multiple physical fields to atomize minute quantities of lubricant. This innovative methodology is distinguished by its capacity to ameliorate the atomization attributes of the lubricant substantially, which subsequently augments the migratory and infiltration proficiency of the droplets within the complex and demanding milieu of the cutting zone. Compared with the traditional minimum quantity lubrication (MQL), the EMQL process is further complicated by the multiphysical field influences. The presence of multiple physical fields not only increases the complexity of the forces acting on the liquid film but also induces changes in the physical properties of the lubricant itself, thus making the analysis of atomization characteristics and energy distribution particularly challenging. To address this objective reality, the current study has conducted a meticulous measurement of the volume average diameter, size distribution span, and the percentage concentration of inhalable particles of the charged droplets at various intercept positions of the EMQL nozzle. A predictive model for the volume-averaged droplet size at the far end of the EMQL nozzle was established with the observed statistical value F of 825.2125, which indicates a high regression accuracy of the model. Furthermore, based on the changes in the potential energy of surface tension, the loss of kinetic energy of gas, and the electric field work at different nozzle orifice positions in the EMQL system, an energy distribution ratio model for EMQL was developed. The energy distribution ratio coefficients under operating conditions of 0.1 MPa air pressure and 0 to 40 kV voltage on the 20 mm cross-section ranged from 3.094‰ to 3.458‰, while all other operating conditions and cross-sections had energy distribution ratios below 2.06‰. This research is expected to act as a catalyst for the progression of EMQL by stimulating innovation in the sphere of precision manufacturing, providing theoretical foundations, and offering practical guidance for the further development of EMQL technology.

Sctudies on adsorption of Brilliant Green from aqueous solution onto nutraceutical industrial pepper seed spent

The study proposed the removal of Brilliant Green, a cationic dye, by adsorption process from wastewater solution utilizing a low-cost adsorbent such as Nutraceutical Industrial Pepper Seed Spent (NIPSS). The study comprises an investigation of the parametric influence on the adsorption process. The parameters identified are pH, dye concentration, process temperature, quantity of the adsorbent, and particle size. The study of statistics found from experiments was carried out by incorporating Freundlich, Brouers-Sotolongo, Langmuir, Toth, Sips, Jovanovic, and Redlich-Peterson isotherm models. The adsorption kinetics were determined by implementing pseudo-first-order and second-order models, diffusion film models, and Dumwald-Wagner and Weber-Morris models. The experimental adsorption capacity qe was found to be about 130 mg/g. This value was closest to the maximum adsorption of 144.6mg/g predicted by the Brouers-Sotolongo isotherm which had a correlation coefficient (R2) of 0.998. The adsorption kinetics data was confirmed to be a pseudo-second-order model. The change in free energy, enthalpy change, and entropy change were vital thermodynamic factors in concluding that adsorption is almost spontaneous and endothermic process. Change in enthalpy (ΔH°) reduced value indicates the physical nature of the process. The adsorption of BG dye on the adsorbent surface was authenticated by FTIR spectroscopy and SEM imaging. A Central Composite Design (CCD) Quadratic model under Response Surface Methodology (RSM) was implemented for statistical optimization of adsorption capacity for the five parameters studied, namely, time, temperature, concentration of the dye, weight of the adsorbent, and pH. Software Design Expert 7.0 was used to evaluate 3D contour plots. The process of optimization yielded a value of 350 mg/g. Thus, incrementing the adsorption process by 84.2 %. The study provides insights on various dye and adsorbent interaction possibilities and derives that NIPSS is an efficient adsorbent to extract BG dye from wastewater solutions.

Anisole-Water and Anisole-Ammonia Complexes in Ground and Excited (S1) States: A Multiconfigurational Symmetry-Adapted Perturbation Theory (SAPT) Study.

Binary complexes of anisole have long been considered paradigm systems for studying microsolvation in both the ground and electronically excited states. We report a symmetry-adapted perturbation theory (SAPT) analysis of intermolecular interactions in anisole-water and anisole-ammonia complexes within the framework of the multireference SAPT(CAS) method. Upon the S1 ← S0 electronic transition, the hydrogen bond in the anisole-water dimer is weakened, which SAPT(CAS) shows to be determined by changes in the electrostatic energy. As a result, the water complex becomes less stable in the relaxed S1 state despite decreased Pauli repulsion. Stronger binding of the anisole-ammonia complex following electronic excitation is more nuanced and results from counteracting shifts in the repulsive (exchange) and attractive (electrostatic, induction and dispersion) forces. In particular, we show that the formation of additional binding N-H···π contacts in the relaxed S1 geometry is possible due to reduced Pauli repulsion in the excited state. The SAPT(CAS) interaction energies have been validated against the coupled cluster (CC) results and experimentally determined shifts of the S1 ← S0 anisole band. While for the hydrogen-bonded anisole-water dimer SAPT(CAS) and CC shifts are in excellent agreement, for ammonia SAPT(CAS) is only qualitatively correct.

Controllable morphology of Pd nanostructures: from nanoparticles to nanofoams

Abstract Metallic nanofoams offer enhanced surface area and reduced density compared to their bulk counterparts while keeping intrinsic metallic properties. This combination makes nanofoams ideal for many applications, such as catalysis and battery. However, the synthesis of nanofoams is still challenging. This work introduces a non-complex synthesis method of Pd nanofoams employing a polar lipid structured as a sponge phase in water. The Pd nanostructures were characterized using Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), x-ray Diffraction (XRD), N2 adsorption–desorption isotherms, x-ray Photoelectron Spectroscopy (XPS), and x-ray Absorption Near Edge Structure (XANES) at Pd K edge techniques. The morphology of the nanostructure, from nanofoam to nanoparticle, is easily controlled by the presence of the polar lipid and the Pd salt used. The Pd nanostructures synthesized are fully oxidized, but the nanofoams reduce quickly (less than 5 min) to metallic Pd after H2 exposure at room temperature. The nanostructures were applied for hydrogen storage and Pd nanofoams achieved a remarkable gravimetric capacity of 0.76 wt% at room temperature and 1 atm H2 pressure. DFT calculation showed that the changes in the morphology of Pd lead to great changes in the adsorption energy of hydrogen, thus allowing the improvement of the material for hydrogen storage applications through the method developed.

Exploring waveforms with non-GR deviations for extreme mass-ratio inspirals

The fundamental process of detecting and examining the polarization modes of gravitational waves plays a pivotal role in enhancing our grasp on the precise mechanisms behind their generation. A thorough investigation is essential for delving deeper into the essence of gravitational waves and rigorously evaluating and validating the range of modified gravity theories. In this line of interest, a general description of black holes in theories beyond general relativity can serve a meaningful purpose where distinct deviation parameters can be mapped to solutions representing distinct theories. Employing a refined version of the deformed Kerr geometry, which is free from pathological behaviours such as unphysical divergences in the metric, we explore an extreme mass-ratio inspiral system, wherein a stellar-mass object perturbs a supermassive black hole. We compute the effects of deformation parameters on the rate of change of orbital energy and angular momentum, orbital evolution and phase dynamics with leading order post-Newtonian corrections. With the waveform analysis, we assess the plausibility of detecting deviations from general relativity through observations facilitated by the Laser Interferometer Space Antenna (LISA), simultaneously constraining the extent of these deviations. Therefore, this analysis provides an understanding while highlighting the essential role of observations in advancing gravitational phenomena beyond general relativity.

Optimization study of methylene blue dye adsorption on Chamaerops humilis fibers biosorption using a central composite design

This research explores the effectiveness of Chamaerops humilis (CH) fibers as a biosorbent for the adsorption of Methylene Blue (MB) dye from aqueous solutions. The fibers were characterized using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR). To optimize the dye removal process, a Design of Experiments methodology, specifically Central Composite Design (CCD), was applied. Factors such as solution pH, adsorbent dosage, contact time, and temperature were varied. The CCD analysis identified the optimal conditions for maximum removal efficiency (99.87 %) of a 10 mg/L MB solution, which were: 1.06 g/L of CH fiber dosage, pH 9.6, and a contact time of 60 min. The adsorption process aligned well with a pseudo-second-order kinetic model, and the maximum adsorption capacity of CH fibers was determined to be 9.422 mg/g. Thermodynamic parameters, including Gibbs free energy (ΔG°), enthalpy (ΔH°), and entropy (ΔS°) changes, were calculated, confirming that the adsorption is spontaneous and endothermic. The study highlights the potential of Chamaerops humilis fibers as an efficient and eco-friendly adsorbent for MB dye removal, offering a sustainable and cost-effective solution for wastewater treatment, particularly in industrial effluent management.

High-resolution Imaging Spectroscopy of a Tiny Sigmoidal Minifilament Eruption

Minifilament eruptions producing small jets and microflares have mostly been studied based on coronal observations at extreme-ultraviolet and X-ray wavelengths. This study presents chromospheric plasma diagnostics of a quiet-Sun minifilament of size ∼ 2″ × 5″ with a sigmoidal shape and an associated microflare observed on 2021 August 7 17:00 UT using high temporal and spatial resolution spectroscopy from the Fast Imaging Solar Spectrograph (FISS) and high-resolution magnetograms from the Near InfraRed Imaging Spectropolarimeter (NIRIS) installed on the 1.6 m Goode Solar Telescope at Big Bear Solar Observatory. Using FISS Hα and Ca ii 8542 Å line spectra at the time of the minifilament activation we determined a temperature of 8600 K and a nonthermal speed of 7.9 km s−1. During the eruption, the minifilament was no longer visible in the Ca ii 8542 Å line, and only the Hα line spectra were used to find the temperature of the minifilament, which reached 1.2 × 104 K and decreased afterward. We estimated thermal energy of 3.6 × 1024 erg from the maximum temperature and kinetic energy of 2.6 × 1024 erg from the rising speed (18 km s−1) of the minifilament. From the NIRIS magnetograms we found small-scale flux emergence and cancellation coincident with the minifilament eruption, and the magnetic energy change across the conjugate footpoints reaches 7.2 × 1025 erg. Such spectroscopic diagnostics of the chromospheric minifilament complement earlier studies of minifilament eruptions made using coronal images.

The Influence of Elite Race Walkers’ Year-Long Training on Changes in Total Energy and Energy Cost While Walking at Different Speeds

The aim of the study was to assess the influence of year-long training of race walkers on physiological cost and total energy center of mass (CoM). The assessment performed was based on indicating the differences between the resulting energy cost in a group of elite race walkers walking at technical, threshold, and racing speeds calculated by physiological and biomechanical methods before beginning and after finishing a year-long training cycle. The study involved 12 competitive race walkers who had achieved champion or international champion level. Their aerobic endurance was determined by means of a direct method, applying an incremental exercise test on the treadmill. The gait of the participants was recorded using the 3D Vicon analysis system. Changes in mechanical energy amounted to the value of the total external work of the muscles needed to accelerate and lift the center of mass during a normalized gait cycle. The highest influence on the total external work increase for increasing speeds of gait in both examinations was attributed to the changes in the kinetic energy resulting from the center of mass movement. A statistically significant decrease of the mean value of total external work for racing speed was observed in the second examination (p &lt; 0.001). An approx. 8% decrease (NS) of EE energy cost, standardized by body mass and distance covered, was found between the first and second examinations. The energy cost and total external work were significantly differentiated by the walkers’ gait speeds (p &lt; 0.05–0.001). The energy cost significantly differed from the total external work at p &lt; 0.001.