Changes In Reflectance Research Articles

Pulmonary artery wave reflection and right ventricular function after lung resection

BackgroundLung resection has been shown to impair right ventricular function. Although conventional measures of afterload do not change, surgical ligation of a pulmonary artery branch, as occurs during lobectomy, can create a unilateral proximal reflection site, increasing wave reflection (pulsatile component of afterload) and diverting blood flow through the contralateral pulmonary artery. We present a cardiovascular magnetic resonance imaging (MRI) observational cohort study of changes in wave reflection and right ventricular function after lung resection. MethodsTwenty-seven patients scheduled for open lobectomy for suspected lung cancer underwent cardiovascular MRI preoperatively, on postoperative Day 2, and at 2 months. Wave reflection was assessed in the left and right pulmonary arteries (operative and non-operative, as appropriate) by wave intensity analysis and calculation of wave reflection index. Pulmonary artery blood flow distribution was calculated as percentage of total blood flow travelling in the non-operative pulmonary artery. Right ventricular function was assessed by ejection fraction and strain analysis. ResultsOperative pulmonary artery wave reflection increased from 4.3 (2.1–8.8) % preoperatively to 9.5 (4.9–14.9) % on postoperative Day 2 and 8.0 (2.3–11.7) % at 2 months (P<0.001) with an associated redistribution of blood flow towards the nonoperative pulmonary artery (r>0.523; P<0.010). On postoperative Day 2, impaired right ventricular ejection fraction was associated with increased operative pulmonary artery wave reflection (r=–0.480; P=0.028) and pulmonary artery blood flow redistribution (r=–0.545; P=0.011). At 2 months, impaired right ventricular ejection fraction and right ventricular strain were associated with pulmonary artery blood flow redistribution (r=–0.634, P=0.002; r=0.540, P=0.017). ConclusionsPulsatile afterload increased after lung resection. The unilateral increase in operative pulmonary artery wave reflection resulted in redistribution of blood flow through the nonoperative pulmonary artery and was associated with right ventricular dysfunction. Clinical trial registrationNCT01892800.

Temporal Variation in Surface Bidirectional Reflectance of the Railroad Valley Vicarious Calibration Test Site in Nevada

Spectral reflectance-based vicarious calibration (VicCal) requires accurate characterization of the bidirectional reflectance distribution function (BRDF) of the ground-based target. Railroad Valley (RRV) Playa, Nevada, has been used as a VicCal test site since 1995 as it is large, appears stable over time, and has a reasonably consistent surface. This study presents the results of a diurnal measurement cycle that closely replicated illumination geometries for Earth Observing (EO) satellites over a year. By measuring the rate of change of the BRDF with respect to time, we recorded the range of BRDF effects while holding the surface constant with respect to moisture and surface condition variation. The rate of spectral reflectance change increased rapidly with view angle in the backscatter direction, reaching rates of change that are 2.3 and 10.5 times greater in the backscatter than in the forward scatter direction for view angles of 20° and 40°, respectively. The results show that larger off-nadir viewing angles in the backscatter direction are particularly sensitive to changes in solar/view geometries.

Determination of electron and phonon temperatures in gold thin film irradiated with an ultrashort laser pulse

We measured transient reflectivity of single-crystalline and polycrystalline gold thin films in the wavelength region of 450–700 nm pumped by a 400 nm femtosecond pulse. The observed reflectivity changes were reproduced well by a reflectivity model that we developed based on the joint-density-of-states calculated from the band structure of gold and the Drude model. By a combination use of the reflectivity model and the two-temperature model, we evaluated the temporal evolution of the electron and phonon temperatures from the observed reflectivity changes. Based on the resultant electron and phonon temperatures, we derived the electron–phonon coupling factors, which were consistent with the literature values, in the wide range of the absorbed energy density.

Fast and slow light-induced changes in murine outer retina optical coherence tomography: complementary high spatial resolution functional biomarkers.

Fast (seconds) and slow (minutes to hours) optical coherence tomography (OCT) responses to light stimulation have been developed to probe outer retinal function with higher spatial resolution than the classical full-field electroretinogram (ERG). However, the relationships between functional information revealed by OCT and ERG are largely unexplored. In this study, we directly compared the fast and slow OCT responses with the ERG. Fast responses [i.e. the optoretinogram (ORG)] are dominated by reflectance changes in the outer segment (OS) and the inner segment ellipsoid zone (ISez). The ORG OS response has faster kinetics and a higher light sensitivity than the ISez response, and both differ significantly with ERG parameters. Sildenafil-inhibition of phototransduction reduced the ORG light sensitivity, suggesting a complete phototransduction pathway is needed for ORG responses. Slower OCT responses were dominated by light-induced changes in the external limiting membrane to retinal pigment epithelium (ELM-RPE) thickness and photoreceptor-tip hyporeflective band (HB) magnitudes, with the biggest changes occurring after prolonged light stimulation. Mice with high (129S6/ev) vs. low (C57BL/6J) ATP(adenosine triphosphate) synthesis efficiency show similar fast ORG, but dissimilar slow OCT responses. We propose that the ORG reflects passive physiology, such as water movement from photoreceptors, in response to the photocurrent response (measurable by ERG), whereas the slow OCT responses measure mitochondria-driven physiology in the outer retina, such as dark-provoked water removal from the subretinal space.

Investigating temporal changes in Jupiter’s aerosol structure with rotationally-averaged 2015–2020 HST WFC3 images

Annual imaging observations of Jupiter from 2015 onward by the Hubble Space Telescope (HST) Wide Field Camera 3 (WFC3) as part of the Outer Planet Atmospheres Legacy (OPAL) program (Simon et al., 2015) have provided a valuable data set from which Jupiter’s temporal variability can be characterized and modeled. Spectral samples at discrete filter bands from the UV to short near-IR wavelengths also provide an opportunity to connect temporal changes in reflectivity with temporal changes in cloud structure. To improve constraints on that cloud structure we used center-to-limb variations that were noise-reduced by rotational averaging during each annual OPAL observation sequence. Fitting observations at multiple and distinctly different observer zenith angles helps to make up for the lack of multiple methane-band filters in discerning the vertical distribution of aerosols. The short-wavelength limit of the OPAL observations also provides better constraints than ground-based observation on the properties of Jupiter’s chromophore, i.e., the compound that creates Jupiter’s variety of red colorations to clouds and hazes composed mainly of colorless condensates. We chose four latitudes to investigate with radiative transfer models based on a simple 3-layer aerosol structure consisting of a deep putative NH3 cloud layer, with a physically thin chromophore layer that has a fitted location at or near the top of the deep cloud, and an overlying stratospheric haze layer. Our chosen planetocentric latitudes were 5.5°S (Equatorial Zone South,EZS), 0° (Equatorial Zone, EZ), 10°N (North Equatorial Belt, NEB), and 21.75°N (North Temperate Belt, NTB). Two major color transformations occurred during the 2015–2020 period we analyzed. One is a dramatic dimming of the center of the Equatorial Zone at short wavelengths, especially after 2017, and a significant reddening of that region. The second is a significant reddening of part of the North Temperate Belt (near 22°N) between 2016 and 2017. Both reddening events can be modeled by doubling of the optical depth of the chromophore layer during the transitions. Comparison with prior 2017 model results for the NEB, EZ, and NTB have revealed agreement with Braude et al. (2020) on the vertical location of the chromophore layer but disagreements on cloud-top pressures and the vertical distribution of stratospheric haze particles. We identified what seems to be common tendency of models based on HST/WFC3 observations to either infer very little stratospheric haze opacity or to put that opacity at too high a pressure.

Present Day Endogenic and Exogenic Activity on Mercury

AbstractExogenic and endogenic activities dictate how planetary surfaces evolve. However, the present‐day influence of each of these activities is not well constrained. MESSENGER (MErcury Surface, Space ENvironment, GEochemistry, and Ranging) temporal imaging recorded surface changes associated with these activities between 2011 and 2015. Here we present the results of a temporal investigation that identified 20 reflectance changes. One change exhibited bright rays extending from the site, consistent with the aftermath of an impact event. If all changes result from impact events, the present flux rate is 1,000 times higher than models predict. Consequently, we also report changes on slopes in areas with concentrations of tectonic landforms and identify a subset of changes that are on or adjacent to hollows, consistent with present‐day endogenic activities. Therefore, we conclude that these observations captured endogenic and exogenic modifications to the surface.

Direct observation of ultrafast carrier coupling dynamics in monolayer graphene/metal system

• Femtosecond laser pump-probe technique measures the reflectivity changes of graphene/copper system. • A model assuming phonon-phonon coupling at graphene/copper interface is built and validated by the experiment. • Establish a new research paradigm to directly study the carrier coupling dynamics between 2D materials and substrates. For promising graphene-based devices, graphene/metal contacts are inevitable. When they operate at high frequencies, it is essential to explore the ultrafast carrier dynamics between graphene and metal, which has been rarely studied. Owing to the special monolayer graphene/copper structure we designed, that is, the graphene is grown on copper, we have directly observed the ultrafast carrier dynamics between monolayer graphene and copper by using femtosecond laser pump-probe technique for the first time. The measured optical reflectivity changes of graphene/copper system are significantly different from that of bare copper, which is attributed to the ultrafast carrier dynamics between graphene and copper, and graphene optical properties. A model considering carriers coupling in graphene and copper, including electron and phonon, has been built and validated by the experiment. Present study provides direct observation of the ultrafast carrier dynamics between graphene and metal, which is of great significance for graphene-based device applications.

Stabilization of the Orbital Motion of a Solar Sail in the Vicinity of a Collinear Libration Point through a Change in Reflectivity

Stabilization of the Orbital Motion of a Solar Sail in the Vicinity of a Collinear Libration Point through a Change in Reflectivity

Within-eye and between-subject variability for reflectance of the retinal nerve fibre layer.

Reflectance of retinal nerve fibre layer (RNFL) can contribute to detecting the presence of glaucomatous damage and defining its extent. As a step towards developing a normative database for RNFL reflectance, we assessed within-eye and between-subject variability for RNFL reflectance in healthy eyes. Vertical 30° × 15° volume scans at the optic disc were gathered using SD-OCT (Spectralis OCT) from people free of eye disease. Scans were gathered for both eyes of 30 younger adults (mean ± SD=27 ± 3 years) and for one eye of 30 older adults (68 ± 8 years). Reflectance was quantified for each voxel as the depth-resolved attenuation coefficient (AC). Values for AC were extracted for four slabs (0-52, 24-52, 24-36 and 36-60 μm) and at depths from 24 to 60 μm below the inner limiting membrane (ILM) in 4μm steps. Between-subject and within-eye standard deviations (SDs) for the logarithm of AC were similar; median differences were 0.02-0.03 log unit across all four slabs and depths from 24 to 48 μm. Means for the logarithm of AC were higher for younger than older eyes by ~0.1 log unit; this age effect was not due to differences in the raw reflectance of the RNFL, but rather to age-related changes in reflectance of deeper retina affecting the calculation of AC. In both groups, within-eye variability in RNFL reflectance near the optic disc was similar to between-subject variability. A better understanding of within-eye variability would be useful for developing normative databases.

Timing and Emotions in Learning Practice Adoption

Reflecting on past performance is perceived as the core activity enhancing organizational learning because it helps organization members improve their cognitive understandings. Yet, reflection could also trigger emotional reactions that may influence organization members’ subsequent actions. In this paper, we integrate such emotional mechanisms into current theories of organizational learning, building on a five-year qualitative study of a management consulting firm. Our model shows how reflection influences organization members’ appraisals that generate emotions. Reflection changes organization members’ thinking about their skills and actions, which triggers emotional reactions that may either support or inhibit subsequent actions. The timing of reflection, in particular, influences their appraisals of controllability. When reflection is performed after a project, appraisals of low controllability lead to low-arousal emotions that inhibit future action and undermine future learning. In contrast, reflection performed during or before a project generates appraisals of high controllability that lead to high-arousal emotions and benefit future actions and learning. Hence, the timing of reflection substantially shapes the emotional effects of reflection and influences whether reflection benefits organizational learning.

Concurrent herbivory and metal accumulation: The outcome for plants and herbivores.

The effects of metals on plants and herbivores, as well as the interaction among the latter, are well documented. However, the effects of simultaneous herbivory and metal accumulation remain poorly studied. Here, we shed light on this topic by infesting cadmium-accumulating tomato plants (Solanum lycopersicum), either exposed to cadmium or not, with herbivorous spider mites, Tetranychus urticae or T. evansi during 14 days. Whereas on plants without cadmium T. evansi had higher growth rate than T. urticae, on plants with cadmium both mite species had similar growth rates, which were lower than on plants without metal. Plants were affected by both cadmium toxicity and by herbivory, as shown by leaf reflectance, but not on the same wavelengths. Moreover, changes in leaf reflectance on the wavelength affected by herbivores were similar on plants with and without cadmium, and vice versa. Long-term effects of cadmium and herbivory did not affect H2O2 concentrations in the plant. Finally, plants infested with spider mites did not accumulate more cadmium, suggesting that metal accumulation is not induced by herbivory. We thus conclude that cadmium accumulation affects two congeneric herbivore species differently and that the effects of herbivory and cadmium toxicity on plants may be disentangled, via leaf reflectance, even during simultaneous exposure.

Elastic interactions in physics are reflections in geometry

A simple standard problem in physics is the study of elastic collisions between elements of an ideal system, which consists of two point masses and a wall. Based on energy and momentum conservation laws, solving the problem consists in finding the intersection of a straight line with a conic. Relationships between the solutions are easily obtained if we consider the right (fundamental) basis to express the solutions. The geometric interpretation follows easily: moving from one point to another on a conic using directions given by this basis. With simple changes in variables, reflections and rotations appear clearly. Similarities with other phenomena such as Heron’s reflection principle in optics and Kepler’s second law of planetary motion are pointed out.

Universal quadratic soil spectral reflectance line and its deviation patterns' relationships with chemical and textural properties: A global data base analysis

Quantitative evidence for the fundamental spectral shape similarity existing between different soils is presented utilizing Pearson's correlation and SAM (Spectral Angle Mapper) analysis in-between signatures representing thousands of soil samples collected from different environments around the world. A universal quadratic soil line (UQSL) was found to highly fit these representative signatures as well as spectra from the ISRIC (International Soil Reference and Information Center) global database including soil samples collected from 58 countries. K-means clustering of ISRIC spectral reflectance deviations from the UQSL facilitated identification of 5 characteristic deviation patterns. Significant correlation was found for a set of 1000 soil samples between changes in multiple chemical properties and corresponding reflectance changes between these clusters. Future availability of large global soil data bases may allow improved determination of the UQSL and generalization of its deviation patterns relationships with PBC (Physical, Biological and Chemical) properties for wide areas monitoring of soil conditions.

Second-Order Photoinduced Reflectivity for Retrieval of the Dynamics in Plasmonic Nanostructures.

Measuring the change in reflectivity (ΔR) using the traditional pump–probe approach can monitor photoinduced ultrafast dynamics in matter, yet relating these dynamic to physical processes for complex systems is not unique. By applying a simple modification to the classical pump–probe technique, we simultaneously measure both the first and second order of ΔR. These additional data impose new constraints on the interpretation of the underlying ultrafast dynamics. In the first application of the approach, we probe the dynamics induced by a pump laser on the local-surface plasmon resonance (LSPR) in gold nanoantennas. Measurements of ΔR over several picoseconds and a wide range of probe wavelengths around the LSPR peak are followed by data fitting using the two-temperature model. The constraints, imposed by the second-order data, lead us to modify the model and force us to include the contribution of nonthermalized electrons in the early stages of the dynamics.

Study on the damage of Zr63.5Cu23Al9Fe4.5 amorphous and crystalline alloys irradiated by high intensity pulsed ion beam

Zr63.5Cu23Al9Fe4.5 amorphous and crystalline alloys were irradiated by high intensity pulsed ion beam to investigate the effects of transient high thermal load irradiation on their microstructure, surface reflectivity and nano-hardness. When the high temperature caused by transient thermal shock did not reach the melting temperature of the alloys, there was no obvious change in the phase-structure of amorphous and crystalline alloys, and irradiation had little impact on surface reflectivity and nano-hardness. When the temperature exceeding the melting temperature, amorphous alloys still maintained amorphous strtucture, and more free volumes generated by remelting and rapid solidification process, resulting in the reduction of nano-hardness; while micrometer-sized amorphization appeared in the crystalline counterpart, which also reduced the nano-hardness. Compared with molybdenum, a candidate material of the first mirror, there was no crack on the surface and less change of surface reflectivity in amorphous and crystalline alloys.

Examining the Impact of Sample Thickness Variations on the Hyperspectral Radiometric Responses of Flowing Blood.

The hyperspectral reflectance and transmittance of flowing blood samples are employed in a wide range of biomedical applied research initiatives such as the detection and monitoring of hematological abnormalities. The success of these initiatives is tied to the correct interpretation of these radiometric quantities. This, in turn, requires a comprehensive understanding about their sensitivity to variations in the experimental conditions in which they have been obtained. In this paper, we aim to contribute to these efforts by systematically examining the effects of sample thickness variations on these quantities. More specifically, we employed controlled in silico experiments to assess these effects on samples with different biophysical characteristics, notably their hematocrit, hemolysis level and orientation of their constituent cells with respect to the flow direction. To ensure a high degree of fidelity in our experiments, we used a first-principles simulation framework supported by measured data. Our findings unveil distinct spectrally-dependent trends associated with reflectance and transmittance changes elicited by sample thickness variations.

Seismic monitoring of CO2 geosequestration using multi-well 4D DAS VSP: Stage 3 of the CO2CRC Otway project

An important part of any CO2 geosequestration project is to ensure CO2 containment and conformance in the subsurface. This is generally done by implementing a comprehensive, risk-based Measurement, Monitoring and Verification plan, a key element of which is active time-lapse seismic monitoring. However, high cost and environmental impact of the standard surface seismic monitoring dictate the need for a cost-effective and environmentally friendly alternative. An opportunity to develop such method emerges with advances in distributed acoustic sensing (DAS) technology, which turns an optical fibre into a seismic sensor with dense spatial sampling. DAS can be permanently deployed in multiple wells across the geosequestration site providing a robust and non-intrusive network of seismic receivers. This approach was developed and tested in the CO2CRC Otway project, where injection of 15 kt of CO2 at 1.5 km depth was monitored with a 4D vertical seismic profiling (VSP) using five borehole DAS arrays and mobile vibroseis sources. The 4D DAS VSP in each of the five wells provides broadly consistent images of the CO2 plume with some differences due to different illumination of the target horizon, lateral variation of velocities, and seismic anisotropy. When the newly injected CO2 reaches a CO2 plume created as a result of an earlier injection into the same formation ∼600 m updip, 4D DAS VSP shows a change in reflectivity in that area and beyond. This shows a potential of 4D DAS VSP for monitoring gas injection into gas-saturated reservoirs.

(Invited) In Situ Time-Resolved Probe of Charge Carrier Dynamics at Planar Semiconductor Photoelectrode/Liquid Interface

Photoelectrochemistry is a promising approach for converting solar energy to storable chemical energy in chemical fuels. The efficiency of photoelectrochemcial devices depends critically on efficient transfer of charge carrier across the electrode liquid interface and the efficiency and selectivity of the catalytic reaction on electrode surface. Although transient absorption spectroscopy is a powerful tool for probing interfacial dynamics in high surface area electrodes, it is often not applicable on planar electrodes because the observed signal is often dominated by carrier dynamics in the bulk. In this talk, we discuss our recent effort in developing in situ time-resolved linear and nonlinear spectroscopic tools that can be used to probe carrier dynamics and reactions at planar electrode/liquid interfaces, focusing on transient reflection spectroscopy and electric field induced second harmonic generation (EFISH) spectroscopy. Compared to transient absorption, transient reflection spectroscopy is more sensitive to surface carrier density that can be more directly correlated to catalysis. We showed that transient reflectance change can be used to follow charge carrier dynamics and their amplitude can be directly correlated to efficiency of initial interfacial charge separation on p-GaP single crystals protected by TiO2 ALD layer. Our finding suggests that IPCE is determined by the product of the efficiency of initial ultrafast (< hundreds of ps) charge separation across the GaP/TiO2 interface and the efficiency of water reduction reaction on the slower time scale. Key loss pathways that limit these efficiencies are discussed. In a second approach, we showed the EFISH signal in a n-doped single crystal TiO2 can be used to probe the accumulation of photogenerated carriers at surface states and these trapped carriers are responsible for the water oxidation reaction.

Analysis of ultrafast carrier dynamics and steady-state reflectivity on lattice expansion in metal halide perovskite during continuous illumination

Lattice expansion in hybrid halide perovskite directly affects its photoelectric properties and the stability of perovskite-based optoelectronic devices, which was certified also to closely connect with relevant inducing mechanisms. From the perspective of carrier relaxation dynamics and dielectric properties, we report the results employing ultrafast time-resolved transient and steady-state reflectivity technology to diagnose the lattice expansion occurring in bulk hybrid perovskite MAPbI3 during continuous illumination and directly heating, respectively. Upon continuous illumination at a constant temperature, there were no evident structural changes in MAPbI3, but in the condition of naturally temperature changes, the lattice expansion can be induced by continuous light illumination and is consistent with the effect of heat-inducted expansion. The present results are based on the physical mechanism that the change of the electronic structure caused by lattice expansion leads to the change of the dielectric properties in MAPbI3 and sequentially to the change of light reflectivity.

Application of UV-Vis Optical Spectroscopy and X-ray Diffraction Methods to Describe the Effect of Alpha-Emitting Radionuclides (Radon) When They Are Detected by Solid-State Film Detectors.

This work aims to evaluate the application of optical and X-ray spectroscopy methods to determine the effect of alpha-emitting radionuclides on the properties of solid-state nuclear track detectors (SSNTD) based on nitrocellulose during their detection. The proposed estimation methods are alternative methods to standard technologies, making it possible to determine the concentration of radon and its decay products without the chemical etching of film detectors and subsequent direct counting of the formed latent tracks from interacting particles. During the research, it was found that the use of optical spectroscopy and X-ray diffraction methods makes it possible to qualitatively determine the irradiation effect on changes in the properties of film detectors when α-particles with different energies pass through them. At the same time, a comparison of the data of optical spectroscopy, X-ray diffraction and the visualization of latent tracks after chemical etching made it possible to establish that a part of the registered α-particles in living quarters has an energy of less than 2.5 MeV, which is not enough to pass through the polymer film of the detector, as a result of which well-like tracks are formed. An increase in the intensity of the interference bands in the region above 700 nm and a decrease in the intensity of diffraction reflection characterized the changes in optical transmission. The penetration of the α-particles through the detecting film decreases the film’s transmission capacity, forming an anisotropic change in diffraction reflections associated with a change in the film’s structure and defective fractions distorting the molecular structure.