Chalcogenide Fiber Research Articles

Polarization squeezing in chalcogenide fibers

Polarization squeezing in chalcogenide fibers

All-fiber coherent supercontinuum generation in a cascade of silica, fluoride, and chalcogenide fibers

Abstract We present an all-fiber coherent supercontinuum spanning the spectral range of 1.7–5.0 µm from a cascade of silica, ZBLAN, and chalcogenide (ChG) nonlinear fibers (NLFs). Coherence is maintained by the combined use of femtosecond pump pulses as well as by allowing deterministic spectral broadening mechanism at every stage of the cascade. The use of femtosecond pump pulses enables avoiding modulation instability (MI) at the onset of the supercontinuum generation process and thus prevent subsequent MI-seeded random noise. Once in the NLF cascade, the pump pulse is instead converted into a soliton of order maintained at N < 6 in the silica and ZBLAN NLFs, ensuring soliton fission followed by self-frequency shift of a few solitons. Finally, in the ChG NLF, spectral broadening is facilitated through self-phase modulation and dispersive wave generation. The deterministic nature of these nonlinear phenomena results in the generation of a coherent supercontinuum. The supercontinuum delivers an average power of 54 mW from an average pump power of 300 mW, yielding a power conversion efficiency of 18%. The experimental results closely align with numerical simulations, from which coherence is estimated. Such a coherent supercontinuum with a megahertz repetition rate is essential for spectroscopic systems based on optical frequency combs and applications in high-precision optical coherence tomography.

5-µm Lasing on Tb3+ Ions in a Chalcogenide Fiber Pumped by a 2.8-µm Er:ZBLAN Laser

5-µm Lasing on Tb3+ Ions in a Chalcogenide Fiber Pumped by a 2.8-µm Er:ZBLAN Laser

Soliton Self-Frequency Shift in a Cascade of Silica, Fluoride, and Chalcogenide Fibers

Soliton Self-Frequency Shift in a Cascade of Silica, Fluoride, and Chalcogenide Fibers

Chalcogenide Ge20Sb5Se75 photonic crystal fiber with seven air-hole rings for ultraflat mid-infrared supercontinuum generation

Supercontinuum (SC) generation in solid-core circular photonic crystal fibers (PCFs) made of Ge20Sb5Se75 is numerically analyzed. A large core is projected to increase light coupling efficiency into selected PCFs as well as raise coupling to standard silica fibers. High nonlinear coefficient and near-zero flat dispersion allow ultraflat SC spanning 1.5–4.6 μm in an all-normal dispersion regime. This requires 3 kW of peak power with 180 fs of pulse duration. The fiber with one zero-dispersion wavelength (ZDW) generates SC bandwidth in the range of 1.54–7.39 μm at 3.5 μm using peak power of 10 kW. For the same input power, the SC spectral covers from 1.39 to 7.36 μm in 10 cm of fiber with two ZDWs. These are wider SC bandwidths than those of previous chalcogenide fibers reached with lower peak powers. Therefore, the proposed Ge20Sb5Se75 PCFs are excellent candidates for the broadband ultraflat mid-infrared SC spectra used in high-speed nonlinear imaging and frequency measurement.

Mid-Infrared Supercontinuum Generation in Highly Nonlinear Chalcogenide Fibers

Interest in mid-infrared broadband laser light sources has surged due to applications in trace gas detection, free-space communications, and countermeasures. Progress in supercontinuum generation leverages fiber-based near-infrared and bulk-optic mid-infrared pump sources. In this paper, the Generalized Nonlinear Schrödinger Equation has been solved, using the Split Step Fourier Method, to simulate the pulse propagation and mid-infrared supercontinuum generation, inside a fiber composed of highly nonlinear As2Se3/As2S3 chalcogenide glass. The effect of various parameters, including fiber nonlinearity, Group Velocity Dispersion (GVD), input power and pulse-width, anomalous and normal dispersion pumping regime, etc. on the output supercontinuum bandwidth has been extensively studied. A tapered chalcogenide fiber is modeled to facilitate continuous simultaneous modification of the GVD and the Kerr nonlinearity parameter. Pumping the waveguides with 230-fs secant pulses at a peak power of 4.2-kW yields a mid-IR supercontinuum extending from [Formula: see text] to [Formula: see text] micrometers.

Chalcogenide mid‐infrared 3 × 1 fiber combiner for highly efficient 2–5 µm power and wavelength combining

AbstractFiber combiner is an effective device to enhance the power level or broaden the spectral wavelengths through a single monolithic output aperture, by fusing multiple fibers together. This is particularly important in mid‐infrared (MIR) 2–5 µm range, in which the output power of a single laser is limited. Due to the high MIR transmission, chalcogenide glass is an ideal host for constructing MIR fiber combiner. In this study, we report the design, fabrication, and characterization of a homemade 3 × 1 chalcogenide glass fiber combiner. The fiber combiner includes a 3 × 1 As–S input fiber bundle and an output fiber. The input fiber bundle was made by tapering three As–S multimode fibers with a core diameter of 200 µm and a cladding diameter of 250 µm. The taper reduction ratio R was 2, and the length of the taper transition region was ∼2 cm. The output fiber with core diameter of 360 µm and cladding diameter of 570 µm was then spliced with the tapered end of the fiber bundle. The total length of the combiner was ∼53 cm. The measurement of power combination at 4.56 µm indicated that the transmission efficiency of three ports reached 80%, whereas the power combining efficiency of the combiner was measured to be ∼48%. In addition, efficient wavelength combining over one octave has been demonstrated, by launching three different lasers at 2.1, 3.39, and 4.56 µm through the 3 × 1 combiner. It proves that chalcogenide fiber combiner is promising for the applications of high‐level power combination and broadband wavelength combining in MIR 2–5 µm range.

5 µm CW Ce3+-doped chalcogenide glass fiber laser with 17% slope efficiency.

Efficient room temperature mid-infrared laser action in a Ce3+-doped chalcogenide fiber was demonstrated. The fiber had a doped selenide glass core in an undoped sulfide glass cladding. The pump source was a CW Fe2+:ZnSe laser emitting at 4.14 µm. The optimized fiber length allowed obtaining up to 7 mW of 5.06 µm output with 17% slope efficiency at room temperature.

High-efficiency and broadband tunable Raman fiber laser in a chalcogenide fiber based on the Fresnel reflection.

A high-efficiency and broadband tunable chalcogenide fiber Raman laser with the Fabry-Perot (F-P) cavity formed by the Fresnel reflection was established. A maximum average power slope efficiency of around 43% and a maximum output peak power of about 2.9 W at 2148 nm were demonstrated by using a 2 µm nanosecond pump source. The laser shows a broadened pulse width of 674 ns and a broadband tunability of the central wavelength from 2100 to 2186 nm. The Raman Fabry-Perot cavity constituted by the Fresnel reflection from chalcogenide fiber endfaces can operate at any wavelength without the aid of any additional optical feedback element. This will facilitate the realization of fiber lasers with excellent performance and compact system, especially in the mid-infrared region.

Efficient Mid-Infrared Soliton Self-Frequency Shift and Dispersive Wave in a Chalcogenide Fiber

Efficient Mid-Infrared Soliton Self-Frequency Shift and Dispersive Wave in a Chalcogenide Fiber

Fabrication of Mid-IR As-Se Chalcogenide Glass and Fiber With Low Scattering Loss

Fabrication of Mid-IR As-Se Chalcogenide Glass and Fiber With Low Scattering Loss

Numerical Modeling of Mid-IR Lasers Based on Tb-Doped Chalcogenide Multicore Fibers

Mid-IR fiber lasers operating at wavelengths near 5 μm are of great interest for many fundamental and industrial applications, but only a few experimental samples based on active chalcogenide fibers have been demonstrated so far. One of the limitations of the power of such lasers may be a fairly low fiber damage threshold. To solve this problem, we developed and numerically investigated in detail a mid-IR fiber laser at 5.3 µm with multi-W output power pumped into the cladding at a wavelength of 2 µm. We proposed using a Tb-doped chalcogenide multicore fiber with 25 single-mode cores arranged in a 5 × 5 square lattice as an active medium. The proposed laser design surpasses the power limit of single-core chalcogenide fibers. When simulating lasers, we specified realistic parameters of Tb-doped chalcogenide glass based on published experimental data. We performed a comprehensive theoretical analysis, studied the influence of various factors on the characteristics of generation, and found optimal system parameters and expected generation parameters.

Mid-infrared seven-core chalcogenide fiber with ultra-large mode field area and high beam quality

A seven-core chalcogenide fiber with an ultra-large mode field for mid-infrared range of 2.5–11 μm is designed and fabricated. Through manipulation of the core radius and pitch in the seven-core configuration, we are engaged in a comprehensive exploration of crosstalk characteristics and the mode field area (MFA). In addition, the relationship between the parameters of seven-core fiber for infrared and the beam quality of the output laser is analyzed for the first time. A theoretical MFA of 8914 μm2 can be calculated with a core radius of 24 μm and the pitch of 50 μm. This impressive MFA is realized through the deployment of an improved drilling technique in the fabrication of a Ge–As–Se seven-core fiber. The fiber has a relatively low loss at the wavelength range of 2.5–11 μm, and the minimum loss is 1.4 dB m−1 at 8.5 μm. The measured MFA of the fiber at 10.6 μm is 7364 μm2, which is 6.2 times higher than that of traditional stepped single-core fiber, but slightly lower than the theoretical value. The power delivery capability of the fiber has been significantly improved about two times compared with that of single-core fiber. The output beam quality factor M 2 is calculated as 1.13. In all, the seven-core fiber exhibits substantial potential for high-power laser propagation with high quality and flexibility.

Short review and prospective: chalcogenide glass mid-infrared fibre lasers

Rare-earth ion doped, silica glass, optical fibre amplifiers have transformed the world by enabling high speed communications and the Internet. Fibre lasers, based on rare-earth ion doped silica glass optical fibres, achieve high optical powers and are exploited in machining, sensing and medical surgery. However, the chemical structure of silica glass fibres limits the wavelength of laser operation to < 2.5 µm, which excludes the mid-infrared longer wavelength range of 3–50 µm. Rare-earth ion doping of fluoride glasses enables manufacture of fibre lasers up to a limiting 3.92 µm wavelength, but the fluoride glass chemical structure again prevents operation at longer wavelengths. Optical fibre lasers that are constructed from different rare-earth ion doped chalcogenide glass fibres will potentially operate across the 4–10 µm wavelength range, where suitable high-power lasers currently do not exist. We present a short review here of our recent work in achieving first time, continuous wave, mid-infrared fibre lasing beyond 5 μm wavelength in Ce3+-doped selenide chalcogenide fibre. We place this disruptive breakthrough into the wider fibre laser context, and also present the unprecedented advances in new cross-sector applications that will be enabled by mid-infrared fibre lasers in the 4–10 µm wavelength range. To surpass the few mW power output of the Ce3+-doped chalcogenide glass fibre lasing achieved to date, the glass quality of the doped chalcogenide fibres must now be improved, similar to the challenges originally facing the first glass fibre lasers based on silica.

A pilot study on non-invasive in situ detection of phytochemicals and plant endogenous status using fiber optic infrared spectroscopy

Traditional methods for assessing plant health often lack the necessary attributes for continuous and non-destructive monitoring. In this pilot study, we present a novel technique utilizing a customized fiber optic probe based on attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) with a contact force control unit for non-invasive and continuous plant health monitoring. We also developed a normalized difference mid-infrared reflectance index through statistical analysis of spectral features, enabling differentiation of drought and age conditions in plants. Our research aims to characterize phytochemicals and plant endogenous status optically, addressing the need for improved analytical measurement methods for in situ plant health assessment. The probe configuration was optimized with a triple-loop tip and a 3 N contact force, allowing sensitive measurements while minimizing leaf damage. By combining polycrystalline and chalcogenide fiber probes, a comprehensive wavenumber range analysis (4000–900 cm−1) was achieved. Results revealed significant variations in phytochemical composition among plant species, for example, red spinach with the highest polyphenolic content and green kale with the highest lignin content. Petioles displayed higher lignin and cellulose absorbance values compared to veins. The technique effectively monitored drought stress on potted green bok choy plants in situ, facilitating the quantification of changes in water content, antioxidant activity, lignin, and cellulose levels. This research represents the first demonstration of the potential of fiber optic ATR-FTIR probes for non-invasive and rapid plant health measurements, providing insights into plant health and advancements in quantitative monitoring for indoor farming practices, bioanalytical chemistry, and environmental sciences.

Design and fabrication of large-mode-area multicore chalcogenide fiber with low bending loss.

Multicore fiber (MCF) has a larger mode-area (LMA) compared to traditional single-core fiber, making it easy to get a mode area of more than 3000 µm2 with an optimized MCF structure. Here, a fine-structured 19-core fiber based on chalcogenide glass was fabricated using a combined method involving extrusion, drilling, and rod-in-tube for the first time. The fiber has a minimum transmission loss of 1.8 dB/m at 6.7 µm. When the bending radius exceeds 6 cm, a low bending loss of about 0.6 dB appears, and the experimental data are in good agreement with the simulation results. In addition, the supermode characteristics of the 19-core fiber are analyzed from both perspectives of simulation and experiment, and these results are perfectly in good agreement. We believe it opens a new way to develop high-power and bend-resisting fiber with such kind of multicore structure.

Exact Solution of the Raman Response Function of Chalcogenide Fiber and Its Influence on the Mid-Infrared Supercontinuum

We fabricated a core-cladding Ge–Sb–Se glass fiber with a Ge12.5Sb15Se72.5 core and Ge15Sb10Se75 cladding, achieved a supercontinuum spectrum spanning from 2 μm to 9 μm by pumping the Ge–Sb–Se fiber with a core diameter of 11 μm using a femtosecond laser pump at 3.8 μm, and numerically simulated the supercontinuum generation using the generalized nonlinear Schrödinger equation. In particular, we investigate the effect of the different Raman response functions that were calculated using the traditional single Lorentzian model and a multiple vibrational mode model on the evolution of the supercontinuum by comparing the supercontinua obtained from simulation and experimental results. We demonstrate that the Raman response function generated by the multiple vibrational mode model captures the actual response behavior of the material, and the supercontinuum generated using this model has more accuracy. To the best of our knowledge, this is the first reported study on supercontinuum generation in Ge–Sb–Se fiber utilizing a Raman response function calculated using the multiple vibrational mode model. This significant advancement enables more accurate simulation of supercontinuum generation in fibers with a multi-peaked structured Raman gain spectrum and holds great potential for optimizing the performance of various mid-infrared supercontinuum sources.

Components development for mid-infrared chalcogenide fiber glass lasers

The paper considers methods and approaches in the creation of the element base for chalcogenide fiber lasers. The results of research on Bragg grating recording and splicing of chalcogenide fibers are given.

Five-micron Ce 3+ ion fiber laser

The spectral and temporal characteristics of a Ce 3+ -doped chalcogenide fiber laser pumped by a continuous Fe 2+ :ZnSe laser were investigated in this work.

Single-Mode Segmented Cladding Chalcogenide Glass Fiber With Ultra-Large Mode Area

Small core size in conventional single mode step-indexed chalcogenide fiber could reduce the ability of mid-infrared (mid-IR) laser power delivery due to its limitation of power density. An effective way to solve the problem is to increase mode area with large core size, but this may degrade the beam quality. In this work, a novel mid-IR segmented cladding fiber (SCF) with leakage structure based on chalcogenide glasses was proposed to obtain large mode area, as well as single-mode condition. The leakage loss and effective mode area of the SCF was analyzed by optimizing the segment number <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">N</i> , duty cycle γ and core radius <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">r</i> . The results show that, when <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">N</i> =4, γ=75% and <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">r</i> =33 μm, the mode area is more than 2000 μm <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sup> in the wavelength range of 3-10 μm and the loss ratio of high order modes (LP <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">11</sub> ) to fundamental mode (LP <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">01</sub> ) is more than 300, indicating the SCF can achieve single-mode operation with a large core. Then, a mid-IR SCF was fabricated via an extrude-and-stack technique based on chalcogenide glasses for the first time. The minimum fiber loss is 3.1 dB/m at 8.6 μm, the bend loss is 3 dB when bend radius is 6 mm. Compared with that in the traditional step-index single-mode fiber, it was found that, the mode area in SCF can be increased over 15 times. All these results demonstrate the SCF possesses the potential of high-power mid-IR laser transmission.