Central Yangtze River Basin Research Articles

Unravelling Coupled Hydrological and Geochemical Controls on Long-Term Nitrogen Enrichment in a Large River Basin.

Many groundwater and surface water bodies around the world show a puzzling and often steady increase in nitrogen (N) concentrations, despite a significant decline of agricultural N inputs. This study uses a combination of long-term hydrogeochemical and hydraulic monitoring, molecular characterization of dissolved organic matter (DOM), column experiment, and reactive transport modeling to unravel the processes controlling N-reactive transport and mass budgets under the impacts of dynamic hydrologic conditions at a field site in the central Yangtze River Basin. Our analysis shows that the desorption of ammonium (NH4+) from sediments via cation exchange reactions dominates N mobilization and aqueous N concentrations, while the mineralization of organic N compounds plays only a minor role. The reactive transport modeling results illustrate the important role of cation exchange reactions that are induced by temporary NH4+ input and cation concentration changes under the impact of both seasonal and long-term hydrologic variations. Historically, cation exchangers have acted as efficient storage devices and mitigated the impacts of high levels of NH4+ input. The NH4+ residing on cation exchanger sites later acts as a long-term N source to waters with the delayed desorption of sediment-bound NH4+ induced by the change of hydrologic conditions. Our results highlight the complex linkages between highly variable hydrologic conditions and NH4+ partitioning in near-surface, river-derived sediments.

Co-occurring characteristics and mechanisms of geogenic ammonium and phosphorus in Quaternary alluvial-lacustrine aquifer systems

High loads of nitrogen (N) and phosphorus (P) in groundwater are a pressing global environmental concern. Geogenic ammonium (NH4+) and P anomalies in groundwater as unique forms of contamination, have been extensively reported. However, despite significant efforts on the enrichment of geogenic NH4+ or P, little is known about their co-occurring characteristics and mechanisms in groundwater. Therefore, focusing on the Dongting Plain (DTP) within the central Yangtze River basin, a typical alluvial-lacustrine plain, this study analyzed hydrogeochemistry, stable carbon isotopes, and dissolved organic matter (DOM) fluorescence. The results revealed a clear correlation between the groundwater DOM humification degree and the redox processes. In different redox processes, four distinct groundwater types emerged sequentially: low-NH4+ & low-P, low-NH4+ & high-P, high-NH4+ & high-P, and high-NH4+ & low-P. In organic matter (OM) degradation process, when dissolved oxygen and nitrate acted as electron acceptors, the low-NH4+ & low-P groundwater dominated. The low-NH4+ & high-P groundwater dominated when Mn(IV) and amorphous Fe(III) (oxyhydr)oxides served as the electron acceptors, where P enrichment was primarily attributed to the reductive dissolution of amorphous Fe(III) (oxyhydr)oxides. The high-NH4+ & high-P groundwater dominated when SO42-, crystalline Fe(III) (oxyhydr)oxides, and CO2 served as the electron acceptors. During this phase, OM mineralization resulted in the enrichment of both NH4+ and P. Furthermore, the reductive dissolution of crystalline Fe(III) (oxyhydr)oxides further increased P concentrations in groundwater. During the strong degradation of OM to the methanogenic stage, two processes occurred simultaneously: anaerobic oxidation of methane and reductive dissolution of Fe(III) (oxyhydr)oxides. These processes led to an increase in the concentration of HCO3– and Fe(II) in groundwater. During this phase, large amounts of HCO3– and Fe(II) combine to form siderite precipitates. These precipitates adsorb P from the groundwater, eventually leading to a decrease in P concentration and the formation of high-NH4+ & low-P groundwater. This study offers novel insights into the simultaneous cycling of N and P in Quaternary alluvial-lacustrine aquifer systems.

Unraveling roles of dissolved organic matter in the co-occurrence of arsenic and ammonium in Quaternary alluvial-lacustrine aquifers

Geogenic arsenic (As) and ammonium (NH4+)-contaminated groundwaters are global public concerns, posing threats to human health and ecological security. However, when considering the enrichment of either As or NH4+ in groundwater, the concurrent occurrence of both contaminants warrants further discussion. Herein, we conducted a hydrogeochemical study in the shallow confined aquifer of the central Yangtze River basin to elucidate the key mechanism of coexistence of As and NH4+ through a thorough analysis of groundwater chemistry, inorganic carbon isotope (δ13C-DIC), and dissolved organic matter (DOM). High As and NH4+ groundwater mainly occurs in meanders of the middle reaches of Yangtze River, with maximum concentrations up to 936 μg/L and 45.3 mg/L, respectively. Our findings indicate that the degradation levels and characteristics of DOM play a significant role in the co-occurrence of As and NH4+ with varying concentrations in groundwater. δ13C-DIC signatures show that there was a simultaneous increase in the concentrations of As and NH4+ in groundwater, with the highest concentration of As during fermentative conditions. In contrast, during the progression of OM degradation towards methanogenesis, the NH4+ concentration reached its peak, while the As concentration was lower compared to the fermentation stage. Optical properties of DOM demonstrate that elevated levels of NH4+ result from the mineralization of N-containing organic compounds particularly as the degradation proceeds to methanogenesis stage, while both fermentation and methanogenesis processes significantly contribute to the microbially reductive dissolution of As-bearing iron oxides in groundwater systems. This study presents isotopic and fluorescent evidence to clarify the co-existence of As and NH4+ in Quaternary alluvial-lacustrine aquifers.

Deciphering the spatial heterogeneity of groundwater arsenic in Quaternary aquifers of the Central Yangtze River Basin

Significant spatial variability of groundwater arsenic (As) concentrations in South/Southeast Asia is closely associated with sedimentogenesis and biogeochemical cycling processes. However, the role of fine-scale differences in biogeochemical processes under similar sedimentological environments in controlling the spatial heterogeneity of groundwater As concentrations is poorly understood. Within the central Yangtze Basin, dissolved organic matter (DOM) and microbial functional communities in the groundwater and solid-phase As-Fe speciation in Jianghan Plain (JHP) and Jiangbei Plain (JBP) were compared to reveal mechanisms related to the spatial heterogeneity of groundwater As concentration. The optical signatures of DOM showed that low molecular terrestrial fulvic-like with highly humified was predominant in the groundwater of JHP, while terrestrial humic-like and microbial humic-like with high molecular weight were predominant in the groundwater of JBP. The inorganic carbon isotope, microbial functional communities, and solid-phase As-Fe speciation suggest that the primary process controlling As accumulation in JHP groundwater system is the degradation of highly humified OM by methanogens, which drive the reductive dissolution of amorphous iron oxides. While in JBP groundwater systems, anaerobic methane-oxidizing microorganisms (AOM) coupled with fermentative bacteria, iron reduction bacteria (IRB), and sulfate reduction bacteria (SRB) utilize low molecular weight DOM degradation to drive biotic/abiotic reduction of Fe oxides, further facilitating the formation of carbonate associated Fe and crystalline Fe oxides, resulting in As release into groundwater. Different biogeochemical cycling processes determine the evolution of As-enriched aquifer systems, and the coupling of multiple processes involving organic matter transformation‑iron cycling‑sulfur cycling-methane cycling leads to heterogeneity in the spatial distribution of As concentrations in groundwater. These findings provide new perspectives to decipher the spatial variability of As concentrations in groundwater.

Spatio-temporal variations of lacustrine groundwater discharge and related nutrient fluxes in a typical lake in front of hillocks

Lacustrine groundwater discharge (LGD) as a hidden hydrologic process has been widely found to affect water and nutrient balance in various lakes, but a comprehensive research on both spatial and temporal variations of LGD and associated nutrient fluxes was poorly conducted. Herein, this study elucidated their spatio-temporal variations and underlying factors of a typical lake in front of hillocks with spatially variable topography and hydrogeology, and intense seasonal groundwater-lake exchange, within central Yangtze River basin. The 222Rn mass balance model was used in conjunction with hydrochemistry, water isotope, and nutrient data. The results showed that the overall LGD rate and related N/P fluxes were clearly higher in the wet season than in the dry season, for which the stronger evaporation relative to precipitation, more groundwater recharge from agricultural irrigation or aquacultural pond infiltration, and more N/P input from anthropogenic or aquacultural activities could be responsible. In the wet season, the area with more recharge from irrigating water or fish pond water infiltration and associated extensive agricultural or aquacultural activities, had the significantly highest LGD rate and related N/P fluxes. In the dry season, the area with the deepest water depth and largest topographic slope, exhibited the significantly highest LGD rate and slightly higher LGD-related N/P fluxes due to relatively low groundwater N/P concentrations. This study enriched the understanding on LGD and related nutrient fluxes in the perspective of both spatial and temporal variations, taking a new type of lakes (i.e., lakes in the transitional zone of hills and plains in temperate climate) as a typical case.

Manganese mobilization from sediment to groundwater in alluvial-lacustrine aquifer system along the lower reaches of Han River

Geogenic contaminants in groundwater limit the drinking water safety and sustainable water supply for domestic purposes throughout the world. Elevated concentrations of manganese (Mn) in groundwater have been one of the major concerns since its adverse health effects to humans, whereas the underlying enrichment mechanism within aquifers is poorly understood. This research aims to connect the spatial distributions of groundwater Mn in different units of the aquifer and the variations of sediment geochemistry to provide comprehensive understanding of Mn provenance and its mobilization through sediment pore-networks into groundwater. Along the lower reaches of Han River within the central Yangtze River Basin, significant heterogenous Mn distribution has been observed with over 60 % of groundwater exceeding the World Health Organization drinking water guideline. Groundwater chemistry and sequential extraction results indicated that the oxidation of organic matter and reduction of Mn oxides and Fe (hydr)oxides in sediments could drive groundwater Mn enrichment. Herein, we propose a burial-dissolution type as the major hydrogeochemical process of Mn mobilization in the region. These findings are of great importance in understanding the geogenic sources of Mn and the controlling processes for its spatial heterogeneity in alluvial-lacustrine aquifer system, which might be applicable to similar Mn-affected geological settings.

Spatiotemporal distribution and controlling factors on ammonium in waters in the central Yangtze River Basin, China

High levels of ammonium in water can compromise the ecological environment and be harmful to human beings. It is of great significance to understand the source and controlling factors of ammonium in waters. However, the distribution and controlling factors on ammonium in the central Yangtze River Basin have been rarely reported. The results showed that 6.58% of the surface water (SW) exceeded the China national guideline of category III for NH4+-N (i.e., 1.0 mg/L) and 30.19% of the groundwater (GW) exceeded the China national guideline of category III for NH4+-N (i.e., 0.5 mg/L). Notably, the ammonium concentrations of the plain area in the middle were much higher, which reached to the highest value at the junction of the Yangtze River and Dongting Lake. Nitrogen in SW may originate from manure but more nitrogen sources in GW. The net anthropogenic nitrogen input (NANI) can provide enough organic nitrogen for the mineralization. NH4+-N in SW was more affected by fertilizer nitrogen and feed nitrogen input but more affected by agricultural nitrogen fixation in GW. Agricultural and industrial activities controlled NH4+-N in SW and GW by increasing nitrogen input and changing hydrological conditions. In general, this research exposed the controlling of different types of factors on ammonium in waters, providing a guidance for the water pollution prevention in study area.

Effect of depositional evolution on phosphorus enrichment in aquifer sediments of alluvial-lacustrine plain

Groundwater with high geogenic phosphorus (P) is increasingly concerned as a potential risk to surface water eutrophication. Although hydrogeochemical processes responsible for P mobilization in groundwater systems have been studied, the burial characteristics of P and the effect of depositional evolution on P enrichment in aquifer sediments remain unclear. In this study, aquifer sediments were collected from the Dongting Lake Plain (DTP) within the central Yangtze River Basin, a high P groundwater area, and the effect of depositional evolution on P enrichment was elucidated by comprehensively analyzing the lithology, grain size, geochronology, and geochemistry of the sediments, coupled with groundwater chemistry and sediment incubation experiments. The results showed that the contents of total organic carbon (TOC), iron (Fe), and P (the relative content of bioavailable phosphorus (BAP)) were higher in lacustrine sediments deposited under a warm-wet climate, but lower in fluvial sediments deposited under a cold-dry climate. During depositional evolution, the sedimentary facies mainly controlled the content of organic phosphorus (OP), while the paleo-climate controlled the content of both OP and Fe-bound inorganic P (FeP), which jointly affected total P content in aquifer sediments. Under the interaction of groundwater and sediment, the reductive dissolution of P-rich Fe (oxyhydr)oxides and the mineralization of OP in sediment continuously release P into groundwater. Notably, the rapid accumulation of alluvial sediments after the Last Glacial Maximum in the DTP and rapid evolution of Dongting Lake during the Holocene led to a large amount of organic matter (OM) and P buried in sediments, providing materials for P release in aquifers, which seriously threatens groundwater quality. This exploration can provide a new understanding of the enrichment of geogenic P in groundwater from the perspective of depositional evolution.

Coupled effects of sedimentary iron oxides and organic matter on geogenic phosphorus mobilization in alluvial-lacustrine aquifers

The organic matter (OM) biodegradation and reductive dissolution of iron oxides have been acknowledged as key factors in the release of geogenic phosphorus (P) to groundwater. However, the coupled effects of natural OM with iron oxides on the mobilization of geogenic P remain unclear. Groundwater with high and low P concentrations has been observed in two boreholes in the alluvial-lacustrine aquifer system of the Central Yangtze River Basin. Sediment samples from these boreholes were examined for their P and Fe species as well as their OM properties. The results show that sediments from borehole S1 with high P levels contain more bioavailable P, particularly iron oxide bound P (Fe-P) and organic P (OP) than those from borehole S2 with low P levels. Regarding borehole S2, Fe-P and OP show positive correlations with total organic carbon as well as amorphous iron oxides (FeOX1), which indicate the presence of Fe-OM-P ternary complexes, further evidenced by FTIR results. In a reducing environment, the protein-like component (C3) and terrestrial humic-like component (C2) will biodegrade. In the process of C3 biodegradation, FeOX1 will act as electron acceptors and then undergo reductive dissolution. In the process of C2 biodegradation, FeOX1 and crystalline iron oxides (FeOX2) will act as electron acceptors. FeOX2 will also act as conduits in the microbial utilization pathway. However, the formation of stable P-Fe-OM ternary complexes will inhibit the reductive dissolution of iron oxides and OM biodegradation, thus inhibiting the mobilization of P. This study provides new insights into the enrichment and mobilization of P in alluvial-lacustrine aquifer systems.

Contrastive mechanisms of groundwater ammonium enrichment in different hydrogeologic settings

Although high levels of geogenic ammonium in groundwater have been widely reported, the mechanisms controlling its heterogeneous distribution are not yet well understood. In this study, a comprehensive investigation of hydrogeology, sediments, and groundwater chemistry was coupled with a set of incubation experiments to reveal the contrasting mechanisms of groundwater ammonium enrichment at two adjacent monitoring sites with different hydrogeologic settings in the central Yangtze River basin. Significant differences were found in the ammonium concentrations of groundwater at two monitoring sites, with the ammonium concentrations in the Maozui (MZ) section (0.30–5.88 mg/L; average of 2.93 mg/L) being much higher than those in the Shenjiang (SJ) section (0.12–2.43 mg/L; average of 0.90 mg/L). For the SJ section, the aquifer medium had a low organic matter (OM) content and a weak mineralization capability, leading to a limited potential for geogenic ammonium release. Moreover, due to the presence of alternating silt and continuous fine sand layers (with coarse grains) above the underlying confined aquifer, the groundwater was in a relatively open environment with oxidizing conditions, which may have promoted the removal of ammonium. For the MZ section, the aquifer medium had a high OM content and a strong mineralization capability, leading to a much higher potential for geogenic ammonium release. Furthermore, due to the presence of a thick and continuous muddy clay layer (aquitard) above the underlying confined aquifer, the groundwater was in a closed environment with strong reducing conditions, which was conductive to the storage of ammonium. Larger sources of ammonium in the MZ section and greater consumption of ammonium in the SJ section contributed collectively to the significant differences in groundwater ammonium concentrations. This study identified contrasting mechanism of groundwater ammonium enrichment in different hydrogeologic settings, which can help explain the heterogeneous distribution of ammonium levels in groundwater.

Hydro-geochemical evolution of groundwater in the central Yangtze River Basin, China

Hydro-geochemical evolution of groundwater in the central Yangtze River Basin, China

Novel insight into iodine enrichment in alluvial-lacustrine aquifers: Evidence from stable carbon and iron isotopes

Reductive dissolution of Fe (oxyhydr)oxides triggered by biodegradation of organic matter (OM) are considered to be key processes controlling iodine (I) release in groundwater systems. However, the precise mechanisms involved in release from organic matter degradation and from Fe (oxyhydr)oxides are unclear. In this study, dual stable isotope analysis (δ13C and δ56Fe) was combined with ultraviolet–visible spectral characterization of dissolved organic matter to elucidate the mechanisms of iodine enrichment in groundwater of the central Yangtze River basin, China, which represents Quaternary alluvial-lacustrine floodplains. High iodine groundwater mainly occurs along the Yangtze River (YR) and Han River (HR), with a maximum concentration of 1220 μg/L. The results suggest that methanogenesis driven by the biodegradation of high molecular weight organic compounds can promote the reductive dissolution of amorphous Fe (oxyhydr)oxides, which is the predominant process controlling iodine enrichment in the YR groundwater system. In addition, fermentation accompanied by sulfate reduction can also trigger the release of iodine into groundwater. The reductive dissolution of crystallized Fe (oxyhydr)oxides driven by the fermentation of small-molecule organic compounds is the dominant process responsible for iodine enrichment in the HR groundwater system. This study provides novel insight into the mechanisms of iodine enrichment in Quaternary alluvial-lacustrine aquifers.

New evidence for linking the formation of high arsenic aquifers in the central Yangtze River Basin to climate change since Last Glacial Maximum

The prevalence of arsenic (As)-affected groundwater in the Late Pleistocene and Holocene aquifers leads to serious arsenicosis worldwide. However, the geogenic foundational processes underlying the high As aquifers remain elusive. Here we present joint lines of evidences from chronological, sediment geochemical and geomicrobial analysis that climate change since the Last Glacial Maximum (LGM) initiates the genesis of high As aquifers in the central Yangtze River Basin, which represents Quaternary alluvial-lacustrine floodplains affected by arsenicosis occurrence. Optically stimulated luminescence-based sediments dating and grain size characterization indicate that the LGM depositional boundary also separates the Late-Pleistocene/Holocene high arsenic aquifers from the underlying arsenic-depleted aquifers. Further examination of solid-phase As/Fe/S speciation and associated microbial communities function suggests that the pre-LGM depositional environments characteristic of S metabolism engender the fixation of As in pyrite, whereas during the post-LGM period climate change to warm and humid leads to As repartitioning to Fe/Mn oxides in response to strong chemical weathering. This may have contributed to a dynamic fate of As in the post-LGM depositional environments and thus a highly variable aqueous As concentrations over depth. Our results highlight the important roles of climate change has played in the genesis of high As aquifers, with implications for other LGM-affected regions worldwide as well as for the evolution of high arsenic aquifers under future climate change.

Source identification of groundwater phosphorus under different geological settings in the central Yangtze River basin

The contribution of geogenic phosphorus (P) in groundwater to surface water eutrophication has become a major concern for aquatic environment protection, but the differences in groundwater P sources in different geological settings are less concerned. In this study, three areas in the central Yangtze River basin under various geological conditions were selected for the identification of groundwater P sources and key factors affecting P enrichment, using hydrogeochemical and geostatistical methods. It was found that P in groundwater of middle and upper Pleistocene aquifers is mainly geogenic and is little affected by anthropogenic activities. In the lower reaches of the Han River (an area with phosphate mining upstream), the dissolution of phosphate minerals such as apatite from P-rich strata is the main source of groundwater P (feature importance of Ca2+ 39%). Along the Jingjiang River (an area with widespread peat deposition in paleo-channels and ancient lakes), the mineralization of organic P (OP) is the dominant groundwater P source (feature importance of NH4-N 46%), with the reductive dissolution of iron (oxyhydr)oxides as a secondary source (feature importance of Fe2+ 26%). In the western part of the Dongting Plain (an area with iron-rich sedimentary rocks and granites in the surrounding mountains), the reductive dissolution of iron (oxyhydr)oxides is the main source of P in groundwater (feature importance of Fe2+ 34%), with mineralization of organic P as a secondary but important source (feature importance of NH4-N 25%). The differences in groundwater P sources in different subareas are clearly linked to specific geological conditions. This study provides new insights into the dependence of P source and enrichment in groundwater systems on regional geology and highlights the importance of using a wide range of research methods for understanding the extremely complex processes in the subsurface environment.

Evolution of the groundwater flow system driven by the sedimentary environment since the Last Glacial Maximum in the central Yangtze River Basin

• Fluctuations in the Yangtze River and sedimentary environment control GFS evolution. • Sedimentary evolution caused unconformable distribution of groundwater age in a GFS. • Continuous uplift of discharge base level favors preservation of ancient groundwater. • Holocene fine-grained sedimentary strata led to the stagnation of regional GFS. Understanding the circulation and evolution of groundwater and its control mechanism in the Jianghan Plain, which exhibits the complex sedimentary evolution and a progressively deteriorating groundwater environment, is highly imperative and challenging to promote the practical application of groundwater flow system (GFS) and protect the groundwater resources in the region. The aim of this work was to elucidate the evolution pattern of the GFS in the Jianghan Plain and its underlying mechanism. To this end, the grain size characteristics of sediments, geochronological information, stable isotopes in clay porewater, paleoclimate indicators, and existing groundwater age were analyzed to reveal the sedimentary environment of aquifer systems at the basin scale in the study area. It was found that the sedimentary environment changed from one of deep downcutting during the Last Glacial Maximum (LGM) to a fluvial facies that was rapidly infilled with coarse-grained sediments during the last deglaciation period (LDP), and then to a stable lacustrine facies with fine-grained sediments during the Holocene warm period (HWP). These changes were closely linked to the fluctuations of the Yangtze River. Consequently, the existing GFS pattern in the basin presents an unconformable distribution of groundwater age, indicating that it results from the temporal superposition of groundwater flow controlled by the historical sedimentary environment. Dramatic sea level fluctuations since the LGM have resulted in significant changes in the water level of the Yangtze River. This process has impacted the driving force of groundwater, resulting in the evolution of the GFS from a pattern of a fully developed regional GFS during the LGM to the present pattern of a multi-hierarchy nested GFS.

Nitrogen burial characteristics of Quaternary sediments and its controls on high ammonium groundwater in the Central Yangtze River Basin

As the strata sedimentary process proceeds, considerable amounts of nitrogen (N) is buried in sediments, which controls the sources and fate of N in the “groundwater-sediment” system. However, there is little concern regarding N burial characteristics in continuous sediment profiles from surface layer to deep aquifer thus far. In this study, lithology, grain size, geochronology, exchangeable N contents and geochemical proxies of sediments were analyzed to reveal the controlling mechanisms of N burial characteristics in Quaternary sediments and to interpret the enrichment of N in groundwater of central Yangtze River Basin. The results demonstrated a similar distribution trend for buried N in two sedimentary cores, which were high in the surface layer and decreased to stable in the deep aquifer. Excessive exchangeable N (EX-N) contents in sediments were mainly attributed to geologic origin. The N burial characteristics were controlled by the evolution of depositional environment: sedimentary facies determined the concentrations of total organic nitrogen (TON), further affecting the mineralization capacity of sediments; while paleoclimate regulated the intensity of the N transformation processes, ultimately influencing the actual concentrations of EX-N in sediments. In addition, due to the fast accumulation of alluvial deposits after Last Glacial Maximum and rapid development of Jianghan Lake Groups during Holocene, abundant organic matter (with high TON contents) was buried in sediments, which were still able to produce more ammonium or nitrate, and further posing continuous threats to groundwater quality. This study provided a new interpretation for the formation of high-ammonium aquifer in terms of depositional evolution.

Predicting the spatial distribution of phosphorus concentration in Quaternary sedimentary aquifers using simple field parameters

Geogenic phosphorus (P) in groundwater has been found in different regions, posing a risk for surface water eutrophication. However, the prediction of groundwater P distribution is less studied. In this study, three machine learning-based regression models including random forest regression (RFR), support vector regression (SVR), and multiple linear regression (MLR) were applied to predict the spatial distribution of geogenic P in alluvial-lacustrine sedimentary aquifers of the central Yangtze River basin, with readily accessible field parameters, such as pH, Eh, EC, depth, NH4+-N and Fe2+. The results indicate that the RFR model achieves the best fit by three times 10-fold cross-validation with the highest R2 (0.49) and explanatory variance (0.52), the lowest root mean square error (0.48) and mean absolute error (0.30), producing a groundwater P distribution that is highly consistent with the observed results. According to the prediction results, the areas with high P (>0.4 mg/L) groundwater and abnormally high P (>1 mg/L) groundwater account for 55% and 11% of the whole study area in JH-DT-P, respectively. Meanwhile, NH4+-N and Fe2+ are the two most prominent indicating factors of P enrichment in groundwater, and NH4+-N has higher relative importance than Fe2+. The wider validity of the model was suggested by its successful application to two regions in Bangladesh with similar hydrogeological conditions.

Sources of ammonium enriched in groundwater in the central Yangtze River Basin: Anthropogenic or geogenic?

The occurrence of excessive ammonium in groundwater threatens human and aquatic ecosystem health across many places worldwide. As the fate of ammonium in groundwater systems is often affected by a complex mixture of transport and biogeochemical transformation processes, identifying the sources of groundwater ammonium is an important prerequisite for planning effective mitigation strategies. Elevated ammonium was found in both a shallow and an underlying deep groundwater system in an alluvial aquifer system beneath an agricultural area in the central Yangtze River Basin, China. In this study we develop and apply a novel, indirect approach, which couples the random forest classification (RFC) of machine learning method and fluorescence excitation-emission matrices with parallel factor analysis (EEM-PARAFAC), to distinguish multiple sources of ammonium in a multi-layer aquifer. EEM-PARAFAC was applied to provide insights into potential ammonium sources as well as the carbon and nitrogen cycling processes affecting ammonium fate. Specifically, RFC was used to unravel the different key factors controlling the high levels of ammonium prevailing in the shallow and deep aquifer sections, respectively. Our results reveal that high concentrations of ammonium in the shallow groundwater system primarily originate from anthropogenic sources, before being modulated by intensive microbially mediated nitrogen transformation processes such as nitrification, denitrification and dissimilatory nitrate reduction to ammonium (DNRA). By contrast, the linkage between high concentrations of ammonium and decomposition of soil organic matter, which ubiquitously contained nitrogen, suggested that mineralization of soil organic nitrogen compounds is the primary mechanism for the enrichment of ammonium in deeper groundwaters.

Modeling the effects of water diversion projects on surface water and groundwater interactions in the central Yangtze River basin

Due to the lack of the quantification of surface water (SW) and groundwater (GW) interaction, the chemicals transport and fate and wetland evolution are hard to predict under impact of both the natural condition and water diversion projects. To address this issue, a 3D regional numerical model is proposed in this study to analyze the effects of the South-to-North Water Diversion (SNWD) and Yangtze-Hanjiang Water Diversion (YHWD) projects on groundwater flow regimes and SW-GW interactions of Jianghan Plain in the central Yangtze River basin. The model results show that the Yangtze River and groundwater interactive pattern varied little, whereas the exchange capacity has been significantly affected by the SNWD but little affected by the YHWD. If only implemented SNWD project, the Hanjiang River and groundwater interactive pattern varied and the net exchange rate between the Hanjiang River and groundwater decreased by 69.3% compared to natural condition. Since YHWD was introduced to complement SNWD, the net exchange rate has been reduced by 25.3% compared with that under the only SNWD. SNWD and YHWD projects implementation caused the decrease of the groundwater level along the Yangtze River with the maximum value of 0.19 m but the increase of groundwater level along the Hanjiang River with the maximum rise reaching up to 0.78 m. This study provides the insights for quantification of GW-SW interaction at regional scale, which will benefiting for integrated water resource management and understanding contaminant reactive transport and wetland evolution in the central Yangtze River basin.

Spatial and temporal patterns of heavy metals and potential human impacts in Central Yangtze lakes, China

Lakes in the central Yangtze River basin have experienced increasing levels of human disturbance during the past several decades, yet large-scale environmental patterns in these lakes and their driving factors remain unclear. Herein we examined spatial and temporal patterns of copper (Cu), zinc (Zn), lead (Pb), arsenic (As), and seven other heavy metals from 16 lakes experiencing a gradient of human disturbance. These lakes were divided among six groups: suburban reservoirs (SR), suburban high-aquaculture lakes (SH), suburban low-aquaculture lakes (SL), suburban no-aquaculture lakes (SN), urban aquaculture lakes (UA) and urban no-aquaculture lakes (UN). Spatially, water-column concentrations of Cd, Ni, Co, Mn, Fe, and Al, and sediment concentrations of Ni were significantly lower in SR compared to other lake groups. Except for Al, heavy metal concentrations did not differ between SN and SL lakes in the water-column or sediments. SH lakes exhibited significantly greater concentrations of Cu, Co, Cr, Mn, and Al in the water-column and Zn in sediments compared to SN lakes. UA lakes contained significantly lower concentrations of Zn, Cd, and Al in sediment compared to UN lakes, though no significant differences were detected within water-column samples. Temporally, with all lake groups combined, summer water-column concentrations of Cd, Pb, Co, Mn, and Al were lower compared to spring and autumn. Additionally, summer sediment concentrations of Zn, As, Co, Fe also were lower compared to autumn. Further results indicated that low-density fish stockings without external feed inputs appeared to have little impact on heavy metals in both suburban and urban lakes. However, high-density fish stockings with external feed inputs were associated with increased heavy-metal concentrations across all lakes. Overall, urbanization has great potential to increase sediment heavy-metal ecological risks. These findings are crucial for developing heavy-metal pollution control and management strategies for freshwater lakes.