Cement Paste Specimens Research Articles

Hydration and Mechanical Properties of Cement Kiln Dust-Blended Cement Composite

This study aims to investigate the effects of cement kiln dust (CKD) on the hydration reactions and mechanical properties of cement, and to evaluate its potential for use as a supplementary cementitious material (SCM). The key variables are the CKD type and the replacement ratio. Cement paste and mortar specimens containing CKD were prepared to examine their effects on the cement hydration and mechanical properties. The effect on hydration was assessed using setting time measurements, heat of hydration tests, and thermogravimetric analyses (TG). In addition, compressive strength tests were conducted to evaluate the effect of CKD on the mechanical properties of the cement. The results indicated that CKD promoted early-age cement hydration and enhanced the early-age mechanical properties. However, owing to its lack of pozzolanic reactivity, it did not significantly affect long-term hydration. Given that the effects of CKD vary slightly depending on its chemical composition, careful consideration of CKD’s properties suggests that its potential use as an SCM is promising.

Assessing cement paste strength evolution under curing: An experimental and numerical investigation through equivalent stiffness parameter identified by embedded piezo sensors

Equivalent stiffness is one of the most important mechanical parameters of any concrete structure which allows engineers to predict the behaviour of the structure. This paper identifies the equivalent stiffness parameter through an embedded piezo sensor (EPS) in the strength development of cement paste using the electro-mechanical impedance (EMI) technique through experimental and numerical investigation. The experiments were conducted on the cement paste specimens; and the compressive strength (destructively) and EMI response were obtained during curing process. Further, a numerical model of cement paste specimen with EPS is developed to validate the EMI response. In addition, an equivalent stiffness parameter is identified from the experimental and simulation EMI data. It is found that the variation in conductance signature during curing process and strength development is effectively captured by the EPS. The identified equivalent stiffness either calculated from experimental or simulation data followed a similar behaviour of the compressive strength.

Chemical and physical effects of the addition of thermochromic VO2 particles to cement

This work aims to deepen the knowledge of systems formed by cement and thermochromic vanadium dioxide particles. Cement paste specimens with 9 % addition of monoclinic VO2 particles show a significant delay of the hydration at early ages with respect to plain cement specimens, seemingly due to the partial inhibition of hydrates precipitation during the first 24 h of reaction. Upon further hydration, a re-activation of the hydration reactions gives rise to a higher mechanical strength and a more refined pore structure in the paste with VO2 addition at 28 days, attributed to the enhanced formation of C–S–H. The stability of the VO2 particles within the matrix is confirmed along the hydration process and provides the cement paste with the associated thermochromic behavior that is demonstrated by a change in the reflection in the near infrared wavelength range upon cooling from 70 °C. The results confirm the viability of producing VO2-based thermochromic cementitious materials for building envelopes. The next steps in their development should target the enhancement of the solar reflectance modulation in order to produce a significant impact in the energy efficiency of buildings and the urban overheating effect.

Effect of electrochemical treatment in mitigating OH− leaching from cement paste and its microscopic analysis at BSE imaging

The present study concerns the electrochemical treatment between steel embedment and an external mesh in mitigating OH− ion leaching from the cement paste into external water, which was ensured by a microscopic observation on the surface of the cement paste specimen at the backscattered electron (BSE) image analysis and by measuring the leaching rate for OH− ions with time. The electrochemical properties for the treatment included 1000 mA/m2 current density and 4 weeks duration. As a result, the pH at the electrochemical treatment in the external water accounted for 9.32 in the pH, while the untreated specimen indicated 13.46, implying a quite reduction of OH− ion leaching to a water environment. The porosity on the surface was reduced to lower the access of external water, while the decomposition of C–S–H gel was lowered. Due to the precipitation of Ca(OH)2, a further solidification of hydration phases could lower OH− ion leaching.

Acidification in cement paste in which clinker is partially replaced with limestone or silica

This paper examines the acid resistance of cement pastes where a portion of the cement clinker is replaced with limestone (LS or calcium carbonate, CaCO3) or ground silica (GS). Specifically, the work is intended to better understand the acid resistance of ASTM C595 IL cement as compared with ASTM C150 cement. The performance of OPC, OPC + GS, and OPC + LS systems were tested in sulfuric acid baths where the pH was held constant at 2.0 and 3.0 using an automated setup that uses titration to add acid. The degradation of the cement paste was measured as a function of time. Thermogravimetric analysis (TGA) was used to quantify changes in the calcium hydroxide (Ca(OH)2) and calcium carbonate (CaCO3) contents of the paste. In addition, the flexural strength of the cement paste specimens was measured. Results indicate that the dissolved sulfate and calcium concentrations due to acidification were not noticeably different for the OPC + GS and OPC + LS mixtures exposed to the same pH. However, as expected, differences were observed between the samples immersed in the solution of pH∼2 and pH∼3 sulfuric acid with the lower pH corresponding to more severe deterioration. TGA results showed that Ca(OH)2 is more susceptible to acid attack than limestone as evidenced by the larger Ca(OH)2 and sulfuric acid consumption in samples immersed at pH∼2. The additional acid consumption that is beyond the consumption of Ca(OH)2 can be explained by the acid attack of other hydration products such as CSH and unreacted cement phases. This results in a significant B3B flexural strength loss for the samples immersed in a pH∼2 as compared to those in the pH∼3 solution. The results demonstrated that the performance of ASTM C595 IL cements was promising and comparable with ASTM C150 cements.

Mechanical properties of nano-modified foamed cement paste

Foamed cement paste has been increasingly used as backfilling material in practice. The unique porous structure characteristic significantly influences the mechanical properties of foamed cement paste. This study conducted a series of laboratory tests to investigate the mechanical properties of nano-silica modified foamed cement paste. Foamed cement paste specimens with densities of 0.6 g/cm3 1.1 g/cm3 1.5 g/cm3 were prepared, incorporating nano-silica in varying concentrations from 1 g/L to 5 g/L. The density test and uniaxial compression test were conducted. The results show that the nano-silica improved the density inhomogeneity of the foamed cement paste and increased the peak strength. The optimal nano-silica content was 3 g/L in this study. This study offers a practical approach for enhancing the performance of foamed cement paste in engineering applications.

Mechanical properties and microstructural discrepancies of concrete with flotation-modified fly ash from circulating fluidized bed and pulverized coal furnaces

Fly ash (FA) is a by-product of coal-fired power generation in thermal power plants. Disparities in coal types and combustion furnaces result in varying levels of unburned carbon in FA, hindering its effective utilization. In this study, FA from a circulating fluidized bed furnace (CFBFA) and pulverized coal furnace (PCFFA) was modified using froth flotation technology, and the influence of the modified FA from the froth flotation process on the mechanical properties and microstructural discrepancy of concrete was analyzed through the preparation of mortar and cement paste specimens. The results indicated that the flotation process proved effective in reducing the unburned carbon content in FA, with modified PCFFA showing higher surface area and fluidity, opposite to CFBFA. Notably, the flotation process altered CFBFA's mineral content, reducing CaSO4·2 H2O from 26.6% to 7.5% and increasing CaSO4, enhancing hydration and strength in concrete applications. The optimal FA dosage was found to be 20%, with CFBFA specimens displaying superior compressive strength across all tests. Conversely, the modified PCFFA exhibited low activity, making it challenging to reach the desired strength after 28-d. This study serves as a theoretical foundation for the application of highly unburned carbon FA in construction engineering and promotes the circular development of FA resources.

Impact of internal pre-damage due to drying shrinkage under various humidity conditions on DEF expansion in cement paste and mortar

This study explores the impact of internal pre-damage from early drying shrinkage on the delayed ettringite formation (DEF) expansion behavior of cement-based materials subjected to high-temperature processes. Specimens of cement paste and mortar with water-cement (W/C) ratios of 0.4, 0.5, and 0.6 were characterized after curing under relative humidity (RH) conditions of 50, 70, and 100 for 56 days. The parameters assessed were drying shrinkage, dynamic elastic modulus, and free water content. Subsequent DEF expansion over time was quantified, and the underlying mechanism was analyzed using XRD and SEM techniques after 270 days of underwater curing. Results indicate that: (1) a lack of adequate early curing humidity significantly reduces the dynamic elastic modulus with more than a 10% drop in cement paste following 56 days at RH50; (2) a higher W/C ratio and lower early curing humidity lead to more internal damage due to shrinkage, thereby promoting DEF expansion; (3) drying intensifies internal pre-damage in the interfacial transition zone (ITZ), causing an earlier deterioration of DEF expansion in mortar compared to cement paste. However, the presence of aggregates constrains this, leading to lesser DEF expansion in mortar; (4) dynamic elastic modulus changes as measured by ultrasonic methods can quantitatively characterize the extent of deterioration caused by DEF expansion, thus offering a tool for non-destructive testing and DEF expansion deterioration analysis.

Beam-hardening correction method for quantifying moisture content in cement paste based on X-ray radiography

The X-ray spectrum changes while traveling through specimen, and this phenomenon, known as the beam-hardening effect, breaks the linear relationship between the intensity variety on radiographs and material thickness. In the detection of water transport in cement-based materials, this effect leads to inaccurate results of the quantitative moisture distribution inside the sample, and it is difficult to eliminate this effect by gravimetric calibration. To solve this problem, this paper proposed a calibration strategy for the attenuation coefficient curve of cement-water two-phase specimens, and provided a heuristic mathematical model for fitting the 2D attenuation coefficient surface of cement paste specimens. The experiments showed that for zones close to saturation, beam-hardening leads to an overestimation of moisture content, while for a zone with a low water content, the X-ray radiography results without correction tend to underestimate it. After correction, the method showed a quantitative result close to that of the gravimetric method, and maintained a good stability in samples of different thickness.

Exploring the Potential of Sr2+ for Improving the Post-Hardening Strength and Durability Characteristics of Cement Paste Composites

This study investigates the effects of strontium ions on enhancing the post-hardening strength and durability characteristics of hydrated cement composites, exploring their potential use as a rehabilitation method for aging concrete structures. A 30% strontium nitrate solution served as the source of strontium ions. Cement paste specimens with a water-to-cement ratio of 0.5, cured for 28 days, were submerged in the 30% strontium nitrate solution to facilitate strontium ion penetration. Compressive and flexural strength tests were conducted on the specimens and compared to those cured in deionized water. Moreover, the durability performance, including surface abrasion resistance, water sorptivity, and porosity, was examined. Scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), and X-ray diffractometry (XRD) analyses were also carried out to investigate the microscopic morphology and chemical characteristics of the specimens. Results indicated that the strontium-treated specimens exhibited notable enhancements in both compressive and flexural strengths, especially in flexural strength. The specimens also demonstrated improved surface abrasion resistance, decreased water absorption, and a marked reduction in porosity. SEM analysis revealed a densified microstructure in the strontium-treated cement paste specimens, and EDS and XRD analyses showed changes in their morphology and chemical compositions and structures, indicating the formation of new types of hydrates. Accordingly, this study suggests that the strontium ion treatment method has significant potential for the maintenance and restoration of aging cementitious materials.

Performance Assessment of Carbon Dioxide Sequestration in Cement Composites with a Granulation Technique.

The cement industry emits a significant amount of carbon dioxide (CO2). Therefore, the cement industry should recycle the emitted CO2. However, sequestration by carbonation in cement composites absorbs a very small amount of CO2. Therefore, a direct way of achieving this is to improve the absorption performance of CO2 in cement composites. In this study, to improve absorption, unlike in existing studies, a granulation technique was applied, and the material used was calcium hydroxide (CH). In addition, granulated CH was coated to prevent a reaction during the curing of cement paste. The coated CH granule (CCHG) was applied to 5% of the cement weight as an additive material, and the specimens were cured for 91 days to wait for the coating of CCHG to fully phase-change. The experiment of CO2 absorption showed an unexpected result, where the use of blast furnace slag (BFS) and fly ash (FA) had a negative effect on CO2 sequestration. This was because BFS and FA had a filler effect in the cement matrix, and the filler effect caused the blocking of the path of CO2. In addition, BFS and FA are well-known pozzolanic materials; the pozzolan reaction caused a reduction in the amount of CH because the pozzolan reaction consumed the CH to produce a calcium silicate hydrate. Therefore, the pozzolan reaction also had a negative effect on the CO2 sequestration performance combined with the filler effect. The CO2 sequestration efficiency was decreased between ordinary cement paste and BFS-applied specimens by 45.45%. In addition, compared to cases of ordinary cement paste and FA-applied specimens, the CO2 sequestration performance was decreased by 63.64%. Comprehensively, CO2 sequestration performance depends on the porosity and amount of CH.

Relationship between Chloride Migration, Bulk Electrical Conductivity and Formation Factor of Blended Cement Pastes

Abstract This study investigates the links between the non-steady-state chloride migration coefficient, the bulk electrical conductivity and the formation factor of blended cement paste specimens. 18 different binders were tested: two Portland cements (low- and high-alkali) in combination with limestone filler, fly ash, calcined clay, two biomass ashes, sewage sludge ash and crushed brick, as well as two Portland composite cements. In addition, the latter and the low-alkali Portland cement were tested in concrete as well for comparison. Mixes with high-alkali cement showed better resistance to chloride transport, and the effect of supplementary cementitious materials was found to be strongly linked with their reactivity. Moreover, the results showed a clear correlation of the migration coefficient with the bulk electrical conductivity and, to a lesser extent, with the formation factor. However, these relationships are strongly influenced by the methods used to determine conductivities and they need to be validated for higher maturities. Finally, the results suggested a fairly good correspondence between the results obtained on paste and concrete.

Monitoring Tools and Strategies for Effective Electrokinetic Nanoparticle Treatment

Nanoparticles are increasingly being used by industry to enhance the outcomes of various chemical processes. In many cases, these processes involve over-dosages that compensate for particle losses. At best, these unique waste streams end up in landfills. This circumstance is inefficient and coupled with uncertain impacts on the environment. Pozzolanic nanoparticle treatments have been found to provide remarkable benefits for strength restoration and the mitigation of durability problems in ordinary Portland cement and concrete. These treatments have been accompanied by significant particle losses stemming from over-dosages and instability of the colloidal suspensions that are used to deliver these materials into the pore structure. In this study, new methods involving simple tools have been developed to monitor and sustain suspension stability. Turbidity measurement was introduced to monitor the progress of electrokinetic nanoparticle treatment. This tool made it possible to amend a given dosing strategy in real time while it remains possible to make effective treatment adjustments. By monitoring the particle stability and using pH and electric field controls to avoid suspension collapse, successful electrokinetic treatment dosage strategies were demonstrated using 20 nm NALCO 1056 alumina-coated silica particles. These trials indicated that turbidity measurements could track the visually imperceptible phenomena of particle flocking early on at the inception of its development. Suspensions of these nanoparticles were successfully delivered into 5 cm diameter by 10 cm tall hardended cement paste (HCP) specimens by monitoring fluid turbidity along with the specific gravity and using these values to guide the active management of the treatment dosage and pH. Under this new strategy, these losses were reduced to 5% as compared to the 80% losses associated with other treatment approaches. The relationship between the turbidity and the specific gravity was found to be linear. These plots indicated regions of turbidity and specific gravity that were associated with particle flocking. The tools, guidelines, and strategies developed in this work made it possible to manage efficient (low-particle-loss) electrokinetic nanoparticle treatments by signaling in real time when adjustments to electric field, pH, and particle dosage increments were needed.

Investigating icing behavior in cementitious material during freeze–thaw using low-temperature low-field NMR

Low-temperature low-field nuclear magnetic resonance was applied to analyze the icing amount in water saturated white cement paste specimens at different temperatures during the freeze–thaw process. An innovative cylindrical specimen shape eliminated temperature gradients and enabled real-time monitoring of icing. The experimental results were compared with the results obtained using classical theory, showing good agreement from 0 °C to −8 °C but notable differences from −8 °C to −18 °C. Therefore, experimental data from specimens saturated with pure water, a 4 % salt solution, and an 8 % salt solution were analyzed to obtain the freezing probability according to pore size classification, and new equations were proposed on this basis to relate the volume of frozen water to temperature during the freezing and thawing of cementitious materials.

Study on Frost Resistance and Interface Bonding Performance through the Integration of Recycled Brick Powder in Ultra-High-Performance Concrete for Structural Reinforcement

This study aims to address the issues posed by frost damage to concrete structures in cold regions, focusing on reinforcement and repair methods to increase the service life of existing structures instead of costly reconstruction solutions. Due to the limitations of conventional concrete in terms of durability and strength, this research focused on ultra-high-performance concrete (UHPC) by replacing part of the cement with recycled brick powder (RBP) to strengthen ordinary C50 concrete, obtaining UHPC-NC specimens. Mechanical tests investigated the bonding performance of UHPC-NC specimens under various conditions, including interface agents, surface roughness treatments, and freeze–thaw after 0, 50, 100, and 150 cycles with a 30% replacement rate of RBP. Additionally, a multi-factor calculation formula for interface bonding strength was established according to the test data, and the bonding mechanism and model were analyzed through an SEM test. The results indicate that the interface bonding of UHPC-NC specimens decreased during salt freezing compared to hydro-freezing, causing more severe damage. However, the relative index of splitting tensile strength for cement paste specimens showed increases of 14.01% and 14.97%, respectively, compared to specimens without an interface agent. Using an interface agent improved bonding strength and cohesiveness. The UHPC-NC bonding model without an interfacial agent can be characterized using a three-zone model. After applying an interfacial agent, the model can be characterized by a three-zone, three-layer bonding model. Overall, the RBP-UHPC-reinforced C50 for damaged concrete showed excellent interfacial bonding and frost resistance performance.

Chemical Mechanisms Involved in the Coupled Attack of Sulfate and Chloride Ions on Low-Carbon Cementitious Materials: An In-Depth Study

This study aims to analyze the individual and combined chemical attacks of sulfate and chloride ions on cementitious materials and assess the efficiency of some selected additives (fly ash, blast furnace slag, and metakaolin) in countering this combined attack. This research is conducted in the context of construction in marine environments, where reinforced concrete structures are often subject to significant challenges due to early exposure to sulfate and chloride ions. This early exposure results in concrete expansion, cracking, and, ultimately, the corrosion of steel reinforcements. Nevertheless, the interaction between sulfate ions, chloride ions, and the cementitious matrix remains poorly understood. Previous research has drawn conflicting conclusions, with some suggesting that sulfate ions mitigate chloride attacks, while others have come to the opposite conclusion. During this study, experimental investigations were conducted by immersing powders obtained from crushed ordinary Portland cement (CEM I) paste specimens, as well as binary, ternary, and quaternary blends, in sulfate, chloride, and sulfate–chloride solutions over the course of 25 days at an early age. Results from different characterization techniques (thermogravimetric analysis, Fourier Transform Infrared spectroscopy, Raman spectroscopy, etc.) indicate that chloride ions delay the formation of ettringite, while the presence of sulfate ions accelerates the chloride attack by limiting the formation of Friedel’s salt. The Mercury Intrusion Porosimetry test confirmed these results by showing a pronounced increase in specimens’ porosity after exposure to solely sulfate after 25 days, compared to the ones exposed to both sulfate and chloride ions. Furthermore, the incorporation of multiple additives, particularly in ternary and quaternary blends, demonstrates the enhanced durability of the studied samples. This was confirmed by a Fourier Transform Infrared spectroscopy analysis, which indicated a delayed ettringite formation in these mixtures. This delay was further affirmed by the complete depletion of sulfate ions in the sulfate solutions upon contact with powders derived from the 100% CEM I paste.

Research on the creep properties of cement paste after microwave pre-curing based on indentation test

This article researched the influence of microwave pre-curing on the creep properties of cement pastes. Microwave pre-curing with different durations was performed on cement paste specimens after standard cured for 3 d. Subsequently, the creep performance of the cement paste and the phase was acquired using indentation tests. The quantitative analysis of the phase was performed on the cement paste specimens after microwave pre-curing. The reasons for the variation of creep properties of the specimens affected by microwave pre-curing were also analyzed based on the pore characteristics, gel structure, and dielectric properties. The results indicated that the creep modulus of cement paste samples gradually increased with the increase of microwave pre-curing time. Microwave pre-curing significantly enhanced the contact creep modulus (CCM) of low-density (LD) C–S–H gel and high-density (HD) C–S–H gel. With the increase of microwave pre-curing time, the porosity in the samples decreased and the pore structure was significantly improved. Microwave pre-curing decreased the percentage of LD C–S–H gel and significantly increased the percentage of HD C–S–H gel, and also increased the complex structure of C–S–H gel. Microwave pre-curing enhanced the dielectric performance of paste specimens and increased their ability to store and absorb electromagnetic waves.

Electrochemical treatment to arrest OH− leaching from cement paste in an aquatic environment

The present study concerns a mitigation of OH− leaching in the cement paste immersed in external water by applying the electrochemical treatment, prior to an exposure to external water. The cement paste specimen was fabricated and exposed to an aquatic environment under air-tight condition. The OH− leaching took place significantly for the first 24 h, followed by a further leaching of OH− ions. As for the electrochemical treatment, an increase in the current density and duration of the treatment resulted in a decrease in the OH− leaching. In particular, the OH− leaching was dramatically reduced at 1000 mA/m2 for 4 weeks. The cumulative OH− concentration leached from the cement matrix accounted for only 1.40 × 10−6 mol/l in 100 days monitoring, whilst untreated specimen leached 0.29 mol/l OH− ions in external water. Moreover, the pH profile in the cement paste indicated the higher alkalinity at electrochemical treatment.

Internal curing mechanism of zeolite pretreated with NaCl under microwave and ultrasonic conditions

Natural zeolite has been used for internal curing to reduce shrinkage of cement-based materials, but the internal curing performance of zeolite needs to be improved. In this study, natural zeolite particles were modified by NaCl solution under conditions of microwave and ultrasonic to improve their internal curing performance. Firstly, the pore structure, chemical bond characteristics, pozzolanic activity, water absorption and water release performance of the modified zeolite were tested. Then, cement paste specimens internally cured with modified zeolite were prepared, the shrinkage, hydration products, and pore structure were tested, and the internal curing mechanism of modified zeolite was discussed. The results show that: (1) Pozzolanic activity of zeolite decreases after NaCl-microwave modification, but increases after NaCl-ultrasonic modification. (2) NaCl modification increases the pore volume and water adsorption of natural zeolite particles. (3) NaCl modified zeolite promotes the formation of ettringite in cement paste, especially for NaCl-microwave modified zeolite. (4) NaCl-microwave modified zeolite has better shrinkage reducing effect and strength improving effect than natural zeolite and NaCl-ultrasonic modified zeolite.

Deterioration of Cement-Based Materials in Low-Temperature Seawater.

Cementitious materials have potential for infrastructure development in low-temperature marine environments, including in seawater at high latitudes and in deep-sea environments (water depths of >1000 m). Although the marine deterioration of cementitious materials has been widely investigated, the influence of seawater temperature has not been elucidated. In this study, to determine the effects of low-temperature seawater on the durability of cementitious materials, cement paste specimens were immersed in a seawater tank at room temperature and 2 °C for 433 days. The specimen immersed in low-temperature seawater exhibited significant deterioration with a partially collapsed surface, whereas the specimen immersed in room-temperature seawater maintained its original shape. Following low-temperature immersion, Ca dissolution was more pronounced and dissolved portlandite, decalcified calcium (alumino)silicate hydrate (C-(A-)S-H), magnesium (alumino)silicate hydrate (M-(A-)S-H), and thaumasite were observed on the collapsed surface. Such significant deterioration can be attributed to the increased solubility of portlandite under low-temperature conditions, which could promote Ca dissolution and subsequently lead to C-(A-)S-H decalcification and the formation of M-(A-)S-H and thaumasite. These insights are expected to contribute to the successful construction and maintenance of cementitious structures in low-temperature seawater.