Exploring the Potential of Sr2+ for Improving the Post-Hardening Strength and Durability Characteristics of Cement Paste Composites

Abstract

This study investigates the effects of strontium ions on enhancing the post-hardening strength and durability characteristics of hydrated cement composites, exploring their potential use as a rehabilitation method for aging concrete structures. A 30% strontium nitrate solution served as the source of strontium ions. Cement paste specimens with a water-to-cement ratio of 0.5, cured for 28 days, were submerged in the 30% strontium nitrate solution to facilitate strontium ion penetration. Compressive and flexural strength tests were conducted on the specimens and compared to those cured in deionized water. Moreover, the durability performance, including surface abrasion resistance, water sorptivity, and porosity, was examined. Scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), and X-ray diffractometry (XRD) analyses were also carried out to investigate the microscopic morphology and chemical characteristics of the specimens. Results indicated that the strontium-treated specimens exhibited notable enhancements in both compressive and flexural strengths, especially in flexural strength. The specimens also demonstrated improved surface abrasion resistance, decreased water absorption, and a marked reduction in porosity. SEM analysis revealed a densified microstructure in the strontium-treated cement paste specimens, and EDS and XRD analyses showed changes in their morphology and chemical compositions and structures, indicating the formation of new types of hydrates. Accordingly, this study suggests that the strontium ion treatment method has significant potential for the maintenance and restoration of aging cementitious materials.