Cotton Cellulose Fibers Research Articles

Studies on the effect of reactive dye on jute and jute blended fabrics

Jute is generally not dyed with reactive dye though it is a cellulosic fiber. While jute is dyed with basic dye, but cotton, viscose, and other cellulosic fibers are frequently dyed with reactive dye. In this study, a novel method for dying blended jute fabrics with reactive dye after bleaching them is presented. Two different reactive dye colors were used to treat this blended jute fabric. By contrasting samples of non-dyed grey blended jute fabric, the GSM, Water uptake percentage, and FTIR of dyed fabric were examined. It has been observed that the dyed sample's GSM (average 76) is higher than the grey fabrics GSM (average 65) due to the chemical modification of grey blended jute fabric. Blended jute fabric has a lower water absorption percentage while dyed sample has a higher absorption percentage such as 150% in 40 min and 145% in 140 min. Due to chemical modification of the surface of the blended jute fabrics, the FTIR spectrum report reveals that –OH group peak appeared in the wave number of 3291 cm−1 and the dyeability of the fabric is significant based on peak analysis.

Application of dynamic image analysis to the optical characterisation of fibrous bulk material

Dynamic image analysis provides an automated evaluation method to determine the size and shape of multiple particles. This method represents a common application for ordinary bulk material. The latest draft of ISO 13322–2:2021 describes the state of the art, but lacks instructions for handling fibrous bulk material. Interlocking fibres complicate the measurement conditions and require a disentanglement of fibrous samples during a pre-dispersion step. A further error source includes the fibre orientation inside the measurement zone of the device. If the thresholding algorithm fails to differentiate between the fibre projection area and the background, a subsequent image optimisation solves the problem. This article addresses the mentioned problems by analysing cotton cellulose and polyacrylonitrile fibres. Besides the execution of a pre-dispersion step, the experiments compare the discrepancies between dry and wet dispersion. Here, the software packages PAQXOS and ImageJ perform the image evaluation. In this case, the wet dispersion setup with a subsequent image evaluation by ImageJ provides comprehensible results.

Comparative Analysis of Non cotton Cellulose Fiber Extracted from Banana variety

Comparative Analysis of Non cotton Cellulose Fiber Extracted from Banana variety

Nano GeSe2/C anchored in carbon sponge skeleton for free-standing flexible lithium-ion battery electrodes

As a typical conversion alloyed anode material, Germanium selenide (GeSe2) exhibits isotropic lithiation behavior and high theoretical charge-discharge specific capacity. However, pure GeSe2 anode faces significant volume expansion (∼250 %−360 %) and further exploration is needed in the preparation of flexible electrode materials and structural design. Herein, a simple strategy is designed to load GeSe2/C-2 nanoparticles with porous carbon-coated structure on a flexible cross-networking substrate. The 3D network substrate is composed of highly conductive carbon nanotubes and adhesive cotton cellulose fibers. A two-step method involving coating and cross-linking is designed to achieve the fabrication of self-supporting flexible electrodes. As an anode for LIBs, the one layer GeSe2 discs with ∼0.65 mm thickness manifest capacities of 827.1, 744.4, 676.3, and 472.9 mAh g−1 at 0.1, 0.2, 0.5, and 1 A g−1, respectively. This superior Li+ storage performance can be attributed to the positive collective impact from the integration of nano-scale material, low crystalline properties, and carbon sponge skeleton. Furthermore, the GITT tests indicate that the diffusion coefficient of Li+ in the GeSe2-based electrodes ranged from 10−15 to 10−12 cm2/s, and the thickness of the flexible electrode (including two layers) has a negligible impact on its electrochemical performance.

Probe sonicated cotton cellulose fibers treated with bone conditioned medium for optimum cell growth and mineralization

Probe sonicated cotton cellulose fibers treated with bone conditioned medium for optimum cell growth and mineralization

Optimized Lytic Polysaccharide Monooxygenase Action Increases Fiber Accessibility and Fibrillation by Releasing Tension Stress in Cellulose Cotton Fibers.

Lytic polysaccharide monooxygenase (LPMO) enzymes have recently shaken up our knowledge of the enzymatic degradation of biopolymers and cellulose in particular. This unique class of metalloenzymes cleaves cellulose and other recalcitrant polysaccharides using an oxidative mechanism. Despite their potential in biomass saccharification and cellulose fibrillation, the detailed mode of action of LPMOs at the surface of cellulose fibers still remains poorly understood and highly challenging to investigate. In this study, we first determined the optimal parameters (temperature, pH, enzyme concentration, and pulp consistency) of LPMO action on the cellulose fibers by analyzing the changes in molar mass distribution of solubilized fibers using high performance size exclusion chromatography (HPSEC). Using an experimental design approach with a fungal LPMO from the AA9 family (PaLPMO9H) and cotton fibers, we revealed a maximum decrease in molar mass at 26.6 °C and pH 5.5, with 1.6% w/w enzyme loading in dilute cellulose dispersions (100 mg of cellulose at 0.5% w/v). These optimal conditions were used to further investigate the effect of PaLPMO9H on the cellulosic fiber structure. Direct visualization of the fiber surface by scanning electron microscopy (SEM) revealed that PaLPMO9H created cracks on the cellulose surface while it attacked tension regions that triggered the rearrangement of cellulose chains. Solid-state NMR indicated that PaLPMO9H increased the lateral fibril dimension and created novel accessible surfaces. This study confirms the LPMO-driven disruption of cellulose fibers and extends our knowledge of the mechanism underlying such modifications. We hypothesize that the oxidative cleavage at the surface of the fibers releases the tension stress with loosening of the fiber structure and peeling of the surface, thereby increasing the accessibility and facilitating fibrillation.

Fast extraction of vanadyl ion using grafted cotton fiber inserted with amidoxime moiety

Egyptian cotton cellulose fibers have been adapted by graft copolymerization of polyacrylonitril (PAN) and then by ingestion of amidoxime moiety to finally generate C-AXO chelating fibers, which have been characterized by various instrumental techniques such as SEM, FTIR, EDX and XRD spectra. Using batch tests, the obtained C-AXO is used for removal and extraction of VO2 + from its aqueous solution. The kinetic studies have shown that the pseudo second-order model is the best fit for the experimental data.

Biodegradable cotton fiber-based piezoresistive textiles for wearable biomonitoring

Electronic textiles are fundamentally changing the way we live. However, the inability to effectively recycle them is a considerable burden to the environment. In this study, we developed a cotton fiber-based piezoresistive textile (CF p-textile) for biomonitoring which is biocompatible, biodegradable, and environmentally friendly. These CF p-textiles were fabricated using a scalable dip-coating method to adhere MXene flakes to porous cotton cellulose fibers. The adhesion is made stronger by strong hydrogen bonding between MXene flakes and hierarchically porous cotton cellulose fibers. This cotton-fiber system provides a high sensitivity of 17.73 kPa−1 in a wide pressure range (100 Pa–30 kPa), a 2 Pa subtle pressure detection limit, fast response/recovery time (80/40 ms), and good cycle stability (over 5, 000 cycles). With its compelling sensing performance, the CF p-textile can detect various human biomechanical activities, including pulsation, muscle movement, and swallowing, while still being comfortable to wear. Moreover, the cotton cellulose is decomposed into low-molecular weight cellulose or glucose as a result of the 1,4-glycosidic bond breakage when exposed to acid or during natural degradation, which allows the electronic textile to be biodegradable. This work offers an ecologically-benign, cost-effective and facile approach to fabricating high-performance wearable bioelectronics.

Evaluation of Photoelectrocatalysis with Electrode Based on Ti/RuO2-TiO2 Modified with Tin and Tantalum Oxides for the Degradation of Indigo Blue Dye.

Indigo Blue (IB) is a dye widely used by the textile sector for dyeing cellulose cotton fibers and jeans, being considered a recalcitrant substance, and therefore resistant to traditional treatments. Several methodologies are reported in the literature for the removal or degradation of dyes from the aqueous medium, among which photoelectrocatalysis stands out, which presents promising results in the degradation of dyes when a dimensionally stable anode (DSA) is used as a photoanode. In the present work, we sought to investigate the efficiency of a Ti/RuO2-TiO2 DSA modified with tin and tantalum for the degradation of Indigo Blue dye by photoelectrocatalysis. For this, electrodes were prepared by the thermal decomposition method and then a physical-chemical and electrochemical analysis of the material was carried out. The composition Ti/RuO2-TiO2-SnO2Ta2O5 (30:40:10:20) was compared to Ti/RuO2-TiO2 (30:70) in the photocatalysis, electrocatalysis, and photoelectrocatalysis tests. The photocatalysis was able to degrade only 63% of the IB at a concentration of 100 mg L-1 in 3 h, whereas the electrocatalysis and photoelectrocatalysis were able to degrade 100% of the IB at the same initial concentration in 65 and 60 min, respectively.

Impact of Cover Crops and Nitrogen on Cotton Fiber Cellulose and Quality Traits

ABSTRACT Fiber quality varies depending on the fruit position of the cotton plant. Nitrogen (N) availability can alter fruiting dynamics and, consequently, fiber quality. The current study evaluated the effect of cover crops and N availability on cellulose content and fiber quality in different plant positions. The experiment was carried out in Presidente Bernardes, São Paulo, Brazil. Experiment design was a split-plot in completely randomized block design with five replicates. Cover crops were allocated: Fallow (F), Velvet bean (VB), Ruzigrass (Urochloa ruziziensis) (R), Inoculated ruzigrass (IR) (Azospirillum), Ruzigrass + velvet bean (R+VB) and Inoculated ruzigrass + velvet bean (IR+VB); and N rates (80 and 120 kg ha−1) in the sub-plots. Cellulose content in the lower, middle, and upper third of the plants were evaluated at 15 and 30 days after anthesis (DAA) and at harvest. At 15 and 30 DAA, the cellulose content was higher in the lower third in most treatments, except in the treatment with ruzigrass (120 N), which was higher in the upper third. Fibers with higher quality and final cellulose content are in the lower parts of the plant, and IR+VB improved fiber quality by providing applications with lower rates of N.

Biomass-based indole derived composited with cotton cellulose fiber integrated as sensitive fluorescence platform for NH3 detection and monitoring of seafood spoilage

Herein, an indole-derived water-soluble fluorescence nanomaterial and biomass-based cellulose filter paper integrated as solid-state fluorescence platform (H2-FP) for seafood spoilage detection was prepared. H2 exhibits high fluorescence stability and good biocompatibility with green beans, onion tissues, blood and zebrafish, which proving that H2 has a wide range of application scenarios. Further, H2-FP with effective, solid-state fluorescence, portable, and reusable characteristics is nanoengineered for NH3 quantitative and qualitative detection (DOL = 2.6 ppm). Then, H2-FP has been successfully used to monitor NH3 release in the seafood spoilage process at various storage time (4 °C and 25 °C). More importantly, fluorescence color of H2-FP is integrated smartphone are converted to digital values through RGB channels and successfully used to visualize semi-quantitative recognition of NH3. This sensing fluorescence platform integrated with smartphone furnishes an effective fabrication strategy and broad prospects for explore various biomass-based materials for sensing NH3 change in biological and environmental samples.

Features of water vapor sorption by cellulose materials

In this research, the sorption of water vapor (WV) by various cellulose samples (microcrystalline cellulose, cotton cellulose, Kraft pulp, mercerized cellulose, and rayon fibers) has been studied. The sorption isotherms of WV for various samples have a sigmoid shape. To describe such isotherms, various models have been proposed, including mono- and multimolecular adsorption, formation of hydrates and solid solutions, as well as mixed models combining various sorption mechanisms. After critical analysis of known models, the improved absorption model was proposed to explain the interaction of VW with cellulose samples. It was confirmed that crystallites are inaccessible for water, and therefore water molecules can be trapped only by polar groups of non-crystalline (amorphous) domains of cellulose materials. The developed model permitted obtaining the general absorption isotherm of water molecules in amorphous domains of cellulose. Moreover, the equation was derived, which describes both the general isotherm and isotherm of any semi-crystalline cellulose sample, when its crystallinity or amorphicity degree was pre-determined. Based on the proposed absorption model, various characteristics can be found, e.g., degrees of amorphicity and crystallinity, the maximum amount of absorbed water, the specific surface area of wet cellulose sample, the amount of capillary condensed water, etc.

Cryogenic grinding of cotton fiber cellulose: The effect on physicochemical properties

The study evaluated the effect of cryogrinding, a relatively new, cost-effective, and sustainable mechanical treatment method, on physicochemical properties of two different micronaire (3.6- and 5.3-) cotton fiber cellulose. Native (type I), mercerized (type II), and acidulated cellulose were subjected to cryogrinding for 48 and 96 min, and their physicochemical properties were investigated. The results demonstrated that cryogrinding resulted in partial amorphization of native and mercerized celluloses, particle size decrease, and a slight reduction of T50%. Importantly, degree of polymerization (DP) of native cellulose reduced significantly: more than two-fold after 12 cycles and more than three-fold after 24 cycles of cryogrinding. No difference in properties was found between 3.6- and 5.3-micronaire cellulose. Advantageous impacts of cryogrinding found in this work will help signify the potential of this technique in cellulose processing and enable the identification of areas for future development.

The DUF288 domain containing proteins GhSTLs participate in cotton fiber cellulose synthesis and impact on fiber elongation

Cotton is one of the most important economic crops in the world, with over 90 % cellulose in the mature fiber. However, the cellulose synthesis mechanism in cotton fibers is poorly understood. Here, we identified four DUF288 domain containing proteins, which we designated GhSTL1-4. These four GhSTL genes are highly expressed in 6 days post anthesis (dpa) and 20 dpa cotton fibers. They are localized to the Golgi apparatus, and can rescue the growth defects in primary cell wall (PCW) and secondary cell wall (SCW) of cellulose synthesis of the Arabidopsis stl1stl2 double mutant at varying degrees. Silencing of GhSTLs resulted in reduced cellulose content and shorter fibers. In addition, split-ubiquitin membrane yeast two-hybrid analysis showed that GhSTL1 and GhSTL4 can interact with PCW-related GhCesA6-1/6-3 and SCW-associated GhCesA7-1/7-2. GhSTL3 can interact with SCW-related GhCesA4-3. These interactions are further confirmed by firefly luciferase complementation imaging assay. Together, we demonstrate that GhSTLs can selectively interact with both the PCW and SCW-associated GhCesAs and impact on cellulose synthesis and fiber development. Our findings provide insights into the mechanism underlying cellulose biosynthesis in cotton fibers, and offer potential candidate genes to coordinate PCW and SCW cellulose synthesis of cotton fibers for developing elite cotton varieties with enhanced fiber quality.

The preparation and characterization of chemically deuterium incorporated cotton fibers

Preparation of deuterium incorporated cellulose is a vital tool to investigate cellulose internal structure and to expand the application fields of cellulose materials. In this study, cellulosic cotton fibers with anti-rehydration (exchange-resistant) deuterium incorporated in cellulose were prepared by chemical hydrogen–deuterium exchange treatment. The chemical hydrogen–deuterium exchange process, along with exchange time, were characterized by nuclear magnetic resonance hydrogen spectroscopy (1H-NMR). The anti-rehydration deuterium incorporation was determined by Fourier Transform infrared spectroscopy (FTIR) and Stable Isotope Ratio Mass Spectrometer (IRSM). The effect of the deuterium hydroxyl substitution on cotton fiber’s spectral data, microstructure, crystalline information, degree of polymerization, as well as it’s thermogravimetric analysis (charcoalization and combustion) are explored. Analysis of the chemical exchange process indicated that the hydrogen–deuterium exchange occurred preferentially in the amorphous cellulose component over the first several minutes. Deuterium exchange in the anti-rehydration crystalline phase took several hours. Increasing the treatment time, enhanced exchange-resistant deuterium incorporation to as high as about 60% of the cotton fibers’ cellulose hydroxyl groups was achieved. The characterization of FTIR, Fourier transform Raman (FT-Raman), and near-infrared spectra (NIR) all exhibited the deuterium spectral isotope effect on cellulose hydroxl groups. While, apart from the effect of reaction temperature, deuterium incorporation isotope effect did not affect the cellulose microstructure, crystalline index and the degree of polymerization properties. Furthermore, the thermogravimetric analysis of deuterated cotton fibers under N2 and air atmosphere were both altered due to the thermodynamic isotope effect. These observations revealed the hydrogen–deuterium exchange treatment process and impacts on cellulose fiber properties, which helped us to better understand the cellulose internal structure and may facilitate the potential utilization of deuterated cellulosic materials.

Polydopamine-modified interface improves the immobilization of natural bioactive-dye onto textile and enhances antifungal activity.

Dermatomycosis, such as candidiasis and mycosis among others, has emerged recently as the most frequent fungal infection worldwide. This disease is due to the skin's exposure to microorganisms that are able to pass through skin barrier defects. Therefore, textiles in direct contact with skin can serve as a source of contamination and fungus spread. In the current study, a sustainable and eco-friendly method for antifungal cotton finishing using Curcuma longa L extracted from rhizomes was investigated. To enhance the natural bioactive dye uptake and attachment, cellulosic cotton fibers were chemically modified using dopamine, a biocompatible molecule, leading to the deposition of a hydrophilic layer of polydopamine. The efficiency of the polydopamine coating on the cotton surface has been assessed by x-ray photoemission spectroscopy analyses, with the detection of nitrogen, and by water contact angle for the wettability enhancement. Furthermore, characterization of the modified samples confirms that the modification did not affect either the cellulosic fiber morphology or the mechanical properties. The dyeability and bioactive dye immobilization were then assessed by colorimetry. Finally, the effectiveness of the finished fabrics against Trichophyton (rubrum/mentagrophytes) and Candida albicans strains was evaluated and was shown to induce growth inhibition mainly on Candida albicans strains.

Rheological Behavior of Nanocellulose Aqueous Suspensions

The rheological properties of aqueous suspensions of spherical and needle-shaped nanocellulose particles in the range of 25–70°C are compared. Nanocellulose samples are obtained by the acid hydrolysis of cotton cellulose fibers in H2SO4 (61–65%) at 25–45°C. The shape of nanocellulose particles affects the yield strength and non-Newtonian character of the suspension flow. In the shear stress region above 100 Pa, a decrease in effective viscosity occurs, depending on the shape of the particles and the temperature of the suspension. In the region of the shear rate close to the yield strength, the activation energy of the viscous flow of suspensions of spherical particles is 12 kJ/mol; needle-shaped particles, 18 kJ/mol. Features of the rheological behavior are due to the fact that spherical particles are involved mainly in rotational-translational motion, while the needle-like particles are oriented in the direction of flow.

Simulation and optimization of combined acid pretreatment and enzymatic saccharification of medical cotton waste

The purpose of the present study was to develop an efficient, cost-effective process towards the valorization of medical cotton waste (MCW). Application of dilute acid pretreatment as an initial step partially degrades the cotton cellulosic fibers rendering the material more amenable to enzymatic hydrolysis towards the production of glucose. MCW was treated with sulfuric acid, in a batch autoclave, at various temperature conditions. An experimental design was set up and applied to study cotton’s behavior to acid hydrolysis. The pretreatment process variables included temperature, time, and sulfuric acid concentration targeting maximal cellulose recovery and enzymatic saccharification yields. The results showed a maximum cellulose conversion to glucose of 95.6% wt. after pretreatment at 220 °C with 22.5 mM acid concentration. To the best of our knowledge, this is the first report in the literature suggesting a treatment process for the utilization of MCW as a source of fermentable sugars.

Flexible and Pressure-Responsive Sensors from Cellulose Fibers Coated with Multiwalled Carbon Nanotubes

Composite cellulose-based materials have shown increasing potential in wearable and flexible hybrid electronics for large-scale deployment because of their flexible, cost-effective, abundant, and biodegradable features. A flexible cotton cellulose-incorporated multiwalled carbon nanotube (MWCNT) based pressure sensor was fabricated. First, the cotton cellulose fibers were swelled in water solution containing sodium hydroxide and urea. Second, the MWCNTs were dispersed uniformly in the cellulosic matrix. Then, cellulosic pressure sensors were formed with a water bath process. The porous and interlaced conductive networks in the pressure sensors containing 10 wt % of MWCNTs exhibited a sensitivity about of −0.0197 kPa–1, a response time of about 20 ms, a recovery time of about 20 ms, and a wide workable pressure range from 0 to 20 kPa. Further, the practical piezoresistivity of sensor specimens was investigated. The proposed pressure sensors are prospective for various applications including smart clothing,...

Chitosan coated cellulose cotton fibers as catalyst for the H2 production from NaBH4 methanolysis

Cellulose cotton fibers (CF) are coated with chitosan (CH) by simple, economic, and environmental friendly method. The CFs are kept in aqueous acetic acid solution to protonate the fibers before coated with CH solution (1.5% w/v in acetic acid aqueous solution (20% v/v)), represented as CF-A-CH. These materials are characterized by ATR-FTIR, XRD, FE-SEM and EDS which shows the successful coating of the CH on the CF surface. The prepared materials are exploited as an effective catalyst for the production of hydrogen (H2) from NaBH4 methanolysis reaction. In addition, other polymers (gelatin and agarose) and surfactants (brij-56, pluronic F-127 and urea) as well as CH in solution form are testified as catalyst for NaBH4 methanolysis reaction. High generation rate (8 times) and increase in amount of H2 (150 mL) is observe using only 50 μL CH solution. Furthermore, influences of various constraints, which affect the H2 production, like catalyst types, catalyst amount, NaBH4 amount, effect of temperature are also explored. A low activation energy (Ea), almost 14.41 ± 0.46 kJ mol−1 is calculated for NaBH4 methanolysis reaction in presence of CF-A-CH at temperature range 0 °C - 45 °C. Moreover, the catalyst reusability is also analyzed and no decline in percent conversion is found, whereas a little reduction in percent performance is detected after every cycle and only 18% lost is observed in its percent activity after completion of five successive cycles.