Energy Conversion Efficiency Of Cells Research Articles

Highly active and stable oxygen electrode PrBaCo2O5+δ-Ba2CoWO6 enabled by In Situ formed misfit dislocation interface for reversible solid oxide cell

The energy conversion efficiency and durability of the reversible solid oxide cell (RSOC) is restricted by the development of highly active and stable oxygen electrode. Herein, an in-situ formed composite PrBaCo2O5+δ-Ba2CoWO6 oxygen electrode is proposed, which consists of a highly active A-site double perovskite (A-DP) phase and a stable B-site double perovskite (B-DP) phase. Misfit dislocation interface is formed between these two phases, exerting lattice tensile stress on the A-DP phase, which enhances catalytic activity and inhibits Ba segregation. Additionally, the B-DP phase suppresses lattice expansion of A-DP phase through the dislocation interface, thereby improving thermo-mechanical stability. Consequently, the composite electrode demonstrates a low polarization resistance of 0.056 Ω cm2 at 650 °C, impressive stability at 650 °C for 500 h in symmetrical cell tests, and excellent thermal-mechanical stability under 29 thermal cycles. A maximum power density of 0.75 W cm−2 and an electrolysis current density of 0.84 A cm−2 at 1.3 V were achieved at 650 °C by the composite electrode on a 260 μm-electrolyte supported cell configuration, which surpass most of the reported oxygen electrode materials. Furthermore, the cell exhibits excellent operational stability, with low degradation rates of 0.49 × 10−1 mV h−1 and 1.5 × 10−1 mV h−1 in fuel cell and electrolysis cell modes, respectively. This work offers an effective method for designing highly active and stable oxygen electrodes for RSOCs.

Strain-Prompted Giant Flexo-Photovoltaic Effect in Two-Dimensional Violet Phosphorene Nanosheets.

As a second-order nonlinear optical phenomenon, the bulk photovoltaic (BPV) effect is expected to break through the Shockley-Queisser limit of thermodynamic photoelectron conversion and improve the energy conversion efficiency of photovoltaic cells. Here, we have successfully induced a strong flexo-photovoltaic (FPV) effect, a form of BPV effect, in strained violet phosphorene nanosheets (VPNS) by utilizing strain engineering at the h-BN nanoedge, which was first observed in nontransition metal dichalcogenide (TMD) systems. This BPV effect was found to originate from the disruption of inversion symmetry induced by uniaxial strain applied to VPNS at the h-BN nanoedge. We have revealed the intricate relationship between the bulk photovoltaic effect and strain gradients in VPNS through thickness-dependent photovoltaic response experiments. A bulk photovoltaic coefficient of up to 1.3 × 10-3 V-1 and a polarization extinction ratio of 21.6 have been achieved by systematically optimizing the height of the h-BN nanoedge and the thickness of VPNS, surpassing those of reported TMD materials (typically less than 3). Our results have revealed the fundamental relationship between the FPV effect and the strain gradients in low-dimensional materials and inspired further exploration of optoelectronic phenomena in strain-gradient engineered materials.

Patterned Liquid Crystal Polymer Thin Films Improved Energy Conversion Efficiency at High Incident Angles for Photovoltaic Cells.

In this report, micro-patterned silicon semiconductor photovoltaic cells have been proposed to improve the efficiency in various incident sunlight angles, using homeotropic liquid crystal polymers. The anisotropic liquid crystal precursor solution based on a reactive mesogen has good flowing characteristics. It can be evenly coated on the silicon solar cells' surface by a conventional spreading technique, such as spin coating. Once cured, the polymers exhibit asymmetric transmittance properties. The optical retardation characteristics of the coated polymer films can be eventually determined by the applicable coating and curing parameters during the processes. The birefringence of light then influences the optical path and the divergence of any encountered sunlight. This allows more photons to enter the active semiconductor layers for optical absorption, resulting in an increase in the photon-to-electron conversion, and thus improving the photovoltaic cell efficiency. This new design is straightforward and could allow various patterns to be created for scientific development. The experimental results have evidenced that the energy conversion efficiency could be improved by 2-3% for the silicon photovoltaic cells, under direct sunlight or at no inclination, when the liquid crystal polymer precursor solution is prepared at 5%. In addition, the efficiency could be much more significantly improved to 14-16% when the angle is inclined to 45°. The unique patterned liquid crystal polymer thin films provide enhanced energy conversion efficiency for silicon photovoltaic cells. The design could be further evaluated for other solar cell applications.

Star-shaped small donor molecules based on benzotriindole for efficient organic solar cells: a DFT study.

The purpose of the S01-S05 series of end-capped modified donor chromophores is to amplify the energy conversion efficiency of organic solar cells. Using quantum chemical modeling, the photophysical and photoelectric characteristics of the S01-S05 geometries are examined. The influence of side chain replacement on multiple parameters, including the density of states (DOS), molecular orbital analysis (FMOS), exciton-binding energy (Eb), molecular electrostatic potential analysis, dipole moment (μ), and photovoltaic characteristics including open circuit voltage (VOC), and PCE at minimal energy state geometries, has been investigated employing density functional theory along with TD-DFT analysis. The molar absorption coefficient (λmax) of all the proposed compounds (S01-S05) was efficiently enhanced by the terminal acceptor alteration technique, as demonstrated by their scaling up with the reference molecule (SR). Among all molecules, S04 has shown better absorption properties with a red shift in absorption having λmax at 845nm in CHCl3 solvent and narrow energy gap (EG) 1.83eV with least excitation energy (Ex) of 1.4657eV. All created donors exhibited improved FF and VOC than the SR, which significantly raised PCE and revealed their great efficiency as OSC. Consequently, the results recommended these star-shaped molecules as easily attainable candidates for constructing extremely efficient OSCs.

Data-Driven Tunnel Oxide Passivated Contact Solar Cell Performance Analysis Using Machine Learning.

Tunnel oxide passivated contacts (TOPCon) have gained interest as a way to increase the energy conversion efficiency of silicon solar cells, and the International Technology Roadmap of Photovoltaics forecasts TOPCon to become an important technology despite a few remaining challenges. To review the recent development of TOPCon cells, this work has compiled a dataset of all device data found in current literature, which sums up to 405 devices from 131 papers. This may seem like a surprisingly small number of cells given the recent interest in the TOPCon architecture, but it illustrates a problem of data dissemination in the field. Notwithstanding the limited number of cells, there is a great diversity in cell manufacturing procedures, and this work observes a gradual increase in performance indicating that the field has not yet converged on a set of best practices. By analyzing the data using statistical methods and machine learning (ML) algorithms, this work is able to reinforces some commonly held hypotheses related to the performance differences between different device architectures. This work also identifies a few more unintuitive feature combinations that would be of interest for further experimentally studies. This work also aims to inspire improvements in data management and dissemination within the TOPCon community.

ПРИМЕНЕНИЕ КВАНТОВЫХ ТОЧЕК В СВЕТОДИОДНОЙ И СОЛНЕЧНОЙ ЭЛЕКТРОНИКЕ

This article discusses the prospects for using quantum dots in LED and solar electronics. Quantum dots have unique optical and electronic properties that make them a promising material for improving the efficiency, stability, and color rendering of LEDs, as well as for increasing the energy conversion efficiency of solar cells. Current advances in the synthesis and application of quantum dots, the main challenges faced by researchers, and possible solutions are discussed. Examples of successful prototypes and commercial devices based on quantum dots are given. Prospects for further development of this technology and its potential impact on the electronics market are also analyzed.

Theoretical investigation of optoelectronic properties of Al-doped BAs using TB-mBJ approach

For quite a long time, the scientific community has been searching for a material that surpasses the existing material systems in terms of energy conversion efficiency for photovoltaic applications. In this study, the optoelectronic properties of pure and Al-doped boron arsenide B[Formula: see text]Al[Formula: see text]As [Formula: see text] in the zinc blende (ZB) structure were systematically examined using the density functional theory (DFT) and the Modified Becke–Johnson (TB-mBJ) exchange correlation (XC) potential. The Perdew–Burke–Ernzerhof generalized gradient approximation (PBE) functional was used for structural optimization. After considering the ground state lattice constant of 4.82[Formula: see text]Å then calculating the bandgap energy of pure BAs, which are consistent with experimental and theoretical findings, we estimated the basic electronic and optical characteristics of Al-doped boron arsenide, including band structures, electronic density of state, dielectric function, refractive index, extinction coefficient, absorption and optical conductivity. The unusual and interesting optoelectronic features of the investigated compounds revealed in this work offer substantial promise for improving the energy conversion efficiency of solar cells.

InGaP Solar Cell with InGaP Multiple Quantum Wells Grown under Optimized V/III Ratio

Indium gallium phosphide (InGaP) solar cells are widely used as top subcells in multi‐junction solar cells, however, there are large open‐circuit voltage (VOC) losses in InGaP solar cells. Improving the radiative efficiency by inserting an InGaP multiple quantum well (MQW) into the InGaP solar cell structure is a promising approach to enhancing the VOC of InGaP solar cells, but such InGaP MQW solar cells are not demonstrated. Moreover, the critical parameters, such as the V/III ratio for an InGaP MQW, are not investigated. This study investigates the optimal V/III ratio for enhancing the radiative efficiency of an InGaP MQW. Doublehetero structures are fabricated, comprising a 330 nm core layer with 55 periods of an InGaP MQW grown under varying V/III ratios. The InGaP MQW grown under V/III = 62 gives the highest photoluminescence intensity among all InGaP structures. An InGaP MQW solar cell grown at V/III = 62 exhibits a 2 mV VOC loss suppression compared with an InGaP bulk solar cell. Therefore, an InGaP MQW grown under proper growth conditions contributes to enhance the energy conversion efficiency of InGaP solar cells. This study provides relevant insights into InGaP MQW crystal growth and the performance improvement in InGaP solar cells.

A conjugated Donor-acceptor blend passivation interlayer for the high-performance carbon-based perovskite solar cells

The interfacial properties between perovskite active layer and carbon electrode significantly affects the energy conversion efficiency and stability of carbon-based perovskite solar cells. In this work a conjugated Donor-Acceptor blend with a dendrite shaped copper phthalocyanine derivative 8TPAEPC as a donor (D) and Y6 as a typical acceptor (A) was designed to enhance the carrier extraction across the perovskite/carbon interface. The respective D and A molecules form strong interactions with I− and Pb2+ on the surface of perovskite by rich functional group atoms, which can synergistically passivate the non-radiative defects. Moreover, the dipoles from D-A coupling construct a strong internal built-in electric field for further suppression of the unwanted recomination. Compared with 8TPAEPC, 8TPAEPC-Y6 blend exhibits the faster charge interface transfer dynamics. Consequently, Carbon-based perovskite solar cells (C–PSCs) optimized by 8TPAEPC-Y6 achieve champion power conversion efficiency (PCE) of 17.07%, superior to those with 8TPAEPC (16.08%), Y6 (15.68%) and pristine perovskite (14.06%). Meanwhile, the C–PSCs with the hydrophobic 8TPAEPC-Y6 blend greatly improved moisture long-term stability that over 90% PCE could remain as long as 90 days. This work finds out an innovative D-A blend interfacial solution for achieving highly efficient and stable C–PSCs.

Wave-heat-electricity conversion: Design and analysis of an electromagnetic energy conversion device

An innovative electromagnetic energy harvester was developed using a compact four-ring single-resistor unit cell. To achieve efficient conversion of electromagnetic waves into electricity, we integrated the high-performance Bi2Te3 thermoelectric material onto the load resistor. Remarkably, this unit cell exhibits exceptional energy harvesting capabilities at a frequency of 5.8 GHz while maintaining polarization insensitivity. Through comprehensive analysis, we evaluated the energy harvesting efficiencies, power loss distribution, and current density distribution. Additionally, we investigated the impact of incident power on the unit cell's temperature and energy conversion efficiencies. To enhance energy concentration on the load, we ingeniously designed an “L-shaped” metal through-hole structure within the four-ring single-resistor unit cell. Our results demonstrate that the four-ring single-resistor unit cell achieves an impressive harvesting efficiency of 94.5% at 5.8 GHz, with a thermal conversion efficiency of 43.3 °C/W, an electrical conversion efficiency of 0.23 mV/°C, and an electrical response rate of 9.4 mV/W. Notably, when subjected to a power input of 7 W, the unit cell produces an output voltage of 65.9 mV, and its theoretical maximum output power reaches 180 mW.

Anti-sine-cosine atom search optimization (ASCASO): a novel approach for parameter estimation of PV models.

Nowadays, solar power generation has gradually become a part of electric energy sharing. How to effectively enhance the energy conversion efficiency of solar cells and components has gradually emerged as a focal point of research. This paper presents a boosted atomic search optimization (ASO) with a new anti-sine-cosine mechanism (ASCASO) to realize the parameter estimation of photovoltaic (PV) models. The anti-sine-cosine mechanism is inspired by the update principle of sine cosine algorithm (SCA) and the mutation strategy of linear population size reduction adaptive differential evolution (LSHADE). The working principle of anti-sine-cosine mechanism is to utilize two mutation formulas containing arcsine and arccosine functions to further update the position of atoms. The introduction of anti-sine-cosine mechanism achieves the populations' random handover and promotes the neighbors' information communication. For better evaluation, the proposed ASCASO is devoted to estimate parameters of three PV models of R.T.C France, one Photowat-PWP201 PV module model, and two commercial polycrystalline PV panels including STM6-40/36 and STM6-120/36 with monocrystalline cells. The proposed ASCASO is compared with nine reported comparative algorithms to assess the performance. The results of parameter estimation for different PV models of various methods demonstrate that ASCASO performs more accurately and reliably than other reported comparative methods. Thus, ASCASO can be considered a highly effective approach for accurately estimating the parameters of PV models.

Thermal laser separation and high-throughput layer deposition for edge passivation for TOPCon shingle solar cells

This work demonstrates the reduction of cutting-induced losses on tunnel-oxide passivated contact (TOPCon) shingle solar cells via edge passivation using high-throughput layer deposition. TOPCon shingle solar cells with a size of 26.46 mm × 158.75 mm are separated from industrial full-square TOPCon host cells either by laser scribing and mechanical cleaving (LSMC) from the emitter-free rear side or by thermal laser separation (TLS) from the front side. TLS yields up to 0.2%abs more efficient shingle cells directly after singulation in comparison to shingle cells that have been separated by LSMC. Passivated edge technology (PET) is applied by depositing aluminum oxide (Al2O3) layers using two different tools: thermal atomic layer deposition (T-ALD) in a lab-scale tool with a throughput of tens of shingle cells per hour and a high-throughput plasma-enhanced ALD (PE-ALD) prototype tool with a throughput of about 60,000 shingle cells per hour. The energy conversion efficiency of the edge-passivated shingle cells after T-ALD Al2O3 PET is found to be 0.4%abs higher than directly after separation. This gain is the same regardless of whether LSMC or TLS is used for cell separation. For PE-ALD Al2O3 and TLS, a gain of 0.5%abs is measured after PET. Stringing tests with electrically conductive adhesive so far indicate that Al2O3 layers do not negatively affect the resistance of cell to cell interconnections. Thus, low-damage cell cutting in combination with high-throughput Al2O3 layer deposition for edge passivation is a very promising approach to maintain high efficiency for industrial TOPCon solar cells in shingled modules.

Studies on the Optical and Photoelectric Properties of Anthocyanin and Chlorophyll as Dihybrid Sensitizer in Dye Sensitized Solar Cell (DSSC)

The production costs and energy conversion efficiency of dye-sensitized solar cells (DSSC) is strongly influenced by the types of dyes used to harvest photons. Natural dyes extracted from different pigments are emerged as a potential dye to enhance the efficiency of DSSC due to their merit properties such as low cost, biodegradable and less environmental concern. Natural pigments were derived from Eleiodoxa conferta (E. conferta) and Spinacia oleracea (S. oleracea) and formation of a mixture of these extracts in (1:1) volume ratio. The dihybrid extract displayed a diverse UV-vis absorption spectrum of 530–550 nm with maximum absorption at ~539 nm. The optical features of the harvested dyes and the photovoltaic productivity of the cells have been explored. The photovoltaic output of the dihybrid delivered the best findings with open-circuit voltage (VOC), short-circuit current density (JSC), fill factor (FF) and energy conversion efficiency values of 0.35 V, 5.83 mA/cm2, 0.63 and 1.29 % respectively.

Influence of spacer and donor groups as tetraphenylethylene or triphenylamine in asymmetric zinc phthalocyanine dyes for dye-sensitized solar cells

Based on the available literature, the carboxylic acid is a suitable electron-withdrawing group for the development of push–pull type AB3 phthalocyanines that can be used in dye-sensitized solar cell (DSSC). This study aims to assess the impact of carboxylic acid groups on solar cell energy conversion efficiency. Two types of carboxylic acid groups were selected as electron-withdrawing groups for this purpose. These groups were attached to the phthalocyanine (Pc) core either directly or via conjugated linker groups. Two novel push–pull zinc phthalocyanine dyes (GT-52 and GGC-22) containing tetraphenylethylene (TPE) or triphenylamine (TPA) substituents as electron donor groups and carboxylic acid or phenoxy carboxylic acid as anchoring groups, respectively, have been synthesized to construct DSSCs. The optical, electrochemical, and photovoltaic properties of the effect of the spacer and electron donor groups in these phthalocyanines are evaluated. Both dyes exhibit good anti-aggregation ability owing to the presence of the bulky donor groups. On the other hand, the DSSC based on GGC-22 showed a significantly higher power conversion efficiency (PCE) of 2.15% than that of GT-52 (0.26%) under AM 1.5G solar conditions. The superior performance of GGC-22 is attributed to the introduction of a phenoxy spacer, which results in a longer distance between the donor groups and the TiO2 surface compared to GT-52 without any spacer. This allows for higher dye loading, resulting in higher JSC, VOC, and PCE for GGC-22. As a result, the presence of a longer anchoring group for the donor groups is an important synthetic strategy for efficient phthalocyanine-based DSSCs.

Modelling and Optimization of A Light Trapping Scheme in A Silicon Solar Cell Using Silicon Nitride (SiNx) Anti-Reflective Coating

Solar cells system has been gaining remarkable attention in the photovoltaic (PV) industry in recent years. Therefore, many people used solar cells in their life. Hence, from time to time, many industries keep improve it to get the best of efficiency of the solar cell. In this work, it presents ray tracing of light trapping (LT) schemes in thin c-Si to enhance broadband light absorption within 300 - 1,200 nm wavelength region. For the ray tracing simulation, mono c-Si wafer with 100 μm thickness is investigated and solar spectrum (AM1.5G) at normal incidence is used. Random planar and upright pyramid front surface with silicon nitride (SiNx) anti-reflective coatings (ARC) with the difference thicknesses are the LT schemes being studies in this work. The broadband anti-reflective coating can effectively reduce the optical loss and improve the energy efficiency in the solar cells. The optical properties of the thin c-Si are analyzed with incremental LT schemes. Not only that, the current density also calculated from the absorption curve. Optical properties and current density were evaluated to find out the best thickness and refractive index of the silicon nitride (SiNx). The initial simulation results show that the solar cell current density is about 24.81 mA/cm2. A great Jmax enhancement in solar cell was achieved with utilizing the ARC thickness and type of front surface. Among the 6 proposed scheme, the scheme with upright pyramid front surface of 75 nm SiNx ARC thickness realized a good improvement in current density of 41.19 mA/cm2. This leads to Jmax enhancement of 66.02 % when compared to the reference c-Si. HIGHLIGHTS Solar cell energy conversion efficiencies for commercially available multicrystalline silicon solar cells are around 14 - 20 % which still insufficient Energy conversion efficiency of solar cell can be enhanced by adding the anti-reflective coating on the front layer of light trapping scheme SiNx as a single layer anti-reflective coating with a certain thickness shown a good behavior in reducing the light reflection hence, effectively absorbing more light into the scheme and leads to enhancing the energy conversion efficiency GRAPHICAL ABSTRACT

Research on solar cells based on electron transport layer

In today ' s world, the energy crisis and environmental pollution are becoming more and more serious. As a renewable energy, solar energy has become one of the important means to meet the global energy demand. Making solar cells using volt effect is an effective way to convert solar energy into electricity. In order to employ solar photovoltaic power generating technology with high efficiency and cheap cost, new solar cell research and development is being done. Among them, organic solar cells are considered as one of the promising solar photovoltaic technologies because of their light weight, simple preparation process, good flexibility and easy to achieve large area processing. While perovskite solar cells are developed in a high speed in recent year because of their simple production and long service life. The urgent problem in this field is further improve the energy conversion efficiency of solar cells. In order to solve these problems, we study the structure principle and electron transport layer of solar cells, and get solutions by analyzing these problems.

Design and evaluation of a quasi-monochromatic and high-energy flow thermophotovoltaic test system

The energy conversion efficiency of thermophotovoltaic (TPV) cells is quite different for different spectral energy and related to the spectral energy intensity. To obtain the energy conversion relationship of the thermophotovoltaic cell for various spectral energy with high-density flux, a test system was designed, which consists of a blackbody radiation source, spectrum control device, temperature control device, thermophotovoltaic cells, and cooling device. To evaluate the performance of the test system, the Monte Carlo ray tracing method and the finite volume method is applied to analyze the spectral energy transfer and temperature of the primary devices. The quasi-monochromatic and high-energy flow that reaches the cell surface can be obtained. The energy conversion performance of thermophotovoltaic cells under a single high-energy spectrum can be thoroughly investigated through this designed test system. The results show that the energy transfer efficiency of this newly designed test system is greater than 14 %. When the radiation source temperature is 1000 K, 1500 K, 2000 K, and 2500 K, the design efficiency of the testing system is 14.11 %, 14.38 %, 14.58 %, and 14.87 %, respectively. When the temperature of the blackbody radiation source is 2000 K and 2500 K, the energy conversion efficiency of the GaSb cell is 20.37 % and 22.85 %, respectively. This work provides theoretical guidance for developing a quasi-monochromatic and high-energy flow thermophotovoltaic test system.

AuNRs attached TiO2 NPs modified by cobalt-imidazolate frameworks as exceptional materials to improve the energy conversion efficiency of dye-sensitized solar cells.

This work reports a significant improvement in both the open-circuit voltage (VOC) and current density (J) of dye-sensitized solar cells (DSSCs) using gold nanorod-modified TiO2 nanoparticles (TiO2/AuNRs) together with a cobalt-imidazolate framework (ZIF-67) as an efficient photoanode. It was demonstrated that adding ZIF-67 (8 wt%) to TiO2 NPs increased the VOC by 160 mV and J by 2.5 times. This observation was described based on the significant increase in the amount of adsorbed dye in the presence of highly porous ZIF-67, which boosts the photoanode's light harvesting. Modifying TiO2 NPs with AuNRs also caused a remarkable enhancement in J (∼ 2.8 times), which can be explained via electron transfer between the TiO2 conduction band and AuNRs. It can result in a more efficient inhibiting effect on the interfacial charge recombination processes in TiO2/AuNRs/ZIF-67 because of the formation of a Schottky barrier at the interface between TiO2 and Au. These effects were confirmed by the reduction in the photoluminescence intensity of TiO2 in the presence of AuNRs. More reduction in the photoluminescence intensity was observed when ZIF-67 was added. The prepared photoanode showed an outstanding improvement in the overall efficiency of the DSSC (η) to 8.38% compared to the bare TiO2-based photoanode (1.83%). The notable improvement in the TiO2/AuNRs/ZIF-67 performance confirmed its practicality for high-efficiency DSSCs.

Recent advances in polymer and perovskite based third-generation solar cell devices

This review article begins with a comparative overview of the configurations, materials, fabrication methods, and energy conversion efficiency of polymer and perovskite solar cells' photovoltaic performances. Firstly, there has been a significant increase in the adoption of solar cells due to the growing need for renewable and clean energy. Among all photovoltaic technologies, polymer and perovskite solar cells have garnered considerable attention owing to their potential to be affordable, lightweight, easy to manufacture, and quick charging. Research on polymer solar cells has spanned over two decades, whereas the use of perovskite solar cells is just eight years old. This expanding topic offers a wealth of information to readers interested in polymers and perovskite. As a basic comparison, the best power conversion efficiency results are 21.6 percent for a 1 cm2 perovskite solar cell and 15.2 percent for polymer solar cells. Finally, this article recommends necessary improvements and future research areas in polymer and perovskite solar cells.

Numerical investigation on energy conversion efficiency of lead-based perovskite solar cells using different transparent conductive oxides

Perovskite solar cells have attracted tremendous attention owing to its rapid increase in power conversion efficiency. This work designed and simulated lead-based perovskite solar cells in planar structure; TCO/ TiO2/ CH3NH3PbI3/Spiro-OMeTAD/Au. To study the effect of various transparent conductive oxides (TCOs) on power conversion efficiency of the devices, Solar Capacitance (SCAP) simulating software was used. To achieve an optimum efficiency, the influence of thickness and band-gap energy of the absorber layer were varied and investigated. The optimized power conversion efficiency (PCE) is achieved using MoO3/TiO2/CH3NH3PbI3/Spiro-OMeTAD/Au architecture with PCE of 22.44 % and Voc, Jsc, and FF of 1.0842 V, 25.57 mA/cm2 and 80.94 % respectively. The numerical simulation shows the potential of substituting the conventional FTO and ITO used in perovskite solar cells with MoO3 as a promising transparent conductive oxide layer.