Research of semiconductors have increased in popularity over the past decades because of their applications in electronics, biomedical devices, photoelectrochemical cells, and detoxification of organic waste. This study intended to analyze the stability and photoefficiency of the semiconductor hybrid consisting of cadmium selenide and poly(o-methoxyaniline) (CdSe/POMA) deposited on various electrode surfaces, such as: Au, Pt and highly organized pyrolytic graphite (HOPG). The formation of the CdSe/POMA composite on HOPG involved electrochemical deposition of CdSe film for 20 cycles, followed by POMA polymerization for 5 cycles using in both cases cyclic voltammetry method. The potential range of CdSe deposition, from the solution of 5 mM CdSO4 and 1 mM SeO2 in 0.1 M HClO4, was varied depending on the type of the electrode surface: HOPG (0 V to -1.2 V), Pt (0.345 V to -1.1 V), Au (0.4 V to -1.1 V). The chronoamperometric deposition of CdSe was also explored on HOPG, with the deposition occurring at a constant -1.045 V for 32 minutes. The polymerization of POMA was carried out at 50 mV/s from -0.2 V to 0.8 V from the solution of 0.06 M o-anisidine in 0.1 M HClO4. The photoelectrochemical studies of the created composites were performed in the 0.1M Na2SO3 solution using cyclic voltammetry, open circuit potentiometry (OCP), and chronoamperometry. The chronoamperometric deposition of CdSe on HOPG had a smaller response to light with (9 μA/cm2) of photocurrent, suggesting it was less successful than CdSe film on HOPG (22 μA/cm2) obtained by cyclic voltammetry. Therefore, the deposition of CdSe/POMA via cyclic voltammetry was further used for the deposition studies on HOPG, Pt, and Au. The electrode system that produced the largest photopotential of 250 mV was CdSe/POMA/Au, while on Pt (230 mV) and HOPG (220 mV) being slightly smaller. However, the CdSe/POMA/HOPG system presented much faster response time than the composite deposited on Au or Pt, suggesting that this system was more easily stabilized. The chronoamperometric studies observed the greatest photocurrent density for the composite deposited on Au with 50 μA/cm2, while HOPG (17 μA/cm2) and Pt (6 μA/cm2) had smaller current densities. Following photostudies, the surface morphology and composition of CdSe/POMA on the various electrodes were analyzed using X-ray Photoelectron Spectroscopy (XPS), Scanning Electron Microscopy (SEM) and Atomic Force Microscopy (AFM). The surface analysis of the samples before and after photo-studies found that degradation occurred as a result of exposure to light. The degradation of CdSe/POMA composites deposited on Au and Pt was visibly greater in comparison to the CdSe/POMA on HOPG.
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