In polarography there are many methods to have been studied to increase the sensitivity.Among them the square wave polarography, studied by Dr.Barker, is recognized to be the most available. The remarkable features of square wave polarography are (1) to use the usual dropping mercury electrode, (2) to need no special pretreatment and (3) to be operated with the same procedure as in the ordinary polarography. The high-sensitive polarograph studied by us, based upon Barker's square wave polarography, is composed of the generator of the square wave voltage applied to the cell, the generator of the gating signal and the current amplifier. The generation of square wave signal may be attained with the clipping as shown in Fig. 1 or with multivibrator as shown in Fig. 2. We obtained the square wave signal from the flip-flop circuit as shown in Fig. 3, which was driven by the input pulses. The pulses were generated by the decatron counting circuit driven with the crystal oscillator. In the decatron counting circuit there was used the double pulse decatron, whose poles are arranged as shown in Fig. 4. The output of the power amplifier with ha.gh4idelity of the square wave signal was applied to the cell. The gating pulses were also derived from the same decatron circuit and in the same way the gating signal were obtained by the flip-flop circuit. The current-amplifier was composed of the pre-amplifier, the gating circuit and the main amplifier. In the preamplifier the transister amplifier was used. In the gating circuit the pentode amplifier was used, whose pedestal was compensated with the balancing circuit as shown in Fig. 5. As the main amplifier, the three-stage frequency selective amplifier was used, so that the remaining pedestal from the gating circuit and the A.C. signal caused by gating the D.C. signal might be eliminated. The frequency selective amplifier was the cathode follower amplifier as shown in Fig. 7, whose negative feed-back circuit was Twin-T network as shown in Fig. 6. In the polarographic circuit, as shown in Fig. 8. the D.C. potential was applied to the anode through the choke coil and the square wave voltage through the condenser. The cathode of the cell was grounded through the resister, whose potential drop signal was given to the pre-amplifier. In the above mentioned circuit of polarograph, the terminals of the D.C. potential applier, the square wave voltage generator and the resister, with which the current signal was obtained, were all grounded, so the noise was kept minimum. With this polarograph the reversible depolarizes such as Cd- or Pb-ion of 2×10-7 mol/l can be detectable. It seems that the factor limiting the sensitivity of detection is the series-resisters connected with the cell and the most noticeable resister is the capillary of the dropping mercury electrode
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