A two-step electrochemical method is proposed for the in-situ deposition of copper and synthesis of copper(Ⅰ) sulfide (Cu 2 S) with controllable morphology on nickel foam (NF), and the thus-prepared self-supported Cu 2 S@NF electrodes exhibit excellent performance as bifunctional electrocatalysts. Characterizations with scanning electron microscopy show rock-shape of the deposited copper through potentiostatic method, which can be further sulfurized to microflower morphology by a unique underpotential electrochemical method. The size and amount of the deposits can be adjusted by controlling applied potentials, leading to the optimization of electrocatalytic activity. The Cu 2 S@NF exhibits superior electrocatalytic performance towards HER and OER in 1 M KOH with the low overpotentials of 105 mV and 194 mV at 10 mA/cm 2 , as well as small Tafel slopes of 92.89 mV/dec and 72.81 mV/dec, respectively. This work provides a simple method for the synthesis of efficient catalysts, which can be extended to the fabrication of other transition metal-based electrocatalysts. • An electrochemical method is proposed to fabricate Cu@NF and Cu 2 S@NF catalysts. • Copper can be sulfurized at a negative potential in the presence of S 2− . • Cu 2 S@NF exhibits excellent catalytic activity towards both HER and OER. • Catalytic performance can be optimized by controlling electrochemical parameters.