Carrier Localization Research Articles

Passive dual-probe near-field microscopy.

Accurate and simultaneous multiposition near-field measurements are essential to study the time-dependent local dynamics, including heat and carrier transfer. The existing passive long-wavelength infrared (LWIR) scattering-type scanning near-field optical microscopy (s-SNOM) systems with a single probe cannot perform precise near-field measurements of the heat or carrier transporting process at the nanoscale level. Therefore, in this study, we developed a passive LWIR s-SNOM system with two probes. To test the effectiveness of the proposed passive LWIR dual-probe s-SNOM system, each probe was precisely controlled using a shear-force feedback system, and the mechanical interference between the probes was used to monitor the distance between the probes. We achieved simultaneous near-field measurements at two different positions 500nm apart using the proposed passive LWIR dual-probe s-SNOM system. The simultaneously detected near-field signals from two different points were extracted individually, making this technique an effective nanoscale analysis tool for local carrier dynamics.

Selective High-Resistance Zones Formed by Oxygen Annealing for -GaO Schottky Diode Applications

Selective area doping technique is essential for diversifying semiconductor device structures. In this letter, selective high-resistance zones on <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\beta $ </tex-math></inline-formula> -Ga2O3 wafers were successfully achieved by a high-temperature oxygen annealing process. Polysilicon, which proved to have an ideal blocking capability against oxygen annealing ambient, was employed as an annealing cap layer to prevent local carrier concentration changes during annealing. Based on this unique process approach, we further demonstrate a high-resistance anode edge termination of Schottky barrier diodes, which can considerably reduce the leakage current and increase the breakdown voltage of the devices. This research broadens the device manufacturing method and promotes the development of Ga2O3 devices.

An Analytical Drain Current Model of ZnO-Based Amorphous Oxide Semiconductor Thin-Film Transistors

An analytical one-piece drain current model of ZnO-based amorphous oxide semiconductor (AOS) thin-film transistors (TFTs) is presented in this article. This model is able to solve the main obstacle in a lack of analytical and physics-based nonregional device modeling for AOSTFTs and is suitable to be implemented into circuit simulators. Based on the effective-charge-density approach, free carrier density and localized carrier density, including tail and deep states, are unified into total carrier density. Then, one-piece surface potential is derived analytically from equivalent 1-D Poisson’s equation described in an effective-charge-density approach. It is also possible that channel carrier mobility is calculated from the ratio between free carrier and effective total carrier densities. Furthermore, drain current expression is derived analytically and validated by experimental data. Good agreements of <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${I}$ </tex-math></inline-formula> – <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${V}$ </tex-math></inline-formula> characteristics prove that the proposed model could serve as a useful simulation tool implemented into circuit simulators.

Metallic ferromagnetism of indium nitride nanosheets doped with Ce ions

• Ce 3+ doped indium nitride with room temperature ferromagnetism nanosheets were synthesized. • Ce 3+ doped InN nanosheets have single crystal properties. • Ce 3+ doping concentration can modulate the saturation magnetization values of sample. • Magnetism originates from d-f interaction between localized carriers of Ce 3+ ions. • Theoretical calculation prove Ce 3+ doped InN system has metallic characteristic. Herein, Ce-doped indium nitride nanosheets with room temperature ferromagnetism were prepared by high temperature nitration reaction. The saturation magnetization value of the InN system materials can controlled by the Ce doping concentration. With the increase of the Ce doping concentration, the saturation magnetization value first increases and then decreases. When the Ce doping concentration at 1.10 at. %, the saturation magnetization of the samples reach the maximum value of 0.125 emu/g. The first-principles calculation illustrate InN:Ce system display metallic characteristic. The magnetic properties of InN:Ce system originates from the interaction of d-f orbital electrons of Ce element. The synthesized Ce-doped InN nanosheets can expand the application range of InN materials in the field of magnetic semiconductors.

Room-temperature lasing from cesium lead halide perovskite heterostructures induced by phase segregation

Lead halide perovskites (LHPs) are very promising semiconductors as optical gain media for lasing. However, the strategy to lower the lasing threshold in LHPs is still under investigation. In this work, we demonstrate that carrier recombination sink based on phase segregation induced perovskite heterostructures enables lasing behavior at room temperature. The CsPb(Br0·709I0.291)3 microplates (MPs) with regular shapes were synthesized by a chemical vapor deposition (CVD) method. After continuous UV irradiation, the mixed halide perovskite is locally degraded into separated Br-rich phase and I-rich phase due to the phase segregation. Consequently, MP with I-rich phase embedded in CsPb(Br0·709I0.291)3 matrix is obtained. The photogenerated carriers converge in the I-rich phase due to the band alignment. Therefore, localized high carrier density at low pump power is achieved. As a result, lasing behavior with threshold of about 7.5 μJ/cm2 is observed at room temperature. This work is expected to inspire the future development of low-threshold lasing based on LHPs.

Unconventional localization of electrons inside of a nematic electronic phase

The magnetotransport behavior inside the nematic phase of bulk FeSe reveals unusual multiband effects that cannot be reconciled with a simple two-band approximation proposed by surface-sensitive spectroscopic probes. In order to understand the role played by the multiband electronic structure and the degree of two-dimensionality, we have investigated the electronic properties of exfoliated flakes of FeSe by reducing their thickness. Based on magnetotransport and Hall resistivity measurements, we assess the mobility spectrum that suggests an unusual asymmetry between the mobilities of the electrons and holes, with the electron carriers becoming localized inside the nematic phase. Quantum oscillations in magnetic fields up to 38 T indicate the presence of a hole-like quasiparticle with a lighter effective mass and a quantum scattering time three times shorter, as compared with bulk FeSe. The observed localization of negative charge carriers by reducing dimensionality can be driven by orbitally dependent correlation effects, enhanced interband spin fluctuations, or a Lifshitz-like transition, which affect mainly the electron bands. The electronic localization leads to a fragile two-dimensional superconductivity in thin flakes of FeSe, in contrast to the two-dimensional high-[Formula: see text] induced with electron doping via dosing or using a suitable interface.

PH-responsive drug release and antibacterial activity of chitosan-coated core/shell borate glass-hydroxyapatite microspheres

Multifunctional drug delivery system that can treat bone infection and concurrently accelerate bone tissue regeneration is highly desirable. In this study, we developed a pH-responsive local drug carrier in which a core/shell microsphere consisting of a borate glass core and a mesoporous hydroxyapatite HA shell (BG-HA) was coated with glutaraldehyde-crosslinked chitosan (CS). At neutral pH, a negligible concentration of vancomycin was released from the BG-HA@CS microspheres. However, in an acidic environment, the pores on the HA shell were uncapped due to the swelling of CS, thus accelerating the drug release. The advantage of the BG-HA@CS was evidenced by comparing with HA@CS that was prepared by fully converting borate glass followed by CS coating. The dissolution of the unconverted borate glass core upon immersing in PBS led to an increase in the local pH. This change of pH regulated the swelling/de-swelling behaviours of CS, thereby realizing more sustained drug release. Furthermore, it revealed that the vancomycin-loaded BG-HA@CS provided highly effective antibacterial activity against S. aureus and E. coli, while the vancomycin-loaded HA@CS did not show inhibitory effect on E. coli. The results indicated that the BG-HA@CS would be a promising multifunctional delivery system that can achieve self-regulated drug release, control the acidic environment of bone infection sites and promote bone tissue regeneration.

Experimental insights toward carrier localization in in-rich InGaAs/InP as candidate for SWIR detection: Microstructural analysis combined with optical investigation

Hyperspectral imaging has been flourished thanks to the huge investigation of the infrared spectrum from NIR to LWIR bands. The ternary InGaAs has been investigated herein in the context of studying the structural dependences of localization phenomenon by X-ray diffraction (XRD), scanning electron microscopy-energy dispersive X-ray (SEM-EDX), Raman, ultraviolet–visible (UV–vis), and photoluminescence (PL) techniques. Using metal-organic vapor phase epitaxy (MOVPE), we succeed to grow the InGaAs directly on InP substrate at 560 °C as an active layer with indium concentration exceeding the “golden” value (53%) to enlarge its cutoff absorption wavelength. X-ray diffraction proved a good crystallinity of the heterostructure with a sharp peak related to the thick substrate and another peak attributed to the thin layer of InGaAs. Moreover, an interfacial layer appeared at the logarithmic scale of XRD patterns and was confirmed by Raman analysis. The SEM-EDX revealed an average indium concentration (62%), almost the growth concentration. However, a cross-section compositional profile over the heterostructure showed an inhomogeneous distribution of the indium. This is predictable from the composition fluctuation in the indium-containing alloys and the volatility (surface segregation) of As (In). On the other side, the optical investigation of InGaAs demonstrated an anomalous behavior of luminescence versus temperature, manifested by the S-shape feature. This trend stems from the potential fluctuation induced by the non-uniform distribution of indium. A numerical simulation was developed based on the localized state ensemble (LSE) model to well-reproduce this anomaly by giving the best fitting parameters and comparing them with those calculated using the semi-empirical models (Viña and Pässler). The results reported here will help in optimizing the epitaxy design of future InGaAs/InP and further studying its surface morphology and device performance.

(Digital Presentation) Sub-THz Front Ends for Future Communication and Sensing Technologies in 130nm Sige Bicmos Technology

Introduction: Beyond the-5G technologies are targeting the available bandwidth (BW) in the D-band and J-band. This promises for very high speed communication and sensing accuracy. Although the advantages of operating beyond 100 GHz from the application point of view, it requires a lot of research and development to design a reliable and power efficient chipsets. In this presentation we will go through the design of wideband 240 GHz transmitter (Tx) and receiver (Rx). Firstly an overview about the link budget analysis will be given, then the design of the local carrier signal generator will be discussed. The wideband Txs and Rxs are to be presented with frequency channelizing concept. At the end the results of the wireless links will be demonstrated. Link Budget Analysis: Operating at sub-THz frequencies approaching the transistor fT put a lot of constraints on the system link budget. The elevated noise figure together with the limited maximum Pout of the transistors lead to solutions which might be limited in BW or power efficiency. Hence the design architecture need to be optimized taking into account the elevated power consumption and heat dissipation. Carrier Generation: Several approaches could be followed to generate the sub-THz carrier frequency. For a power efficient solution the fundamental oscillators promise for a power efficient solution but with limited phase noise performance and tuning range. Such a solution is more common for imaging systems operating at a single frequency. In order to achieve wider tuning ranges for multi-channel scenario or FMCW radar systems, the frequency multiplication chains are common, whereas the multiplication factor depends on the system parameters. Sub-THz Rx: Different approaches were followed to realize a wideband sub-THz Rx. For some technologies the transistors ft does not promise the realization of low noise amplifiers (LNA) with reasonable noise figure, gain and BW. Hence the mixer first approach were followed trying to optimize the noise figure of the down conversion mixer as much as possible. This also enhances the input compression point (IP1dB) of the Rx which is better for monostatic radar applications. On the other hand, if the technology in use allows the development of well performing LNA’s, the LNA first approach was followed to enhance the all over NF of the receiver and ease the implementation of IQ Rxs. In our work an LNA was implemented followed by IQ downconversion mixers and baseband chain as presented in [3]. Sub-THz Tx: The Tx main challenging performance parameter in the sub-THz frequency range is to achieve high output compression point across the required BW with as high efficiency as possible. Increasing the power handling capabilities of the power amplifiers (PA) by increasing the transistors sizes of the output stages, leads to low output impedance and hence higher impedance transformation ratios for the matching structures and eventually narrow band designs. Hence the power combining architectures were proposed as an alternative to increase the output power either by combining on-chip or combining in air. In this work a fully integrated IQ Tx is to be presented with on-chip LO chain and 4-way power combined power amplifier. Baseband Signal Generation and Processing The baseband topology depend on the application. For mobile communication or localization use cases a wideband channels are not available directly from the digital processors, a kind of channel bonding is required either in the digital domain or in the analog domain. As a proof of concept we present here 3-IQ frequency interleaving combiner. Wireless Link Demonstrator Two demonstrators are to be presented. The first demonstrator is transmitting a broadband IQ signal generated from an arbitrary wave generator wirelessly utilizing an IQ 240GHz Tx and Rx. Data rates up to 100 Gbps were demonstrated across a 1m of wireless link. The second demonstrator includes the implementation of 3-channel IQ channelizer to create the complex modulated signal at several intermediate frequencies (IFs) and then upconverted to the 240GHz carrier signal. On the Rx side the de-channelizer convert the down modulated signal to three IQ channels. Data rates up to 8Gbps were demonstrated wirelessly with the channelization with potential of further enhancements for more channels integration. Outlook The future of the sub-THz wireless links for high speed communication and localizations goes towards implementing phased array and MIMO systems. This requires the research community to develop novel architectures to develop large scale arrays with acceptable power consumptions and suitable packaging solution. On the baseband side also the channel bonding solutions are still in an early stage, requiring more work to bond modularly larger number of channels.

Excitons in a disordered medium: A numerical study in InGaN quantum wells

Excitons in InGaN quantum wells are investigated numerically, considering random alloy disorder and Coulomb interaction on equal footing in the Schr\"odinger equation. Their statistical properties are systemically explored as a function of the quantum well thickness and composition, revealing a complex competition between disorder-induced carrier localization, Coulomb attraction, and field-induced wave function separation. This results in a class of semiconductor quasiparticle with hybrid properties in between hydrogenoid excitons and disorder-localized free particles. Exciton screening by free carriers is investigated and shows distinct behavior from the screening of bulk excitons. Finally, a highly accurate approximate solution of the excitonic Schr\"odinger equation, with reduced numerical complexity, is introduced.

Optical characteristics of bilayer decoupling MoS2 grown by the CVD method.

Study of exciton recombination process is of great significance for the optoelectronic device applications of two-dimensional transition metal chalcogenides (TMDCs). This research investigated the decoupling MoS2 structures by photoluminescence (PL) measurements. First, PL intensity of the bilayer MoS2 (BLM) is about twice of that of the single layer MoS2 (SLM) at low temperature, indicating no transition from direct bandgap to indirect bandgap for BLM due to the decrease of interlayer coupling which can be shown by Raman spectra. Then, the localized exciton emission appears for SLM at 7 K but none for BLM, showing different exciton localization characteristics. The PL evolution with respect to the excitation intensity and the temperature further reveal the filling, interaction, and the redistribution among free exciton states and localized exciton states. These results provide very useful information for understanding the localized states and carrier dynamics in BLM and SLM.

Vertical profiling of ultrafast carrier dynamics in partially strain relaxed and strained InGaN grown on GaN/sapphire template of different In composition

InGaN is one of the important ternary alloys which enables the nitrides to have bandgap energy in a wide range of 0.77–3.44 eV corresponding to the photon wavelength of 360–1610 nm by simply adjusting In content. However, the research on the InGaN has primarily focused on low-dimensional structures though knowledge of the physical properties of bulk InGaN thin-film is important in designing optoelectronic applications that utilize thick InGaN layers. In this study, we revisited partially strain relaxed bulk InGaN thin-films of different In compositions. We found that fast carrier decay was caused by hot carrier cooling due to the presence of oxygen impurity, and the slow carrier decay was governed by the carrier localization initiated by V-shape defects which concentrated at the bottom of the InGaN layer starting at InGaN/GaN interface. We also observed that the V-shape defects became severe, and the slow decay carrier lifetime decreased as In composition of the InGaN layer increased. Our observation gives guidance in designing optoelectronic applications using partially relaxed thick InGaN layers, such as buffer layers for long-wavelength InGaN light emitting diodes as well as solar absorber layer for InGaN photovoltaic cells.

Time-dependent transport in graphene Mach-Zender interferometers

Graphene nanoribbons provide an ideal platform for electronic interferometry in the Integer Quantum Hall regime. Here, we solve the time-dependent four-component Schroedinger equation for single carriers in graphene and expose several dynamical effects of the carrier localization on their transport characteristics in pn junctions. We simulate two kinds of Mach-Zender Interferometers (MZI). The first is based on Quantum Point Contacts and is similar to traditional GaAs/AlGaAs interferometers. As expected, we observe Aharonov-Bohm oscillations and phase averaging. The second is based on Valley Beam Splitters, where we observe unexpected phenomena due to the intersection of the Edge Channels that constitute the MZI. Our results provide further insights into the behavior of graphene interferometers. Additionally, they highlight the operative regime of such nanodevices for feasible single-particle implementations.

Poly (vinylidene fluoride) solid polymer electrolyte structure revealed by secondary ion mass spectrometry

Due to the processability safety, polymer-matrix composites can be considered as a solid polymer electrolytes and have attracted widespread attention. However, their electrical properties, as low ionic conductivity cannot meet the requirements of practical applications. Using the high energy mixing technique, the ionic conductivity was increased from 1.6 × 10 −6 to 9.4 × 10 −5 S cm −1 . The application of the Secondary Ion Mass Spectrometry technique revealed the distribution of lithium ions in the structure of the polymer matrix, which allows to directly connect the conductive properties and the homogeneity of the polymer composite. • High energy mixing technique increased conductivity of solid polymer electrolytes. • Increased conductivity results from changes in the structure of the composites. • Changes were detected and confirmed using the SIMS technique. • Secondary Ion Mass Spectrometry technique is an effective tool to assess charge carriers localization in composite materials.

Dielectric and electrical properties of reduced graphene oxide paper after electron irradiation

We present the results of a study of the dielectric and electrical properties of macroscopic reduced graphene oxide paper (RGOP) before and after 1 MeV electron irradiation with a low dose of 1⋅1016 cm−2. It was found that the Coulomb interaction affects the transport of charge carriers and causes their strong localization within graphene domains. The conductivity of the RGOP can be described by the charge carrier tunneling through a disordered graphene quantum dot array. It was shown that charge carrier localization length decreases from 5–8 nm to 1–2 nm after electron irradiation. Structural and electrical studies revealed that the irradiated sample demonstrates electrical conductivity higher than the initial one, despite the lower sp2-carbon fraction, the lower localization length, unchanged average size of graphene domains, and the higher defect states and functional groups content. The improvement in conductivity is also accompanied by an increase in the dielectric permittivity ɛ from 5 for the initial RGOP to 35 after electron irradiation. The data obtained indicate that disordered regions can affect the electrical properties of reduced graphene oxide.

Superior External Quantum Efficiency of LEDs via Quasi-2D Perovskite Crystals Implanted with Phenethylammonium Acetate.

The multiple quantum well structure of a quasi-two-dimensional (quasi-2D) perovskite leads to nonradiative Auger recombination (AR). This is due to high local carrier density in recombination centers, although the radiative recombination is improved by efficient energy transfer. In this study, we suppress the AR by introducing phenethylammonium acetate (PEAAc) into the quasi-2D PEA2Csn-1PbnBr3n+1 perovskite. The recombination centers of n ≥ 4 phases can be promoted because the COO- preferentially coordinates with Pb2+, inhibiting the fast formation of n = 1, 2, 3 phases with phenethylammonium anion (PEA+). Thus, the AR is suppressed due to the lower density of local charge carriers. To balance the AR suppression and decreasing binding energy in promoting the n ≥ 4 phases, the PEAAc:PEABr molar ratios are adjusted. At the optimal molar ratio, perovskite light-emitting diodes (PeLEDs) with a maximum luminescence of ∼29942 cd m-2 and a maximum external quantum efficiency of ∼20.2% are achieved. These results confirm the most efficient PeLEDs based on PEA2Csn-1PbnBr3n+1 without passivation. Moreover, the efficiency roll off is significantly mitigated with a high threshold of over 3.51 mA/cm2. This study develops high-efficiency PeLEDs with a low efficiency rolloff.

Computational Method for Evaluating the Thermoelectric Power Factor for Organic Materials Modeled by the Holstein Model: A Time-Dependent Density Matrix Renormalization Group Formalism.

Organic/polymeric materials are of emerging importance for thermoelectric conversion. The soft nature of these materials implies strong electron-phonon coupling, often leading to carrier localization. This poses great challenges for the conventional Boltzmann transport description based on relaxation time approximation and band structure calculations. In this work, combining the Kubo formula with the finite-temperature time-dependent density matrix renormalization group (FT-TD-DMRG) in the grand canonical ensemble, we developed a nearly exact algorithm to calculate the thermoelectric power factor PF = α2 σ, where α is the Seebeck coefficient and σ is the electrical conductivity, and apply the algorithm to Holstein Hamiltonian with electron-phonon coupling to model organic materials. Our algorithm can provide a unified description covering the weak coupling limit described by the bandlike Boltzmann transport to the strong coupling hopping limit.

Photoassisted High-Performance Lithium Anode Enabled by Oriented Crystal Planes.

Lithium (Li) metal anodes are candidates for the next-generation high-performance lithium-ion batteries (LIBs). However, uncontrolable Li dendrite growth leads to safety issues and a low Coulombic efficiency (CE), which hinders the commercialization of Li metal batteries. Stable Li anodes based on the tailored plane deposition and photoassisted synergistic current collectors are currently the subject of research; however, there are few related studies. To suppress the growth of Li dendrites and achieve dense Li deposition, we design a low-cost customized-facet/photoassisted synergistic dendrite-free anode. The tailored (002) plane endows it with a nanorod array/microsphere composite structure and exhibits a strong affinity for Li, which effectively reduces the Li+ nucleation overpotential and promotes uniform Li deposition. Notably, during the photoassisted Li deposition/stripping process, due to electron-hole separation, a weakly charged layer is formed on the (002) surface and local charge carrier changes are induced, reducing the overpotential by 8.3 mV, enhancing the reaction kinetics, and resulting in a high CE of ∼99.3% for the 300th cycle at 2 mA cm-2. This work is of great significance for the field of next-generation photoassisted Li metal anodes.

Symmetric domain segmentation in WS2 flakes: correlating spatially resolved photoluminescence, conductance with valley polarization

The incidence of intra-flake heterogeneity of spectroscopic and electrical properties in chemical vapour deposited (CVD) WS2 flakes is explored in a multi-physics investigation via spatially resolved spectroscopic maps correlated with electrical, electronic and mechanical properties. The investigation demonstrates that the three-fold symmetric segregation of spectroscopic response, in topographically uniform WS2 flakes are accompanied by commensurate segmentation of electronic properties e.g. local carrier density and the differences in the mechanics of tip-sample interactions, evidenced via scanning probe microscopy phase maps. Overall, the differences are understood to originate from point defects, namely sulfur vacancies within the flake along with a dominant role played by the substrate. While evolution of the multi-physics maps upon sulfur annealing elucidates the role played by sulfur vacancy, substrate-induced effects are investigated by contrasting data from WS2 flake on Si and Au surfaces. Local charge depletion induced by the nature of the sample-substrate junction in case of WS2 on Au is seen to invert the electrical response with comprehensible effects on their spectroscopic properties. Finally, the role of these optoelectronic properties in preserving valley polarization that affects valleytronic applications in WS2 flakes, is investigated via circular polarization discriminated photoluminescence experiments. The study provides a thorough understanding of spatial heterogeneity in optoelectronic properties of WS2 and other transition metal chalcogenides, which are critical for device fabrication and potential applications.

Robust estimation of charge carrier diffusivity using transient photoluminescence microscopy.

Transient microscopy has emerged as a powerful tool for imaging the diffusion of excitons and free charge carriers in optoelectronic materials. In many excitonic materials, extraction of diffusion coefficients can be simplified because of the linear relationship between signal intensity and local excited state population. However, in materials where transport is dominated by free charge carriers, extracting diffusivities accurately from multidimensional data is complicated by the nonlinear dependence of the measured signal on the local charge carrier density. To obtain accurate estimates of charge carrier diffusivity from transient microscopy data, statistically robust fitting algorithms coupled to efficient 3D numerical solvers that faithfully relate local carrier dynamics to raw experimental measurables are sometimes needed. Here, we provide a detailed numerical framework for modeling the spatiotemporal dynamics of free charge carriers in bulk semiconductors with significant solving speed reduction and for simulating the corresponding transient photoluminescence microscopy data. To demonstrate the utility of this approach, we apply a fitting algorithm using a Markov chain Monte Carlo sampler to experimental data on bulk CdS and methylammonium lead bromide (MAPbBr3) crystals. Parameter analyses reveal that transient photoluminescence microscopy can be used to obtain robust estimates of charge carrier diffusivities in optoelectronic materials of interest, but that other experimental approaches should be used for obtaining carrier recombination constants. Additionally, simplifications can be made to the fitting model depending on the experimental conditions and material systems studied. Our open-source simulation code and fitting algorithm are made freely available to the scientific community.