Oxidation Of Carbon Monoxide Research Articles

Reduction of Emission and Fuel Consumptions based on Mingled Nano Additives in Biodiesel

Using the lipids identified as well as extra residual cooking oil, vegetable, and animal fats, bio-diesel a substitute for fuels derived from petroleum can be produced. Since the 1970s oil crisis, there has been a resurgence of interest in using biodiesel as a fossil fuel substitute due to the fuel's rapidly rising prices, availability uncertainties, and growing environmental and greenhouse gas (GHG) concerns.To produce biodiesel, glycerin and fat or vegetable oil are separated chemically through a process termed transesterification. Glycerin, a valuable byproduct that is typically sold to be used in soaps and other products, and methyl esters, the chemical term for biodiesel, are the two products left over from the process. The industrial term for diesel derived from petroleum, petro diesel, and biodiesel have similar viscosities. Due to the nearly zero sulfur content,it is recommended to be used as an additive in diesel oil formulations to improve the lubricity of pure ultra-low sulfur diesel (ULSD).The current work focuses heavily on reducing emissions and fuel consumption in automobiles. In addition to lowering pollutants and fuel consumption, the transition metal oxide (Copper oxide) additions in nanocrystalline particle form aid in molecular combustion. To create a stable Nano fluid, soap nut biodiesel is combined with metal oxide additive and ultrasonicated. For our experimental investigation, single cylinder, air cooled, constant speed Kirloskar engine is used. The reduction of hydrocarbon (HC), carbon monoxide (CO) and nitrogen oxide (NOx) emissions is investigated. The highest break power of the biodiesel employed in the study is 3.82 KW, greater than the typical diesel's 3.23 KW. The result shows improved engine efficiency, reduced emissions, and better brake thermal efficiency.

Empirical study on butanol-ethanol-gasoline blends using Artocarpus heterophyllus peel resource for eco-friendly gasoline engine application

Since using current engine fuels contributes to climate change and global warming, there is intense competition to provide an ecologically friendly and less harmful substitute fuel. It proved to be rather feasible to mix engine-designed fuel with alcohol fuel. In this work, the peel of Artocarpus heterophyllus is used to produce the bioethanol. In three ratios—10 % butanol-ethanol + 90 % petrol (BEG10), 20 % butanol-ethanol + 80 % petrol (BEG20), and 30 % butanol-ethanol + 70 % petrol (BEG30)-butanol-ethanol and petrol were mixed in the present work. Using a four-stroke, spark ignition (SI) engine one-cylinder, the effect of the butanol-ethanol-gasoline combination on operational properties was examined and studied. Three test fuels (BEG10, BEG20, and BEG30) were studied in the engine speed range of 2500 rpm to 4500 rpm. The best practical responses found were brake thermal efficiency (43.21 %) and brake-specific fuel consumption (0.23 kg/kWh). The findings showed that more significant concentrations of ethanol-butanol improve the performance characteristics. In the end, engine emission parameters such as hydrocarbon (40 %), carbon monoxide (25 %), and nitrogen oxide (5.88 %) were reduced by the butanol-ethanol combination with petrol. Artificial neural network (ANN) models of multiple regression are used to forecast the engine performance parameters. An ANN model is trained using a database produced from the experimental findings. It shows that the suggested artificial neural network model can provide a precise correlation between input variables and output replies. The input parameters like Speed, Load, and Blend were predicted using the identified model. The R2 (0.9638, 0.9735) value of BTE and BSFC obtained indicated that the neural network approach model generated was more accurate for the prediction process. ANN application is thus a superior forecasting tool for SI engine performance characteristics.

Combination of high cetane diesel fuel and post injection mode in a diesel engine: A path towards lower exhaust emissions

The major objective of the presented work is to explore the effect of post injection (PI) strategy using neat diesel fuel (D100) blended with cetane number enhancer (CNE). The motive behind adding CNE in diesel fuel was to lower its self-ignition temperature and hence delay period subsequently. This can lead to more efficient combustion of post injected fuel which leads to lower incomplete combustion losses. The CNE used was Di-Tert-Butyl Peroxide (DTBP) which was blended with D100 in proportion of 1 % by volume. Initially experiments were conducted with D100 under various PI modes where variation of post injection timing (PIT) as well as post quantity (PQ) was considered. The experimental results showed that implementing PI resulted in lower smoke, unburned hydrocarbon (UHC), carbon monoxide (CO) and nitrogen oxides (NOx) emissions compared to single injection while affecting fuel consumption negatively. Then after similar experiments under various PI modes were repeated using blends of D100 and DTBP (D/DTBP) and results were compared with D100 case. It was found that addition of CNE in D100 resulted in more complete combustion of post fuel which further reduced CO and UHC emissions. The shorter delay period in case of D/DTBP blend compared to D100 case led to lower NOx emissions as well as higher smoke emissions. The obtained results revealed that PI mode with 3 mg PQ and 20° after top dead center (ATDC) PIT with D/DTBP blend offered 41.18 %, 17.55 %, 64 % and 62.5 % reduction in smoke, NOx, UHC and CO emissions respectively compared to single injection mode using D100 fuel.

Advances in Catalytic Oxidation of Methane and Carbon Monoxide (2nd Edition)

Advances in Catalytic Oxidation of Methane and Carbon Monoxide (2nd Edition)

CO-Free Fuel Processing of Water Gas Shift Feedstocks: Effect of Support on CuMn Spinel Performance

AbstractCleaning up carbon monoxide (CO) in water gas shift feedstocks is crucial for fuel cell applications. The catalytic transformation of CO in hydrogen-rich feeds poses a significant challenge in environmental catalysis. To address this issue, a range of Cu–Mn-based monometallic and bimetallic catalysts with diverse supports (such as alumina, silica, zirconia, and titania) were employed. Temperature programming techniques were utilised to observe the reduction and oxidation behaviours of these catalysts. The investigation involved testing CO oxidation at various temperatures over copper and manganese-based supported catalysts in the presence of H2O and CO2 (simulating realistic conditions). A positive impact of H2O on catalytic performance was noted, whereas CO2 had a suppressive effect. Furthermore, the specific support materials (Al2O3, SiO2, TiO2, and ZrO2) were studied to understand their roles in CO oxidation under realistic conditions. In the presence of water, alumina catalysts containing bimetallic metals (Cu–Mn) exhibited 100% CO conversion even at a lower temperature of 160 °C. Conversely, under the predominant influence of CO2, alumina catalyst (Cu–Mn) showed 55% CO conversion. The exceptional performance was attributed to CO preferential adsorption on highly active Cu–Mn sites and a small H2-oxidative atmosphere of the catalysts. The activity results highlighted the strong dependence of CO conversion on reaction temperatures, the presence of metals, and the types of supports. Overall, these findings suggest the potential use of these catalysts for H2 purification under realistic conditions. Graphical Abstract

Catalytic Decontamination of Carbon Monoxide Using Strong Metal–Support Interactions on TiO2 Microparticles

The traditional catalytic oxidation of carbon monoxide (CO) using metal oxide catalysts often requires either high temperatures (thermocatalysis) or ultraviolet light (UV) excitation (photocatalysis), limiting practical applications under ambient conditions. Our research aimed to develop a catalytic system capable of oxidizing CO to CO2 at room temperature and in the dark. Using the Strong Metal–Support Interaction (SMSI) methodology, several titanium oxide (TiO2)-complexed metals were prepared (Ag, Au, Pd, and Pt). The highest catalytic efficiency of CO oxidation at room temperature was demonstrated for the TiO2-Pt complex. Therefore, this complex was further examined structurally and functionally. Two modes of operation were addressed. The first involved applying the catalytic system to remove CO from an individual’s environment (environmental system), while the second involved the installation of the catalysis chamber as a part of a personal protection unit (e.g., a mask). The catalytic activity exhibited a significant reduction in CO levels in both the environmental and personal protection scenarios. The practical application of the system was demonstrated through efficient CO oxidation in air emitted from a controlled fire experiment conducted in collaboration with the Israel Fire and Rescue Authority.

Hydrogen-natural gas fuel blending in a “rich burn” engine with 3-way catalyst

Interest in hydrogen (H2) fuels is growing, with industry planning to produce it with stranded or excess energy from renewable sources in the future. Natural gas (NG) utility companies are now taking action to blend H2 into their preexisting pipelines to reduce greenhouse gas (GHG) emissions from burning NG. Stoichiometric (“rich burn”) NG engines that operate on pipeline NG and will receive blended fuel as more gas utilities expand H2 production. These engines are typically chosen for their low emissions owing to the 3-way catalyst control, so the focus of this paper is on the change in emissions like carbon monoxide (CO) and nitrogen oxides (NOx) as the fuel is blended with up to 30% H2 by volume. The Caterpillar CG137-8 natural gas engine used for testing was originally designed for industrial gas compression applications and is a good representative for most “rich burn” engines used across industry for applications such as power generation, gas compression, and water pumping. A significant greenhouse gas (GHG) emissions reduction is observed as more H2 is added to the fuel. Increasing H2 in the fuel changes combustion behavior in the cylinder, resulting in faster ignition and higher cylinder pressures, which increase engine-out NOx emissions. Post-catalyst CO and NOx both decrease slightly with increasing H2 while operating at the optimal “air-fuel” equivalence ratio (λ). A “rich burn” engine with 3-way catalyst can tolerate up to 30% H2 (by vol.) while still meeting NOx and CO emissions limits. However, at elevated levels of H2, increased engine-out NOx emissions narrow the λ range of operation. As H2 is added to NG pipelines, some “rich burn” engine systems may require larger catalysts or more precise λ control to accommodate the increased NOx production associated with a H2-NG blend. Sudden step-increases in H2 cause dramatic changes in λ, resulting in large emissions of post-catalyst NOx during the transition. Comparable changes in H2 at elevated concentrations cause larger spikes in NOx than at lower concentrations. Better tuned engine controllers respond more quickly and produce less NOx during H2 step-transitions.

Experiment and density functional theory researches on (Mn, Hf) co-doped Ce-based applied surface catalysts for carbon monoxide oxidation and thermal stability

Catalyst addition can improve system after treatment efficiency of pollutants purification. In this study, the performance of (Mn, Hf) co-doped Ce-based catalysts has been investigated in oxidation to mitigate CO emission of engines. A series of Ce-Mn-Hf-Ox with different metal ratios (Ce: Mn: Hf = 8:1:1,7:2:1,7:1:2,6:1:3,6:2:2 and 6:3:1) catalysts were prepared. DFT (density functional theory) calculations were carried out to investigate the mechanism of applied surface catalytic reaction. XRD (X-ray Diffraction) analysis and SEM (Scanning Electron Microscope) revealed Mn and Hf doping increased the catalysts surface area contact with the CO gas with the catalytic performance improvement. XPS (X-ray Photoelectron Spectra), H2-TPR (Temperature-Programmed Reduction) and DFT calculations manifested the Mn and Hf doping would promote the formation of oxygen vacancy to enhance the catalytic performance for CO oxidation. The thermal stability of the catalysts increased with Hf content increasement. Ce6Mn3Hf1 had the highest catalytic activity with the favorable thermal stability according to the temperature-programmed oxidation of CO experiment. T10, T50 and T90 of CO oxidation were 156, 188 and 198 °C, which lost 4.82 % mass at 500°C and 6.18 % mass at 900 °C. Ce6Mn1Hf3Ox displayed the best thermal stability according to TG with the lowest catalytic activity.

Photothermal Oxidation of Volatile Organic Compounds Over Co3O4‐Based Inverse Opal

AbstractThe growing preference for photothermal catalysis stems from its minimal energy consumption and heightened catalytic efficacy. Nonetheless, material photon utilization efficiency is frequently hindered by catalyst structural design constraints and bandgap limitations. Herein, we present a Co3O4‐based inverse opal featuring a three‐dimensional ordered macroporous (3DOM‐Co3O4) architecture tailored for photothermal VOCs oxidation. The 3DOM‐Co3O4 exhibits superior catalytic performance in carbon monoxide oxidation, methane oxidation, and toluene oxidation, with a photothermal enhancement of more than 100 %. Further experimental and theoretical analyses reveal that the three‐dimensional periodic array of pores facilitates the slow photon effect, augmenting the light absorption capabilities of the catalyst. Thus, it generates more photoexcited electrons, promoting VOCs molecular activation. Additionally, the well‐ordered porous structure facilitates the diffusion of reactants and products, further accelerating the catalytic reaction. This work highlights promising prospects for leveraging inverse opals as an innovative strategy towards enhancing photothermal catalytic VOCs oxidization efficiency.

Applied AMT machine learning and multi-objective optimization for enhanced performance and reduced environmental impact of sunflower oil biodiesel in compression ignition engine

Biodiesel has emerged as a compelling substitute for conventional diesel fuel, providing a sustainable and eco-friendly choice for fueling compression ignition engines. This comprehensive study investigates the influence of biodiesel, specifically derived from sunflower oil, through the esterification method, on crucial engine performance parameters and environmental effects. The study examines the impact of varying engine torque on the performance of a single-cylinder, four-stroke compression ignition engine, encompassing parameters such as brake thermal efficiency (BTE) and brake specific fuel consumption (BSFC), as well as exhaust emissions, including unburned hydrocarbons (HC), carbon monoxide (CO), and nitrogen oxides (NOx). Four distinct biodiesel blends (B10, B20, B30, B40) with varying sunflower oil content are systematically compared to pure diesel (B0). The engine operates at a consistent speed of 1700 rpm, while the torque undergoes controlled adjustments from 0 to 10 Nm. Subsequently, this study explores the application of an alternating model tree (AMT) machine learning algorithm to establish relationships between independent factors, specifically torque and biodiesel volume (%vol), and dependent variables, including BTE, BSFC, CO, and NOx in a combustion engine. Additionally, the study employs a multi-objective ameliorative whale optimization algorithm (AWOA) to optimize the model's output. The objective is to identify optimal values for torque and%vol that maximize engine performance (BTE) while minimizing engine emissions (CO and NOx) and reducing fuel consumption (BSFC). The optimization process yields noteworthy results, with AWOA achieving peak BTE at 29.714 %, BSFC at 0.262 kg.kWh-1, and NOx emissions at 992 ppm at torque 7.3 N.m and 13% vol. In contrast, particle swarm optimization (PSO) secured the minimum CO level at 0.123 %, with torque set at 7.6 N.m and 26% vol. The AMT models demonstrate high prediction accuracy, with coefficient of determination (R2) values exceeding 0.98.

WITHDRAWN: Evaluating Collaborative Emission Reduction Efforts in Urban Road Passenger Transportation: insights from the City Scale

Road passenger transportation contributes significantly to carbon dioxide (CO2) and pollutant emissions, posing challenges for urban sustainability, particularly in rapidly urbanizing cities such as Fuzhou, which was recognized as a global sustainable development city for 2023. This study addresses the research gap by integrating road green factors, which refer to the ecological attributes of roads, such as green space, vegetation, and tree coverage that contribute to improving air quality and reducing pollution, into emission reduction strategies for city-scale road passenger transportation. This novel approach has not been extensively explored in the existing literature. The purpose of this study was to identify a rational pathway for emissions reduction by analyzing the economic, demographic, transportation infrastructure, road green space, and policy factor impacts on emissions. Employing a system dynamics (SD) model, this research evaluates the emissions from road passenger transportation in Fuzhou from 2010 to 2030 under various scenarios, including a baseline scenario (BS), controlled private cars travel demand (CPD), promotion of new energy vehicles (PVE), improvement in energy efficiency (IEE), increase in road capacity (IRC), and improvement in road green level (IRG). The principal results indicate that by optimizing the traffic structure and integrating other emission reduction measures, peak CO2 emissions can be achieved by 2024 under the three scenarios or by 2023 under the four scenarios. Furthermore, significant reductions in pollutants of 84.62% and 86.07% are projected, respectively. The study concluded that the economic benefits of CO2 emissions reductions consistently exceeded those of carbon monoxide (CO), hydrocarbon (HC), and nitrogen oxide (NOx) reductions, highlighting the importance of a holistic approach to emissions reduction strategies. Based on these findings, policy recommendations were proposed to guide the formulation of effective road passenger transportation policies aimed at achieving sustainable urban development.

Performance of supported Co3O4 catalysts in the preferential oxidation of carbon monoxide: Effect of support type and synthesis method

This study investigated the performance of supported Co3O4 catalysts during the preferential oxidation of carbon monoxide (CO-PrOx) in a H2-rich environment, focusing on the effects of different catalyst synthesis methods, namely, wetness impregnation (WI) and solution combustion synthesis (SCS), and different support materials, namely, Al2O3 and SiC. During CO-PrOx, the SiC-supported Co3O4 catalysts attained higher CO2 yields when compared with the Al2O3-supported Co3O4 catalysts possibly because of the existence of weaker interactions between Co3O4 and SiC. Moreover, the catalysts prepared via SCS achieved higher CO2 yields than the catalysts prepared via WI likely due to the presence of smaller and well-dispersed Co3O4 particles in the SCS-prepared catalysts. Significantly high amounts of unwanted CH4 were produced over the SiC-supported catalysts between 225 and 250 °C. The high CO methanation activity was also attributed to the weaker Co3O4-SiC interactions, which enabled the easier reduction of Co3O4 to methanation active metallic Co.

A comparative study of first and second generation biodiesel blends under quaternary injection strategies for enhanced engine performance and reduced emissions

Biodiesel is a promising renewable alternative fuel, offering compatibility with conventional engines without necessitating significant engine modifications. To facilitate the practical integration of biodiesel into engine systems, this study evaluates the performance of two different biodiesel blends (fatty acid methyl ester and hydrogenated catalytic) in a turbocharged inter-cooled diesel engine. The research employs quaternary injection techniques an advanced injection technique, which involve multiple injection events per cycle to enhance engine combustion and emission characterictics of the biodiesel blend fuels and comparing their performance and emission characteristics with those of conventional diesel. Results showed that fatty acid methyl ester biodiesel effectively reduced the CO, UHC, and NOx emissions at lower blend ratios (up to 10 %), with minimal impact on the brake-specific fuel consumption. Conversely, hydrogenated catalytic biodiesel demonstrates notable advantages in reducing fuel consumption with carbon monoxide and particle emissions, particularly for higher blend ratios (20 %), leading to improved indicated thermal efficiency. Additionally, an investigation on higher biodiesel blends under varying early injection timings showed that, optimal fuel efficiency was observed at an early injection timing of −43.6 °CA, accompanied by reductions in total particle number and unburned hydrocarbon emissions albeit with elevated carbon monoxide and nitrogen oxide emissions. These findings suggest that advanced injection strategies combined with sustainable biodiesel blends can significantly improve engine performance and reduce environmental impact, supporting the transition towards cleaner and more efficient transportation fuels.

Selective and reversible carbon mono oxide gas detection using silver doped octahedral molecular sieves (OMS-2) nanorods

In this work a potable, resistive sensor is fabricated for the selective detection of CO gas using nanorods of Ag doped octahedral molecular sieves-2 (Ag-OMS-2). During exposure to carbon monoxide (CO) gas at room temperature, resistance of Ag-OMS-2 film was dropped from 557 kΩ to 352 kΩ in just 18 sec. However, exposed sample regained its initial resistance value in 25 sec when CO gas source was removed. Both sensing and recovery processes were carried out at room temperature. The sensor film showed excellent reproducibility during several cycles of CO gas exposure. Swift activation of oxygen molecules for the oxidation of CO by the silver present in the tunnel of manganese oxide network is supposed to be responsible for sensing activity of Ag-OMS-2 towards carbon monoxide gas.

Long-term hypothermic storage of oocytes of the European common frog Rana temporaria at various pressure regimes in gas mixtures based on oxygen, carbon monoxide, and nitrous oxide

In recent years, the challenge of preserving amphibian biodiversity has increasingly been addressed through technologies for the short-term storage of unfertilized spawn at low positive temperatures. Previously the possibility of using a 6.5 atm gaseous mixture of carbon monoxide and oxygen for prolonged hypothermic preservation of unfertilized oocytes for more than 4 days was shown. This study aimed to investigate the viability of oocytes R. temporaria preserved under conditions of hypothermia at 2.5, 3 and 6.5 excess atm pressure in the various gas mixture compositions (CO, N2O, O2) and pure oxygen. The use of pressure up to 3 excess atmospheres was significantly beneficial compared to 6.5 atm at the 7 days storage period. The results indicate that oxygen pressure is a critical factor in maintaining oocyte viability. Admixing CO or N2O to oxygen reduced variability in the results but did not significantly affect the measured indicators (fertilization, hatching) in the experimental groups. The composition CO + O2 (0.5/3.5 ratio, 3 excess atm) reliably extended the shelf life of viable oocytes, indistinguishable from native controls by fertilization and hatching rates, to 4 days. After 7 days, oocytes exhibited fertilization and hatching rates that were 79 % and 48 % compared to native control. Reducing the pressure of the preserving gas mixture to 3 atm, as utilized in this study, simplifies the practical implementation of gas preservation technology for maintaining endangered amphibian species during breeding in laboratory conditions.

Microbial assemblages and associated biogeochemical processes in Lake Bonney, a permanently ice-covered lake in the McMurdo Dry Valleys, Antarctica

BackgroundLake Bonney, which is divided into a west lobe (WLB) and an east lobe (ELB), is a perennially ice-covered lake located in the McMurdo Dry Valleys of Antarctica. Despite previous reports on the microbial community dynamics of ice-covered lakes in this region, there is a paucity of information on the relationship between microbial genomic diversity and associated nutrient cycling. Here, we applied gene- and genome-centric approaches to investigate the microbial ecology and reconstruct microbial metabolic potential along the depth gradient in Lake Bonney.ResultsLake Bonney is strongly chemically stratified with three distinct redox zones, yielding different microbial niches. Our genome enabled approach revealed that in the sunlit and relatively freshwater epilimnion, oxygenic photosynthetic production by the cyanobacterium Pseudanabaena and a diversity of protists and microalgae may provide new organic carbon to the environment. CO-oxidizing bacteria, such as Acidimicrobiales, Nanopelagicales, and Burkholderiaceae were also prominent in the epilimnion and their ability to oxidize carbon monoxide to carbon dioxide may serve as a supplementary energy conservation strategy. In the more saline metalimnion of ELB, an accumulation of inorganic nitrogen and phosphorus supports photosynthesis despite relatively low light levels. Conversely, in WLB the release of organic rich subglacial discharge from Taylor Glacier into WLB would be implicated in the possible high abundance of heterotrophs supported by increased potential for glycolysis, beta-oxidation, and glycoside hydrolase and may contribute to the growth of iron reducers in the dark and extremely saline hypolimnion of WLB. The suboxic and subzero temperature zones beneath the metalimnia in both lobes supported microorganisms capable of utilizing reduced nitrogens and sulfurs as electron donors. Heterotrophs, including nitrate reducing sulfur oxidizing bacteria, such as Acidimicrobiales (MAG72) and Salinisphaeraceae (MAG109), and denitrifying bacteria, such as Gracilimonas (MAG7), Acidimicrobiales (MAG72) and Salinisphaeraceae (MAG109), dominated the hypolimnion of WLB, whereas the environmental harshness of the hypolimnion of ELB was supported by the relatively low in metabolic potential, as well as the abundance of halophile Halomonas and endospore-forming Virgibacillus.ConclusionsThe vertical distribution of microbially driven C, N and S cycling genes/pathways in Lake Bonney reveals the importance of geochemical gradients to microbial diversity and biogeochemical cycles with the vertical water column.

Innovative research on waste tire recycling for sustainable biofuel production: Assessment of its usability on multi-cylinder diesel engine employing constant injection of oxyhydrogen and biogas through a premixing device

This study investigates the production of waste tire pyrolyzed oil on a laboratory scale and its potential use as a fuel along with biogas and hydrogen in a variable-speed transportation engine. The pyrolyzed oil, obtained from waste tire pieces through a lab-scale plant, undergoes distillation and is blended with diesel fuel in a 20% ratio. This blended fuel is supplied to a multi-cylinder variable-speed transportation engine, either alongside biogas or HHO separately or both combined, at fixed flow rates with air passage through a premixing device (venturi). This study aimed to assess engine combustion characteristics such as in-cylinder pressure and heat release rate; performance parameters, including brake thermal efficiency (BTE) and brake-specific fuel consumption (BSFC), as well as emissions of hydrocarbons (HC), carbon monoxide (CO), and nitrogen oxides (NOx). The results indicate that using pyrolyzed oil in unmodified diesel engines reduces combustion characteristics and performancewhile increasing HC and NOx emissions and decreasing CO emissions. In addition, supplying biogas and the fuel mixture further deteriorates combustion and performance, while increases HC and CO emissions, and reduces NOx emissions. The focus of the present research is to evaluate the impact of adding green hydrogen (HHO) gas to a pyrolyzed oil fuel mixture and a biogas-led fuel mixture in a compression ignition (CI) engine. The results indicate that the addition of hydrogen enhances combustion characteristics, engine performance and reduces emissions, except for NOx. Specifically, there is an increase in cylinder peak pressure and HRR by around 6–10% range, improvement in BTE by 16–20% and BSFC by 5–7%, along with a decrease in HC and CO emissions by 13–16% and 11–13%, respectively. However, there is an increase in NOx emissions of 6–9%. In essence, the addition of green hydrogen enhances engine performance and reduces emissions in waste tire-derived pyrolyzed oil and biogas blends, indicating a viable path for sustainable transportation fuel.

The role of hydrogen sulfide in the regulation of necroptosis across various pathological processes.

Necroptosis is a programmed cell death form executed by receptor-interacting protein kinase (RIPK) 1, RIPK3 and mixed lineage kinase domain-like protein (MLKL), which assemble into an oligomer called necrosome. Accumulating evidence reveals that necroptosis participates in many types of pathological processes. Hence, clarifying the mechanism of necroptosis in pathological processes is particularly important for the prevention and treatment of various diseases. For over 300 years, hydrogen sulfide (H2S) has been widely known in the scientific community as a toxic and foul-smelling gas. However, after discovering the important physiological and pathological functions of H2S, human understanding of this small molecule changed, believing that H2S is the third gas signaling molecule after carbon monoxide (CO) and nitric oxide (NO). H2S plays an important role in various diseases, but the related mechanisms are not yet fully understood. In recent years, more and more studies have shown that H2S regulation of necroptosis is involved in various pathological processes. Herein, we focus on the recent progress on the role of H2S regulation of necroptosis in different pathological processes and profoundly analyze the related mechanisms.

The Electrostatic Stimulation of Adsorbed Carbon Monoxide Oxidation on Pt in Aqueous Acidic Electrolytes

The oxidation of adsorbed carbon monoxide on Pt electrodes, CO(ads)|Pt, in aqueous electrolytes ranks among the most studied reactions in electrocatalysis both from theoretical[1]and experimental viewpoints.[2][3] Much of the interest in this electron transfer process stems from the role CO(ads) plays as an impurity that affects adversely the operation of H2|O2 fuel cells. Consensus appears to have been reached regarding the role of adsorbed hydroxyl, OH.(ads) in controlling the activation and ultimate oxidation of CO(ads). The present contribution illustrates the use of electrochemical stimulation techniques developed in our laboratory[4] to explore new aspects of this process not as yet unveiled by the use of more conventional methods. As described in our earlier publications,[4,5] electrode stimulation refers to changes in the rates of heterogeneous electron transfer processes involving adsorbed species induced by modifications in the electrostatic potential in the solution immediately adjacent to the electrode generated by the passage of current between an electrode placed very close to the working electrode, WE, polarized at constant potential, and a second electrode far away from it. The electrochemical cell used for these experiments consisted of a glass tube covered at each end with custom-made Teflon caps and, thus, similar in design to that described by Qi et al.[4] Experiments were performed in Ar-purged 0.1 M H2SO4 involving CO adsorbed at saturation coverages on polycrystalline Pt, polarized at EWE = 0.8 V, a potential very close to the onset of CO(ads) oxidation with a Au disk electrode placed directly above it working as a stimulating electrode, SE, i.e. face to face configuration. Shown in Fig. 1 are plots of the current flowing through the SE (red), iSE and iWE (black) (see Left Panel) and their expanded views during stimulation (Middle Panel) and CO full oxidation (Right Panel), respectively. As shown in the middle panel in this figure. the passage of a negative iSE, elicits a positive iWE ascribed to CO oxidation, which persists even when iSE turns positive, until the end of the stimulation process (see Right Panel), which takes several seconds. In brief, a single stimulation lasting 140 ms can trigger the full oxidation of the entire adsorbed CO layer in CO|Pt over a subsequent period of ca. 4 s. The most likely explanation for this unique effect may be found in the formation of adsorbed OH. on sites previously covered with CO, as the CV of bare Pt would strongly suggest, which will promote the subsequent oxidation of CO(ads), a process that will propagate through the entire Pt surface. Further support for this mechanism was provided by an experiment in which the WE potential was stepped down to 0.4 V immediately after the stimulation was applied, which stopped virtually instantaneously the further oxidation of CO(ads). Experiments are now in progress to image the surface of the CO|Pt electrode during and after the stimulation to monitor in real time the rates of propagation and to provide a more details theoretical model to account for this phenomenon. References 1 Gao, W.; Mueller, J.E.; Jiang, Q.; Jacob, T. Angew. Chem. Int. Ed. 2012, 51, 9448 –94522 Scott, S.B.; Kibsgaarda, J.; Vesborga, P.C.K.; Chorkendorff, I. Electrochim. Acta 2021, 374, 1378423 Scott, S.B.; Kibsgaarda, J.; Vesborga, P.C.K.; Chorkendorff, I. Electrochim. Acta 2021, 374, 1378444 Han, Q.; Georgescu, N. S.; Gibbons, J.; Scherson, D. Electrochim. Acta 2019, 325, 1349575 Heer, A.S.; Mantelli, H; Han, Q.; Georgescu, N. S.; Scherson, D. in preparation. Acknowledgement Support for this work provided by NSF, CHE-1808592.Fig. 1. Plots of iWE and iSE recorded for EWE = 0.8 V prior, during and following WE stimulation (see text for details) (Left Panel). The middle and right panels show expanded views of the data in the left panel during stimulation and CO full oxidation, respectively. Figure 1

A Review of Alternative Aviation Fuels

One of the most promising mid-term solutions for reducing GHG emissions from the aviation sector is alternative aviation fuels, especially sustainable aviation fuels (SAFs). Regulations imposed by the Fit for 55 package to use 38% of SAFs until 2050 require a comprehensive analysis of SAFs and production pathway development with increased blending limits of alternative fuel. Within this review, a summary of key aspects of alternative aviation fuels is presented. The review contains a description of the certification process and certified production pathways with an analysis of feedstocks used for SAF production. SAF emissions also have been analyzed based on available research. SAFs reduce particulate matter emissions significantly, even by 70%, compared to fossil fuels. The emission of gaseous exhaust compounds, such as carbon monoxide, unburned hydrocarbons and nitrogen oxides, also is discussed. Alternative aviation fuels have a lower LCA compared to conventional aviation fuel and the LCAs of specific feedstocks are presented.