Efficient Carbon Research Articles

Polyelectrolyte Additive‐Modulated Interfacial Microenvironment Boosting CO2 Electrolysis in Acid

Acidic CO2 electrolysis offers a promising strategy to achieve high carbon utilization and high energy efficiency. However, challenges remain in suppressing the competitive hydrogen evolution reaction (HER) and improving product selectivity. High concentrations of potassium ions (K+) can suppress HER and accelerate CO2 reduction, but they still inevitably suffer from salt precipitation problems. In this study, we demonstrate that the sulfonate‐based polyelectrolyte, polystyrene sulfonate (PSS), enables to reconstruct the electrode‐electrolyte interface to significantly enhance the acidic CO2 electrolysis. Mechanistic studies reveal that PSS induces high local K+ concentrations through electrostatic interaction between PSS anions and K+. In situ spectroscopy reveals that PSS reshapes the interfacial hydrogen–bond (H–bond) network, which is attributed to the H–bonds between PSS anions and hydrated proton as well as the steric hindrance of the additive molecules. This greatly weakens proton transfer kinetics and leads to the suppression of undesirable HER. As a result, a Faradaic efficiency of 93.9% for CO can be achieved at 250 mA cm–2, simultaneous with a high single‐pass carbon efficiency of 72.2% on commercial Ag catalysts in acid. This study highlights the important role of the electrode‐electrolyte interface induced by polyelectrolyte additives in promoting electrocatalytic reactions.

Instantaneous growth: a compact measure of efficient carbon and nitrogen allocation in leaves and roots of C3 and C4 plants.

Elucidating plant functions and identifying crop productivity bottlenecks requires the accurate quantification of their performance. This task has been attained through photosynthetic models. However, their traditional focus on the leaf's capacity to uptake CO2 is becoming increasingly restrictive. Advanced bioengineering of C3 plants has made it possible to increase rates of CO2 assimilation by packing photosynthetic structures more densely within leaves. The operation of mechanisms that concentrate CO2 inside leaves can boost rates of assimilation while requiring a lower investment in carboxylating enzymes. Therefore, whether in the context of spontaneous plants or modern manipulation, considering trade-offs in resource utilization efficiency emerges as a critical necessity. I've developed a concise and versatile analytical model that simulates concurrent leaf and root growth by balancing instantaneous fluxes of carbon and nitrogen. Carbon is made available by leaf photosynthesis, encompassing all types of biochemistries, while nitrogen is either taken up by roots or remobilized after senescence. The allocation of leaf nitrogen between light or carbon reactions was determined using a fitting algorithm: growth maximisation was the only reliable fitting goal. Both the leaf nitrogen pool and the root-to-leaf ratio responded realistically to various environmental drivers (CO2 concentration, light intensity, soil nitrogen), replicating trends typically observed in plants. Furthermore, modifying the strength of CO2 concentrating mechanisms proved sufficient to alter the root-to-leaf ratio between C3 and C4 types. This direct and mechanistic one-to-one link convincingly demonstrates, for the first time, the functional dependence of a morphological trait on a single biochemical property.

Flexible and synergistic methanol production via biomass gasification and natural gas reforming

Sustainable liquid fuels are essential for decarbonization of various means of transportation which are challenging to address through electrification or hydrogen use. A possible method for producing low-carbon liquid fuel is through the thermochemical biomass to liquid (BTL) process. In this study, we conduct a technoeconomic-environmental analysis of two processes which take advantage of integration of natural gas reforming and biomass gasification, with the objective of improving the economics. By integrating H2-rich syngas (a mixture of H2/CO) obtained from natural gas reforming with carbon-rich syngas from biomass gasification, we harness synergistic effects. This combination allows us to achieve the optimal H2/CO ratio required for methanol synthesis, while also ensuring efficient carbon utilization. In the first design, natural gas is reformed in an autothermal reformer (ATR) to produce syngas. A Solid Oxide Electrolysis Cell (SOEC) is utilized to supply the O2 for both gasification and reforming processes. The H2 produced by the SOEC adjusts the H2 content in the syngas before the methanol synthesis reactor. In the second design, natural gas is reformed in a gas-heated-reformer (GHR) before an ATR, while an Air Separation Unit (ASU) produces the O2 for the process. As a benchmark, the economics and flexible operation of both processes are compared to a conventional BTL process. In addition, the techno-economic impact of operating in biomass-only or natural gas-only modes are investigated. For a 134 MWth plant with 50 % of entering carbon from biomass, the levelized cost of methanol (LCOMeOH) of ATR+SOEC case is 34 % higher than the BTL reference case, while that of ATR+GHR case is 24 % lower than the BTL reference case. A lifecycle analysis (LCA) is conducted for these designs. Utilizing renewable electricity and 50 % biogenic carbon, the ATR+SOEC case emits 908 kgCO2e /tonne MeOH for a 100-year Global Warming Potential (GWP), while the ATR+GHR case emits 721 kgCO2e /tonne MeOH. For a 20-year GWP, these emissions are 1055 and 915 kgCO2e /tonne MeOH, respectively. These emissions correspond to more than 50 % reduction in LCA emissions when compared to natural gas based LCA emissions.

Genomic synergistic efficient carbon fixation and nitrogen removal induced by excessive inorganic carbon in the anammox-centered coupling system

Given the significance of HCO3- for autotrophic anammox bacteria (AnAOB), excessive HCO3- was always provided in anammox-related systems and engineering applications. However, its impact mechanism on anammox process at genome-level remains unknown. This study firstly established an anammox-centered coupling system that entails heterotrophic partial denitrification (PD) and hydrolytic acidification (A-PDHA) fed mainly with inorganic carbon (high HCO3- concentration and low C/N ratio). Metagenomic binning and metatranscriptomics analyses indicated that high HCO3- concentration enhanced expression of natural most efficient phosphoenolpyruvate (PEP) carboxylase within AnAOB, by up to 30.59 folds. This further induced AnAOB to achieve high-speed carbon-fixing reaction through cross-feeding of phosphate and PEP precursors with heterotrophs. Additionally, the enhanced activity of transporters and catalytic enzymes (up to 4949-fold) induced by low C/N ratio enabled heterotrophs to eliminate extracellular accumulated energy precursors mainly derived from carbon fixation products of AnAOB. This maintained high-speed carbon-fixing reaction within AnAOB and supplemented heterotrophs with organics. Moreover, assimilated energy precursors stimulated nitrogen metabolism enzymes, especially NO2- reductase (968.14 times), in heterotrophs. This established an energy-saving PD-A process mediated by interspecies NO shuttle. These variation resulted in efficient nitrogen removal (>95 %) and reduced external organic carbon demand (67 %) in A-PDHA system. This study unveils the great potential of an anammox-centered autotrophic-heterotrophic coupling system for achieving cost-effective nitrogen removal and enhancing carbon fixation under excessive HCO3- doses.

Exploring Biomass Conversion Technologies: From Raw Materials to Valuable Products

The global demand for eco-friendly energy has propelled biomass into the spotlight. This report delves into biomass conversion technologies, including biochemical and thermochemical processes, with a focus on hydrothermal conversion. It highlights challenges related to cost-effectiveness and commercial viability. Thermochemical conversion processes, such as pyrolysis and combustion, unlock energy from organic matter. Hydrothermal processing's three approaches and their efficiency are discussed, particularly in biofuels, chemicals, and biochar production. The review analyzes hydrothermal gasification, emphasizing its efficiency and minimal processing time. Carbon and hydrogen gasification efficiencies are crucial in determining gas yields in supercritical conditions. Yield distribution and the influence of feedstock nature and composition on product yield are examined. In conclusion, this report offers insights into biomass conversion technologies and their sustainability for energy and chemical needs.

탄소저감 기술동향 분석 및 적용사례 연구 - 공원 및 숲을 중심으로

As the threat of climate change due to global warming intensifies, the world is increasingly experiencing extreme weather phenomena. Consequently, the importance of achieving carbon neutrality is expected to grow. Parks and forests play a crucial role in capturing and storing carbon, offering the most eco-friendly spaces that provide convenience and relaxation for users, as well as resilience for cities. They also serve as essential elements of carbon neutrality with their scenic and touristic value. This study focuses on these aspects, reviewing the trends in existing carbon reduction technologies and investigating carbon dioxide capture and utilization technologies that can increase the amount of carbon that parks and forests can capture. These technologies were classified according to six principles, identifying bioconversion technology as the most applicable and dry capture and mineral carbonation technologies as relatively superior. The study analyzes the current policy foundation and shortcomings for the commercialization and business application of these technologies, along with future improvements that need to be addressed. The purpose of this research is to establish a foundation for creating carbon-neutral parks and forests by identifying applicable technologies, assessing policy hurdles, and suggesting improvements, thereby enabling faster and more efficient carbon absorption and storage. According to the findings of this study, by identifying and expanding the application of technologies suitable for parks and forests and improving policies accordingly, it is expected that a more eco-friendly and efficient reduction of carbon dioxide can be achieved.

Spatio-temporal distribution and peak prediction of energy consumption and carbon emissions of residential buildings in China

With the acceleration of urbanization and the improvement of people's living standards, the carbon emissions of residential buildings (BCE) in China have been increasing, hindering the achievement of carbon peaking and carbon neutrality goals. It has become increasingly urgent and important to analyze and grasp the dynamic trends of BCE. Given the notable regional variations in carbon emissions, it is necessary to delve into the distribution characteristics of BCE and the underlying factors influencing them. First, based on the emission factor method, the energy consumption and carbon emissions calculation models are established. Next, the main influencing factors are obtained by improving Kaya's constant equation. Meanwhile, the GA-PPC-Kmeans model is established to divide BCE into different regions. Then, the STIRPAT-Ridge model is built to predict the peak carbon emissions. Finally, a combination of static and dynamic methods is used to forecast peaks under three scenarios, which are low-carbon (LC) scenario, baseline (BA) scenario, and high-carbon (HC) scenario. The results show that five pivotal factors significantly impact BCE in China, which are energy carbon emission intensity (ECEI), energy intensity (EI), economic density (ED), residential housing level (RHL) and population size(P). Furthermore, BCE is categorized into five distinct regions: low-carbon demonstration area, energy efficiency improvement area, carbon concentration and innovation area, high-carbon optimization area, and carbon poverty development area. Under BA scenario, the peaks for BCE in these regions converge primarily around 2040 and 2045. This study provides a regional research perspective for China's residential buildings to reach the peak of carbon emissions, and serves as a reference for formulating carbon emission reduction plans in different regions.

Short-term sedimentary evidence for increasing diatoms in Arctic fjords in a warming world

Arctic fjords are hotspots of marine carbon burial, with diatoms playing an essential role in the biological carbon pump. Under the background of global warming, the proportion of diatoms in total phytoplankton communities has been declining in many high-latitude fjords due to increased turbidity and oligotrophication resulting from glacier melting. However, due to the habitat heterogeneity among Svalbard fjords, diatom responses to glacier melting are also expected to be complex, which will further lead to changes in the biological carbon pumping and carbon sequestration. To address the complexity, three short sediment cores were collected from three contrasting fjords in Svalbard (Krossfjorden, Kongsfjorden, Gronfjorden), recording the history of fjord changes in recent decades during significant glacier melting. The amino acid molecular indicators in cores K4 and KF1 suggested similar organic matter degradation states between these two sites. In contrast to the turbid Kongsfjorden and Gronfjorden, preserved fucoxanthin in Krossfjorden indicated a continuous increase in diatoms since the mid-1980s, corresponding to a 59 % increase in biological carbon pumping, as quantified by the δ13C of sedimentary organic carbon. The increasing biological carbon pumping in Krossfjorden is further attributed to its hard rock types in the glacier basin, compared to Kongsfjorden and Gronfjorden, which are instead covered by soft rocks, as confirmed by a one-dimensional model. Given the distribution of rock types among basins in Svalbard, we extrapolate our findings and propose that approximately one-fifth of Svalbard's fjords, especially those with hard rock basins and persistent marine-terminated glaciers, still have the potential for an increase in diatom fractions and efficient biological carbon pumping. Our findings reveal the complexity of fjord phytoplankton responses and biological carbon pumping to increasing glacier melting, and underscore the necessity of modifying Arctic marine carbon feedback to climate change based on results from fjords underlain by hard rocks.

Climate neutrality of the French energy system: overview and impacts of sustainable aviation fuel production

CO2 emission reduction of sectors such as aviation, maritime shipping, road haulage, and chemical production is challenging but necessary. Although these sectors will most likely continue to rely on carbonaceous energy carriers, they are expected to gradually shift away from fossil fuels. In order to do so, the prominent option is to utilize alternative carbon sources—like biomass and CO2 originating from carbon capture—for the production of non-fossil carbonaceous vectors (biofuels and e-fuels). However, the limited availability of biomass and the varying nature of other carbon sources necessitate a comprehensive evaluation of trade-offs between potential carbon uses and existing sources. Then, it is primordial to understand the origin of carbon used in sustainable aviation fuel (SAF) to understand the implications of defossilizing aviation for the energy system. Moreover, the production of SAF implies deep changes to the energy system that are quantified in this work. This study utilizes the linear programming cost optimization tool EnergyScope TD to analyze the holistic French energy system, encompassing transport, industry, electricity, and heat sectors while ensuring net greenhouse gas neutrality. A novel method to model and quantify carbon flows within the system is introduced, enabling a comprehensive assessment of greenhouse gas neutrality. This study highlights the significance of fulfilling clean energy requirements and implementing carbon dioxide removal measures as crucial steps toward achieving climate neutrality. Indeed, to reach climate neutrality, a production of 1,046 TWh of electricity by non-fossil sources is needed. Furthermore, the findings underscore the critical role of efficient carbon and energy valorization from biomass, providing evidence that producing fuels by combining biomass and hydrogen is optimal. The study also offers valuable insights into the future cost and impact of SAF production for air travel originating from France. That is, the European law ReFuelEU would increase the price of plane tickets by +33% and would require 126 TWh of hydrogen and 50 TWh of biomass to produce the necessary 91 TWh of jet fuel. Finally, the implications of the assumption behind the production of SAF are discussed.

Mechanochemical carbonation of recycled concrete fines: Towards a high-efficiency recycling and CO2 sequestration

The relative slow carbonation efficiency for conventional wet and dry carbonation of recycled concrete fines (RCF) limits its resource industrial utilization. In this study, an innovative mechanochemical carbonation (MC) method was developed. The carbonation kinetics, phase assemblage and microstructure evolution of RCF during the MC process were extensively examined. The results exhibited a substantial enhancement in the carbonation efficiency and CO2 utilization rate, as evidenced by achieving a notable carbonation degree within 10 min. This accomplishment surpassed what could be achieved even after a prolonged 2 h period of wet carbonation, and the CO2 uptake capacity and utilization rate achieved via MC reached >0.3 g-CO2/g-RCF and 80 %, respectively. The superior performance of MC was ascribed to the influence of mechanochemical effects. These effects contributed to the refinement in the geometrical characteristics of RCF, exfoliation of the passivating layers, and facilitation of CO2 dissolution, which favored the structural disintegration of RCF and carbonation progress. Another distinctive aspect of MC treatment was the production of a greater proportion of metastable CC characterized by reduced crystalline size, which was attributed to modifications in the carbonation environment and the structural alterations induced by mechanochemical effects. Moreover, the precipitation of silica gels commenced at approximately 4 min in the MC process, a notably earlier onset when compared with wet carbonation; additionally, a greater abundance of silica gels was observed in the current MC procedure, resulting from the higher carbonation degree caused by mechanochemical effects. The encouraging conclusions in the present work validated the feasibility of producing carbonated RCF more efficiently and paved the way for future industrial practice.

Effects of wet carbonation with ethanol solution on the mechanical, durability properties, and microstructure of recycled concrete aggregates and derived block products

The carbonation treatment of recycled concrete aggregates (RCA) can significantly enhance their properties and reusability. To improve carbonation efficiency, a wet cyclic carbonation method using ethanol solution was proposed to treat RCA and a wet carbon curing method was applied to its product, recycled blocks (RB). The results showed that wet carbonation with 30 % ethanol solution for 10 min significantly reduced RCA’s water absorption and crushing index and increased its apparent density. This is attributed to ethanol’s high carbon-solubilizing properties, which allow the RCA to generate more calcium carbonate precipitates to fill the voids and optimize the pore structure. When the concentration of ethanol solution was increased above 50 %, the improvement was inefficient and limited. In addition, the second cycle of wet carbonation can further improve the properties of RCA. Optimally processed RCA was used to make recycled masonry blocks. The 10 min wet carbonation curing proved beneficial to the mechanical properties of RB and also improved its resistance to shrinkage and salt freeze-thaw. This rapid method enhances RCA construction materials' performance and durability, improving industrial use in sustainable construction materials.

In-situ co-growth of ZIF-8-derived bio-carbon spheres with meso-macroporous hierarchy for stable and rapid carbon dioxide capture

Efficient carbon dioxide (CO2) capture from post-combustion flue gases is crucial for industrial applications. Adsorbents with high adsorption capacity, exceptional stability, high selectivity, and low cost are essential to meet these requirements. In this study, we present the synthesis of bio‑carbon spheres derived from zeolitic imidazolate framework-8 (ZIF-8) using a macro-fluidic technique. The bio‑carbon spheres integrate ZIF-8 for structural orientation and chitosan for the directional assembly of ZIF-8, thereby addressing the limitations of low strength in chitosan-derived carbon spheres and the challenge of macroscopic shaping of ZIF-8 particles. Additionally, the incorporation of ZIF-8 and the enhancement of the carbon skeleton increased the meso-macroporosity, improving CO2 transport and adsorption performance. The bio‑carbon spheres demonstrated a 46.9% higher CO2 adsorption capacity (101 kPa, 1.40 mmol·g−1) compared to pure chitosan carbon granules (101 kPa, 0.96 mmol·g−1) and a 17.8% faster mass transport rate compared to ZIF-8 carbon particles. Moreover, the bio‑carbon spheres exhibit a low wear rate in a simulated fluidized bed, good thermal stability, and stable cyclic regeneration performance. This study offers a novel strategy for developing industrially applicable adsorbents with hierarchical pore structures to enhance CO2 capture.

A critical review on synthesis and application aspect of venturing the thermophysical properties of hybrid nanofluid for enhanced heat transfer processes

Recently, nanofluids (NFs) have gathered significant attention among researchers due to their varied properties, which can be made per the requirements. NFs, created by infusing nanoparticles into a base-fluid, enhance their fundamental properties. A hybrid nanofluid (HNF) is a nanofluid (NF) containing different types of nanoparticles, and it is being studied for its customizable properties. Recently, researchers delved into the applications regarding HNFs, particularly in cases relating to heat transfer (HT). This study analyzes HNFs’ preparation methods and thermophysical properties, giving more importance to their applications in HT, including heat-exchange, solar thermal, and cooling systems. Considering stability, the two-step synthesis method is preferred over the single-step method. Multiple research efforts have led to the development of a fluid that possesses superior HT capabilities compared to the base-fluid. However, while bettering HT, an increase in volume concentration (VC) also raised challenges such as increased viscosity and pressure drop, particularly in porous media, necessitating additional pumping power. The use of turbulators and other configurations, along with HNF in systems like parabolic trough solar collectors (PTSCs), enhances solar thermal systems (STSs) by improving their HT capabilities. An advantageous use of EG-based multiwalled carbon nanotubes (MWCNTs) NF in solar collectors (SCs) is their ability to increase thermal efficiency and decrease carbon dioxide emissions, making them an attractive choice for use in SCs. Researchers face significant challenges in determining the ideal composition and concentration of nanoparticles in HNFs to attain optimal HT without causing excessive viscosity that could impede practical usability. Specifically, this study examines the distinctive thermophysical characteristics of HNFs that substantially improve their efficacy in HT applications.

Natural carbonation boost for hardened cement fines by dripping technique

This study proposes a dripping technique to improve the carbonation efficiency of hardened cement fine (HCF), which mimicked the binder part of waste concrete, sized between 0.6 mm and 1.18 mm under atmospheric CO2 concentration. After a 7-day carbonation using the dripping technique, the carbonation degree doubled compared with that at 85 % relative humidity (RH). This improved carbonation efficiency can be attributed to two factors: 1) The pores created during drying accelerate the infiltration of the solution, releasing more calcium ions; 2) The difference in calcium ion concentration between the surface aqueous film and pore solution causes calcium ions to migrate to the surface, accelerating the dissolution of calcium-bearing hydrates in the pore solution and releasing more calcium ions. Adjusting the dripping interval and drying conditions according to the particle size and amount of carbonatable calcium improves the carbonation efficiency. This strategic approach offers a practical means to contribute to the sustainable recycling of waste concrete.

Carbon emission trading, carbon efficiency, and the Porter hypothesis: Plant-level evidence from China

Focusing on large thermal power plants in China, we examine the causal effect of carbon emission trading scheme (CETS) on their carbon emission efficiency. Using the staggered installation of CETS pilots as a natural experiment, we show that carbon emission trading significantly improves power plants’ carbon efficiency. Specifically, the CETS leads to a 6.9 % increase in carbon efficiency. The carbon efficiency growth effects are stronger for plants that are not state-owned, large in scale, or plants located in regions with high level of marketization. Moreover, the improvement in carbon efficiency mainly comes from the reduction in carbon emission, not the improvement in power generation level. The mechanism analysis indicates that the implementation of CETS increases the number of granted patents by as much as 23 %, which provides supporting evidence for the Porter hypothesis.

Does vegetation greening have a positive effect on global vegetation carbon and water use efficiency?

Terrestrial ecosystems have undergone significant changes as a result of climate change, profoundly affecting global carbon and water cycling processes. Notably, the synergistic changes in vegetation carbon use efficiency (CUE) and water use efficiency (WUE) and their response to patterns of climate change over the last 40 years are unknown. Therefore, in this study, global vegetation WUE and CUE were inverted using Gross primary productivity (GPP), Net primary productivity (NPP) and total evaporation (ET) data from 1981 to 2019 to reveal their temporal and spatial patterns of change through trend analysis and stability analysis. A stepwise regression algorithm was used to reveal the potential driving law of environmental factors on vegetation WUE and CUE. The results shows that (1) From 1981 to 2019, the global vegetation WUE and CUE showed in a relatively stable state, and the trends of WUE and CUE were -0.00004/year and 0.006 g C m−2 mm−1/year, respectively; (2) the greening of vegetation was the most important cause of the changes in WUE and CUE, and the driving force of rain and heat conditions on the CUE of vegetation was smaller than that of solar radiation and soil water, the regions where CO2 is the dominant factor affecting CUE and WUE are mainly in the north temperate zone; (3) the region of synergistic growth of WUE and CUE accounts for about 31.38 % of the global terrestrial area, and this pattern of change suggests that the global vegetation carbon sink potential is huge, and the popularization of vegetation planting patterns under the synergistic growth of CUE and WUE should be strengthened. The research has shown that vegetation greening is a key factor influencing changes in the WUE and CUE of vegetation, therefore, the implementation of ecological engineering will be an important step in combating climate change.

Unlocking the efficacy of cement-shell encapsulation for microbial self-healing process of concrete cracks

Oxygen supply and bacterial viability are crucial for efficient calcium carbonate precipitation in concrete crack healing processes. However, the open deliverance of oxygen-releasing compounds (ORCs) and bacterial spores during concrete mixing and casting poses a threat to spore viability and limits oxygen availability. To address these challenges, we developed an innovative approach integrating an oxygen self-supply strategy with bacterial strain B6. As such, B6 spores, along with Ca(OH)2 and CaO2 as oxygen sources and essential nutrients, were embedded within cement-shell microcapsules to build a microbial self-healing system. The result shows that in the presence of oxygen source and nutrients, B6 group (BPN) exhibits successful crack repair, achieving a repair ratio of approximately 100% after 30 days, while other control groups show less effective repair rates (20–60%). Moreover, water permeability significantly improves in the BPN specimens after crack repair, reaching 0 ml/cm−2·min, highlighting the efficacy of the developed self-healing system. Encapsulating the healing agent within cement shell effectively mitigates the reactivity between ORCs (CaO2) and water, thereby facilitating stable oxygen supply and safe delivery of microbial agents during crack healing. Furthermore, in-situ micromorphology and composition identification of crack repair materials affirm the presence of calcium carbonate precipitation to seal the concrete cracks. The encapsulation of healing material within cement shell stands out as an innovative approach, demonstrating an efficient self-healing process of concrete cracks. These findings might unveil new possibilities for bio-concrete to be used in sustainable and resilient construction practices, particularly in environments prone to cracking and water ingress.

Fe-Co co-doped 1D@2D carbon-based composite as an efficient catalyst for Zn-air batteries

A Fe-Co dual-metal co-doped nitrogen-containing carbon composite (FeCo-HNC) was prepared by adjusting the ratio of iron to cobalt as well as the pyrolysis temperature with the assistance of functionalized silica template. Fe1Co-HNC, which was made from 1D carbon nanotubes and 2D carbon nanosheets with a rich mesoporous structure, presented exceptional oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) catalytic activity. The ORR half-wave potential is 0.86 V (vs. reversible hydrogen electrode, RHE), and the OER overpotential is 0.76 V at 10 mA cm−2 with the Fe1Co-HNC catalyst, which can be applied to zinc-air batteries with superior performance. It is worth noting that the zinc-air batteries with Fe1Co-HNC-1000 as the cathodic catalyst achieved the highest power density of 94.9 mW cm−2 under a current density of 159.8 mA cm−2. This method provides a promising strategy for fabricating efficient transition metal-based carbon catalysts.

Physics-constrained deep learning approach for solving inverse problems in composite laminated plates

The applications of physics-informed neural networks (PINNs) in material parameters identification of composite laminates are currently research highlights. We present an efficient physics-constrained deep learning approach based on PINNs for solving material parameters of composite laminates. We explain the details of incorporating first-order shear deformation theory as physical information into designed loss functions. The performance of proposed approach is demonstrated through a numerical example of idealized composite laminated plates under uniform pressure conditions. The computational errors of material parameters are less than 0.1%. Moreover, the applicability of transfer learning (TL) has been illustrated for inversion of material parameters with few datasets. The ambition is to improve the identification efficiency of carbon and glass fiber reinforced plies material parameters across various loading conditions. Intensive studies are conducted to compare convergence time between with and without TL through a numerical example under thermal-force coupling conditions. The comparison shows PINNs with TL obtain average error of 0.144% and 0.077% in carbon and glass fiber reinforced plies, which is better than without TL of 0.472% and 0.284%, respectively. The proposed work emphasizes the effective application of PINNs-based approach that combines first-order deformation and data-driven solution features for inverse solving material parameters of composite laminates.

Non-stoichiometric protic ionic liquids for efficient carbon dioxide capture and subsequent conversion under mild conditions

Protic ionic liquids (PILs) have emerged as innovative solvents with significant potential for CO2 capture and transformation, presenting a sustainable alternative to conventional methods which often involve energy-intensive processes or environmentally detrimental chemicals. Herein, a novel strategy for CO2 capture and conversion at mild conditions using non-stoichiometric protic ionic liquids (NPILs) was demonstrated for the first time. These NPILs, employed as sorbents, solvents, and catalysts, were composed of imidazole (Im) and 1,8-diazabicyclo [5.4.0] undec-7-ene (DBU) in various ratios. Correlations between the mole ratio of DBU/Im and physicochemical properties such as viscosity, conductivity, thermal stability, and the distribution of neutral and ionic species were systematically investigated. Effects of the absorption temperature and CO2 partial pressure on the absorption capacity were also studied. Different absorption mechanisms, including carbonate and carbamate pathways, were analyzed using FT-IR and NMR spectroscopy. Moreover, the fixed CO2 could be catalytically converted to quinazoline-2,4(1H,3H)-diones under exceptionally mild reaction conditions (1 atm, 50 °C, metal-free process). A plausible reaction mechanism involving simultaneous CO2 activation and substrate activation for the transformation of CO2 into quinazoline-2,4(1H,3H)-diones was verified through NMR spectra. It is believed that the new insights into the CO2 mechanism will facilitate the rational design of functional ionic liquids for CO2 capture, utilization, and storage in the future.