In the modelling of heat, mass and momentum transfer phenomena which occur in a capillary porous medium during drying, the liquid and gas flows are usually described by the generalised Darcy laws. Nevertheless, the question of how to determine experimentally the relative permeability relations remains unanswered for most materials that consist of water and humid air, and as a result, arbitrary functions are used in the drying codes. In this paper, the emphasis is on deducing from both numerical and experimental studies a method for estimating pertinent relations for these key parameters. In the first part, the sensitivity of liquid velocity and, consequently, of drying kinetics in the variation of the relative permeabilities is investigated numerically by testing various forms. It is concluded that in order to predict a realistic liquid velocity behaviour, relative permeabilities can be linked to a measurable quantity: the capillary pressure. An estimation technique, based on simulations coupled with experimental measurements of capillary pressure, together with moisture content kinetics obtained for low or middle temperature convective drying, is deduced. In the second part, the proposed methodology is applied to pine wood. It is shown that the obtained relations provide closer representation of physical reality than those commonly used.