The Wire Electrical Discharge Machining (WEDM) process is an accurate method for manufacturing high-added-value components for industry. Continuous developments in the process have resulted in specialized machines used in sectors such as aerospace and biomedical engineering. However, some fundamental aspects of the discharge process remain unresolved. This work aims to study the influence of discharge location and bubble expansion on the occurrence of subsequent discharges. A high-speed video camera observation system was constructed to capture images of each discharge. From the acquired images, an algorithm was devised to determine the discharge location based on grayscale analysis. Moreover, the voltage and current waveforms of the discharges and the framing signals of the high-speed video camera were then obtained using an oscilloscope. Synchronizing the observation images and signals allowed for calculating the delay time for each single discharge. The results indicate that most of the discharges occurred near the boundary of the bubble and during bubble expansion. This finding has been observed for a variety of machining conditions and can be explained by the effect of the debris particles concentrated at the bubble boundary. This study provides useful information for better understanding the discharge process in WEDM.