Calcium Oxide Nanoparticles Research Articles

Seed Nano-Priming with Calcium Oxide Maintains the Redox State by Boosting the Antioxidant Defense System in Water-Stressed Carom (Trachyspermum ammi L.) Plants to Confer Drought Tolerance.

This paper explores the potential of nano seed priming with calcium oxide nanoparticles in maintaining the redox status in carom (Trachyspermum ammi L.) plants by modulating non-enzymatic antioxidants and enzymatic antioxidants. Calcium oxide nanoparticles were prepared in four testing regimes comprising 25, 50, 75, and 100 ppm along with the control treatment of 0 ppm (distilled water). Priming was performed by soaking the carom seeds in the aerated water, and plants were grown under split plots corresponding to drought and water. Seed priming with 75 ppm CaONPs reduced hydrogen peroxide, malondialdehyde contents and electrolyte leakage by 23.3%, 35.9% and 31.6%, respectively, in the water-stressed carom plants. The glutathione s-transferase, superoxide dismutase and peroxidase functions improved under water stress by 42.3%, 24.1% and 44.8%, respectively, in the carom plants raised through 100 ppm primed seeds with CaO_NPs. Priming induced better Ca2+ signaling, which affected the enzymes of the ascorbate glutathione cycle, enabling them to maintain redox status in the carom plants exposed to drought stress. The morpho-agronomic traits of carom plants in terms of number of umbels, hundred seeds weights, shoot and root length and biomass improved significantly upon seed priming treatments. Seed priming with CaO_NPs is a viable strategy to combat reactive oxygen species-mediated damages in the carom plants.

Quantum and experimental investigation of the application of Crassostrea gasar (mangrove oyster) shell–based CaO nanoparticles as adsorbent and photocatalyst for the removal of procaine penicillin from aqueous solution

The present study was designed to synthesize and characterize calcium oxide nanoparticles (using mangrove oyster shell as a precursor) and apply the synthesized nanoparticles as a photocatalyst to degrade procaine penicillin in an aqueous solution. The photocatalyst exhibited an average band gap of 4.42eV, showed a maximum wavelength of absorbance in the UV region (i.e., 280nm), and is a microporous nanoparticle with a particle diameter of 50nm. The photocatalyzed degradation of the drug was conducted under natural sunlight, and the influence of parameters such as the period of contact, catalyst load, pH, initial drug concentration, and ionic strength was investigated concerning the degradation profile. The results obtained from response surface analysis indicated that an optimum degradation efficiency of about 93% can be obtained at a concentration, pH, and catalyst dosage of 0.125M, 2, and 0.20g respectively, at 0.902 desirabilities. The Langmuir-Hinshelwood, modified Freundlich, parabolic diffusion, pseudo-first-/second-order, and zero-, first-, and second-order kinetic parameters were tested to ascertain the best model that best described the experimental data. Consequently, the Langmuir-Hinshelwood, modified Freundlich, and pseudo-second-order models were accepted based on the minimum error and higher R2 values. Based on the Langmuir-Hinshelwood rate constants for adsorption and photodegradation as well as the evaluated valence bond potential, the degradation of the drug first proceeded through the mechanism of adsorption and followed by the oxidation of the drug by superoxide (generated from the interaction of electrons that generated by through the absorption of UV radiation). The quantum chemical calculation gave evidence that pointed towards the establishment of strong agreement with experimental data and also showed that the carboxyl functional group in the drug is the target site for adsorption and subsequent degradation.

Biosynthesis and Characterization of Calcium Oxide Nanoparticles from Citrullus colocynthis Fruit Extracts; Their Biocompatibility and Bioactivities

Modern nanotechnology encompasses every field of life. Nowadays, phytochemically fabricated nanoparticles are being widely studied for their bioactivities and biosafety. The present research studied the synthesis, characterization, stability, biocompatibility, and in vitro bioactivities of calcium oxide nanoparticles (CaONPs). The CaONPs were synthesized using Citrullus colocynthis ethanolic fruit extracts. Greenly synthesized nanoparticles had an average size of 35.93 ± 2.54 nm and showed an absorbance peak at 325 nm. An absorbance peak in this range depicts the coating of phenolic acids, flavones, flavonols, and flavonoids on the surface of CaONPs. The XRD pattern showed sharp peaks that illustrated the preferred cubic crystalline nature of triturate. A great hindrance to the use of nanoparticles in the field of medicine is their extremely reactive nature. The FTIR analysis of the CaONPs showed a coating of phytochemicals on their surface, due to which they showed great stability. The vibrations present at 3639 cm-1 for alcohols or phenols, 2860 cm-1 for alkanes, 2487 cm-1 for alkynes, 1625 cm-1 for amines, and 1434 cm-1 for carboxylic acids and aldehydes show adsorption of phytochemicals on the surface of CaONPs. The CaONPs were highly stable over time; however, their stability was slightly disturbed by varying salinity and pH. The dialysis membrane in vitro release analysis revealed consistent nanoparticle release over a 10-h period. The bioactivities of CaONPs, C. colocynthis fruit extracts, and their synergistic solution were assessed. Synergistic solutions of both CaONPs and C. colocynthis fruit extracts showed great bioactivity and biosafety. The synergistic solution reduced cell viability by only 14.68% and caused only 16% hemolysis. The synergistic solution inhibited Micrococcus luteus slightly more effectively than streptomycin, with an activity index of 1.02. It also caused an 83.87% reduction in free radicals.

Effect of calcium oxide, zinc oxide nanoparticles and their combined treatments on growth and yield attributes of Solanum lycopersicum L.

Tomato (Solanum lycopersicum L. Syn Lycopersicon esculentum Mill.) occupies a significant position among vegetable crops. With the increasing population, the food supply is going to be short and will be causing a major problem. Therefore, the enhancement of crop production is necessary for food security. To enhance nutrient efficiency and yield in an agricultural field, nanotechnology can play a key role. In the present study, zinc oxide (ZnO) and calcium oxide (CaO) nanoparticles (NPs) were synthesized by following green synthesis i.e., by using water extract of Nigella sativa seeds. These particles were characterized by UV visible spectroscopy and particle size analyzer. A UV–visible spectrum of ZnO and CaO NPs showed absorption peaks at 230 nm and 220 nm respectively. The particle size of 50–60 nm and 5 to 10 nm was observed for ZnO and CaO nanoparticles respectively. Sterilized seeds of tomato were germinated and grown in pots, which were treated with foliar spray of ZnO, and CaO nanoparticles in various concentrations (50, 100, 200 ppm) with three replications separately. The effect of ZnO, CaO, and CaO + ZnO NPs was observed by measuring vegetative growth parameters (i.e. plant length, number of leaves/plant, leaf area/plant, fresh and dry weight of the whole plant) and biochemical parameters (i.e. titratable acidity, total phenolics and zinc and calcium metal content). Results revealed that nano-spray of CaO and ZnO NPs gave positive results on the physiological parameters of tomato plants. A combined effect of ZnO and CaO on S. lycopersicum was significantly higher as compared to the separate treatments of ZnO and CaO. The combined effect of ZnO + CaO with the concentration of 50 ppm gave positive results in shoot length, number of shoots, number of roots, yield/plant, fruit weight, and leaf area. Whereas, root length, plant weight, and fruit diameter were higher at 200 ppm of ZnO + CaO. Biochemical parameters were also improved by using the nano-spray application as CaO < ZnO < ZnO + CaO respectively. The research proved to be cost-effective, less toxic, and eco-friendly which will also be beneficial for future perspectives.

Synergistic application of calcium oxide nanoparticles and farmyard manure induces cadmium tolerance in mung bean (Vigna radiata L.) by influencing physiological and biochemical parameters.

Mung bean (Vigna radiata L.) grown under heavy metals such as cadmium stress shows poor growth patterns and yield attributes which can be extenuated by the application of calcium and organic manure to the contaminated soil. The present study was designed to decipher the calcium oxide nanoparticles and farmyard manure-induced Cd stress tolerance through improvement in physiological and biochemical attributes of mung bean plants. A pot experiment was conducted by defining appropriate positive and negative controls under differential soil treatments with farmyard manure (1% and 2%) and calcium oxide nanoparticles (0, 5, 10, and 20 mg/L). Root treatment of 20 mg/L calcium oxide nanoparticles (CaONPs) and 2% farmyard manure (FM) reduced the cadmium acquisition from the soil and improved growth in terms of plant height by 27.4% compared to positive control under Cd stress. The same treatment improved shoot vitamin C (ascorbic acid) contents by 35% and functioning of antioxidant enzymes catalase and phenyl ammonia lyase by 16% and 51%, respectively and the levels of malondialdehyde and hydrogen peroxide decreased by 57% and 42%, respectively with the application of 20 mg/L CaONPs and 2% of FM. The gas exchange parameters such as stomata conductance and leaf net transpiration rate were improved due to FM mediated better availability of water. The FM improved soil nutrient contents and friendly biota culminating in good yields. Overall, 2% FM and 20 mg/L CaONPs proved as the best treatment to reduce cadmium toxicity. The growth, yield, and crop performance in terms of physiological and biochemical attributes can be improved by the application of CaONPs and FM under the heavy metal stress.

Facile synthesis of copolymerized cellulose grafted hydrogel doped calcium oxide nanocomposites with improved antioxidant activity for anti-arthritic and controlled release of doxorubicin for anti-cancer evaluation

The combination treatment is considered an approach to attaining synergistic impact while minimizing applied dosage. Hydrogels are analogous to the tissue environment attributed to hydrophilic and porous structure. Despite extensive study in biological and biotechnological domains, their restricted mechanical strength and limited functionalities impede their potential uses. Emerging strategies are centred on research and developing nanocomposite hydrogels to combat these issues. Herein, we prepared copolymerized hydrogel by grafting poly-acrylic acid P(AA) onto cellulose nanocrystals (CNC) and adding CNC-g-PAA as dopant (2 and 4 wt%) in calcium oxide (CaO) nanoparticles to generate an effective hydrogel doped nanocomposite (NCH) (CNC-g-PAA/CaO) for biomedical applications such as anti-arthritic, anti-cancer, and antibacterial investigations alongside their comprehensive characterization. CNC-g-PAA/CaO (4 %), compared to other samples, had a substantially higher antioxidant potential (72.21 %). Doxorubicin, a potential chemotherapeutic drug, was then effectively loaded into NCH (99 %) via electrostatic interaction, and pH-triggered based release was found to be >57.9 % in 24 h. Furthermore, molecular docking investigation against targeted protein Cyclin-dependent kinase 2 and in vitro cytotoxicity study verified the improved antitumor effectiveness of CNC-g-PAA and CNC-g-PAA/CaO. These outcomes indicated that hydrogels might serve as potential delivery vehicles for innovative multifunctional biomedical applications.

EVALUATION OF CALCIUM OXIDE NANOPARTICLES TO ENHANCE HEAVY METAL STRESS TOLERANCE IN PLANTS

Heavy metal contamination is a severe environmental problem affecting global food production and safety. Heavy metal stress due to its toxicity, bioaccumulation, and non-biodegradability, it become quite serious in nature. The available strategies for preventing heavy metal contamination are not frequently used because of their inefficient and time- or money-consuming properties. Recent developments in nanotechnology have been made based on ameliorative strategies which have a potential alternative to physic-chemical methods. Under heavy metal stress, the application of calcium oxide nanoparticles (CaO-NPs) significantly boosts plant biomass, anti-oxidative enzyme activities (such as catalase (CAT), ascorbate peroxidase (APX), superoxide dismutase (SOD), and glutathione reductase (GR)), and the level of non-enzymatic antioxidants (ascorbate and glutathione). Additionally, CaO-NPs enhance the gene expression linked to anti-oxidative enzymes. It can be suggested that CaO-NPs could be used as a potential chemical to reduce heavy metal uptake and toxicity in the plants grown under heavy metal contaminated soil. This review provides an overview of plant-CaO-NPs research in increasing heavy metal stress tolerance in plants.

Modified calcium oxide nanoparticles derived from oyster shells for biodiesel production from waste cooking oil

SiO2np derived from rice husk were chemically connected to the surface of modified Calcium Oxide (CaO) in a straightforward manner to produce fatty acid methyl ester (FAME) from waste cooking oil (WCO) with great efficiency. After 3 h at a reaction temperature of 80° C, it was discovered that WCO could produce 97.8% yield of the FAME of the modified CaO, which is much greater than the yield of 83.5% over unmodified CaO under the same reaction circumstances. The results showed that following modification, well-dispersed CaO with relatively tiny particle sizes and large surface areas was produced. Additionally, the changed CaO with very little Ca(OH)2 is produced during the modification process. The use of leftover modified CaO-nanoparticles as a heterogeneous transesterification catalyst has been identified after fourteen cycles.

Effects of green synthesized calcium oxide nanoparticles from extracts of Citrullus colocynthis on body weight, plasma atherogenic index, and histology of liver and stomach of high-fat-diet-fed rats

Citrullus colocynthis has been used to treat obesity and hyperlipidemia. Nanoparticles, due to their nano size, phytochemical adsorption, improved systemic absorption and high bioavailability, can potentially improve the bioactivity of C. colocynthis. The present research focused on studying the effects of green synthesized calcium oxide nanoparticles (CaONPs) from C. colocynthis fruit extracts (CCFE) on the body weight, the atherogenic index of plasma (AIP), and the histopathology of male albino rats. Ethyl??-d-glucopyranoside was the major constituent of CCFE, along with phenols and fatty acids. The total phenolic and flavonoid contents of CCFE were 203.52 and 173.56 mg/g, respectively. Male albino rats (n=36) were divided into six groups (six rats per each group). Rats in different groups received a normal diet, a high?fat diet (HFD), HFD with lovastatin (10 mg/kg), HFD with CCFE (20 mg/kg), HFD with CaONPs (2 mg/kg), and HFD with a synergistic solution of CCFE (10 mg/kg) and CaONPs (1 mg/kg), respectively. When CaONPs were administered in combination with CCFE, significant weight-lowering activity (36.36%), improved cardiovascular health as per AIP (0.12?0.01b), and fewer disturbances in liver function parameters were observed. Histological analysis at the end of the experiment showed that CaONPs were not toxic to the gastric mucosa and were slightly toxic to hepatocytes. It can be concluded that CaONPs synthesized from CCFE can be a potent weight-lowering and antilipidemic agent with fewer side effects.

Effect of nanoparticles on antibacterial efficacy of intracanal medicament: A scoping review

ABSTRACT Aim: The aim of this scoping review is to highlight the effect of nanoparticles (NPs) when incorporated as an intracanal medicament to direct imminent research to understand the efficiency of NPs in clinical scenarios. Methods: A PubMed, Scopus, EBSCO host, and manual search were performed April 18, 2022. Inclusion criteria were set that had to be met by each study for it to be selected for the review. “The review was conducted according to the Preferred Reporting Items for Systematic Reviews and Meta-Analyses extension for Scoping Reviews Checklist.” Results: Ten in vitro studies that fulfilled the inclusion criteria were included in this review. Six studies evaluated silver NPs, one study with bioactive glass NPs, one study with chitosan-propolis NPs, one study with zinc oxide NPs, two studies with calcium hydroxide NPs, and one with calcium oxide NPs. In endodontics, materials such as zinc oxide and silver NPs disturb biofilm and lessen bacterial load within biofilm. The small size of the particles allows them to readily penetrate greater depths into dentinal tubules, resulting in an amplified antimicrobial action on root canal pathogens. Conclusion: According to the included studies, the findings indicate that the antibacterial efficacy of intracanal medicament was higher in groups containing NPs and provide a basis for future studies to be conducted in vivo and direct future research on NPs and its various unexplored applications.

In vitro and in vivo study on antiprotozoal activity of calcium oxide (CaO) and magnesium oxide (MgO) nanoparticles on promastigote and amastigote forms of Leishmania major

Background: Currently, anti-leishmanial drugs have been developed. However, the available compounds have several side effects such as drug resistance and toxicity that cause some limitation for use. The development of nanoparticles (NPs) use in biological research and the proven effectiveness of CaONPs and MgONPs on bacteria and fungi, along with the lack of information about its antileishmanial effects, have motivated this study. CaO and MgONPs possess considerable antibacterial effects because of their alkalinity and active oxygen species. This study has taken into account the impacts of these two NPs on the L. major in vitro and in vivo. Methods: To evaluate the antileishmanial activity of NPs, the cytotoxic effect of CaONPs, MgONPs, and MgOCaONPs against L. major amastigotes, promastigotes, as well as macrophages, was evaluated using counting or MTT assay. The possible apoptosis of L. major by CaONPs, MgONPs, and MgOCaONPs was evaluated via flow cytometry assay. For in vivo study, BALB/c mice were allocated to five groups and the lesions of infected mice with L. major promastigotes were treated with a 200 μg/mL concentration CaONPs, MgONPs, and MgOCaONPs, then the mice underwent a 4-week follow-up to examine the wound diameter and survival rates. Results: The XRD-pattern related to CaONPs and MgONPs indicating the cubic phase and Rocksalt cubic structures. According the effects of nanoparticle on promastigotes the IC50 values of CaONPs, MgONPs, and MgOCaONPs within 72 h were 7.9 ug/mL, 10.3 ug/mL, and 8.0 ug/mL respectively. CaONPs, MgONPs, and MgOCaONPs induced apoptosis in about 7.8%, 53.57%, and 12.8% of promastigotes. All mice presented lesions. MgONPs was the most effective in reducing the size of the lesions. Conclusion: According to the results of the present research, MgONPs and CaONPs showed good in vitro and in vivo effects on L. major promastigotes and intracellular amastigotes especially MgONPs, and also it seems that MgONPs are applicable in Leishmania infection treatment due to their potential antileishmanial effects.

Seed priming with Calcium oxide nanoparticles improves germination, biomass, antioxidant defence and yield traits of canola plants under drought stress

• Seed priming with calcium oxide nanoparticles have remediating effects of drought in canola plants. • Seed priming with calcium oxide nanoparticles improves germination parameters of canola plants exposed to drought stress. • Seed priming with calcium oxide nanoparticles improves the growth and antioxidant defence of canola plants under drought. • •Seed priming with calcium oxide nanoparticles improves performance of canola in terms of yield attributes. Recent advances in calcium signalling have proved that calcium plays a key role in mitigating abiotic stresses and strengthening the internal defence of plants. In the present research, calcium was imparted through seed nano-priming with calcium oxide nanoparticles (CaONPs) at concentrations of 25, 50, 75, and 100 ppm compared to control (0 ppm) under PEG-induced drought in the canola plants. During the germination experiment, seedlings were given drought conditions simulated by PEG-6000 treatment maintaining water potential at -0.15 MPa and pH of 5.5 supplemented with Hoagland solution at room temperature. As a control, no PEG-6000 was given. After the germination experiment, a pot experiment was conducted under artificial climate chambers. Seed nano-priming with 75 ppm CaONPs improved germination percentage and seedling fresh weight by 30% and 34% respectively under drought stress. Seed nano-priming with 75 ppm CaONPs increased the number of leaves by 16%, total chlorophyll contents by 28.9%, improved the number of pods per branch, number of seeds per pod, 100 seed weights, and yield by 29.99%, 73.076%, 35.13%, and 35.18% respectively under drought stress. Furthermore, the levels of antioxidant enzymes were improved and levels of stress indicators declined significantly. Present research recommends the use of CaONPs as pre-sowing treatments to the seed to improve the performance of canola plants.

Green synthesis of calcium oxide nanoparticles impregnated activated carbon from algal–bacterial activated sludge: its application in ciprofloxacin removal

Green synthesis of calcium oxide nanoparticles impregnated activated carbon from algal–bacterial activated sludge: its application in ciprofloxacin removal

Synthesis and Study of Structural Properties of Calcium Oxide Nanoparticles Produced by Laser-Induced Plasma and its Effect on Antibacterial Activity

A LIBS technique was used to investigate the antibacterial activity of calcium oxide nanoparticles (CaO NPs). CaO NPs were prepared using a Q-switched Nd: YAG pulsed laser with a fundamental wavelength of 1064 nm at different energies (400-600 mJ) and constant frequency (6 Hz). A calcium powder sample was prepared after being pressed into a disc with a diameter of 1 cm. Analyzing X-ray diffraction (XRD) showed the crystalline structure of CaO NPs, crystalline size was 30.99±2 and 34.20±2.2 nm for laser energy 500 and 600 mJ. (FE-SEM) to reveal the topography of produced CaO NPs, the results showed a homogenous compact and dense surface with the formation of CaO NPs like flakes, cubes, and tubes. Atomic force microscopy (AFM) has shown that the CaO NPs were nanoscale and had a coordinated surface structures. The results also revealed the stabilizing zeta potential of the prepared CaO NPs, average (ZP) -18.3±1.6 mV in 600 mJ and -8.8±2.3 mV for 500 mJ. Different laser energies used in preparing CaO NPs resulted in the varying killing of the number of bacteria Klebsiella pneumoniae and Staphylococcus aureus bacteria. Complete bacterial inhibition or cell growth inactivation was found when the laser energy prepared for the CaO NPs was 600 mJ.

Effect of calcium oxide nanoparticles produced from Lavetira critica leaf extract on the freshness of fresh‐sliced fruits

This study was piloted to assess the fusion of nanoparticles (LCCaNP) from leaf extract of Lavatera critica (LC) and calcium chloride and to observe their impact on the safety of fresh-sliced fruits and extend their shelf life. LCCaNP were synthesized by mixing calcium chloride and LC leaf extract, followed by the addition of sodium hydroxide. The quality of the produced LCCaNP was proven by conducting different physical and chemical tests. Fresh apples, strawberries, and guavas were independently immersed in diverse concentrated LCCaNP and 2% calcium chloride solution for 5 min. These treated sliced fruits were stuffed in polypropylene plastic bags and stored at 5°C. The total soluble solid content (TSS), pH, firmness, and weight reduction rate, 2,2-diphenylpicrylhydrazyl (DPPH), and sensory analysis were conducted for the total storage period of 25 days in a 5-day interval. LCCaNP and calcium chloride were proficient to preserve the fruits for up to 20 days. Our findings showed that LCCaNP-treated fresh-sliced fruits had an improved and enhanced shelf-life than control (nontreated) samples. In conclusion, the leaf of LC is an eventual source for the making of calcium oxide nanoparticles and could serve as an improved food conservation with proficiency to extend the fruit's shelf life for up to 20 days. Novelty impact statement For the first time had produced the natural LCCaNP from a natural plant of LC and evaluated its impact on the safety of fresh-sliced fruits. The natural nanosized LCCaNP is successfully produced by using the natural Ayurvedic plant of LC. LCCaNP acted as a better food preservative and had the capability to extend the shelf life of apples, strawberries, and guavas for up to 20 days without causing any side effects.

Theoretical and experimental studies on photocatalytic removal of methylene blue (MetB) from aqueous solution using oyster shell synthesized CaO nanoparticles (CaONP-O).

The development of technologies for the removal of dye from aqueous solution is most desirable if the end product is relatively green (i.e., environmentally friendly). Photodegradation (as one of such technology) and photolysis (without the catalyst) was applied to investigate the role of sol-gel synthesized calcium oxide nanoparticle (using the oyster shell as the precursor). The results obtained gave substantial evidence that calcium oxide nanoparticles catalyzed the degradation of the methylene blue dye up to a maximum percentage of 98 % removal. Degradation efficiency displayed a strong dependency on time, initial dye concentration, catalyst load, pH, and ionic strength. Chi-square and sum of square error analysis indicated that the photodegradation kinetics fitted the Langmuir-Hinshelwood, first order, and pseudo first-order models best. The half-life of the dye was significantly reduced from hours to minutes due to photocatalysis. Quantum chemical calculations indicated that the degradation proceeded through adsorption, deformation/degradation, and desorption through the chloride end of the molecule linked to the calcium active center of the catalyst. Results from Fukui functions and molecular descriptors analysis confirmed the mechanism of photocatalysis.

Synthesis of Biodiesel from Ricinus communis L. Seed Oil, a Promising Non-Edible Feedstock Using Calcium Oxide Nanoparticles as a Catalyst

This work aimed to synthesize biodiesel from Ricinus communis L., using calcium oxide (CaO) nanoparticles as a catalyst. The CaO nanoparticles were examined by scanning electron microscopy (SEM) and X-Ray Diffraction (XRD). The physico-chemical properties of biodiesel were studied through H and C-NMR, GC-MS, FT-IR, and fuel properties were studied according to ASTM and EN standard methods. The oil content of the feedstock was 53.7% with a free fatty acid (FFA) content of 0.89 mg KOH/g. The suitable condition for the optimum yield (89%) of biodiesel was 1:15 of oil to methanol using 20 mg of catalyst at a temperature of 60 °C for 80 to 100 min of reaction time. The H and C-NMR confirm the biodiesel synthesis by showing important peaks at 3.661, 2.015–2.788, 24.83–34.16 and 174.26 and 130.15 ppm. Similarly, GC-MS spectroscopy confirmed 18 different types of fatty acid methyl esters (FAME) in the biodiesel sample. FT-IR spectroscopy confirmed the synthesis of biodiesel by showing characteristic peaks of biodiesel formation in the range of 1725–1750 cm−1 and 1000–1300 cm−1. The fuel properties were compared with the international ASTM and EN standards. The physico-chemical properties confirm that RCB is both an engine and environmentally friendly fuel.

Efficient, Recyclable, and Heterogeneous Base Nanocatalyst for Thiazoles with a Chitosan-Capped Calcium Oxide Nanocomposite.

Calcium oxide (CaO) nanoparticles have recently gained much interest in recent research due to their remarkable catalytic activity in various chemical transformations. In this article, a chitosan calcium oxide nanocomposite was created by the solution casting method under microwave irradiation. The microwave power and heating time were adjusted to 400 watts for 3 min. As it suppresses particle aggregation, the chitosan (CS) biopolymer acted as a metal oxide stabilizer. In this study, we aimed to synthesize, characterize, and investigate the catalytic potency of chitosan–calcium oxide hybrid nanocomposites in several organic transformations. The produced CS–CaO nanocomposite was analyzed by applying different analytical techniques, including Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and field-emission scanning electron microscopy (FESEM). In addition, the calcium content of the nanocomposite film was measured using energy-dispersive X-ray spectroscopy (EDS). Fortunately, the CS–CaO nanocomposite (15 wt%) was demonstrated to be a good heterogeneous base promoter for high-yield thiazole production. Various reaction factors were studied to maximize the conditions of the catalytic technique. High reaction yields, fast reaction times, and mild reaction conditions are all advantages of the used protocol, as is the reusability of the catalyst; it was reused multiple times without a significant loss of potency.

AND logic gate supported novel speckled phosphorus-doped carbon dots decorated ZrO2/CaO/MgO sonocatalysts for efficient MB dye decolorization

Textile dyes are significant contributors to aquatic pollution in developing nations, and also the current pace of human-caused contamination of worldwide freshwater bodies is frightening. Herein, we report the sonocatalytic decolorization of the methylene blue (MB) dye using a novel synthesis of composite materials of zirconium oxide (ZrO2), calcium oxide (CaO), and magnesium oxide (MgO) nanoparticles (NPs) decorated by phosphorus-doped carbon dots (PCDs). The monoclinic phase of ZrO2 has shown the highest catalytic activity, thus imparting greater decolorization efficiency (DE) in the synthesized metal oxide nanoparticles (MONPs) decorated with PCDs (MONPs@PCDs). The sonocatalytic efficiency of MONPs@PCDs was evaluated using MB as the analyte molecule. We report DE of up to 99.54% via speckled PCDs decoration and synergistic effect in a short time of 30 min at just 20 kHz frequency. The sonocatalytic activity of MONPs@PCDs is AND logic gate supported and was found as ZCMO@PCDs (99.54%) > ZMO@PCDs (96.47%) > ZO@PCDs (94.68%) > ZCO@PCDs (93.40%). However, the sonocatalytic activity of MONPs was only ZCMO (11.21%) > ZMO (9.26%) > ZO (3.79%) > ZCO (2.92%), under identical experimental conditions. The synergistic effect in polymetallic systems opens new pathways to be explored in sonocatalysis. We confirmed the synthesis of PCDs and their speckled decoration on the surface of MONPs using scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The speckled nanocomposites, i.e., MONPs@PCDs, showed an enhanced and faster decolorization efficiency than the bare MONPs, as demonstrated by the kinetics studies as 101 fold increase in k values and 101 fold decrease in t1/2 values. Novelty statementNovel nanocomposites have been developed for MB dye decolorization using a low frequency of just 20 kHz and possessing 99.54–93.40% DE in only 30 min, thus may aid in industrial dye decolorization and the reuse of wastewater for environmental sustainability.

Short- and long-terms stimulatory impacts of calcium oxide nanoparticles (CaONPs) on the growth, photosynthesis and antioxidant enzymes of Chlorella sp.

Short- and long-terms stimulatory impacts of calcium oxide nanoparticles (CaONPs) on the growth, photosynthesis and antioxidant enzymes of Chlorella sp.