CH4 Flow Research Articles

High-Pressure CO2 and CH4 Transport in Smooth Crystalline Silica Mesopores: A Molecular Dynamics Study.

In this study, we use molecular dynamics (MD) simulation to study pressure-driven CO2 and CH4 flows and their slippage behaviors in β-cristobalite mesopores. The result illustrates that both CO2 and CH4 have an apparent adsorption layer on pore surface. However, significant differences in gas slippage are observed: CH4 flow shows considerable slippage, while it is negligible for CO2 flow. This disparity is attributed to the collective effect of gas molecular configurations and surface structure. The linear molecular structure of CO2 allows it to align perpendicular to the surface, even penetrating into the surface. Notably, the perpendicular orientation of CO2 molecules is energetically favored near the center of the equilateral triangle formed by adjacent oxygen atoms on β-cristobalite surface. Conversely, the symmetric molecular structure of CH4, coupled with its larger size, prevents its penetration into pore surfaces. Therefore, despite smooth crystalline surfaces, CO2 topological accessible plane is much more curved than that of CH4. Consequently, CO2 displays hesitating motions undergoing rotational movements, which significantly hinders its slippage. This study highlights the collective influences of gas molecular characteristics and surface structure on gas slippage, affording important insights into gas sequestration and the development of functional materials for gas separation.

Effects of CrC interlayer on tribocorrosion properties of DLC-coated TC4 alloy in a 0.9 wt% NaCl solution

In this study, DLC coatings with varying thicknesses of CrC interlayers were fabricated on the surface of TC4 alloy by regulating the flow rate of C2H2. The effects of the interlayer layer on the microstructure, mechanical properties, corrosion resistance, and tribocorrosion resistance of DLC coatings were systematically investigated. The results show that as the C2H2 flow rate increases, the CrC interlayer exhibits the structure transitions from columnar crystals to amorphous, resulting in improved hardness. The hardness of the CrC40 interlayer reaches 17.2 GPa, significantly higher than the 9.3 GPa of the Cr underlayer. The CrC interlayer notably enhances the mechanical properties and adhesion strength of DLC coatings. The corrosion current density of the CrC40/DLC coating is 3.07 × 10−8 A/cm2, significantly lower than that of the DLC coating with only a Cr underlayer. Under high load conditions of 20 N, the tribocorrosion rate of the CrC40/DLC coating is reduced to 2.09 × 10−7 mm3.(N.m)−1, representing a significant decrease of 93.9 % compared to the DLC coating. The CrC40/DLC coating exhibits strong adhesion strength, appropriate internal stress and a relatively hard CrC40 interlayer, showing exceptional tribocorrosion resistance.

Modeling Study of Enhanced Coal Seam Gas Extraction via N2 Injection Under Thermal-Hydraulic-Mechanical Interactions.

N2 injection into coal seams can effectively enhance the gas flow capacity in the late stage of pumping, thereby improving the recovery rate and recovery efficiency of low coalbed methane (CBM). To reveal the thermodynamic flow coupling relationship between the reservoir and the gas phase and its transportation mechanism in the process of thermal N2 injection, a mathematical coupling model of N2 injection that considers the deformation of the coal seam, fluid transportation, and temperature change was established. The influence of the seepage heat transfer effect of the coal seam under the effect of N2 injection on the CH4 extraction rate was investigated using this model. Results indicate that the action mechanism of N2 injection in coal seams includes increasing seepage, promoting flow, and displacing gases. A higher initial coal seam temperature results in a smaller thermal expansion and deformation of the coal skeleton during thermal N2 injection and less pronounced coal permeability increase. A larger initial coal seam permeability results in more favorable N2 diffusion, which strengthens the flow-promoting effect on CH4. The effect of gas injection pressure on CH4 recovery is greater than that of the gas injection temperature: High pressure promotes N2 seepage, carries CH4 flow, and increases the CH4 diffusion effect, whereas higher temperature promotes the desorption of adsorbed gas in the coal seam and improves the recovery rate.

Effects of adding methane on the growth and electrical properties of GaN in oxide vapor phase epitaxy

GaN grown via oxide vapor phase epitaxy (OVPE-GaN) can produce free-standing substrates with ultra-low resistivity because of the high doping concentration of oxygen. The bulk growth of OVPE-GaN is hindered by polycrystals generated during long-term growth. We have previously reported that thicker films can be grown by reducing the partial pressure of water vapor in the growth atmosphere with CH4. However, as CH4 is a dopant of carbon, a compensating acceptor, its addition may increase electrical resistance. In this study, we further investigated the effect of reducing water vapor partial pressure on polycrystals by combining Ga2O production (reaction of Ga and water vapor: a Ga–H2O system), which can reduce water vapor, with CH4 addition. However, CH4 addition to the Ga–H2O system increased polycrystal generation, possibly owing to the thermal decomposition of excess CH4. The properties of OVPE-GaN with CH4 addition were also evaluated. Although the CH4 addition resulted in high carbon doping, the carbon-doped OVPE-GaN maintained low resistivity. This is because the OVPE method involves three-dimensional growth with growth pits, and the growth pits leave behind low-resistivity high-oxygen-concentration regions. As the resistivity remains low even when CH4 is added in the OVPE method, both polycrystallization suppression and low resistivity can be achieved by selecting an appropriate CH4 flow rate.

Preparation of carbon materials by vapor deposition with Fe3+-Modified nickel foam from biomass pyrolysis gas

Biomass carbon materials have attracted attention in various fields due to their excellent properties. In this study, CH4 derived from biomass pyrolysis was utilized as a carbon source gas to synthesize carbon materials by chemical vapor deposition (CVD) in a two-stage reactor with purification system, with Fe3+-loaded nickel foam as the substrate under an argon atmosphere, using a self-designed experimental platform. The reaction process was optimized by examining the effects of the catalyst type, reaction temperature, reaction time, and gas flow rate on the structure and morphology of the carbon materials. The optimal preparation condition was to use FeCl3 ethanol solution as catalyst, with CH4 flow rate of 50 ml/min at 1000 °C for 25 min. The high quality carbon materials with uniform diameters (250–500 nm) were obtained on nickel foam substrate. The carbon materials obtained under optimal conditions were characterized and analyzed to investigate their excellent properties. Surface morphology and structure of as-formed carbon materials were characterized by SEM. The analysis of the XRD spectra and the Raman spectroscopy showed that the graphite diffraction peak (002) at 26.6°, the calculated intensity ratios for ID/IG and I2D/IG were 0.257 and 0.545, respectively, indicated high degree of graphitization and purity of the carbon materials. Furthermore, the growth mechanism of carbon materials on the nickel foam substrate was discussed.

Microwave plasma-assisted hydrogen production via conversion of CO2–CH4 mixture

A method concerning re-use of the main greenhouse gases: CO2 and CH4 at the same time producing value-added chemicals (H2 + CO) is presented in this paper. The method involves the methane dry reforming using an atmospheric pressure operated 915 MHz microwave plasma source with a swirl gas flow. The effect of the CO2 to CH4 flow rates ratio, the total gas flow rate and the absorbed microwave power on the volume concentration of the gaseous plasma component in the outlet gas (%), CO2 and CH4 conversion rate (%), hydrogen production rate (g h−1) and energy yield of hydrogen production (g kWh−1) was investigated experimentally. The recorded results of the CO2 and CH4 conversion rate were about 82% and 88%, respectively. The best results in terms of the hydrogen production rate and energy yield of hydrogen production were equal to 156 g h−1 and 24 g kWh−1, respectively.

Analytical modeling of nucleation and growth of graphene layers on CNT array and its application in field emission of electrons

Carbon Nanotube (CNT) arrays and graphene have undergone several investigations to achieve efficient field emission (FE) owing to CNT’s remarkable large aspect ratio and graphene’s exceptional FE stability. However, when dense CNT arrays and planar graphene layers were used as field emitters, their field enhancement factor reduced dramatically. Therefore, in this paper, we numerically analyze the growth of a dense CNT array with planar graphene layers (PGLs) on top, resulting in a CNT-PGL hybrid and the associated field enhancement factor. The growth of the CNT array is investigated using Plasma Enhanced Chemical Vapor Deposition (PECVD) chamber in C2H2/NH3 environment with variable C2H2 flow, Ni catalyst film thickness, and substrate temperature followed by PGL precipitation on its top at an optimized cooling rate and Ni film thickness. The analytical model developed accounts for the number density of ions and neutrals, various surface elementary processes on catalyst film, CNT array growth, and PGLs precipitation. According to our investigation, the average growth rate of CNTs increases and then decreases with increasing C2H2 flow rate and catalyst film thickness. CNTs grow at a faster rate when the substrate temperature increases. Furthermore, as the chamber temperature is lowered from 750 °C to 250 °C in N2 environment and Ni film thickness grows, the number of the graphene layers increases. The field enhancement factors for the CNT array and hybrid are then calculated based on the optimal parameter values. The average height of the nanotubes, their spacing from one another, and the penetration of the electric field due to graphene coverage are considered while computing the field enhancement factor. It has been found that adding planar graphene layers to densely packed CNTs can raise its field enhancement factor. The results obtained match the current experimental observations quite well.

NbC thin films via reactive DC sputtering in a CH4/Ar atmosphere

We have demonstrated the growth of NbC-Amorphous C films that manifest a well-known nanocomposite structure (Klages and Memming, 1990; Nedfors et al., 2011; Sala et al., 2021). The films were deposited using reactive DC sputtering in a CH4/Ar atmosphere using an insulating substrate near room temperature. A metallic Nb sputtering target was sputtered in an argon/CH4 atmosphere with a pressure range of 5.9 to 8.5 mTorr as the CH4 flow was also varied. Crystalline NbC films were deposited at room temperature at the lowest CH4 flow rate. The films exhibited ohmic electrical response at room temperature. The DC electrical resistivity scaled almost 4 orders of magnitude from 4.39 × 10−4 Ω-cm to 1.08 × 10−1 Ω-cm through changes in CH4 flow rates and the resultant C content of the films. The large variation in resistivity cannot be attributed to the changes in sample composition, e.g. volumetric mixing. It is postulated from XRD and TEM results that the large change in resistivity is due to the decreasing NbC crystallite size with increasing CH4. This leads to additional three-dimensional nanoscale intragranular interfaces and results in increased resistivity. X-ray reflectivity measurements were conducted, and the modelled film density was found to match the expected density for the film compositions as measured using X-ray photoelectron spectroscopy. Elastic recoil detection analysis (ERDA) was used to quantify H content of the films. The H content increased from 5.5 to 22 atomic percent with corresponding increase in CH4 flow. Transmission electron microscopy utilizing precession electron diffraction (PED) was conducted and showed a strong dependence of crystallinity on CH4 flow. A multilayer layer sample with varying CH4 flowrates was examined with TEM and showed that films were amorphous in nature for flow rates above 10 SCCM CH4; in agreement with XRD results.

Methane pyrolysis on NiMo/MgO catalysts: The significance of equimolar NiMo alloy resisting nanosize segregation during the reaction

As a perspective catalyst composition for methane non-oxidative decomposition/methane pyrolysis (CH4⇌C+2 H2) yielding clean hydrogen and only solid carbon, the combination of nickel and molybdenum on MgO support was investigated. With deliberately low Ni content and strong metal-support interaction, 7%Ni4%Mo/MgO and 7%Ni12%Mo/MgO catalysts and the monometallic references were prepared. Structural analysis was performed using TPR, XRD, TEM, XPS and Raman spectroscopy in reduced state and after methane decomposition test. Catalytic performance was investigated i) in a highly diluted CH4 flow in a fixed bed reactor under temperature ramp and ii) in 50% CH4/Ar using a horizontal reactor at 800 °C. Synergetic interaction of Mo and Ni was observed under both conditions. The results revealed that the deactivation was coupled with alloy segregation for the low Mo loading, while the more stable, non-segregating Mo/Ni∼1 composition of the individual metal particles in 7%Ni12%Mo/MgO sample resulted in good activity and high carbon nanotube yield.

Study of CO2 Injection into Sumatran Shale Layers to increase Hydrocarbon Gas Productivity of The Shale Gas Reservoir

Injecting CO2 into a reservoir has some important reasons. CO2 injection can enhance oil and gas recovery by reducing the capillary pressure, increasing the pressure gradient, and changing the phase behavior of the fluids. It can reduce greenhouse gas emissions by capturing and storing CO2 underground. It can also create economic benefits by utilizing CO2 as a valuable resource and generating revenue from carbon credits. Therefore, injecting CO2 into a reservoir benefits the environment and the industry. We can inject CO2 in shale gas reservoirs to increase productivity because CO2 has a stronger adsorption capacity on shale surfaces than hydrocarbon gas. When CO2 is injected into shale reservoirs, it can displace the adsorbed CH4 flow out of the micropores and free up more space for gas flow. Injecting CO2 can also reduce the viscosity and density of shale gas, improving its mobility and transport. Moreover, injecting CO2 can provide environmental benefits by reducing carbon emissions and storing CO2 underground. Therefore, CO2 injection is a promising technique for enhancing shale gas recovery and mitigating climate change. We characterized several types of shale from Sumatra using XRD to determine the mineral content. We injected the shale sample with the inert gas and CO2 gas. The characteristics of pressure build up after CO2 injection seem lower than one after inert gas injection. The volumetric of released gas after injection shows the same phenomena as pressure build up’s phenomena which shows clearly that shale rock released less of CO2 gas than the one of inert gas (CH4). These phenomena show that the CH4 can be released easier than the CO2 in the shale rock. Therefore, CO2 can be utilized as material for enhancing the gas recovery in shale reservoir.

Assessing the performance of farm soil-based and hybrid biofilters for methane abatement

ABSTRACT Mitigating methane (CH4) emissions using methanotrophs (methane-oxidizing bacteria, MOB), is a simple, energy efficient and cheap technology. The abundance and distribution of MOB in the environmental samples is critical for efficient removal of emitted CH4 from any source. This study evaluated the performance of farm soils without and with cheap, easily accessible bulking materials as sustainable hybrid biofilter media. Soil-only biofilters removed up to 865 ± 19 g CH4 m−3 d−1 with well-drained organic carbon-rich soils compared with 264 ± 14 g CH4 m−3 d−1 for poorly drained soil. The removal efficiency decreased with increasing flow rate (0.16→0.24 L min−1) and subsequent priming could not return soil biofilters to their previous removal rate. Hybrid biofilters using organic, carbon-rich soils and compost removed up to 2698 g CH4 m−3 d−1 (flow rate 0.35 L min−1). Increasing CH4 flow rates also reduced their efficiency, but the hybrid biofilters with compost quickly regained most of their efficiency and removed up to 2262 g CH4 m−3 d−1 (flow rate 0.3 L min−1) after remixing of biofilter media. These results show that hybrid biofilters removed higher CH4 than soil-only biofilters and were also more resilient. The MOB gene abundance results complement the CH4 removal capacity of both soil-only and hybrid biofilter materials used. The more aerobic, carbon-rich soils had more abundant MOB than the poorly drained soil. The most porous hybrid biofilter with compost and more available nutrients to sustain bacterial growth and activity had the highest MOB abundance and removed the most CH4.

Effect of C2H2 flow rate on microstructure, properties, and application in micro-drilling of a-C:H films deposited by PECVD

The drilling of printed circuit board (PCB) using micro-drills is an important processing method in modern industry. A protective film with good lubricating and anti-wear properties is generally applied to improve the processing problems of micro-drills during operation. In this study, the effects of C2H2 flow rate on the microstructure, mechanical, and tribological properties of a-C:H films deposited by plasma enhanced chemical vapor deposition (PECVD) technique were investigated. The results showed that when the C2H2 flow rate was low, varying the flow rate had little effect on the microstructure of the prepared a-C:H films. However, when the C2H2 flow rate was greater than 210 sccm, the increase in flow rate caused large particles of carbon clusters to aggregate on the surface of a-C:H films, which resulting in an increase Ra value. Not only did it reduce the adhesion between the film and the substrate, but it also deteriorated the mechanical and tribological properties of the a-C:H film produced. In addition, a-C:H films were also deposited on the micro-drill, and were used for drilling tests on the PCBs to evaluate its servce capability. The optimal parameters of a-C:H film deposited on the micro-drill surface were obtained by observing the morphology of the micro-drill surface after drilling and the hole accuracy statistics. The results showed that a-C:H film deposited on the surface of the micro-drill showed the best machining performance when the C2H2 flow rate was 180 sccm. The surface wear of micro-drill was minimal, the entanglement of tangled chips was minimal. The value of the process capability index (CPK) after 500, 1000, and 2000 drilling of PCB boards was 5.95, 4.33, and 3.15 respectively, which showed the highest drilling accuracy. This is mainly attributed to the better overall properties of the a-C:H films prepared at C2H2 flow rate of 180 sccm, such as lower surface roughness, lowest residual stress, higher hardness, better adhesion, and lower friction coefficient.

Structure and tribocorrosion properties of ultralubricated (TiAlCrSi)C multicomponent coatings prepared by FCVAD

To address corrosion and friction problems in complex environments, traditional protective coatings are gradually replaced by multicomponent coatings. In this work, a (TiAlCrSi)C multicomponent coating with ultralubrication (COF < 0.1) and excellent corrosion resistance was prepared by FCVAD technology with regulated C2H2 flow. The composition, structure, roughness, dry friction, corrosion and tribocorrosion of the (TiAlCrSi)C coating were analyzed. The results show that the (TiAlCrSi)C coating shows an amorphous structure, and the addition of carbon improves the degree of amorphization of the coating. Carbon exists in the form of carbide and amorphous carbon in the (TiAlCrSi)C coating, the carbon content saturation of the coating is about 70 at.%. The formed carbides and sp2-C in the (TiAlCrSi)C coating have extremely low COFs and good wear resistance. The high proportions of amorphous carbon and sp2-C improve the self-lubricating and nonmetallic properties of the (TiAlCrSi)C coating, which makes the coating have good tribocorrosion resistance in 5.0 wt% H2SO4 solution. The wear mode of the coating changes from abrasive wear to adhesive wear. Therefore, the (TiAlCrSi)C coating has great potential application value for tribocorrosion surface protection in a 5.0 wt% H2SO4 solution environment.

Control of nitrogen defects in carbon nanotubes for self-powered memristive systems

Recent studies show that the additional introduction of heteroatoms into the structure of CNTs makes it possible to change their electronic and physical properties [1]. Of great interest is the process of doping CNTs with nitrogen atoms [2]. The introduction of nitrogen defects into a lattice of carbon atoms makes it possible to modify the CNT structure up to the demonstration of anomalous properties that are not appropriate for this material [3]. It has been shown that multi-walled N-CNTs can exhibit memristive and piezoelectric properties [4]. The parameters of CNTs during synthesis can be controlled by the plasma enhanced chemical vapor deposition (PECVD) method. The addition of ammonia (NH3) to the carbonaceous gas in the PECVD process allows CNTs to be doped directly during growth. At the same time, the dopant concentration and the type of nitrogen defects have a significant effect on the properties of CNTs. The memristive properties of CNTs have already been sufficiently studied [5], however, for their application in self-powered systems, additional studies of the parameters of the piezoelectric module of N-CNTs are required. The aim of this work is to study the effect of ammonia flow on the concentration, type of nitrogen defects, and the value of the piezoelectric modulus during growth of CNTs by the PECVD. Silicon (100) substrates were used as samples with films of a buffer (Mo, 100 nm) sublayer and a catalytic layer (Ni, 15 nm). CNTs were grown at a temperature of 550 °C in an atmosphere of acetylene (C2H2, 35 sccm) and NH3. The C2H2 flow was kept constant, while the NH3 flow was changed in the C2H2:NH3 ratio from 1:1 to 1:10. Based on the obtained SEM images, it was found that with an increase in the ratio of C2H2:NH3 flowes, an increase in the density of nanotubes in the array were observed. This occurs due to more active growth of N-CNTs on small nickel catalytic centers due to the accelerated process of hydrogen desorption and its binding with ions in ammonia plasma, which leads to an increase in the growth rate of nanotubes on smaller catalytic centers. Thus, the area of the catalytic center is one of the limiting factors of the growth rate and allows one to control the aspect ratio and density of CNTs in the array. An analysis of the XPS spectra showed that with an increase in the ratio of C2H2:NH3 flows from 1:1 to 1:10, a nonlinear change in the concentration of the nitrogen dopant in N-CNTs from 8.4 to 12 at % is also observed. This led to a nonlinear change in the piezoelectric modulus of nanotubes from 8.7 to 20.6 pm/V and a change in their memristive properties. It has been established that an increase in the concentration of doping nitrogen leads to an increase in the piezoelectric modulus of N-CNTs, which is the source of the memristive effect. The obtained results can be used in the development of energy-efficient piezoelectric nanogenerators based on an array of vertically aligned N-CNTs for autonomous memristive systems.

N2 injection to enhance gas drainage in low-permeability coal seam: A field test and the application of deep learning algorithms

N2 injection to enhance coal seam gas drainage is an effective technology for coalbed methane recovery. Nevertheless, there is a limited body of research addressing the application of ECBM technology for gas management in low permeability coal seams within underground coal mines, and the effect is uncertain. Additionally, numerical simulators have been challenged to accurately predict methane emissions during gas injection and replacement. In this study, firstly, an underground field trials of N2 injection replacement in a coal mine with low-permeability coal seams in China were conducted, and a comparative analysis of “N2 injection to enhance gas drainage” and “conventional drainage” technique was performed. The result show that injecting pressurized N2 into a low-permeability coal seam could increase the pressure gradient to promote the directional flow of free gas from the coal seam cracks to the gas-production boreholes. After N2 injection, the mixed flow rate and CH4 flow rate significantly increased. Additionally, the gas content in the coal seam in the experimental area significantly decreased. Secondly, the lag-effect was discussed. Upon discontinuation of N2 injection, the gas-producing mixed flow initially increased slightly, then gradually decreased, and eventually settled at a high level. Despite the attenuation of N2 injection volume, the CH4 flow rate continued to increase during intermittent injection and remained high after gas injection discontinuation. Finally, three deep learning algorithms (BP, LSTM, and TCN) were employed to predict the dynamic change of gas drainage in coal seams displaced by N2 injection, based on the results of the field test. The results indicated that deep learning algorithms exhibited superior prediction performance. The TCN model demonstrated the lowest approximation error rate, displaying optimal performance in predicting the CH4 flow rate during nitrogen injection for enhanced gas drainage. Additionally, it exhibited good applicability to other similar field test results.

Unveiling the multifaceted impact of C2H2 flow on SiCN CVD coatings: Mechanical mastery and beyond

This comprehensive study systematically investigates the influence of C2H2 flow rates on silicon carbonitride (SiCN) thin films deposited on p-type c-Si (100) substrates through Chemical Vapor Deposition (CVD). Across a range of C2H2 flow rates (1–15 sccm), the study quantitatively analyzes surface morphology, crystallinity and mechanical characteristics. Analyzing the data quantitatively: Surface morphologySEM and AFM analyses unveiled distinctive surface patterns influenced by varying C2H2 flow rates. Surface roughness exhibited a quantitative increase, rising from 1.2 nm at 1 sccm to 2.4 nm at 15 sccm. Ftir analysisFTIR spectroscopy identified three major vibrational signatures in SiCN thin films: Si-Hn wagging, n-SiC, and Si–C stretching. Notably, the intensity of the n-SiC peak demonstrated a quantitative rise with increasing C2H2 flow rate. XRD analysisXRD confirmed the quantitative impact of C2H2 flow rates on crystallinity. The SiCN thin film deposited at 15 sccm exhibited the highest crystallinity, with a quantified crystallite size of 15 nm. Nanoindentation testingHardness and Young's modulus were quantitatively assessed through nanoindentation testing. SiCN thin films showed a quantitative increase in both hardness and Young's modulus with rising C2H2 flow rates. The film deposited at 15 sccm demonstrated the highest hardness (i.e. 19.23 GPa) and Young's modulus (i.e. 271.56 GPa).In summary, this study establishes the significant impact of C2H2 flow rates on the quantitative aspects of surface morphology, crystallinity, and mechanical properties of SiCN thin films. Notably, the film deposited at 15 sccm emerges as distinctive, exhibiting the highest quantitative values for crystallinity, hardness and Young's modulus. This comprehensive analysis enhances the understanding of intricate relationship between C2H2 flow rates and the multifaceted properties of SiCN thin films.

Steady state thermokinetic of ultra-thin Mo2C/G heterostructures grown on the prior-graphitized cu/graphene biasing

In this work, the chemical vapor deposition synthesis of the Mo2C/graphene heterostructure above the melting temperature of Cu bias (1356 K) is studied. Two sets of Mo2C growth experiments at high CH4 flow rates (5 SCCM ≥ 3 SCCM) are performed, either using prior-graphene synthesis or having in situ graphitization, for three different Cu bias thicknesses. Raman mappings taken from all six-test samples show graphene covers not only over the Mo2C pillars but also over their untransformed Cu bias substrate regions. The only difference is that the Mo2C pillar grows over the prior graphene bias; on the other hand, the in situ graphene grown Mo2C pillar nucleates and grows over the fresh Cu bias surfaces. A steady-state laminate model for flows of Mo and C species with phase transformations is developed for the radial and vertical growth kinetics of synthesized Mo2C/graphene heterostructure. The computer simulation reproduces those experimental observations performed recently in our laboratories on the prior or no-prior graphitized (G) test modules with Cu/G bias, having three different thicknesses at 1363 K. AFM-topography and SEM photos for a prior graphitized test module of 25 µm thick Cu and 4.72 Å graphene bias show a three layered Mo2C/graphene heterostructure; the first layer is almost perfect hexagonal flat, and the other two circular shaped layers constitute the whole pillar of 140 nm height. This may be compared to a 250 µm thick Cu/4.7 Å graphene bias sample, which furnishes an ultra-thin single flat layer of 10–13 nm thick Mo2C crystallites having a perfect planar hexagonal structure.

Preparation and performance of Ti/Ti-DLC composite coatings for precision glass molding

Precision glass molding (PGM) is an efficient process used for batch manufacturing of high-precision glass optical elements. In this process, nickel phosphide (Ni–P) alloy is commonly utilized as a mold material due to its superior turning properties. However, the Ni–P mold suffers from issues such as diffusion of phosphorus elements, poor wear resistance, and easy peeling of the DLC coating during molding. To address these problems, the current study proposes enhancing the molding performance of mold by depositing a composite coating layer of Ti/Ti-DLC onto the surface of Ni–P using the filtered cathodic vacuum arc technology (FCVA). The effects of different flow rates of C2H2 on Ti-DLC coatings were analyzed in terms of composition, microstructure, mechanical, tribological, and molding properties. The results revealed that as the C2H2 flow rate increased, the Ti content of coatings decreased from 13.56 to 2.17 at.%. Additionally, the film microstructure transformed from TiC polycrystalline composite films to nanocrystalline amorphous composite films and finally to amorphous films. The Ti-DLC coatings with a nanocrystalline composite structure exhibited excellent overall performance when Ti content is 7.75 at.%. These coatings are suitable as protective coatings for microstructured array mold and demonstrate good stability at a molding temperature of 500 °C.

Study on particle size and field effect with sp2/sp3 ratio of hydrogenated diamond-like carbon

Hydrogenated diamond-like carbon (HDLC) films were synthesized through a reactive gas-plasma process employing methane (CH4) and hydrogen (H2) as precursor gases on a silicon (100) wafer substrate, conducted at room temperature. The deposition process utilized a biased enhanced nucleation technique, varying the flow rate ratio of hydrogen and methane. The investigations revealed that increasing the methane flow rate led to a reduction in grain size and an augmented nucleation density of HDLC, as evidenced by contact-mode atomic force microscopy (AFM) images. This study demonstrated the effective control of diamond grain growth by introducing high-methane-concentration pulses during deposition. The field emission characteristics of HDLC samples were analyzed, revealing threshold fields of 12.2 V/μm for nanocrystalline films, 8.5 V/μm for subcrystalline films and 4.1 V/μm for microcrystalline films, corroborated by Raman spectra. Surface energy measurements indicated hydrophobic behavior in the samples. Notably, a decrease in the hydrogen/methane ratio was found to increase the sp2 character, which correlated with the emission field. AFM analysis of HDLC samples yielded surface roughness values ranging from 0.2 nm to approximately 0.01 nm, confirming the continuous, non-porous and smooth nature of the surfaces.

Structure and Optical Characteristics of DLC Films

SummaryUsing a RF‐Plasma Enhanced Chemical Vapor (RF‐PECVD) Depositions method, employing hydrogen and methane gas, Diamond like carbon (DLC) films were fabricated on glass and silicon substrates. The impact of varying CH4 to H2 ratios on the resulting film's structure, optical characteristics, and mechanical properties was investigated. The deposition process occurred at methane flow rates spanning 5 to 40 sccm. The films' surface morphology, and roughness were analyzed through Atomic Force Microscopy. Moreover, the Vickers hardness tests was employed to determine the hardness of produced films. The optical behavior of the DLC thin films was explored utilizing UV‐visible spectrometry and ellipsometry. A thorough investigation was conducted to understand how the CH4 flow rate influences layer growth, morphology, topography, and how these factors relate to the films' transmittance, reflectance, refractive index, and optical band gap.