Polybutadiene Research Articles

Crosslinked Natural Rubber and Styrene Butadiene Rubber Blends/Carbon Black Composites for Self-healable and Energy-saved Applications

Crosslinked Natural Rubber and Styrene Butadiene Rubber Blends/Carbon Black Composites for Self-healable and Energy-saved Applications

Investigating the impact of manufacturing conditions on crack growth rate in nitrile butadiene rubber for enhanced service life – Part 02: Crosslink density via multi-stage swelling analysis

The importance of the state of cure of elastomer components with regard to fatigue behavior and thus also durability was already discussed in more detail in Part 01 of the paper. It was shown that crosslinking time and temperature have an enormous influence on the crack growth behavior in nitrile butadiene rubber (NBR). In the course of this, a fourfold deceleration in crack growth was observed with a 20 K increase in manufacturing temperature. To confirm this trend, test specimens were produced at 180 °C. Crack growth was found to be 40 times slower, especially in high tearing energy ranges, compared to 150 °C. To analyze the observed behavior in more detail, cylindrical samples were taken from the plain strain test specimens (used for the crack growth measurements), and multi-stage swelling was performed with them. This allowed a detailed analysis of the degree of cure and the sulfur chain composition. It was found that the crosslink density decreases with increasing manufacturing temperature due to decomposition and the proportion of polysulfidic crosslinks decreases with increasing heating time due to desulfurization. Furthermore, a correlation between the results found by means of the rubber process analyzer (RPA) and the swelling results could be established looking at the maximum transmitted torque during the isothermal crosslinking phase.

How does heat generation affect the cut and chip wear of rubber?

AbstractTire wear is a fracture process that has a decisive impact on tire life and on the environment. When a tire rolls, a heating process occurs due to friction caused by the viscoelastic rubber sliding over uneven road. This process occurs globally in the contact patch area and locally around the asperity tips, heating the tread and transferring heat to the surrounding material. On roads with a good quality pavement, the stress, and therefore the heat, is evenly distributed throughout the rubber material of the tire, which has a direct effect on fatigue wear. In contrast, unevenly distributed stress, and therefore heat, is generated in the tread when the tire rolls and slides over sharp asperities in rough terrain. This leads to very pronounced, unstable fracture processes that cause unevenly distributed wear, known as cut and chip (CC). The extent of heat generation or temperature evolution and its effect on CC wear have not yet been investigated and described in scientific publications. Therefore, this study firstly presents the detailed characterization of the influence of temperature development on the CC wear of a styrene–butadiene rubber, which commonly is used in treads of consumer tires. The investigations were carried out using the unique instrumented cut and chip technique in combination with a high-speed thermography.

Systematic Investigation on the Swelling Response and Oil Resistance of NBR Using the Prediction Models Determined by the Modified Flory-Huggins Interaction Parameter.

The equilibrium swelling test was employed to determine the swelling response of Nitrile Butadiene Rubber (NBR) with various acrylonitrile (ACN) contents, and the three-dimensional solubility parameter (HSP) and modified Flory-Huggins interaction parameter (χHSP) were used to establish the prediction model of the oil-resistant property. The results indicate that the energy difference (Ra) between NBR and solvents calculated by HSP values can be correlated with the swelling response qualitatively with an inversed "S-shape", and high swelling response occurs at Ra < 8 MPa1/2 for NBR. For the purpose of establishing the prediction model, the new modified χHSP value has been calculated and fitted with the swelling response using exponential and logarithmic fittings, respectively. Two prediction models considering all the possible influencing factors have been obtained to determine the swelling response and oil resistance of NBR-based rubber products in bio-fuels, represented by the bio-diesel and IRM 903 test oil in this work. The swelling response of NBR can be evaluated precisely, and high swelling regions can be predicted and avoided in the new emerging fuels through the prediction models. Thus, the oil resistance of NBR-based rubber products, such as seals, holes and gaskets can be well predicted now.

Temperature-dependent evolution of synthetic coal-derived graphite fillers and their reinforcement in styrene butadiene rubber composites

This study investigated the structural evolution of synthetic coal-derived graphite (SCG), produced from anthracite through high-temperature treatments ranging from 1000 to 2900 °C, and its reinforcement potential in styrene butadiene rubber (SBR) composites. Upon heating the anthracite to 2000 °C, We observed a gradual structural transformation from an amorphous carbon structure with mixed sp2-sp3 bonding to an ordered sp2-bonded nano-sized graphitic structure. This transformation was accompanied by the evaporation of heteroatom functional groups, an increase in high surface energy site as well as micropore and void structures, and enhanced hydrophobic surface property. Beyond 2000 °C, a flake-like graphite with a larger particle size (average lateral size >10 μm) was gradually formed through lateral and vertical crystalline growth mechanisms. The reinforcing potential of SCG fillers was revealed by incorporating them into SBR and evaluating the properties of the resulting composites. It was found that the tensile strength and 300 % tensile modulus initially enhanced with SCG fillers treated up to 2000 °C, but decreased for fillers treated at 2300 and 2900 °C. On the other hand, storage modulus, tear resistance, and gas permeability consistently improved with fillers treated at higher temperatures. These findings highlight the relationship between the temperature-induced structural evolution of SCG fillers and their reinforcement performance in SBR composites, offering valuable insights for industrial rubber applications, particularly enhancing the performance and sustainability of automotive tire.

Rebound characteristics of flexible and stiff jute rubber/epoxy hybrid composite under low-velocity impact

This present work aims to assess the low-velocity impact response of novel configuration based on jute/rubber/epoxy flexible and stiff composites having varying layup sequences using an experimental study. The Charpy and drop weight impact tests are done according to the standards. Drop weight low-velocity impact test at an energy level of 15J was performed using a conical shape impactor. Carboxylated Nitrile Butadiene Rubber (XNBR) containing carbon fillers ( N330 and N550) consisting 35 phr concentration each is used in the stacking sequence of the composite due to its high toughness and energy dissipation property. During drop weight tests conducted at a 15J energy level, the flexible RJRJR composite exhibited a peak force of 486 N, whereas the stiffer RJEJR composite demonstrated a peak force of 1075 N. The flexible composite shows no damage for the energy level tested. However, the stiff composite made using epoxy in between jute layers fails due to the matrix cracking in the composite. The peak force and specific energy absorption is dependent on stacking configuration and increases with the addition of rubber interface in the stiff composite. The energy absorption of stiff composite is higher as compared to flexible composite as indicated by the peak force.

Study on the elimination characteristics of smoke particles with different materials using electric agglomeration technology

ABSTRACT Fire smoke, consisting of solid particles and liquid droplets, poses risks of asphyxiation, poisoning, making it a significant contributor to fire-related fatalities and environmental pollution. The exploration of effective smoke control methods represents a vital approach to reducing the threat of fire smoke to public health and safety. This study aims to determine the characteristics of elimination for the fire smoke generated from burning four typical materials, thereby validating the universality of electric agglomeration smoke elimination technology. The results indicate that the elimination efficiency of electric agglomeration varies with the material type of the smoke. The rate of change in smoke transmittance from fast to slow is: polyvinyl chloride (PVC), polystyrene (PS), wood, and styrene butadiene rubber (SBR), respectively. With an external potential of 4 kV, PVC smoke reaches the safe threshold after 12.1 s, while SBR smoke achieves it in just 4.9 s. Analysis of the microscopic morphology of agglomerates with scanning electron microscopy (SEM) reveals that particle size distribution is an important factor affecting electric agglomeration elimination. This is because larger initial particles carry a greater charge, enabling the formation of larger agglomerates for more efficient removal. This study provides theoretical guidance for the practical application of electric agglomeration in eliminating smoke particles.

Enhanced mechanical properties of rubber/clay nanocomposite via compounding butadiene-styrene-vinyl pyridine rubber-contained clay gel with styrene butadiene rubber

An efficient and environmentally friendly strategy is demonstrated for improving the clay dispersion in non-polar rubbers and enhancing their interaction at the interface. In this work, we introduced butadiene-styrene-vinyl pyridine rubber (VPR) latex into clay gel to prepare VPR/clay gel, which was then incorporated into the styrene-butadiene rubber (SBR) to prepare SBR/VPR/clay nanocomposites (NCs), by gel compounding method. The results showed that the dispersion of the clay layer improved by the incorporation of VPR, and the interfacial strength between clay and rubber increased. As a result, the mechanical properties of SBR/VPR/clay NC significantly improved. The tensile strength of SBR/VPR/clay NC was up to 16.3 MPa, which was 930 % higher than that of the pure SBR and nearly 30 % higher than that of the SBR/organoclay nanocomposite (SBR/oclay NC) with the same filler loading.

Influence of Tire Reclaimed Rubber (TRR) Loadings on Cure Characteristics and Mechanical Properties of Natural Rubber/Styrene Butadiene Rubber (NR/SBR) Blends

This investigation delves into the potential utilization of Tire Reclaimed Rubber (TRR) as a filler within Natural Rubber/Styrene Butadiene Rubber (NR/SBR) blends. TRR is obtained from discarded rubber tires and stands as a pertinent resource that necessitates its effective utilization in the production of eco-friendly, value-added rubber-based products. This is due to the rising of rubber waste tires which causes environmental concerns and all sorts of pollution. The TRR filled NR/SBR blends were fabricated using two-roll mills. The loadings of TRR were varied ranging from 20 phr to 100 phr. The aim of this study is to investigate the influence of TRR loading on the curecharacteristics and mechanical properties of blends in terms of tensile strength, rebound resilience, hardness, and density. It is found that the MH and Δ torque exhibited a decreasing trend which would indicate a reduction in crosslink density due to high loading of TRR. Meanwhile, the ts2 and tc95 increased with the increase of TRR loading. Furthermore, the tensile strength, hardness, density, and rebound resilience of blends experience a steady reduction with the incorporation of TRR. The decrement of those properties might be due to the low molecular weight of TRR. Regarding the collective findings, TRR emerges as a potentially viable candidate for waste rubber repurposing, serving as a non-reinforcing filler with optimal utility achieved at a 30 phr loading level.

Trapping Ions to Enhance High-Field Energy Harvesting Performance by Filling Polar Macromolecular Dielectrics.

In the quest for sustainable and renewable energy sources, researchers and engineers have explored innovative technologies to harvest energy from various environmental sources. Dielectric elastomer generators (DEGs) with high energy harvesting performance have been proven to be promising energy collectors, but achieving a high dielectric constant (ε') and low electrical conductivity (EC) under high electric fields of dielectric elastomer (DE) simultaneously is a struggle, which poses significant challenges. In this study, high-content carboxyl group-grafted liquid polybutadiene (HCPB) is synthesized and then adopted as an organic dielectric filler to blend and cocross-link with a butadiene rubber (BR) matrix to prepare DE composites with high energy harvesting performance. The introduction of carboxyl groups enhances polarization while trapping free Al3+ in the matrix, which revolutionarily achieves a significant increase in ε' under extremely low EC. Ultimately, the contradiction between increased ε' and decreased EC under high electric fields is reconciled, resulting in a 30 HCPB/BR composite with high energy density (w = 91.9 mJ/cm3) and fine power conversion efficiency (PCE = 24.1%). This advancement paves the way for the development of HCPB/BR composite-based DEGs with enhanced ε' and energy harvesting performance.

N-[(1RS)-Camphan-2-ylidene]-4-ethoxyaniline and its reduction product as stabilizers of nitrile butadiene rubbers

Objectives. To investigate the protective efficacy of unreduced and reduced forms of the condensation product of D,L-camphor and p-ethoxyaniline in nitrile butadiene rubber formulations when compared with the conventional stabilizer N-isopropyl-N′-phenyl- p-phenylenediamine aged under laboratory and in situ climatic conditions in the tropics.Methods. The thermostabilizing effect of the condensation product of D,L-camphor and p-ethoxyaniline was evaluated by means of infrared spectroscopy using the dynamics of changes in the absorption bands of carbonyl and hydroxyl groups. The features of rubber vulcanization were studied by means of rotorless rheometry. Changes in the physical and mechanical properties of rubbers and degree of cross-linking were evaluated after thermo-oxidative aging in laboratory conditions. They also took into account the results of longterm exposure of samples in undeformed and deformed state in a tropical climate, taking into account meteorological data of the Can Gio climatic testing station.Results. It was found for the first time that condensation products of D,L-camphor and p-ethoxyaniline exhibit a stabilizing effect in formulations of rubbers based on polar nitrile butadiene rubber.Conclusions. According to the results of laboratory and in situ tests, the study established that the use of N-[(1RS,2RS)-camphan-2-yl]- 4-ethoxyaniline (reduced form) as an antifatigue agent is preferable. This is due to the presence of a mobile hydrogen atom at the nitrogen atom. The protective effect is manifested in terms of the better preservation of elastic-strength properties of rubbers with less change in hardness.

Ion Transport at Polymer-Argyrodite Interfaces.

Solid-state electrolytes, particularly polymer/ceramic composite electrolytes, are emerging as promising candidates for lithium-ion batteries due to their high ionic conductivity and mechanical flexibility. The interfaces that arise between the inorganic and organic materials in these composites play a crucial role in ion transport mechanisms. While lithium ions are proposed to diffuse across or parallel to the interface, few studies have directly examined the quantitative impact of these pathways on ion transport and little is known about how they affect the overall conductivity. Here, we present an atomistic study of lithium-ion (Li+) transport across well-defined polymer-argyrodite interfaces. We present a force field for polymer-argyrodite interfacial systems, and we carry out molecular dynamics and enhanced sampling simulations of several composite systems, including poly(ethylene oxide) (PEO)/Li6PS5Cl, hydrogenated nitrile butadiene rubber (HNBR)/Li6PS5Cl, and poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP)/Li6PS5Cl. For the materials considered here, Li-ion exhibits a preference for the ceramic material, as revealed by free energy differences for Li-ion between the inorganic and the organic polymer phase in excess of 13 kBT. The relative free energy profiles of Li-ion for different polymeric materials exhibit similar shapes, but their magnitude depends on the strength of interaction between the polymers and Li-ion: the greater the interaction between the polymer and Li-ions, the smaller the free energy difference between the inorganic and organic materials. The influence of the interface is felt over a range of approximately 1.5 nm, after which the behavior of Li-ion in the polymer is comparable to that in the bulk. Near the interface, Li-ion transport primarily occurs parallel to the interfacial plane, and ion mobility is considerably slower near the interface itself, consistent with the reduced segmental mobility of the polymer in the vicinity of the ceramic material. These findings provide insights into ionic complexation and transport mechanisms in composite systems, and will help improve design of improved solid electrolyte systems.

Enhancing lateritic soil for sustainable pavement subbase with polymer-modified cement: A comparative study of styrene butadiene rubber and styrene acrylic latex applications

This study evaluates styrene butadiene rubber (SBR) and styrene acrylic latex (SA) as modifiers in cement-treated subbase materials (CTSB) to enhance mechanical properties and reduce cement usage sustainably. Optimal ratios for stabilizing sub-standard lateritic soils were identified, reducing water demand and increasing mechanical strength in polymer-modified cement pastes. A 10 % SA and a 15 % SBR as cement replacement by mass significantly improved bearing strength and strain capacities in CTSB, signifying enhanced flexibility and elasticity. Despite slight changes in compaction characteristics, the study identified 1.6 % SA and 2.4 % SBR as optimal binder (i.e., polymer-cement mixture) contents, compared to 3.3 % cement for conventional CTSB with similar unconfined compressive strength standards. SBR-enriched CTSB exhibited superior resilient modulus, indicating stronger inter-particle bonding. The integration of SA and SBR reduced capillary rise and enhanced moisture stability. This sustainable approach enhances pavement durability and reduces CO2 emissions by minimizing cement use. The findings emphasize the potential of polymer-modified CTSB for cost-effective and environmentally friendly road construction, offering significant implications for advancing pavement engineering materials and promoting eco-friendly practices within the industry.

Photo‐Curable Stretchable High‐k Polymer/TiO2 Nanosheet Hybrid Dielectrics for Field‐Effect Transistors

Elastomeric polymer materials are of interest due to their stretchability, low‐temperature processing, and scalability. In addition, the incorporation of 2D materials can further enhance the dielectric properties and capacitance of elastic polymer materials, thereby reducing the driving voltage and energy consumption. In this study, titanium dioxide (TiO2) nanosheets are cross‐linked with nitrile butadiene rubber using thiol‐ene click chemistry, which leads to the preparation of nanocomposite dielectric films with stretchability and high dielectric constant. Furthermore, by controlling the doping amount of the nanosheets, it is observed that the capacitance of the nanocomposite films increases from 25.61 to 684.67 nF cm−2, and the dielectric constant increases from 14.96 to 161.98. Finally, the stretchable nanocomposite films exhibit good insulating properties even at 50% strain. In this study, insight is provided into the potential of in situ cross‐linking between elastic polymer materials and 2D materials to produce high‐k dielectric materials with both stretchability and high insulating properties.

Morphology and properties of carbon black‐filled thermoplastic vulcanizate (TPV) composites based on hydrogenated acrylonitrile butadiene rubber and thermoplastic polyester elastomer

AbstractThe unique morphology of thermoplastic vulcanizates (TPVs) reveals a significant correlation between the microstructure and performance, and the development of high‐performance TPV composites for specialized applications has become a current research priority. This study is devoted to developing heat‐ and oil‐resistant TPV composites filled with carbon black (CB) based on hydrogenated acrylonitrile butadiene rubber (HNBR) and thermoplastic polyester elastomer (TPEE) following the masterbatch procedure of dynamic vulcanization. Herein, it focuses on the effects of CB content on the morphology, filler network structure, and properties of the TPV/CB composites. As observed by morphological studies, CB nanoparticles are interconnected and aggregated to form a dual network structure of rubber and CB particles in the composite. With the increasing CB content, it's demonstrated that dual networks have enhanced and shifted to rigid. Consequently, the hardness, thermal stability, and oil resistance of TPV/CB composites are improved, with a 104% elevation in the stress at 300% strain. The flowability in the molten state, toughness (the elongation at break decreased from 690% to 310%), and elasticity deteriorated by oversized (0.5 ~ 1.2 μm) CB agglomerates and rigid rubber particles. This study gives new insight into the microstructure‐properties relationship of TPVs, offering theoretical guidance for fabricating HNBR‐based TPV composites.

Surface one-step modification of graphene oxide with N-cyclohexylbenzothiazole-2-sulfonamide to enhance the wear resistance of natural rubber/butadiene rubber composites

Natural rubber (NR) and butadiene rubber (BR) composites are frequently used in manufacturing tires and conveyor belts, which are susceptible to severe wear, leading to product failure and significant losses. To enhance the wear resistance of NR/BR composites, we prepared NR/BR composites reinforced with a synergy of N-cyclohexylbenzothiazole-2-sulfonamide surface one-step modified reduced graphene oxide (CZ-rGO) and carbon black N234 (CB) using a latex co-precipitation method. This study explored the effects of GO content and CZ modification on the structure, wear resistance, thermal conductivity, and mechanical properties of the NR/BR blended composites. It showed that adding 2 phr of GO resulted in excellent filler dispersion, significantly improving the tensile strength, elongation at break, tear strength, thermal conductivity, and wear resistance of the composites. The incorporation of CZ-rGO further increased the crosslinking density, vulcanization performance, and filler dispersion with enhanced mechanical properties, thermal conductivity, and wear resistance of the composites. Notably, the DIN abrasion volume was reduced to 77.88 mm³, surpassing the ISO 10247 standard for conveyor belt cover rubber in terms of wear resistance. The wear resistance of NR/BR/CZ-rGO composites is not only significantly higher than that of single NR- or SBR-based rubber composites, but also significantly higher than that of other binary rubber blend composites, and the CZ-rGO filler is simpler in composition and structure and exhibits a more prominent wear enhancement. This work provides guidance for an efficient and environmentally friendly approach to GO surface modification, as well as useful insights for the development of high wear-resistant rubber composites with excellent overall performance.

Toxicological mechanisms and molecular impacts of tire particles and antibiotics on zebrafish

Tire microplastics (TMPs) and antibiotics are emerging pollutants that widely exist in water environments. The coexistence of these pollutants poses severe threats to aquatic organisms. However, the toxicity characteristics and key molecular factors of the combined exposure to TMPs in aquatic organisms remain unknown. Therefore, the joint toxicity of styrene–butadiene rubber TMPs (SBR-TMPs) and 32 antibiotics (macrolides, fluoroquinolones, β-lactams, sulfonamides, tetracyclines, nitroimidazoles, highly toxic antibiotics, high-content antibiotics, and common antibiotics) in zebrafish was investigated using a full factorial design, molecular docking, and molecular dynamics simulation. Sixty-four combinations of antibiotics were designed to investigate the hepatotoxicity of the coexistence of SBR-TMPs additives and antibiotics in zebrafish. Results indicated that low-order effects of antibiotics (e.g., enoxacin–lomefloxacin and ofloxacin–enoxacin–lomefloxacin) had relatively notable toxicity. The van der Waals interaction between additives and zebrafish cytochrome P450 enzymes primarily affected zebrafish hepatotoxicity. Zebrafish hepatotoxicity was also affected by the ability of SBR-TMPs to adsorb antibiotics, the relation between antibiotics, the affinity of antibiotics docking to zebrafish cytochrome P450 enzymes, electronegativity, atomic mass, and the hydrophobicity of the antibiotic molecules. This study aimed to eliminate the joint toxicity of TMPs and antibiotics and provide more environmentally friendly instructions for using different chemicals.

The Influence of Oil and Thermal Aging on the Sealing Characteristics of NBR Seals.

Nitrile Butadiene Rubber (NBR) is widely used as a sealing material due to its excellent mechanical properties and good oil resistance. However, when using NBR material, the seal structure is unable to avoid the negative effects of rubber aging. Hence, the influence of oil and thermal aging on the characteristics of NBR seals was studied by coupling the mechanical behavioral changes with the tribological behavioral changes of NBR in oil and the thermal environment. For this paper, aging testing and compression testing of NBR were carried out. Additionally, friction testing between friction pairs under different aging times was carried out. The surface morphology of the NBR working surface under different aging conditions was also observed. Finally, coefficients of different test conditions were introduced into the finite element model of NBR seals. It can be seen from the results that the elastic modulus increased with the increase in aging time in the thermal oxidative aging testing. The elastic modulus after 7 days of thermal oxidative aging increased by 135.45% compared to the unaged case, and the elastic modulus after 7 days of oil aging increased by 15.03% compared to the unaged case. The compression set rate of NBR increased significantly with the increase in aging time and temperature. The coefficient of friction (COF) between friction pairs increased first and then decreased with the increase in aging time. The maximum contact pressure decreased by 2.43% between the shaft and sealing ring and decreased by 4.01% between the O-ring and groove. The proportion of the effective sealing area decreased by 3.05% between the shaft and sealing ring and decreased by 6.11% between the O-ring and groove. Furthermore, the sealing characteristics between the O-ring and groove were better than those between the shaft and sealing ring.

Solid-state NMR of vulcanized natural rubber / butadiene rubber blends: Local organization and cross-linking heterogeneities

Elastomer blends, among which natural rubber (NR) and butadiene rubber (BR), are involved in many components of the automotive/tire industry. A comprehensive understanding of their mechanical behavior requires, among other features, a detailed description of the cross-link density in these mixtures. In the case of vulcanized immiscible blends, the distribution of the cross-link density within each of the NR- and BR-rich domains is key information, but difficult to determine using the conventional approaches used for one-component cross-linked elastomers. In this study, the vulcanization within NR/BR blends is investigated using a robust 1H double-quantum (DQ) MAS recoupling experiment, BaBa-xy16. Two kinds of cross-linked NR/BR blends were considered with two different microstructures for the BR component. The bulk organization of the resulting blends was first probed by analyzing the 1H spin-lattice relaxation behavior. In a second step, BaBa-xy16 was used to investigate, in a selective way, the cross-link heterogeneities within NR/BR blends. In particular, for immiscible NR/BR mixtures, the distribution of the cross-link density between both phases was compared and the observed differences were discussed.

Recent development of metal-organic frameworks as a novel flame-retardant in polymeric applications

Abstract The increasing concern regarding hazardous fires related to polymeric materials has prompted numerous research into eco-friendly flame retardants. in recent years metal-organic Frameworks (MOFs) have emerged as promising flame-retardant materials, characterized by metal-containing units linked to organic linkers to create strong and porous crystalline frameworks. The organic ligands make MOFs possess significant surface area and adsorption properties desirable for different applications including flame retardancy. This paper gathers many of the recently published to discuss the use performance of polymer composites with MOFs for flame retardancy in comparison with polymeric composite materials without MOFs. Besides, a comparison based on mechanical, physical, and thermal properties shows the effect of MOF on the total effectiveness of the polymeric composite materials. This paper is of great interest to both the readers involved in the sphere of heat-resistance materials, encompassing contemporary advanced composite materials used for dampening hazardous fires. Furthermore, prospective trends, including the integration of innovative fillers such as MOFs in rubber composites such as NBR (Nitrile Butadiene Rubber), EPDM (Ethylene Propylene Diene Monomer), and silicone rubber, are deliberated upon.