Decarbonization involves the intensive use of renewable energy to obtain a sustainable energy matrix. Brazil has an electrical matrix strongly anchored in renewable sources, historically in hydraulic energy, and more recently, in solar, photovoltaic, and wind sources. The latter are stochastic and, therefore, have strong restrictions on their insertion into the matrix in a broad and dominant manner. Due to these limitations, excess supply can be used to produce green hydrogen and even methane in a process called methanation (chemical reaction between CO2 and H2). The use of electrical energy from renewable sources for the production of fuels is known in literature as power-to-gas. These fuel vectors (H2 and CH4) can be used directly to generate energy or can be mixed with natural gas to enrich it in terms of energy and potentially reduce emissions. This study evaluates the effect of enriching mixtures of natural gas and hydrogen on CO, CO2, and NOx emissions, considering combustion applications in Gas Turbines. The analyses were numerical and involved the use of a thermodynamic combustion model with chemical equilibrium. The chemical equilibrium model is based on chemical equilibrium constants and assumes that the reactants and products are ideal gases. The volumetric fractions of H2 in the mixture from 0 to 30% and the effect of the combustion pressure were investigated. The pressure was varied according to the application chosen. Gas turbines are part of the combined power cycles, and plants can operate with gas turbines of different pressure ratios according to the model, power, and manufacturer of the Gas Turbine. The analyses focused on medium and large gas turbines, and the chosen pressure range was 12:1 to 24:1.
Read full abstract