Bulk Interactions Research Articles

Inhomogeneous matrix product ansatz and exact steady states of boundary-driven spin chains at large dissipation.

We find novel site-dependent Lax operators in terms of which we demonstrate exact solvability of a dissipatively driven XYZ spin-1/2 chain in the Zeno limit of strong dissipation, with jump operators polarizing the boundary spins in arbitrary directions. We write the corresponding nonequilibrium steady state using an inhomogeneous matrix product ansatz, where the constituent matrices satisfy a simple set of linear recurrence relations. Although these matrices can be embedded into an infinite-dimensional auxiliary space, we have verified that they cannot be simultaneously put into a tridiagonal form, not even in the case of axially symmetric (XXZ) bulk interactions and general nonlongitudinal boundary dissipation. We expect our results to have further fundamental applications for the construction of nonlocal integrals of motion for the open XYZ model with arbitrary boundary fields, or the eight-vertex model.

Bulk and interfacial interactions between hydroxypropyl-cellulose and bile salts: Impact on the digestion of emulsified lipids

Hydroxypropyl-cellulose (HPC) is a surface-active, non-digestible polysaccharide, commonly used in food emulsions as thickener and/or emulsifier. Due to these dual characteristics, HPC is a potential ingredient to modulate lipid digestion. Since bile salts (BS) are key players during lipid digestion, the aim of this work was to investigate the impact that interactions of HPC with BS has on the digestion of emulsified lipids. We studied the effect of two BS species differing in bile-acid moiety, sodium-taurocholate (NaTC) and sodium-taurodeoxycholate (NaTDC). A Quartz-Crystal-Microbalance (QCM-D) was used to evaluate HPC-BS interfacial interactions during the sequential and simultaneous adsorption of both components at a hydrophobic surface, while micro-Differential-Scanning-Calorimetry was used to examine bulk interactions. In vitro lipid digestion was studied by using a pH-stat method. Results showed that, under fed-state conditions, NaTDC micelles were more effective at displacing a pre-adsorbed HPC layer from the surface than NaTC monomers. Nevertheless, HPC was resistant to complete displacement by both BS. Additionally, HPC was more susceptible to interact with NaTDC in the bulk, compared to NaTC, which made the adsorption more competitive for NaTDC. The reduced amount of free NaTDC in solution could explain the delayed lipolysis shown by HPC-stabilized emulsions when NaTDC was used to simulate duodenal conditions. These findings show that the delay of lipid digestion by HPC is due to the combined effect of HPC-BS interfacial and bulk interactions, with BS-binding in solution mostly contributing to this effect, and the BS molecular and micellar structure playing essential roles on both situations.

Dynamics of black holes in Jackiw-Teitelboim gravity

We present a general solution for correlators of external boundary operators in black hole states of Jackiw-Teitelboim gravity. We use the Hilbert space constructed using the particle-with-spin interpretation of the Jackiw-Teitelboim action, which consists of wavefunctions defined on Lorentzian AdS2. The density of states of the gravitational system appears in the amplitude for a boundary particle to emit and reabsorb matter. Up to self-interactions of matter, a general correlator can be reduced in an energy basis to a product of amplitudes for interactions and Wilson polynomials mapping between boundary and bulk interactions.

Discrete-to-Continuum Limits of Multibody Systems with Bulk and Surface Long-Range Interactions

We study the atomistic-to-continuum limit of a class of energy functionals for crystalline materials via Gamma-convergence. We consider energy densities that may depend on interactions between all ...

A1-meson-baryon coupling constants in the framework of soft-wall and hard-wall AdS/QCD models

We calculate the [Formula: see text]-meson-nucleon ([Formula: see text]-baryon) coupling constant in the framework of soft-wall and hard-wall AdS/QCD models. Interaction Lagrangian in the bulk of AdS space was written for a minimal gauge coupling, a magnetic type coupling and a triple coupling of bulk fields. Applying AdS/CFT correspondence from the bulk interaction Lagrangian, we obtain holographic expressions for the [Formula: see text]-axial-vector meson-nucleon ([Formula: see text]-baryon) coupling constant in the boundary QCD theory. Numerical results for the [Formula: see text] coupling constant in the framework of both models are close to the known phenomenological estimates. The [Formula: see text]-axial-vector meson-[Formula: see text]-baryon coupling constant was considered in the framework of hard-wall model.

Interactions of bile salts with a dietary fibre, methylcellulose, and impact on lipolysis

Methylcellulose (MC) has a demonstrated capacity to reduce fat absorption, hypothetically through bile salt (BS) activity inhibition. We investigated MC cholesterol-lowering mechanism, and compared the influence of two BS, sodium taurocholate (NaTC) and sodium taurodeoxycholate (NaTDC), which differ slightly by their architecture and exhibit contrasting functions during lipolysis.BS/MC bulk interactions were investigated by rheology, and BS behaviour at the MC/water interface studied with surface pressure and ellipsometry measurements. In vitro lipolysis studies were performed to evaluate the effect of BS on MC-stabilised emulsion droplets microstructure, with confocal microscopy, and free fatty acids release, with the pH-stat method.Our results demonstrate that BS structure dictates their interactions with MC, which, in turn, impact lipolysis. Compared to NaTC, NaTDC alters MC viscoelasticity more significantly, which may correlate with its weaker ability to promote lipolysis, and desorbs from the interface at lower concentrations, which may explain its higher propensity to destabilise emulsions.

Opacity and effective field theory in anti–de Sitter backgrounds

We consider quantum field theory in a five-dimensional anti-de Sitter background, possibly truncated by four-dimensional (4D) branes. In the Euclidian version of this space, it is known that propagators exponentially decay when they go far enough toward the Poincar\'e horizon, i.e. deep enough into the IR region of the AdS bulk. In this note, we show that an analogous property exists in Lorentzian AdS. The exponential suppression is found to occur in the presence of bulk interactions dressing the AdS propagators. We calculate one-loop gravitational dressing and find that the suppression effect comes from the scalar component of the 5D graviton. We then argue that, at least at strong coupling, this exponential decay censors the region of spacetime where the 5D effective field theory would become invalid. As an application we estimate the rate for the cascade decay of bulk fields---which are known to produce soft spherical events with high multiplicity---and find this rate to be exponentially suppressed.

Current-Driven Dynamics of Magnetic Hopfions.

Topological magnetic textures have attracted considerable interest since they exhibit new properties and might be useful in information technology. Magnetic hopfions are three-dimensional (3D) spatial variations in the magnetization with a nontrivial Hopf index. We find that, in ferromagnetic materials, two types of hopfions, Bloch-type and Néel-type hopfions, can be excited as metastable states in the presence of bulk and interfacial Dzyaloshinskii-Moriya interactions, respectively. We further investigate how hopfions can be driven by currents via spin-transfer torques (STTs) and spin-Hall torques (SHTs). Distinct from 2D ferromagnetic skyrmions, hopfions have a vanishing gyrovector. Consequently, there are no undesirable Hall effects. Néel-type hopfions move along the current direction via both STT and SHT, while Bloch-type hopfions move either transverse to the current direction via SHT or parallel to the current direction via STT. Our findings open the door to utilizing hopfions as information carriers.

Toward an Atomistic Understanding of Deep Eutectics Solvents Electrochemical Interfacial Structure

Green, stable, and wide electrochemical window deep eutectics solvents (DESs) are ideal candidates for electrochemical systems, such as batteries, supercapacitors, catalysis, electrodeposition, and many more. However, since these mixtures are highly dense and composed of only large asymmetric ionic and molecular components, short-range ion-ion, ion-molecule interactions play a dominant role both in the bulk as well as at the interface properties. This results in breakdown of the standard mean-field approximation, which is the basis of dilute solution theory. In addition, due to the hygroscopic nature of DESs, the presence of latent water is unavoidable. Therefore, understanding the DESs-electrode interface (electrical double layer structure, EDLS) together with the role of water at a molecular scale is of great importance for the widespread use of these solvents in electrochemical systems [1-3]. In this presentation, we will first review the benchmark study on conventional dilute solution electrical double layer structure and secondly present our recent findings and theoretical developments on the electrochemical interfacial structure of deep eutectic solvents using a combined experimental and a novel atomistic molecular dynamics approach. In the presentation, we focused on the computational approach. The use of such an atomistic-molecular approach allows investigation of all the possible bulk and interfacial interactions and, consequently, helps to shed light on the nanoscale electrochemical interfacial structure of DESs. Unlike the interfacial structures observed and proposed for other electrolyte-electrode interfaces (compact- diffuse double layer for dilute solution [4]; overscreening or crowding for concentrated solutions [5]), the simulations of DESs-electrode interfacial structure show an unexpected and previously unrecognized phenomenon: the electrochemical interface is composed of a mixed layer structure followed by a mixed charged clustered layer regardless of the surface polarization [1,2]. Some of the findings will be discussed in this presentation.

Adsorption of interacting self-avoiding trails in two dimensions.

We investigate the surface adsorption transition of interacting self-avoiding square lattice trails onto a straight boundary line. The character of this adsorption transition depends on the strength of the bulk interaction, which induces a collapse transition of the trails from a swollen to a collapsed phase, separated by a critical state. If the trail is in the critical state, the universality class of the adsorption transition changes; this is known as the special adsorption point. Using flatPERM, a stochastic growth Monte Carlo algorithm, we simulate the adsorption of self-avoiding interacting trails on the square lattice using three different boundary scenarios which differ with respect to the orientation of the boundary and the type of surface interaction. We confirm the expected phase diagram, showing swollen, collapsed, and adsorbed phases in all three scenarios, and confirm universality of the normal adsorption transition at low values of the bulk interaction strength. Intriguingly, we cannot confirm universality of the special adsorption transition. We find different values for the exponents; the most likely explanation is that this is due to the presence of strong corrections to scaling at this point.

Effect of 1-octanol on the stabilization of crude oil emulsions with hydrophobically modified polyacrylamide

The formation of a stable crude oil emulsion is of great significance for enhancing oil recovery in oilfield development. The effect of 1-octanol (C8OH) on the emulsifying properties of hydrophobically modified polyacrylamide (HMP) was studied based on a novel multiple light scattering method. The emulsions stabilized by different polymer systems were evaluated in terms of stability and rheological properties. The obtained results show that the combined system of HMP + C8OH gives more stable emulsion with smaller droplet size compared to individual HMP. There is a strong bulk and interface interaction between HMP and C8OH for stabilizing emulsions, while such effect was observed neither between partially hydrolyzed polyacrylamide and 1-octanol nor between HMP and 1-octane. In the bulk phase of aqueous solution, the C8OH can be solubilized in the micro-domains of HMP, enhancing the intermolecular association structure and slowing down the creaming rate of the corresponding emulsions. The adsorption at the oil-water interface of HMP can be enhanced and tighter interfacial film can be formed due to the formation of the hydrogen bond between HMP and C8OH. The obtained results are of obvious importance for designing the amphiphilic polymer-containing emulsion more suitable to improve oil recovery as well as for better understanding the self-assembling mechanism of amphiphilic polymers and fatty alcohols.

Route to form skyrmions in soft magnetic films

Magnetic skyrmions which are topologically nontrivial magnetization configurations have attracted much attention recently due to their potential applications in information recording and signal processing. Conventionally, magnetic skyrmions are stabilized by chiral bulk or interfacial Dzyaloshinskii-Moriya interaction (DMI) in noncentrosymmetric B20 bulk crystals (at low temperatures) or ultrathin magnetic films with out-of-plane magnetic anisotropy (at room temperature), respectively. The skyrmion stability in the ultrathin films relies on a delicate balance of their material parameters that are hard to control experimentally. Here, we propose an alternate approach to stabilize a skyrmion in ferromagnetic media by modifying its surroundings in order to create strong dipolar fields of the radial symmetry. We demonstrate that artificial magnetic skyrmions can be stabilized even in a simple media such as a continuous soft ferromagnetic film, provided that it is coupled to a hard magnetic antidot matrix by exchange and dipolar interactions, without any DMI. Néel skyrmions, either isolated or arranged in a 2D array with a high packing density, can be stabilized using antidot as small as 40 nm in diameter for soft magnetic films made of Permalloy. When the antidot diameter is increased, the skyrmion configuration transforms into a curled one, becoming an intermediate between the Néel and Bloch skyrmions. In addition to skyrmions, the considered nanostructure supports the formation of nontopological magnetic solitons that may be regarded as skyrmions with a reversed core.

Phase transitions in solvent-dependent polymer adsorption in three dimensions.

We consider the phase diagram of self-avoiding walks (SAWs) on the simple cubic lattice subject to surface and bulk interactions, modeling an adsorbing surface and variable solvent quality for a polymer in dilute solution, respectively. We simulate SAWs at specific interaction strengths to focus on locating certain transitions and their critical behavior. By collating these new results with previous results we sketch the complete phase diagram and show how the adsorption transition is affected by changing the bulk interaction strength. This expands on recent work considering how adsorption is affected by solvent quality. We demonstrate that changes in the adsorption crossover exponent coincide with phase boundaries.

Five year iron changes in relapsing-remitting multiple sclerosis deep gray matter compared to healthy controls

BackgroundRelapsing-Remitting MS (RRMS) Deep Grey Matter (DGM) 5 year changes were examined using MRI measures of volume, transverse relaxation rate (R2*) and quantitative magnetic susceptibility (QS). By applying Discriminative Analysis of Regional Evolution (DARE), R2* and QS changes from iron and non-iron sources were separated. Methods25 RRMS and 25 age-matched control subjects were studied at baseline and 5-year follow-up. Bulk DGM mean R2* and QS of the caudate nucleus, putamen, thalamus and globus pallidus were analyzed using mixed factorial analysis (α = 0.05) with sex as a covariate, while DARE employed non-parametric analysis to study regional changes. Regression/correlation analysis was performed with disease duration and MS Severity Score (MSSS). ResultsNo significant change in Extended Disability Status Score was found over 5 years (baseline = 2.4 ± 1.2; follow-up = 2.8 ± 1.3). Significant time effects were found for R2* in the caudate (Q = 0.000008; η2 = 0.36), putamen (Q = 0.0000007; η2 = 0.43), and globus pallidus (Q = 0.0000007; η2 = 0.43), while significant longitudinal effects were only found for QS in the putamen (Q = 0.002; η2 = 0.22). Significant bulk interaction was only found for thalamus volume (Q = 0.02; η2 = 0.20). Iron decrease was the only detected significant effect using DARE, and the highest significant DARE effect size was mean thalamus R2* iron decrease (Q = 0.002; η2 = 0.26). No significant correlations or regressions were demonstrated with clinical measures. ConclusionsThalamic atrophy was the only bulk effect that demonstrated different rates of changes over 5 years compared to age-matched controls. DARE Iron decrease in regions of the caudate, putamen, and thalamus were prominent features in stable RRMS over 5 years.

Edge-induced topological phase transition of the quantum Hall state at half filling

We show that in quantum Hall systems at half-filling, edge potentials alone can drive transitions between the Pfaffian and anti-Pfaffian topological phases. We conjecture this is true in realistic systems even in the presence of weak bulk interactions that break the particle-hole symmetry. The strong effects of edge potentials could be understood from different topological shifts of competing phases, manifested on the disk geometry as the variation of orbital numbers at fixed number of particles. In particular, we show analytically particle-hole conjugation of Hamiltonians on the disk is equivalent to the tuning of edge potentials, which allows us to explicitly demonstrate the phase transition numerically. The importance of edge potentials in various experimental contexts, including the recently discovered particle-hole symmetric phase is also discussed.

Hydrodynamic and ballistic AC transport in two-dimensional Fermi liquids

Electron transport in clean 2D systems with weak electron-phonon (e-ph) coupling can transition from an Ohmic to a ballistic or a hydrodynamic regime. The ballistic regime occurs when electron-electron (e-e) scattering is weak whereas the hydrodynamic regime arises when this scattering is strong. Despite this difference, we find that vortices and a negative nonlocal resistance believed to be quintessentially hydrodynamic are equally characteristic of the ballistic regime. These non-Ohmic regimes cannot be distinguished in DC transport without changing experimental conditions. Further, as our kinetic calculations show, the hydrodynamic regime in DC transport is highly fragile and is wiped out by even sparse disorder and e-ph scattering. We show that microwave-frequency AC sources by contrast readily excite hydrodynamic modes with current vortices that are robust to disorder and e-ph scattering. Indeed, current reversals in the non-Ohmic regimes occur via repeated vortex generation and mergers through reconnections, as in classical 2D fluids. Crucially, AC sources give rise to strong correlations across the entire device that unambiguously distinguish all regimes. These correlations in the form of nonlocal current-voltage and voltage-voltage phases directly check for the presence of a nonlocal current-voltage relation signifying the onset of non-Ohmic behavior as well as also for the dominance of bulk interactions, needed to confirm the presence of a hydrodynamic regime. We use these probes to demarcate all regimes in an experimentally realizable graphene device and find that the ballistic regime has a much larger extent in parameter space than the hydrodynamic regime.

Influence of hydrophilic silica nanoparticles on the adsorption layer properties of non-ionic surfactants at water/heptane interface

There is a notable paucity of studies investigating the impact of charged nanoparticles on the interfacial behavior of nonionic surfactants, assuming that the interactions are negligible in the absence of electrostatic forces. Here, we argue about our observations and the existence of a complex interfacial behavior in such systems depending on the type and chemical structure of surfactant. This study set out to investigate the effects of interactions between hydrophilic silica nanoparticles (NP) and non-ionic surfactants on water/heptane dynamic interfacial properties using drop profile analysis tensiometry (PAT). Three surfactants were studied, namely Triton X-100 (significantly soluble in water phase), C12DMPO (well soluble in both phases) and SPAN 80 (oil-soluble). The different chemical structures and partition coefficients of the surfactants enabled us to cover possible interactions and differentiate between bulk and interfacial interactions. We observed that hydrophilic silica NPs had a negligible effect on the interfacial behavior of Triton X-100, that they increased the surface activity of C12DMPO when both compounds are initially in the aqueous phase. Most interestingly is that the added NPs generated unstable interfacial NP-surfactant complexes and reduced the pseudo-equilibrium interfacial tension of oil-soluble surfactant, Span 80, even though NPs and surfactants were in different bulk phases.

Assembling responsive microgels at responsive lipid membranes

Directed colloidal self-assembly at fluid interfaces can have a large impact in the fields of nanotechnology, materials, and biomedical sciences. The ability to control interfacial self-assembly relies on the fine interplay between bulk and surface interactions. Here, we investigate the interfacial assembly of thermoresponsive microgels and lipogels at the surface of giant unilamellar vesicles (GUVs) consisting of phospholipids bilayers with different compositions. By altering the properties of the lipid membrane and the microgel particles, it is possible to control the adsorption/desorption processes as well as the organization and dynamics of the colloids at the vesicle surface. No translocation of the microgels and lipogels through the membrane was observed for any of the membrane compositions and temperatures investigated. The lipid membranes with fluid chains provide highly dynamic interfaces that can host and mediate long-range ordering into 2D hexagonal crystals. This is in clear contrast to the conditions when the membranes are composed of lipids with solid chains, where there is no crystalline arrangement, and most of the particles desorb from the membrane. Likewise, we show that in segregated membranes, the soft microgel colloids form closely packed 2D crystals on the fluid bilayer domains, while hardly any particles adhere to the more solid bilayer domains. These findings thus present an approach for selective and controlled colloidal assembly at lipid membranes, opening routes toward the development of tunable soft materials.

Effect of Heating on the Structure and Properties of a Solid-Phase Diffusion Bond Based on a Forced Fit in OT4-1 Alloy

The production of a solid-phase diffusion bond in OT4-1 alloy on the basis of a cold forced fit of components in a shaft–hole configuration is considered. The influence of the maximum stress–strain state in the cold forced fit and subsequent heat treatment (in autonomous vacuum) on the structural evolution and properties of the contact region is investigated. In cold plastic deformation of the alloy with the formation of a solid-phase diffusion bond, deformational relief (traces of grain-boundary slip) is observed in the microstructure of the contact region. In addition, decrease is noted in the area of the contact surfaces, and fewer bulk interactions are noted in the contact plane (grain distortion) and in the contact volume (regions of dislocation departure). The basic characteristics of the structural interface—the unit parameter of structural organization, the grain density, the mean grain-boundary density, and the development of the grain boundaries—exceed by factors of 10, 4, 1.8, and 1.5, respectively, those of the basic metal in the initial state. Heating in autonomous vacuum in the range of α → β phase transitions leads to stepwise structural changes in the basic metal and in the contact region of the solid-phase diffusion bond. Initially, a globular component appears in the microstructure. With further heating, this component reverts to the initial acicular structure (with some increase in microhardness). The formation of globular structure on heating plastically deformed metal is observed not only at temperatures corresponding to phase transition but also at higher temperatures; this has not previously been noted. With increase in temperature, the duration of this stage decreases. In addition, with less developed plastic deformation, the formation of globular structure is observed close to the polymorphic-transformation temperature Tpt, with shorter holding. For the basic metal (with little deformation), the globular structure disappears practically completely after heating for 10 min at 950°C. In the cold-deformed contact region of the solid-phase diffusion bond, the globular structure disappears on heating for 1 h at 950°C, for 40 min at 975°C, and for 20 min at 1000°C. At those temperatures the sealing of discontinuities is practically complete. In other words, the weld line disappears: the metal with continuous microstructure in the contact region does not differ from the basic metal, except for a slight enlargement of the microstructure. Quantitative assessment of the structural changes in terms of the basic characteristics of the structural interface permits determination of their mechanism and kinetics and also the dependence of the structure on the plastic strain and the heat treatment. On that basis, it is possible to identify conditions such that the discontinuities are eliminated, the boundaries disappear, and the properties of the solid-phase diffusion bond are no worse than those of the basic metal.

Holographic quantization of linearized higher-spin gravity in the de Sitter causal patch

We study the dS/CFT duality between minimal type-A higher-spin gravity and the free Sp(2N) vector model. We consider the bulk spacetime as “elliptic” de Sitter space dS4/ℤ2, in which antipodal points have been identified. We apply a technique from arXiv:1509.05890, which extracts the quantum-mechanical commutators (or Poisson brackets) of the linearized bulk theory in an observable patch of dS4/ℤ2 directly from the boundary 2-point function. Thus, we construct the Lorentzian commutators of the linearized bulk theory from the Euclidean CFT. In the present paper, we execute this technique for the entire higher-spin multiplet, using a higher-spin-covariant language, which provides a promising framework for the future inclusion of bulk interactions. Aside from its importance for dS/CFT, our construction of a Hamiltonian structure for a bulk causal region should be of interest within higher-spin theory itself. The price we pay is a partial symmetry breaking, from the full dS group (and its higher-spin extension) to the symmetry group of an observable patch. While the boundary field theory plays a role in our arguments, the results can be fully expressed within a boundary particle mechanics. Bulk fields arise from this boundary mechanics via a version of second quantization.